• 제목/요약/키워드: techniques chain

검색결과 434건 처리시간 0.027초

Molecular Structural Characterization of Properties of Polymethacrylates by Molecular Modeling Techniques

  • Jung, Keun-Yung;Kim, Hyung-Il;Ju-Whan Liu
    • Macromolecular Research
    • /
    • 제8권2호
    • /
    • pp.59-65
    • /
    • 2000
  • We simulated the conformational changes of polymethacrylates which have side chains with different lengths (methyl and butyl) by molecular dynamics simulation technique. Bulk states of atactic amorphous polymers relaxed at a higher temperature were generated. The chain behaviors of polymethacrylates were investigated upon varying temperatures. Molecular structural information was then obtained by characterizing radial distribution function(RDF), mean square displacement, self diffusion constant, and Connolly surfaces, among others. The estimated self diffusion constants and RDF values of PMMA and PBMA were found to be in good agreement with our expectation in view of the chain flexibility.

  • PDF

Bayesian updated correlation length of spatial concrete properties using limited data

  • Criel, Pieterjan;Caspeele, Robby;Taerwe, Luc
    • Computers and Concrete
    • /
    • 제13권5호
    • /
    • pp.659-677
    • /
    • 2014
  • A Bayesian response surface updating procedure is applied in order to update the parameters of the covariance function of a random field for concrete properties based on a limited number of available measurements. Formulas as well as a numerical algorithm are presented in order to update the parameters of response surfaces using Markov Chain Monte Carlo simulations. The parameters of the covariance function are often based on some kind of expert judgment due the lack of sufficient measurement data. However, a Bayesian updating technique enables to estimate the parameters of the covariance function more rigorously and with less ambiguity. Prior information can be incorporated in the form of vague or informative priors. The proposed estimation procedure is evaluated through numerical simulations and compared to the commonly used least square method.

농업경영의 가치사슬 구조에 근거한 지속가능성 연구 (A Sustainability Study Based on Farm Management Value-Chain Structure)

  • 정훈희;김사균;허승욱
    • 농촌지도와개발
    • /
    • 제16권2호
    • /
    • pp.363-384
    • /
    • 2009
  • This study aimed at finding directions for Korean agriculture to establish a new paradigm of sustainable development. Various problematic issues and concerns in the environment necessitate the transformation of Korea's development paradigm from unconditional growth to "Green Growth" through new policies on green value and review of various advanced researches. In this research, the environment-friendly agriculture's problems, particularly in agribusiness were analyzed. Drawing from Michael Porter's Value Chain Analysis, this research developed a value chain model in agriculture that reflects the environment and the present situations. Future directions in the agriculture sector were also discussed. Korea realized food self-sufficiency through the green revolution in the early 1970s. However, a lot of problems have also occurred, including ground and water pollution and the destruction of ecosystems as a result of the overuse of pesticides and chemical fertilizers. In the late 1970s, the growing interest on environment-friendly agriculture led to the introduction of sustainable methods and techniques. Unfortunately however, these were not innovative enough to foster environment-friendly agriculture. Thereafter, the consumers' distrust on agricultural products has worsened and concerns about health have increased. In view of this, the Ministry of Food, Agriculture, Forestry and Fisheries introduced in December 1993 a system of Quality-Certified Products for organic and pesticide-free agri-foods. Although a fundamental step toward the sustainability of the global environment, this system was not enough to promote environment-friendly agriculture. In 2008, Korea's vision is for "Low Carbon Green Growth" to move forward while also coping with climate change. But primary sectors in a typical value chain do not consider the green value of their operations nor look at production from an environmental perspective. In order to attain sustainable development, there is a need to use less resources and energy than what is presently used in Korean agricultural and value production. The typical value chain should be transformed into a "closed-loop" such that the beginning and the end of the chain are linked together. Such structure allows the flow of materials, products and even wastes among participants in the chain in a sustained cycle. This may result in a zero-waste sustainable production without destroying the ecosystem.

  • PDF

결핵진단의 면역학적 및 분자생물학적 방법 (Diagnosis of Tuberculosis; Serodiagnosis and Molecular Biologic Approach)

  • 신완식
    • Tuberculosis and Respiratory Diseases
    • /
    • 제39권1호
    • /
    • pp.1-6
    • /
    • 1992
  • The diagnosis of tuberculosis is usually established using staining and culturing techniques. Fluorescent stains have improved the sensitivity of direct microscopy. Improved culture media coupled with radiometric means of detecting early mycobacterial growth have shortened the time needed for cultural diagnosis. Rapid immunodiagnostic techniques based on the detection of mycobacterial antigen or of antibodies to theses antigens have not, however, come into widespread clinical use. The DNA or RNA hybridization tests with labeled specific probes which have been described so far are not sensitive enough to be used for clinical speicimens without prior culturing. The advent of the polymerase chain reaction (PCR) has opened new possibilities for diagnosis of microbial infections. This technique has already been applied to a number of microorganisms. In the field of mycobacteria the PCR has been used to identify and to detect DNAs extracted from various mycobacteria. However, despite the extraordinary enthusiasm surrounding this technique and the considerable investiment, PCR has not emerged from the developmental "trenches" in the passed several years. It may be a considerable lenth of time before clinical microbiology laboratories become PCR playgrounds because many details remain to be worked out.

  • PDF

Geostatistics for Bayesian interpretation of geophysical data

  • Oh Seokhoon;Lee Duk Kee;Yang Junmo;Youn Yong-Hoon
    • 한국지구물리탐사학회:학술대회논문집
    • /
    • 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
    • /
    • pp.340-343
    • /
    • 2003
  • This study presents a practical procedure for the Bayesian inversion of geophysical data by Markov chain Monte Carlo (MCMC) sampling and geostatistics. We have applied geostatistical techniques for the acquisition of prior model information, and then the MCMC method was adopted to infer the characteristics of the marginal distributions of model parameters. For the Bayesian inversion of dipole-dipole array resistivity data, we have used the indicator kriging and simulation techniques to generate cumulative density functions from Schlumberger array resistivity data and well logging data, and obtained prior information by cokriging and simulations from covariogram models. The indicator approach makes it possible to incorporate non-parametric information into the probabilistic density function. We have also adopted the MCMC approach, based on Gibbs sampling, to examine the characteristics of a posteriori probability density function and the marginal distribution of each parameter. This approach provides an effective way to treat Bayesian inversion of geophysical data and reduce the non-uniqueness by incorporating various prior information.

  • PDF

고분자량 점도지수향상제가 첨가된 오일의 음향점도 특성 (Acoustic Viscosity Characteristics of Oils with High Molecular Weight VI Improver Additives)

  • 공호성;;한흥구
    • Tribology and Lubricants
    • /
    • 제25권4호
    • /
    • pp.236-242
    • /
    • 2009
  • Oil viscosity is one of the important parameters for machinery condition monitoring. Basically, it is expressed as kinematic viscosity measured by capillary flow and dynamic or absolute viscosity measured by rotary shear viscometry. Recently, acoustic wave techniques appear in the market, measuring viscosity as the product of dynamic viscosity and density. For Newtonian fluids, knowledge of density allows conversion from one viscosity parameter to the other at a specific shear rate and temperature. In this work, oil samples with different chain lengths of viscosity index (VI) improvers and concentrations were examined by different viscometric techniques. Results showed that acoustic viscosity measurements give misleading results for oil samples with high molecular weight VI improvers and at low temperatures ${\leq}40^{\circ}C$.

Poly(n-butyl methacrylate)의 열분해에 관한 연구 (Study on the Thermal Degradation of Poly(n-bulyl methacrylate))

  • 곽기철;설수덕;손진언
    • Elastomers and Composites
    • /
    • 제23권3호
    • /
    • pp.213-222
    • /
    • 1988
  • The thermal decomposition of poly(n-butyl methacrylate)(Pn-BMA) was studied using a dynamic and isothermal thermogravimetry in nitrogen gas with 50ml/min at several heating rates from 1 to $20^{\circ}C/min$, and at several heating temperature from 320 to $370^{\circ}C$. The mathematical techniques used for calculation of activation energy were Kissinger, Anderson, Chatterjee-Conrad, Friedman, Fuoss, Ozawa and isolthermal method. The range of activation energies obtained using the several techniques was between 43 and 51Kcal/mol except Chatterjee-Conrad and this range agreed with each other very well. The thermal degradation of Pn-BMA was considered to be carried out by main chain scission.

  • PDF

Current Status and Scope of Lymph Node Micrometastasis in Gastric Cancer

  • Lee, Chang Min;Park, Sung-Soo;Kim, Jong-Han
    • Journal of Gastric Cancer
    • /
    • 제15권1호
    • /
    • pp.1-9
    • /
    • 2015
  • Recently, lymph node micrometastasis has been evaluated for its prognostic value in gastric cancer. Lymph node micrometastasis cannot be detected via a usual pathologic examination, but it can be detected by using some other techniques including immunohistochemistry and reverse transcription-polymerase chain reaction assay. With the development of such diagnostic techniques, the detection rate of lymph node micrometastasis is constantly increasing. Although the prognostic value of lymph node micrometastasis remains debatable, its clinical impact is apparently remarkable in both early and advanced gastric cancer. At present, studies on the prognostic value of lymph node micrometastasis are evolving to overcome its current limitations and extend the scope of its application.

Performance Evaluation of the VoIP Services of the Cognitive Radio System, Based on DTMC

  • Habiba, Ummy;Islam, Md. Imdadul;Amin, M.R.
    • Journal of Information Processing Systems
    • /
    • 제10권1호
    • /
    • pp.119-131
    • /
    • 2014
  • In recent literature on traffic scheduling, the combination of the two-dimensional discrete-time Markov chain (DTMC) and the Markov modulated Poisson process (MMPP) is used to analyze the capacity of VoIP traffic in the cognitive radio system. The performance of the cognitive radio system solely depends on the accuracy of spectrum sensing techniques, the minimization of false alarms, and the scheduling of traffic channels. In this paper, we only emphasize the scheduling of traffic channels (i.e., traffic handling techniques for the primary user [PU] and the secondary user [SU]). We consider the following three different traffic models: the cross-layer analytical model, M/G/1(m) traffic, and the IEEE 802.16e/m scheduling approach to evaluate the performance of the VoIP services of the cognitive radio system from the context of blocking probability and throughput.

MOLECULAR BASIS OF LUBRICATION

  • Hsu, S.M.
    • 한국윤활학회:학술대회논문집
    • /
    • 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
    • /
    • pp.49-50
    • /
    • 2002
  • Rapid advancements in analytical instrumentations and techniques in the last several decades offer an unprecedented opportunity to analyze the complex chemistry and probe the surfaces for chemical evidence. Recent developments in nanotechnology provide further ability to examine phenomena and mechanisms at the nanometer level. As a result of these advances, our understanding of the complex lubrication system has improved significantly. This paper will attempt to provide a molecular basis of how lubricant and additives function in lubrication.

  • PDF