• Title/Summary/Keyword: temperature dependent physical properties

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Nonlocal strain gradient-based vibration analysis of embedded curved porous piezoelectric nano-beams in thermal environment

  • Ebrahimi, Farzad;Daman, Mohsen;Jafari, Ali
    • Smart Structures and Systems
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    • v.20 no.6
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    • pp.709-728
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    • 2017
  • This disquisition proposes a nonlocal strain gradient beam theory for thermo-mechanical dynamic characteristics of embedded smart shear deformable curved piezoelectric nanobeams made of porous electro-elastic functionally graded materials by using an analytical method. Electro-elastic properties of embedded curved porous FG nanobeam are assumed to be temperature-dependent and vary through the thickness direction of beam according to the power-law which is modified to approximate material properties for even distributions of porosities. It is perceived that during manufacturing of functionally graded materials (FGMs) porosities and micro-voids can be occurred inside the material. Since variation of pores along the thickness direction influences the mechanical and physical properties, so in this study thermo-mechanical vibration analysis of curve FG piezoelectric nanobeam by considering the effect of these imperfections is performed. Nonlocal strain gradient elasticity theory is utilized to consider the size effects in which the stress for not only the nonlocal stress field but also the strain gradients stress field. The governing equations and related boundary condition of embedded smart curved porous FG nanobeam subjected to thermal and electric field are derived via the energy method based on Timoshenko beam theory. An analytical Navier solution procedure is utilized to achieve the natural frequencies of porous FG curved piezoelectric nanobeam resting on Winkler and Pasternak foundation. The results for simpler states are confirmed with known data in the literature. The effects of various parameters such as nonlocality parameter, electric voltage, coefficient of porosity, elastic foundation parameters, thermal effect, gradient index, strain gradient, elastic opening angle and slenderness ratio on the natural frequency of embedded curved FG porous piezoelectric nanobeam are successfully discussed. It is concluded that these parameters play important roles on the dynamic behavior of porous FG curved nanobeam. Presented numerical results can serve as benchmarks for future analyses of curve FG nanobeam with porosity phases.

A study on Crack Healing of Various Glassy Polymers (part I) -theoretical modeling- (유리질 중합체의 균열 Healing에 관한 연구 (제1보) -이론 모델링-)

  • Lee, Ouk-Sub
    • Journal of the Korean Society for Precision Engineering
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    • v.3 no.1
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    • pp.40-49
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    • 1986
  • Crack, craze and void are common defects which may be found in the bulk of polymeric materials such as either themoplastics or thermosets. The healing phenomena, autohesion, of these defects are known to be a intrinsic material property of various polymeric materials. However, only a few experimental and theoretical investigations on crack, void and craze healing phenomena for various polymeric materials have been reported up to date [1, 2, 3]. This may be partly due to the complications of healing processes and lacking of appropriate theoretical developments. Recently, some investigators have been urged to study the healing phenomena of various polymenic materials since the significance of the use of polymer based alloys or composites has been raised in terms of specific strength and energy saving. In the earlier published reports [1, 2, 3, 4], the crack and void healing velocity, healing toughness and some other healing mechanical and physical properties were measured experimentally and compared with predicted values by utilizing a simple model such as the reptation model under some resonable assumptions. It seems, however, that the general acceptance of the proposed modeling analyses is yet open question. The crack healing processes seem to be complicate and highly dependent on the state of virgin material in terms of mechanical and physical properties. Furthermore, it is also strongly dependent on the histories of crack, craze and void development including fracture suface morphology, the shape of void and the degree of disentanglement of fibril in the craze. The rate of crack healing may be a function of environmental factors such as healing temperature, time and pressure which gives different contact configurations between two separated surfaces. It seems to be reasonable to assume that the crack healing processes may be divided in several distinguished steps like stress relaxation with molecular chain arrangement, surface contact (wetting), inter- diffusion process and com;oete healing (to obtain the original strength). In this context, it is likely that we no longer have to accept the limitation of cumulative damage theories and fatigue life if it is probable to remove the defects such as crack, craze and void and to restore the original strength of polymers or polymer based compowites by suitable choice of healing histories and methods. In this paper, we wish to present a very simple and intuitive theoretical model for the prediction of healed fracture toughness of cracked or defective polymeric components. The central idea of this investigation, thus, may be the modeling of behavior of chain molecules under healing conditions including the effects of chain scission on the healing processes. The validity of this proposed model will be studied by making comparisons between theoretically predicted values and experimentally determined results in near future and will be reported elsewhere.

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ACCELERATION OF COSMIC RAYS AT COSMIC SHOCKS

  • KANG HYESUNG
    • Journal of The Korean Astronomical Society
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    • v.36 no.1
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    • pp.1-12
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    • 2003
  • Nonthermal particles can be produced due to incomplete thermalization at collisionless shocks and further accelerated to very high energies via diffusive shock acceleration. In a previous study we explored the cosmic ray (CR) acceleration at cosmic shocks through numerical simulations of CR modified, quasi-parallel shocks in 1D plane-parallel geometry with the physical parameters relevant for the shocks emerging in the large scale structure formation of the universe (Kang & Jones 2002). Specifically we considered pancake shocks driven by accretion flows with $U_o = 1500 km\;s^{-l}$ and the preshock gas temperature of $T_o = 10^4 - 10^8K$. In order to consider the CR acceleration at shocks with a broader range of physical properties, in this contribution we present additional simulations with accretion flows with $U_o = 75 - 1500 km\;s^{-l}$ and $T_o = 10^4K$. We also compare the new simulation results with those reported in the previous study. For a given Mach number, shocks with higher speeds accelerate CRs faster with a greater number of particles, since the acceleration time scale is $t_{acc}\;{\propto}\;U_o^{-2}$. However, two shocks with a same Mach number but with different shock speeds evolve qualitatively similarly when the results are presented in terms of diffusion length and time scales. Therefore, the time asymptotic value for the fraction of shock kinetic energy transferred to CRs is mainly controlled by shock Mach number rather than shock speed. Although the CR acceleration efficiency depends weakly on a well-constrained injection parameter, $\epsilon$, and on shock speed for low shock Mach numbers, the dependence disappears for high shock Mach numbers. We present the 'CR energy ratio', ${\phi}(M_s)$, for a wide range of shock parameters and for $\epsilon$ = 0.2 - 0.3 at terminal time of our simulations. We suggest that these values can be considered as time-asymptotic values for the CR acceleration efficiency, since the time-dependent evolution of CR modified shocks has become approximately self-similar before the terminal time.

Study on the fabrication of Ceramic Core using a Gel-casting Process in Aqueous Medium(II) : Physical Properties of Sintered Ceramic Core Body (수용액 매체에서 젤-케스팅 공정을 이용한 세라믹 코어 제조에 관한 연구(II) : 세라믹 코어 소결체의 물성)

  • Kim, Jae-Won;Kim, Du-Hyeon;Kim, In-Su;Yu, Yeong-Su;Choe, Baek-Gyu;Kim, Ui-Hwan;Jo, Chang-Yong
    • Korean Journal of Materials Research
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    • v.11 no.6
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    • pp.465-471
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    • 2001
  • The effect of sintering condition on the mechanical properties and leachability of polydispersed ceramic core body made by gel-casting process in aqueous medium have been investigated. The polydispersed ceramic slip that has low viscosity($\leq$1000cP, at 1000cP (at $50sec^{-1}$ ) and high solid loading(50vo1%) was obtained. The green bodies were fabricated through casting and gelation at room temperature followed by drying at $25^{\circ}C$for 48hrs under relative humidity of 80%. Crack-free green body was successfully fabricated through the above process. The strength at room temperature, apparent bulk density, and shrinkage of the ceramic core body increased propotionally with increasing sintering temperature(1100~150$0^{\circ}C$). However, porosity of the ceramic core body showed relatively low vague. Leaching rate of sintered core body increased with increasing porosity of the sintered body, and was significantly dependent upon the concentration of alkali caustic solution at the same leaching temperature.

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Spatio-temporal Fluctuations of Size-structured Phytoplankton over an Annual Cycle in the Youngsan Lake

  • Song, Eun-Sook;Shin, Yong-Sik
    • Korean Journal of Ecology and Environment
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    • v.41 no.4
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    • pp.530-540
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    • 2008
  • The temporal and spatial variations of size-structured phytoplankton dynamics in Youngsan Lake were investigated to explore potential mechanims controlling the dynamics in the Youngsan Lake. Field data were collected monthly from February to October, 2003 at 6 stations along the axis of Youngsan Lake. In this study, phytoplankton (chlorophyll $\alpha$) were categorized into three size classes: micro-size ($>20{\mu}m$), nano-size ($2{\sim}20{\mu}m$) and pico-size ($<20{\mu}m$). Water temperature, light attenuation coefficients, PAR (photosynthetically active radiation) and suspended solids were measured to analyze relationship between physical-chemical properties and size structure of phytoplankton. Phytoplankton blooms developed during March, July and October in the upper region of the main stem whereas small-scaled spring bloom was observed in the lower region. The scales of phytoplankton blooms were higher in the upper regions than the lower region and blooms were predominated by micro-size class in upper region but predominated by nano-size class in lower region. Growth of size-structured phytoplankton appeared to be controlled by rather light availability than temperature-dependant metabolisms in the system. Phytoplankton growth may be also supported by ambient nutrients available in the water column from analyses of chlorophyll $\alpha$ vs. nutrient concentrations including nitrite+nitrate and orthophosphate. Growth of nano-sized phytoplankton alone appeared to be supported by orthophosphate as well as nitrite+nitrate indicating that response of phytoplankton to nutrient inputs may be size-dependent.

Effect of tannin contents on the physicochemical characteristics of acorn starch (탄닌함량에 따른 도토리전분의 물리화학적 특성)

  • Ahn, Ho-Kyoung;Choi, Hyeong-Taeg;Kim, Byong-Lyoung;Oh, Doo-Hwan
    • Applied Biological Chemistry
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    • v.33 no.4
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    • pp.301-306
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    • 1990
  • The Physical and chemical properties or dry acorn starch(DS), detannined acorn starch (DTS) and defatted and detannined acorn starch(Drn) were investigated. Ail acorn starch sample, observed by a scanning electron microscope, showed a hemispherical shape ud its size was about $5{\sim}10{\mu}m$ in diameter. It had a little change on the pasting temperature of DS, DTS and DFTS but peak viscosity of DTS was somewhat higher than that of n. Flow behavior of gelatinized starch pastes showed a pseudoplastic behavior and flow behavior index was lower than unit. The consistency coefficient showed concentraion and temperature dependency. The activation energies of DS, DTS and DFTS were $2.09{\sim}3.58Kcal/g\;{\cdot}\;mol and time dependent characteristic of acorn starch samples showed thixotrpic behavior.

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Changes of Functional Compounds in, and Texture Characteristics of, Apples, during Post-Irradiation Storage at Different Temperatures (감마선 조사와 저장온도에 따른 사과의 기능성 성분 및 조직감 변화)

  • Yun, Hye-Jeong;Lim, Sang-Yong;Hur, Jung-Mu;Jeong, Jin-Woo;Yang, Soo-Hyung;Kim, Dong-Ho
    • Food Science and Preservation
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    • v.14 no.3
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    • pp.239-246
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    • 2007
  • The effects of gamma irradiation on the physiochemical and physical characteristics of apples were investigated during post-irradiation storage at $4^{\circ}C\;and\;25^{\circ}C$. The contents of total and reducing sugars were analyzed and the results indicated that apples receiving 1 kGy of gamma irradiation did not show significant differences in sugar contents compared to non-irradiated controls. Important physiological characteristics were evaluated by measurement of total phenolic content and total flavonoid content, reducing power, and radical scavenging ability, and the results indicated that gamma irradiation at a dose of 1 kGy did not affect physiological activities. Changes in physical parameters such as weight loss, strength, cohesiveness and hardness, during post-irradiation storage, were temperature-dependent, whether the apples were irradiated or not The color and sensory acceptance of the apples were not affected by irradiation during cold storage. However, minor deterioration in color quality and sensory acceptance of irradiated apples was noted under ambient temperature storage. We conclude that gamma irradiation(1 kGy) does not affect apple nutritional content stability, functional properties, or physical characteristics, especially upon cold storage after radiation treatment.

Application of PCM Technology to Concrete II : Effects of SSMA(Sulfonated Styrene-Maleic Anhydride) on the Properties of the 1-Dodecanol Micro-Capsule (PCM 기술의 콘크리트 적용 II : 계면중합법에 의한 1-도데카놀 마이크로 캡슐에 있어서 계면활성제로 사용된 SSMA의 표면활성도가 마이크로 캡슐의 특성에 미치는 영향)

  • Shin, Se-Soon;Jung, Jae-Yun;Lim, Myung-Kwan;Choi, Dong-Uk;Kim, Young-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.1
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    • pp.17-25
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    • 2013
  • Thermal storage technology used for indoor heating and cooling to maintain a constant temperature for a long period of time has an advantage of raising energy use efficiency. This, the phase changing material, which utilizes heat storage properties of the substances, capsulizes substances that melt at a constant temperature. This is applied to construction materials to block or save energy due to heat storage and heat protection during the process in which substances melt or freeze according to the indoor or outdoor temperature. The micro-encapsulation method is used to create thermal storage from phase changing material. This method can be broadly classified in 3 ways: chemical method, physical and chemical method and physical and mechanical method. In the physical and chemical method, a wet process using the micro-encapsulation process utilized. This process emulsifies the core material in a solvent then coats the monomer polymer on the wall of the emulsion to harden it. In this process, a surfactant is utilized to enhance the performance of the emulsion of the core material and the coating of the wall monomer. The performance of the micro-encapsulation, especially the coating thickness of the wall material and the uniformity of the coating, is largely dependent on the characteristics of the surfactant. This research compares the performance of the micro-capsules and heat storage for product according to molecular mass and concentration of the surfactant, SSMA (sulfonated styrene-maleic anhydride), when it comes to micro-encapsulation through interfacial polymerization, in which Dodecan-1 is transformed to melamin resin, a heat storage material using phase changing properties. In addition, the thickness of the micro-encapsulation wall material and residual melamine were reduced by adjusting the concentration of melamin resin microcapsules.

Direct Conversion of Cellulose into Polyols over Pt Catalysts Supported on Zeolites (제올라이트에 담지된 백금 촉매를 이용한 셀룰로우스의 폴리올로의 직접 전환)

  • You, Su Jin;Baek, In Gu;Park, Eun Duck
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.435-441
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    • 2012
  • The direct conversion of cellulose into polyols in $H_2$ was examined over Pt catalysts supported on various zeolites, viz., mordenite, Y, ferrierite, and ${\beta}$. For comparison, Pt catalysts supported on ${\gamma}-Al_2O_3$, $SiO_2-Al_2O_3$, and $SiO_2$ were also tested. The physical properties of the catalysts were probed with $N_2$ physisorption. The surface acidity was measured with temperature programmed desorption of ammonia ($NH_3$-TPD). The Pt content was quantified with inductively coupled plasma-atomic emission spectroscopy (ICP-AES). The Pt dispersion was determined with CO chemisorptions and transmission electron microscopy (TEM). The conversion of cellulose appeared to be mainly dependent on the reaction temperature and reaction time because it depends on the concentration of $H^+$ ions reversibly formed in hot water. Pt/H-mordenite (20) showed the highest yield to polyols among the tested catalysts. Pt/H-zeolite was superior to Pt/Na-zeolite for this reaction. The polyol yield was dependent on the surface acid density and the external surface area.

Laboratory Evaluation of Polysulfide Epoxy Overlay Material for Bridge Deck (교면포장용 폴리설파이드 에폭시재료의 실내물성 평가)

  • Kim, Jun-Hyung;Suh, Young-Chan
    • International Journal of Highway Engineering
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    • v.13 no.2
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    • pp.159-166
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    • 2011
  • This research was performed to evaluate physical properties of polysulfide epoxy overlay material for bridge deck as part of a review for possibility of domestic application of polymer concrete for bridge deck pavement. In order to evaluate strength characteristics, compressive strength, flexural strength and bond strength were tested, and, for durability characteristics, chloride ion penetration resistance and freeze/thaw resistance were tested along with ultraviolet rays impact evaluation. The tests showed that the results met the criteria suggested by the American Concrete Institute in terms of compressive strength, flexural strength and bond strength. However, in terms of the strengths measured at various test temperatures, it was found that the epoxy material was highly dependent on temperature, and, therefore, this should be considered at the time of domestic application of the epoxy material later. Deflection characteristics was checked through flexural strength test and it was found that bridge deck pavement using the epoxy material was excellent compared to bridge deck pavement using asphalt. Furthermore, the results of chloride ion penetration resistance test and freeze/thaw resistance test were also excellent. In the evaluation of ultraviolet rays impact on epoxy slurry mixture, reduction of strain was noticed with increased strength, but the deflection characteristics after exposure to ultraviolet rays was better than the existing acryl polymer concrete. Therefore, it is concluded from the research that the polysulfide epoxy overlay material has the physical properties that are appropriate to pavement of bridge deck.