• Korean Journal of Materials Research
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• v.14 no.2
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• pp.141-145
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• 2004

Silicon nitride thin films were deposited by atomic layer deposition (ALD) technique in a batch-type reactor by alternating exposures of precursors. XJAKO200414714156408$_4$ or$ SiH_2$$Cl_2$ was used as the Si precursor, $NH_3$ was used as the N precursor, and the deposited films were characterized comparatively. The thickness of the film linearly increased with the number of deposition cycles, so that the thickness of the film can be precisely controlled by adjusting the number of cycles. As compared with the deposition using$ SiCl_4$, the deposition using $SiH_2$$Cl_2$ exhibited larger deposition rate at lower precursor exposures, and the deposited films using $SiH_2$$Cl_2$ had lower wet etch rate in a diluted HF solution. Silicon nitride films with the Si:N ratio of approximately 1:1 were obtained using either Si precursors at $500^{\circ}C$, however, the films deposited using $SiH_2$$Cl_2$ exhibited higher concentration of H as compared with those of the $SiC_4$ case. Silicon nitride thin films deposited by ALD showed similar physical properties, such as composition or integrity, with the silicon nitride films deposited by low-pressure chemical vapor deposition, lowering deposition temperature by more than $200^{\circ}C$.

• Journal of the Korea institute for structural maintenance and inspection
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• v.13 no.6 s.58
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• pp.126-134
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• 2009

Generally, reinforced concrete structures exposed to the outside temperature are affected by freezing and thawing process during winter and early spring. These freeze-thawing process can lead to the reduction in durability of concrete as cracking or surface spalling. This paper is to study the flexural behavior of RC beams exposed to freeze-thawing environments. To compare the difference in flexural behavior of RC Beams, limited tests were conducted under different types of Longitudinal steel ratio and freeze-thawing cycles. For this purpose, fourteen small-scale RC beams ($100mm{\times} 100mm {\times}600mm$) were strengthened in monotonic and cyclic loadings, subjected to up to 150, 300 cycles freeze-thawing from $-18{\sim}4^{\circ}C$. It is thought that experimental results will be used as basic data to evaluate flexural behavior of RC beams exposed to freeze-thawing.

• Journal of Industrial and Engineering Chemistry
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• v.68
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• pp.161-167
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• 2018

In this study, transition metal coated carbon nanofibers (CNFs) were synthesized and applied as anode materials of Li secondary batteries. CNFs/Ni foam was immersed into 0.01 M transition metal solutions after growing CNFs on Ni foam via chemical vapor deposition (CVD) method. Transition metal coated CNFs/Ni foam was dried in an oven at $80^{\circ}C$. Morphologies, compositions, and crystal quality of CNFs-transition metal composites were characterized by scanning electron microscopy (SEM), Raman spectroscopy (Raman), and X-ray photoelectron spectroscopy (XPS), respectively. Electrochemical characteristics of CNFs-transition metal composites as anodes of Li secondary batteries were investigated using a three-electrode cell. Transition metal/CNFs/Ni foam was directly employed as a working electrode without any binder. Lithium foil was used as both counter and reference electrodes while 1 M $LiClO_4$ was employed as the electrolyte after it was dissolved in a mixture of propylene carbonate:ethylene carbonate (PC:EC) at 1:1 volume ratio. Galvanostatic charge/discharge cycling and cyclic voltammetry measurements were taken at room temperature using a battery tester. In particular, the capacity of the synthesized CNFs-Fe was improved compared to that of CNFs. After 30 cycles, the capacity of CNFs-Fe was increased by 78%. Among four transition metals of Fe, Cu, Co and Ni coated on carbon nanofibers, the retention rate of CNFs-Fe was the highest at 41%. The initial capacity of CNFs-Fe with 670 mAh/g was reduced to 275 mAh/g after 30 cycles.

• Journal of People, Plants, and Environment
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• v.23 no.2
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• pp.179-189
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• 2020

In order to increase the indoor air purification effect of plants, plants need to be placed on 5-10% of indoor spaces. To increase the density and utilization of plants in indoor spaces, studies on bio-wall, a vertical green wall system, have been recently conducted. The purpose of this study was to investigate the growth characteristics of 7 indoor plants introduced to the system and their rooting zones at different irrigation cycles. This study was conducted to investigate a proper irrigation cycle for the continuous maintenance of bio-wall systems. The conditions of their growth environment were maintained as follows: light intensity, 20-50 μmol·m^-2·s^-1 PPFD; and temperature, 20 - 25℃. For fertilization, Hyponex diluted with water at the ratio of 1:1,000 was supplied to plants. Irrigation was treated at intervals of 1, 3, 5, and 7 days for 1 hour at a time. As a result, there was no significant difference in the growth of plants between different irrigation cycles. Dieffenbachia 'Marianne' showed a significant decrease in the number of leaves at the irrigation cycle of 7 days. In addition, the chlorophyll content was relatively low at the irrigation cycle of 7 days. In terms of the color of leaves, a decrease in L value and b value and an increase in a value were observed, resulting in changes in brightness and color. Ardisia pusilla 'Variegata' showed a slightly higher photosynthetic activity and stomatal conductance when it was watered every day and once per 5 days, while Epipremnum aureum showed a relatively higher photosynthetic activity and stomatal conductance at the irrigation cycle of 3 days. In the case of root activity, it was found that the longer irrigation cycle, the higher root activity compared to daily irrigation. The development of roots of Peperomia clusiifolia was promoted by watering at long intervals. However, in the case of Aglaonema 'Siam-Aurora', the total number of roots decreased at the interval of 7 days. In conclusion, a proper irrigation cycle for the sustainable maintenance of vertical bio-wall systems seems to be 3 days.

• Journal of the Korean Wood Science and Technology
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• v.30 no.4
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• pp.41-50
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• 2002

Small clear specimens of Quercus acutissima Carr. and Larix caempferi Carr. were used to measure shrinkage and thermal conductivity for the reasonable and effective use. All samples were conditioned to 18, 12, 5% moisture contents in a humidity chamber of 86, 66, 20% relative humidity(RH), respectively and room temperature(23℃) All specimens were conducted on the shrinkage and thermal conductivity test at each MCs. These processes(cycle) were repeated three times. The radial and tangential shrinkages of Quercus acutissima Carr. and Larix caempferi Carr. decreased at each level of MCs, with the increasing cycles. The radial and tangential shrinkages increased as the specific gravity(on oven-dry weight and volume basis) increased. Thermal conductivities of the radial and tangential direction of Quercus acutissima Carr. and Larix caempferi Carr. increased at each levels of MCs, with increasing cycles. Good correlations were obtained between shrinkages and thermal conductivities of radial and tangential direction, and specific gravity (on oven-dry weight and oven-dry volume basis) and MC.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.36 no.1
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• pp.81-87
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• 2023

Heaters using the resistance heating principle are used in various industrial fields that require heat and are also essentially used in bidet among small home appliances. A planar heater and a coil-inserted heater mounted on a conventional commercially used bidet have disadvantages and limitations of complicated manufacturing process and local heating. In this study, silver-palladium (Ag-Pd) powder material was used for a screen-printing process that is more advantageous in achieving simplification than the existing process, and a rod-type heater for bidet was manufactured. The on-off cycle test under actual conditions was conducted to confirm the durability and the capability of the fabricated heater, and the fabricated heater operated more than 2,600 on-off cycles, which means it could be applied for a commercial product. In addition, through the on-off cycles under harsh conditions, the cause of failure was identified after the test that the durability limit temperature of the heater was 850℃. Through Ag-Pd rod heater in this study, it is expected to contribute to the efficient development of electrode materials for heaters and the improvement of the durability of heaters in the future.

• Journal of the Korean Society for Heat Treatment
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• v.36 no.1
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• pp.7-14
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• 2023

We investigated the effect of multiple tempering on the microstructure and mechanical properties of AISI 4340 steel. The austenitized and quenched AISI 4340 steels were tempered at 550, 600, and 650℃ for 1, 2, and 4 h by single-tempering (ST). The multiple tempering was conducted for 4 h by double-tempering (DT, 2 h + 2 h), and quadruple-tempering (QT, 1 h + 1 h + 1 h + 1 h). As tempering temperature increases, yield strength and ultimate tensile strength decrease and elongation increases due to recovery and recrystallization of martensite and coarsening of carbides. At 550℃, as the number of tempering cycles increases, the yield strength and tensile strength decrease at the expense of fracture elongation. At 600 and 650℃, the yield strength and tensile strength increase with increasing the number of tempering cycles while fracture elongation maintains similar values. The multiple tempering at the same tempering time of 4 h improves the modulus of toughness at all tempering temperatures, which is presumed to be due to the change in carbide precipitation behavior by multiple tempering.

• Journal of Mechanical Science and Technology
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• v.20 no.1
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• pp.59-65
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• 2006

A half-scaled large test model for the main components of the real annular structure was built and the thermal behaviors were experimented and obtained by thermal cyclic loads. The model design and the test conditions for the thermal loads were determined to take into consideration the thermal and mechanical loads acting on the real annular structure by finite element analyses. Temperature profiles and strains of the main components of the model were measured at an early stage of the test and periodically throughout the test in the given test conditions. After completion of the thermal cyclic tests, no evidence of crack initiation and propagation were identified by a dye penetration test. The measured strains at the critical parts were slightly increased proportionally with the increase in the number of the thermal cycles.

• Journal of Electrical Engineering and Technology
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• v.1 no.2
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• pp.263-267
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• 2006

A new thermal bimorph actuator for large out-of-plane displacement is designed, fabricated and tested. The deflecting beam is composed of polyimide, heater, and polyvinyl difluorides with tetrafluoroethylene (PVDF-TrFE). The large difference of coefficient of thermal expansion (CTE) of two polymer layers (polyimide and PVDF-TrFE) can generate a significant deflection with relatively small temperature rise. Compared to the most conventional micro actuators based on MEMS (micro-electro mechanical system) technology, a large displacement, over 1 mm at 20 mW, could be achieved. Additionally, we can achieve response time of 14.6 ms, resonance frequency of 12 Hz, and reliability ability of $10^5$ cycles. The proposed actuator can find applications where a large vertical displacement is needed while maintaining compact overall device size, such as a micro zooming lens, micro mirror, micro valve and optical application.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3317-3322
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• 2007

THC(Total Hydrocarbon) emissions during cold start and warm-up phase constitute the majority of THC emissions during the FTP-75 mode. As the basic approach to improve the emission performance of Gasoline engine during transient phase, the effect of spark timing retard from MBT on THC emission characteristics is studied by engine test using a Fast response Flame Ionization Detector(FFID). A cyclic analysis of the combustion process shows that high THC emissions are produced first few cycles during the transient phase. This paper presents the results of engine performance and emission of Gasoline engine with various spark timing. consequently, This paper was focused on the combustion phenomena with various spark timing during transient phase which was analyzed by Fast response Flame Ionization Detector (FFID) equipment to measure the cyclic THC emission characteristics.