• Bulletin of the Korean Chemical Society
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• v.28 no.12
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• pp.2226-2230
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• 2007

As a cathode material of lithium rechargeable batteries, charged Li[Co0.1Ni0.15Li0.2Mn0.55]O2 electrodes, which were aged thermally at 25 oC and 90 oC respectively, were characterized by means of charge/discharger, impedance spectroscopy, and X-ray diffraction. The discharge capacity diminution of the electrodes aged at 25 oC and 90 oC for 1 week was 4% and 23%, respectively. The cell aged at 25 oC was recovered on cycling. However, the capacity loss after ageing at 90 oC was not recovered in a subsequent cycling test, which demonstrates that the reaction occurring during ageing at 90 oC is irreversible. A significant impedance increase of aged electrode at 90 oC is associated with irreversible capacity loss. The structural changes including phase transformation were not detected by XRD analysis, because it could be due to out of detection limit. After ageing, impedance was slightly decreased during subsequent cycling test. It could be explained the cyclic performance of aged sample is stable. The thermal stability was not deteriorated by ageing even at the high temperature of 90 oC.

• Bulletin of the Korean Chemical Society
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• v.32 no.9
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• pp.3223-3228
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• 2011

To quantify the presence of mercuric ions in aqueous solution, double-stranded DNA (dsDNA) of poly(dT) was employed using a light switch compound, $Ru(phen)_2(dppz)^{2+}$ (1) which is reported to intercalate into dsDNA of a right-handed B-form. Addition of mercuric ions induced the dehybridization of poly(dT)${\cdot}$poly(dA) duplexes to form a hairpin structure of poly(dT) at room temperature and the metal-to-ligand charge transfer emission derived from the intercalation of 1 was reduced due to the dehybridization of dsDNA. As the concentration of $Hg^{2+}$ was increased, the emission of 1 progressively decreased. This label-free emission method had a detection limit of 0.2 nM. Other metal ions, such as $K^+$, $Ag^+$, $Ca^{2+}$, $Mg^{2+}$, $Zn^{2+}$, $Mn^{2+}$, $Co^{2+}$, $Ni^{2+}$, $Cu^{2+}$, $Cd^{2+}$, $Cr^{3+}$, $Fe^{3+}$, had no significant effect on reducing emission. This emission method can differentiate matched and mismatched poly(dT) sequences based on the emission intensity of dsDNA.

• Journal of the Korean Ceramic Society
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• v.39 no.6
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• pp.576-581
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• 2002

In order to simultaneously vitrify the ton Exchange Resin(IER) and Dry Active Waste(DAW) generated from the Nuclear Power Plants, a vitrification pilot test was conducted using an induction cold crucible melter. The PCT result evaluating the chemical durability of the vitrified from showed that the final glass was more durable than the benchmark glass. Liquidus temperature for the final vitrified form was 1048 K(775$\^{C}$) fur heat treatment experiments. The value of the compressive strength for the vitrified form was ninety times higher than the regulation limit, 34 kg/㎠. The glasses on bottom, middle and top of the CCM were homogeneous with no secondary phase. The precipitation of the magnetic metal phase was able to be avoided by simultaneously fEeding of DAW with IER containing strongly reducing organics. Volume reduction factor of 74 was achieved through the vitrification Pilot test for mixed waste.

• Journal of the Korean Ceramic Society
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• v.51 no.1
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• pp.43-50
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• 2014

We fabricated undoped and Sb-doped $SnO_2$ thin films on glass substrates by a pulsed laser deposition (PLD) process. Undoped and 2 - 8 wt% $Sb_2O_3$-doped $SnO_2$ targets with a high density level of ~90% were prepared by the spark plasma sintering (SPS) process. Initially, the effects of the deposition temperature on undoped $SnO_2$ thin films were investigated in the region of $100-600^{\circ}C$. While the undoped $SnO_2$ film exhibited the lowest resistivity of $1.20{\times}10^{-2}{\Omega}{\cdot}cm$ at $200^{\circ}C$ due to the highest carrier concentration generated by the oxygen vacancies, 2 wt% Sb-doped $SnO_2$ film exhibited the lowest resistivity value of $5.43{\times}10^{-3}{\Omega}{\cdot}cm$, the highest average transmittance of 85.8%, and the highest figure of merit of 1202 ${\Omega}^{-1}{\cdot}cm^{-1}$ at $400^{\circ}C$ among all of the doped films. These results imply that 2 wt% $Sb_2O_3$ is an optimum doping content close to the solubility limit of $Sb^{5+}$ substitution for the $Sb^{4+}$ sites of $SnO_2$.

• The Transactions of the Korean Institute of Power Electronics
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• v.10 no.3
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• pp.226-232
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• 2005

Recently, many nation have released standard such as IEC 61000-3-2 and IEEE 59, which impose a limit on the harmonic current drawn by equipment connected to AC line in order to prevent the distortion of an AC Line. Therefore, Plasma Display Panel(PDP) which is highlightened in digital display device also has the Power Factor Correction(PFC) circuit to meet the harmonic requirements. In PDP power module, the conventional boost converter is usually used for the PFC circuit. However, it comes serious thermal problem on it's bridge diode due to heat of PDP, and therefore the system stability is not guaranteed. In this paper, the bridgeless boost converter, which is used for PFC circuit of the PDP power module, is designed and verified the possibility of the application In a practical product in a view of efficiency, component count, temperature and etc.

• Progress in Superconductivity and Cryogenics
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• v.17 no.2
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• pp.41-44
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• 2015

Critical current of high-temperature superconducting (HTS) coil is influenced by its own self magnetic field. Direction and density distribution of the magnetic field around the coil are fixed after the shape of the coil is decided. If the entire part of the HTS tape has homogeneous $I_c$ distribution characteristic, quench would be initiated in fixed location on the coil. However, the actual HTS tape has inhomogeneous $I_c$ distribution along the length. If the $I_c$ distribution of the HTS tape is known, we can expect the spot within the HTS coil that has the highest probability to initiate the quench. In this paper, $I_c$ distribution within the HTS coil under self-field effect is simulated by MATLAB. In the simulation procedure, $I_c$ distribution of the entire part of the HTS tape is assume d to follow Gaussian-distribution by central limit theorem. The HTS coil model is divided into several segments, and the critical current of each segment is calculated based on the-generalized Kim model. Single pancake model is simulated and self-field of HTS coil is calculated by Biot-Savart's law. As a result of simulation, quench-initiating spot in the actual HTS coil can be predicted statistically. And that statistical analysis can help detect or protect the quench of the HTS coil.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.11a
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• pp.424-424
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• 2008

Dye-sensitized Solar Cell (DSC) is a new type of solar cell by using photocatalytic properties of $TiO_2$. The electric potential distribution in DSCs has played a major role in the operation of such cells. Models based on a built-in electric field which sets the upper limit for the open circuit voltage(Voc) and/or the possibility of a Schottky barrier at the interface between the mesoporous wide band gap semiconductor and the transparent conducting substrate have been presented. $TiO_2$ thin films were deposited on the FTO substrate by Nd:YAG Pulsed Laser Deposition(PLD) at room temperature and post-deposition annealing at $500^{\circ}C$ in flowing $O_2$ atmosphere for 1 hour. The structural properties of $TiO_2$ thin films have investigated by X-ray diffraction(XRD) and atomic force microscope(AFM). Thickness of $TiO_2$ thin films were controlled deference deposition time and measurement by scanning electron microscope(SEM). Then we manufactured a DSC unit cells and I-V and efficiency were tested using solar simulator.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2001.04a
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• pp.905-909
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• 2001

The significance of casting/forging process for reducing the production cost of large components is being noted in these days. This casting/forging process is a method of forging a workpiece preformed by casting into the final shape. In this study, the casting/forging process has been applied in manufacturing a large aluminum flange in order to determine the optimum forging condition of the aluminum flange. The optimum range of forging temperature of Al 5083 was from $420^{\circ}C$ to $450^{\circ}C$. The suitable strain rate was 1.5 $sec^{-1}$. The deformation amount of a preform in a forging process is key role in the mechanical properties of casting/forging products. In order to find the change of mechanical properties according to effective stain of cast aluminum billets, a hot upsetting test were performed with rectangular blocks and then a uniaxial tensile test was performed with specimens cut from the upsetted billets. The tensile strength and the elongation of cast/upsetted aluminum billets were increased largely until the effective strain was 0.7. FE analysis was performed to determine the configurations of cast preform and die for an aluminum flange. In the FE analysis, the forging load-limit was fixed 1500ton for the low equipment cost. The cast preform was designed so that the effective stain around the neck of a flange exceeds 0.7. In the forging experiment for an aluminum flange, it was confirmed that the optimal configuration of the cast preform predicted by FE analysis was very useful. The cast/forged products using designed preform were made perfectly without any defects.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.34 no.7
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• pp.935-941
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• 2010

HANARO is an open-tank-in-pool-type Korean research reactor that generates 30MW of thermal power. It differs from power plant reactor in that the heat generated by HANARO is exhausted into the atmosphere through a secondary cooling tower, thus maintaining the core temperature constant. During every monthly inspection of the cooling tower, large vibrations that exceeded the permissible limit were observed at cooling fan gear reducer No. 4 of the cooling tower. The purpose of this study is to identify the origin of the large vibration and to repair it. FFT spectrum analysis is performed to identify the part that caused the large vibration. The results of the frequency analysis showed that the vibration frequency was 354 Hz, which is twice the natural frequency of the pinion gear. A check of the pinion gear revealed that there was a crack on the surface of the pinion gear. After the gear was replaced, the reducer operated normally.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.32 no.9
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• pp.740-753
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• 2008

The conventional Split Hopkinson Pressure Bar (C-SHPB) technique with aluminum pressure bars to achieve a closer impedance match between the pressure bars and the specimen materials such as hot temperature degraded POM (Poly Oxy Methylene) and PP (Poly Propylene) to obtain more distinguishable experimental signals is used to obtain a dynamic behavior of material deformation under a high strain rate loading condition. An experimental modification with Pulse shaper is introduced to reduce the nonequilibrium on the dynamic material response during a short test period to increase the rise time of the incident pulse for two polymeric materials. For the dynamic stress strain curve obtained from SHPB experiment under high strain rate, the Johnson-Cook model is applied as a constitutive equation, and we verify the applicability of this constitutive equation to the probabilistic reliability estimation method. The methodology to estimate the reliability using the probabilistic method such as the FORM and the SORM has been proposed, after compose the limit state function using Johnson-Cook model. It is found that the failure probability estimated by using the SORM is more reliable than those of the FORM, and the failure probability increases with the increase of applied stress. Moreover, it is noted that the parameters of Johnson-Cook model such as A and n, and applied stress affect the failure probability more than the other random variables according to the sensitivity analysis.