• Title/Summary/Keyword: temperature limit

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Measurement and Prediction of Fire and Explosion Properties of 3-Hexanone (3-헥사논의 화재 및 폭발 특성치의 측정 및 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.17 no.6
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    • pp.33-38
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    • 2013
  • For the safe handling of 3-hexanone(ethyl propyl ketone), this study was investigated the explosion limits of 3-hexanone in the reference data. The flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower flash points of 3-hexanone by using closed-cup tester were experimented at $18^{\circ}C$. The lower flash points of 3-hexanone by using open cup tester were experimented in $27^{\circ}C{\sim}32^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for 3-hexanone. The experimental AIT of 3-hexanone was at $425^{\circ}C$. The lower explosion limit( LEL) by the measured lower flash point of 3-hexanone was calculated as 1.21 Vol%.

Application of thermodynamics to chemical vapor deposition (화학증착에서 열역학의 응용)

  • Latifa Gueroudji
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.1
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    • pp.80-83
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    • 1999
  • Processing of thin films by chemical vapor deposition(CVD) is accompanied by chemical reactions, in which the rigorous kinetic analysis is difficult to achieve. In these conditions, thermodynamic calculation leads to better understanding of the CVD process and helps to optimise the experimental parameters to obtain a desired product. A CVD phase diagram has been used as guide lines for the process. By determining the effect of each process variable on the driving force for deposition, the thermodynamic limit of the substrate temperature for a diamond deposition is calculated in the C-H system by assuming that the limit is defined by the CVD diamond phase diagram. The addition of iso-supersaturation ratio lines to the CVD phase diagram in the Si-Cl-H system provides additional information about the effects of CVD porcess variables.

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Numerical Study of Fire Behavior Induced by Gas Leakage in Combined Cycle Power Plant (복합발전플랜트 내의 가스 화재 거동에 관한 수치해석)

  • Park, Jaeyong;Sung, Kunhyuk;Li, Longnan;Choi, Jinwook;Kim, Daejoong;Lee, Seong Hyuk;Ryou, Hong Sun
    • Journal of ILASS-Korea
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    • v.20 no.2
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    • pp.107-113
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    • 2015
  • To date, the demand for Combined Cycle Power Plant (CCPP) has been continuously increased to overcome the problem of air pollution and lack of energy. In particular, the underground CCPP is exposed to substantial fire and explosion risks induced by gas leakage. The present study conducted numerical simulations to examine the fire behavior and gas leakage characteristics for a restricted region including gas turbine and other components used in a typical CCPP system. The commercial code of FLUENT V.14 was used for simulation. From the results, it was found that flammable limit distribution of leakage gas affects fire behavior. Especially, the flame is propagated in an instant in restricted region with LNG gas. In addition, consequence analysis factors such as critical temperature and radiation heat flux are introduced. These results would be useful in making the safety guidelines for the underground CCPP.

Effect of Gd Substitution for the Ca Site in the Bi1.84Pb0.34Sr1.91 ({Ca1-xGdx)2.03Cu3.06O10+δ(x=0.0~0.06) Superconductors

  • Lee, Min-Soo
    • Journal of the Korean Ceramic Society
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    • v.40 no.5
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    • pp.405-409
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    • 2003
  • The effect of substitution of Gd ions for Ca ions in the B $i_{1.84}$P $b_{0.34}$S $r_{1.91}$(C $a_{1-x}$ G $d_{x}$)$_{2.03}$ C $u_{3.06}$ $O_{ 10+{\delta}}$/ (x=0.0~0.06) was investigated by measuring x-ray diffraction patterns, lattice constants, do resistivity and Hall effect. We found the solubility limit of Gd in the 110 K phase to be x < 0.015. Within the solubility limit, the c-axis seemed to decrease with increasing x. In the region of the 110 K single phase, the critical temperature $T_{c}$ gradually decreased with an increasing the Gd concentration x, corresponding to a small change of the carrier concentration.

Thermal Performance of a Small-scale Loop Heat Pipe for Terrestrial Application (지상용 소형 루프히트파이프 성능에 관한 연구)

  • Chung, Won-Bok;Boo, Joon-Hong
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1052-1057
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    • 2004
  • A small-scale loop heat pipe with polypropylene wick was fabricated and tested for its thermal performance. The container and tubing of the system was made of stainless steel and several working fluids were used to see the difference in performance including methanol, ethanol, acetone, R134a, and water. The heating area was 35 mm ${\times}$ 35 mm and there were nine axial grooves in the evaporator to provide a vapor passage. The pore size of the polypropylene wick inside the evaporator was varied from 0.5 m to 25 m. The size of condenser was 40 mm (W) ${\times}$ 50 mm (L) in which ten coolant paths were provided. The inner diameter of liquid and vapor transport lines were 2.0 mm and 4.0 mm, respectively and the length of which were 0.5 m. The PP wick LHP was operated with methanol, acetone, and ethanol normally. R134a was not compatible with PP wick and water was unsuitable within operating limit of $100^{\circ}C$. The minimum thermal load of 10 W (0.8 W/cm2) and maximum thermal load of 80 W (6.5 W/cm2) were achieved using methanol as working fluid with the condenser temperature of $20^{\circ}C$ with horizontal position.

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Combustion Characteristics of Methane-Hydrogen-Air Premixture( I ) (메탄-수소-공기 예혼합기의 연소특성( I ))

  • Kim, B.S.;Kwon, C.H.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.3 no.3
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    • pp.129-139
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    • 1995
  • This study investigates the combustion characteristics of methane-hydrogen-air premixture in a constant volume combustion chamber. Primary factors of the combustion characteristics of methane- hydrogen-air premixture are the equivalence ratio and hydrogen supplement rate. In the case of $\phi$= 1.1, maximum combustion pressure and heat release rate have peaks, and they increase as the initial pressure and hydrogen supplement rate increase. The total burning time is also the shortest at the $\phi$= 1.1, it shorten by lowering the initial pressure and by increasing the hydrogen supplement rate. The maximum flame temperature is shown at the $\phi$= 1.0, and increasing the initial pressure and hydrogen supplement rate, it increases. The concentration of NO reveals the highest value at the $\phi$= 0.9, and it increases by increasing the initial pressure and hydrogen supplement rate. It is also found that the limit of lean inflammability of methane-hydrogen-air premixture is greatly widened by increasing the hydrogen supplement rate.

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Comparative Analysis of Gross Calorific Value by Determination Method of Lignocellulosic Biomass Using a Bomb Calorimeter

  • Ju, Young Min;Ahn, Byung-Jun;Lee, Jaejung
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.6
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    • pp.864-871
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    • 2016
  • This study was conducted to compare and analyze gross calorific values from measurement methods of lignocellulosic biomass and calculation data from calorific value prediction models based on the elemental content. The deviation of Liriodendron tulipifera (LT) and Populus euramericana (PE) was shown 7.7 cal/g and 7.4 cal/g respectively in palletization method, which are within repeatability limit 28.8 cal/g of ISO FDIS 18125. In the case of Thailand charcoal (TC), nontreatment method and palletization method was satisfied with repeatability limit as 22.8 cal/g and 8.8 cal/g respectively. Seowon charcoal (SC) was shown deviation of 11.4 cal/g in nontreatment method, because the density and chemical affinity of sample increases as the carbon content increases from heat treatment at high temperature in the case of TC and SC. In addition, after applying the elemental content of each of these samples to the calorific value prediction models, the study found that Model Equation (3) was relatively consistent with measured calorific values of all these lignocellulosic biomass. Thus, study about the correlation between the density and size of particle should be conducted in order to select the measurement method for a wide range of solid biofuels in the future.

Hemispherical Grained Silicon formation Condition on In-Situ Phosphorous Doped Amorphous-Si Using The Seeding Method (Seeding Method를 이용한 인이 도우핑된 Amorphous-Si에서의 HSG형성 조건)

  • 정양희;강성준
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.5 no.6
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    • pp.1128-1135
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    • 2001
  • In this paper, a new HSG-Si formation technology, "seeding method', which employs Si$_2$H$_{6}$-molecule irradiation and annealing, was applied for realizing 64Mbit DRAMs. By using this technique, grain size controlled HSG-Si can be fabricated on in-situ phosphorous-doped amorphous-Si electrode. The new HSG-Si fabrication technology achieves twice the storage capacitance with high reliability for the stacked capacitors. In this technique, optimum process conditions of the phosphorous concentration, storage polysilicon deposition temperature and thickness of hemispherical grain silicon are in the range of 3.0-4.0E19atoms/㎤, 53$0^{\circ}C$ and 400$\AA$, respectively. In the 64M bit DRAM capacitor using optimum process conditions, limit thickness of dielectric nitride is about 65$\AA$.

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Failure Mode and Fracture Behavior Evaluation of Pipes with Local Wall Thinning Subjected to Bending Load (감육배관의 굽힘하중에 의한 손상모드와 파괴거동 평가)

  • Ahn, Seok-Hwan;Nam, Ki-Woo;Kim, Seon-Jin;Kim, Jin-Hwan;Kim, Hyun-Soo;Do, Jae-Yoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.1
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    • pp.8-17
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    • 2003
  • Fracture behaviors of pipes with local wall thinning are very important for the integrity of nuclear Power Plant. In Pipes of energy Plants, sometimes, the local wall thinning may result from severe erosion-corrosion (E/C) damage. However, the effects of local wall thinning on strength and fracture behaviors of piping system were not well studied. In this paper, the monotonic bending tests were performed of full-scale carbon steel pipes with local wall thinning. A monotonic bending load was applied to straight pipe specimens by four-point loading at ambient temperature without internal pressure. From the tests, fracture behaviors and fracture strength of locally thinned pipe were manifested systematically. The observed failure modes were divided into four types; ovalization. crack initiation/growth after ovalization, local buckling and crack initiation/growth after local buckling. Also, the strength and the allowable limit of piping system with local wall thinning were evaluated.

Calculation of Limit Temperature on H-Beam Flexural Member Through the Thermal Stress Analysis under the Lateral Load (재하된 H형강 휨재의 열응력해석을 이용한 한계온도 산정)

  • Yoon, Sung Kee;Lee, Chy Hyoung;Koo, Bon Hoon
    • Journal of Korean Society of Steel Construction
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    • v.27 no.4
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    • pp.387-397
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    • 2015
  • The domestic fire resistance performance test is conducted as a prescriptive design method such as quality test. In quality test there are 2 methods, unloaded fire resistance test and fire resistance test under load. In realistic, these tests, however, have problems with expense, time and diversity of structure. This study reviewed fire resistance performance of H-beam flexural member by thermal stress analysis using finite element ABAQUS program. This research is for the performance-based design reviewing applicability of domestic standard. As a result of this study, limit temperatures per each load ratio provied for proper performance of fire resistancy.