• 제목/요약/키워드: temperature stable characteristics

검색결과 964건 처리시간 0.031초

Effect of Al on Structural and Magnetic Characteristics of CoCrFeNiMnAlx High Entropy Alloys

  • Majid Tavoosi;Ali Ghasemi;Gholam Reza Gordani;Mohammad Reza Loghman Estarki
    • 한국재료학회지
    • /
    • 제33권3호
    • /
    • pp.95-100
    • /
    • 2023
  • This research examines the effect of adding aluminum on the structural, phasic, and magnetic properties of CoCrFe NiMnAlx high-entropy alloys. To this aim, the arc-melt process was used under an argon atmosphere for preparing cast samples. The phasic, structural, and magnetic properties of the samples were characterized by x-ray diffraction (XRD), scanning electron microscopy (SEM), and vibrational magnetometry (VSM) analyses. Based on the results, the addition of aluminum to the compound caused changes in the crystalline structure, from FCC solid solution in the CoCrFeNiMn sample to CoCrFeNiMnAl BBC solid solution. It was associated with changes in the magnetic property of CoCrFeNiMnAlx high-entropy alloys, from paramagnetic to ferromagnetic. The maximum saturation magnetization for the CoCrFeNiMnAl casting sample was estimated to be around 79 emu/g. Despite the phase stability of the FCC solid solution with temperature, the solid solution phase formed in the CrCrFeNiMnAl high-entropy compound was not stable, and changed into FCC solid solution with temperature elevation, causing a reduction in saturation magnetization to about 7 emu/g.

소성온도에 따른 ZnO계 적층형 칩 바리스터의 미세구조와 전기적 특성의 변화 (Effect of Firing Temperature on Microstructure and the Electrical Properties of a ZnO-based Multilayered Chip Type Varistor(MLV))

  • 김철홍;김진호
    • 한국세라믹학회지
    • /
    • 제39권3호
    • /
    • pp.286-293
    • /
    • 2002
  • 소성온도에 따른 ZnO계 적층형 세라믹 칩 바리스터(약칭 MLV)의 미세구조와 전기적 특성의 변화를 조사하였다. 소성온도 1100$^{\circ}$C에서 Ag/Pd(7:3) 내부전극층의 두께가 불균일하게 변화하면서 부분적인 공극이 발생하기 시작하고, 1150$^{\circ}$C에서는 상당한 전극 패턴의 소멸과 박리가 관찰되었다. 950$^{\circ}$C로 소성한 MLV의 경우 누설전류의 열화가 특히 컸는데 이는 미반응의 pyrochlore상이 잔류하여 액상과 천이원소의 균일한 분포가 일어나지 않았기 때문이라 사료된다. 1100$^{\circ}$C 이상의 온도로 소성한 경우에는 바리스터 특성 및 그 재현성의 저하가 관찰되었는데, 이는 내부전극의 소멸, 전극물질과 소체의 반응, 그리고 $Bi_2O_3$의 휘발에 기인한 것으로 보인다. 한편, 950∼1100$^{\circ}$C의 전 소성온도 범위에 걸쳐 온도가 증가할수록 정전용량과 누설전류는 증가하고 항복전압과 피크전류는 감소하였으나, 비선형계수와 클램핑 비는 각각 ∼30 및 1.4로 거의 일정한 값을 유지하였다. 특히 1000∼1050$^{\circ}$C 소성체의 경우 칩 바리스터에 적합한 바리스터 특성이 재현성 있게 나타났다. 결과적으로 Ag/Pd(7:3) 합금은 1050$^{\circ}$C의 동시 소성 온도이하에서는 $Bi_2O_3$를 함유한 대부분의 ZnO계 MLV의 내부전극으로 충분히 사용가능한 것으로 판단된다.

하이드레이트 펠릿의 비평형 분해과정 수치해석 (NUMERICAL ANALYSIS OF NON-EQUILIBRIUM HYDRATE PELLET DECOMPOSITION)

  • 강정호;남진현;김찬중;송명호
    • 한국전산유체공학회지
    • /
    • 제13권4호
    • /
    • pp.50-57
    • /
    • 2008
  • The prediction of hydrate pellet decomposition characteristics is required to design the regasification process of GTS (gas to solid) technology, which is considered as an economic alternative for LNG technology to transport natural gas produced from small and stranded gas wells. Mathematical model based on the conservation principles, the phase equilibrium relation, equation of gas state and phase change kinetics was set up and numerical solution procedure employing volume averaged fixed grid formulation and extended enthalpy method are implemented. Initially, porous methane hydrate pellet is at uniform temperature and pressure within hydrate stable region. The pressure starts to decrease with a fixed rate down to the final pressure and is kept constant afterwards while the bounding surface of pellet is heated by convection. The predicted convective heat and mass transfer accompanied by the decomposed gas flow through hydrate/ice solid matrix is reported focused on the comparison of spherical and cylindrical pellets having the same effective radius.

이산화탄소 재순환이 순산소 난류제트 확산화염에 미치는 영향 (Effects of $CO_{2}$ Recirculation on Turbulent Jet Diffusion Flames with Pure Oxygen)

  • 차민석;김호근;김한석;안국영
    • 한국연소학회:학술대회논문집
    • /
    • 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
    • /
    • pp.255-260
    • /
    • 2003
  • Characteristics of methane jet diffusion flames using pure oxygen with recirculating $CO_{2}$ as an oxidizer were investigated experimentally. A coflow burner was considered, and the diameter of confinement was larger than that of the coflow. No stabilized flame could be observed over 75% of $CO_{2}$ volume percent. A comparison between air and $O_{2}/CO_{2}$ mixture was made in terms of liftoff velocity, flame liftoff height, and blowout conditions. As results, more stable flame could be observed with $O_{2}/CO_{2}$ mixture for the case of having similar flame temperature.

  • PDF

초소형 열광전변환 장치용 열재순환 초소형 이미터 내 연소특성에 관한 연구 (Combustion Characteristics in a Heat-recirculating Microemitter for a Micro Thermophotovoltaic System)

  • 이경호;권오채
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2007년도 춘계학술대회B
    • /
    • pp.2360-2365
    • /
    • 2007
  • A new microemitter (microcombustor) configuration for a micro thermophotovoltaic system in which thermal energy is directly converted into electrical energy through thermal radiation was investigated experimentally and computationally. The microemitter as a thermal heat source was designed for a few watt power-generating micro thermophotovoltaic system. In order to satisfy the primary requirements for designing the microemitter, i.e., stable burning in the small confinement and maximum heat transfer through the emitting walls but uniform distribution of temperature along the walls, the present microemitter is cylindrical with an annular-type shield for heat recirculation to apply for the excessive enthalpy concept. Results show that the heat recirculation substantially improves the performance of the microemitter: the observed and predicted thermal radiation from the microemitter walls indicated that heat generated in the microemitter is uniformly emitted.

  • PDF

전기 절연유의 열화 패턴에 따른 정전용량형 센서의 열화감지특성 평가 (Evaluation of Diagnosis Properties of Capacitive Sensor about Deteriorated Pattern of Electrical Insulating Oil)

  • 김주한;김재훈;이원영;김필환;한상옥;김한준
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2004년도 하계학술대회 논문집 C
    • /
    • pp.1829-1831
    • /
    • 2004
  • This paper described the capacitive sensor for the diagnosis of deterioration of electrical insulating oils applying guard-ring type the 3-terminal electrodes. To measure stable capacitance of the sensor and to determine the design factors of the sensor, we utilized computational analysis, FEM software. This capacitive sensor discern the extent of deterioration measuring relative permittivity of electrical insulating oils. The result of measuring numerous sample, mineral oils, as serviced year, we confirmed an increase in relative permittivity of oils. Moreover, we confirmed the superior characteristics of the sensor as a species, aged pattern of oils and operating temperature.

  • PDF

5톤/일 shaft형 pilot plant에서 자동차 폐차 잔재의 가스화 용융 특성 (Gasification melting characteristics of Automobile shredder residue in 5t/d shaft pilot plant)

  • 노선아;김우현;윤진한;홍병권
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2010년도 추계학술대회 초록집
    • /
    • pp.160-160
    • /
    • 2010
  • ELVs (End-of-Vehicles) in Korea incrasease continusely because of increase of used car. Automobile Shredder Residue (ASR) is final product of ELVs (End-of-Vehicles) after recycling. Automobile Shredder Residue are composed of light and heavy fluffs and soil/dust. In this study, 5 ton/day pilot plant of shaft type has been designed and constructed and 15 times of test run were performed. For the stable operation, operation conditions such as the amount of fed ASR and cokes, air flow and temperature in the gasification melting system have been changed and the composition of the produced gas such as $H_2$, CO and $CH_4$ and air pollution compound including dioxin discharged from the stack have been analyzed.

  • PDF

LCD TV 백라이트 구동특성 개선을 위한 면광원 인버터 개발 (Development of Flat Fluorescent Lamp (FFL) Inverter for Improvement of LCD TV Backlight Driving Characteristics)

  • 허정욱;임성규
    • 전자공학회논문지 IE
    • /
    • 제44권2호
    • /
    • pp.47-53
    • /
    • 2007
  • 본 논문에서는 Level Control Block (LCB)를 이용한 면광원 인버터를 개발하여 면광원을 이용한 LCD TV 백라이트의 구동특성이 향상되었음을 확인하였다. 또한 LCB를 사용하여 면광원의 시동 시간, 휘도 안정화 시간, 전류의 크기를 조절할 수 있고 개선됨을 확인할 수 있었으며, LCB를 이용하여 면광원램프를 사용한 LCD TV용 백라이트를 넓은 온도범위에서 안정되게 동작시킬 수 있었다.

기체분리용 세라믹 복합분리막의 개발 : IV. ${\gamma}$-알루미나 분리막의 투과 특성 (Development of Ceramic Composite Membranes for Gas Separation: IV. Permeation Characteristics of ${\gamma}$-Alumina Membranes)

  • 현상훈;강범석;최두진
    • 한국세라믹학회지
    • /
    • 제29권12호
    • /
    • pp.970-980
    • /
    • 1992
  • ${\gamma}-alumina$ membranes were prepared by sol-gel dip coating or pressurized coating of boehmite sols on slipcasted ${\gamma}-alumina$ support tubes. The particle size of sols synthesized via the modified Yoldas-method could be controlled below 5 mn according to the mole ratio of nitric acid/aluminumtri-sec-butoxide (0.07~1.0). The reproducible crack-free composite membranes were produced by the 2nd dip coating or the pressurized coating technique using very stable sols with the particle size of 45 nm. Nitrogen gas permeability through the top-layer in the composite membrane was about $70~55{\times}10^{-7}\;mol/m^2{\cdot}s{\cdot}Pa$. The thermal stability of the top layer was proved to be good enough upto the heat-treatment temperature of $500^{\circ}C$.

  • PDF

졸-겔 법에 의한 $\gamma-LiAlO_2$ 화이버의 제조 및 특성 (Preparation and Characteristics of $\gamma-LiAlO_2$ Fibers by the Sol-Gel Method)

  • 현상훈;홍성안;신현철
    • 한국세라믹학회지
    • /
    • 제32권2호
    • /
    • pp.197-208
    • /
    • 1995
  • ${\gamma}$-LiAlO2 fibers for fiber reinforced molten carbonate fuel cell (MCFC) matrix have been produced from LiAlO2 complex polymeric sols using the sol-gel process. The stable and spinnable LiAlO2 sols could be synthesized by mixing LiNO3 alcohol solutions in aluminum complex polymeric sols prepared through the condensationpolymerization reaction of 1 more of aluminum tri-sec-butoxide with 0.55 mole of mixed chelates (mole ratio of acetylaceton/triethanolamine=0.25/0.3). It was found that the viscosity range for fiber-spinning should be higher than 30 poise. The defect-free flexible ${\gamma}$-LiAlO2 fibers with the average tensile strength of 350 MPa could be obtained when the spinned fibers were heat-treated to 120$0^{\circ}C$ on the specified heating schedule after dried at room temperature.

  • PDF