• Title/Summary/Keyword: tCR

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Synthesis and Quality of Cr-doped AIN Thin Films Grown by RF Sputtering

  • Quang, Pham Hong;Hung, Tran Quang;Dai, Ngo Xuan;Thanh, Tran Hoai;Kim, Cheol-Gi
    • Journal of Magnetics
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    • v.12 no.4
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    • pp.149-151
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    • 2007
  • The AlCrN films were grown by RF reactive sputtering method under the selected conditions. The Cr concentration was varied by the number of Cr pieces placed on the Al target. The sample quality has been studied by XRD, Auger spectroscopy, optical absorption and electrical resistant measurements. The XRD and Auger results show that the samples consist of a major phase with the $Al_{1-x}Cr_xN$ formula, which has a hexagonal structure, and a few percents at. of oxygen, which may form $Al_2O_3$. There exist the Cr clusters in the samples with high concentration of Cr. The optical absorption measurement provides the information about the band gap that relates strongly to the quality of samples. The quality of samples is also clearly reflected in electrical measurement, i.e., the temperature dependence of resistance exhibits a semiconductor characteristic only for the samples that have no Cr cluster. In these cases, the values of ionization energies $E_a$ can be derived from R(T) plots by using the function R(T) = Ro exp $(E_a/k_BT)$.

The Study of Hyperfine Fields for Co0.9Zn0.1Cr1.9857Fe0.02O4 (Co0.9Zn0.1Cr1.9857Fe0.02O4 물질의 초미세자기장 연구)

  • Choi, Kang-Ryong;Kim, Sam-Jin;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.18 no.1
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    • pp.39-42
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    • 2008
  • [ $AB_2X_4$ ](A, B=Transition Metal, X=O, S, Se) are cubic spinel normal ferrimagnets, in which M ions occupy the tetrahedral sites and Cr ions occupy the octahedral sites. Recently, they have been investigated for behaviour of B site ions and A-B interaction. Polycrystalline $[Co_{0.9}Zn_{0.1}]_A[Cr_{1.98}{^{57}Fe_{0.02}}]_BO_4$ compound was prepared by wet-chemical process. The ferrimagnetic transition was observed around 90K. $M\"{o}ssbauer$ absorption spectra at 4.2K show that the well-developed two sextets are superposed with small difference in hyperfine fields($H_{hf}$). The hyperfine fields of $CoCr_{1.98}{^{57}Fe_{0.02}}O_4$ and $Co_{0.9}Zn_{0.1}Cr_{1.98}{^{57}Fe_{0.02}}O_4$ were determined to be 488, 478 kOe and 486, 468 kOe, respectively. We notice that the one of the magnetic hyperfine field values changes with Zn ion substitution. These results suggest the incommensurate states and spin-reorientation temperature($T_S=18K$) changes with Zn ions substitution below spin-reorientation temperature($T_S=28K$) of $CoCr_{1.98}{^{57}Fe_{0.02}}O_4$

Supplmentation of the Mineral and Surfactant for Replacement of Antibiotics for Ruminant Aninmal (천연물질을 이용한 반추동물 항생제 대체용 미량광물질 및 천연유화제의 이용)

  • Lee, Su-Rok;Kim, Sam-Churl;Choi, Nag-Jin
    • Korean Journal of Organic Agriculture
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    • v.24 no.2
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    • pp.263-272
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    • 2016
  • The present study investigated the effect of inclusion of chromium propionate (Cr-P) and lysophopholipid (LPL) in diet on blood parameters and meat quality of Hanwoo steer. Feeding trial was performed from late fattening period to slaughter and blood parameters (insulin, blood glucose and non-esterified fatty acid (NEFA) concentration) and meat quality were examined. Total 4 experimental groups including control (no addition), T1 (Cr-P 0.2%), T2 (LPL 0.2%) and T3 (Cr-P 0.1% + LPL 0.1%) were employed. For blood parameters, insulin concentration in T1 and T3 showed an elevating patterns from $3.13{\mu}U/mL$ to $3.35{\mu}U/mL$ (T1) and from $4.38{\mu}U/mL$ to $5.23{\mu}U/mL$ (T3). The changes of NEFA in all groups were detected as a decreasing patterns according to days of feeding. However, significant difference was not found. In growth performance, T2 showed greater daily gain and T1 showed greater carcass yield compared to others. However, there were no significance in difference. In meat quality, T1 showed greater yield and intra-muscular fat levels and lower sharing force compared to others. However, significant differences were not detected.

Effect of Solidified/Stabilized Sewage Sludge using Neutral Solidifying Chemical Agent and Alkaline Agent as Landfill Cover on Decomposition of Organic Matter in Lysimeter (중성계 및 알칼리성 고화재를 이용한 고화하수슬러지의 복토재가 모형매립조 내 유기물 분해에 미치는 영향)

  • Kim, Hye-Jin;Park, Jin-Kyu;Song, Sang-Hoon;Lee, Nam-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.8
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    • pp.768-774
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    • 2008
  • To evaluate the effect of the solidified/stabilized sewage sludge on landfill sites, lysimeter tests were conducted. Lysimeters (LR1, LR2, and LR3) were filled with the material(Compost : Fodder : Sand = 10 : 10 : 80) and covered with different types of the cover soils, the G solidified sludge produced from the neutral solidifying chemical agent(LR1), the A solidified sludge produced from the alkali solidifying chemical agent(LR2), and the weathered granite soil(LR3). Those lysimeters were kept at the temperature controlled room with 30 $\pm$ 2$^{\circ}C$ for about 450 days. As the results, it was appeared LR2 > LR1 > LR3 that total gas production rate(L), gas production rate(L/VS(kg)) and cumulative gas(CO$_2$ + CH$_4$) production. There were not significant differences at decrease of the COD$_{Cr}$ in the leachate from LR1 and LR3. Thus, it had been shown that the use of the G solidified sludge as cover soil did not affect the COD$_{Cr}$ in the leachate. The COD$_{Cr}$ from LR2 had been increased since around 250 days because solidified/stabilized sewage sludge became re-slurry. T-N and T-P from LR3 also were higher than LR1 and LR2. Also were, the use of the solidified/stabilized sewage sludge as a cover soil, therefore, did not affect the T-N and T-Pconcentrations in the leachate.

The Magnetic Characteristics of Co-Cr Thin Films Deposited by Facing Targets Sputtering (대향타겟식 스퍼터로 제작된 Co-Cr 박막의 자기적 특성)

  • Kim, K.H.;Son, I.H.;Kim, M.H.;Kim, J.H.;Nakagawa, S.;Naoe, M.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1320-1322
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    • 1997
  • The distribution of coercivity in the thickness direction were investigated by using Kerr hysteresis loop tracer for the Co-Cr films deposited by Facing Targets Sputtering apparatus. It $H_{c{\bot}}(S)- H_{c{\bot}}(I)$ correlated strongly with ${\Delta}H_c$, which represents the degree of distribution of coercivity. Furthermore, the Cr content was varied in order to improve the coercivity of intial growth layer $H_{c{\bot}}(I)$ took a maximum value of 750 Oe and the distribution of coercivity became sharper at the Cr content of 25 at.%.

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Study on the Measurement of $^{51}Cr-tagged$ Red Cell Survival - Reevaluation of its method & the effect of Blood loss on red cell suruival with $^{51}Cr$ - (방사성동위원소(放射性同位元素) $^{51}Cr$을 이용(利用)한 적혈구수명(赤血球壽命) 측정(測定)에 관(關)한 고찰(考察) -$^{51}Cr$-적혈구수명(赤血球壽命) 측정법(測定法)의 재평가(再評價)와 실혈(失血)이 수명측정(壽命測定)에 미치는 영향(影響)에 관(關)한 연구(硏究))

  • Choi, Hak-Yong;Koh, Chang-Soon;Lee, Moon-Ho
    • The Korean Journal of Nuclear Medicine
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    • v.4 no.2
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    • pp.55-66
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    • 1970
  • Reappraisal measurements of apparent half survival time of red cell by $^{51}Cr$ method was made and effects of blood-letting over red cell survival were observed. The study was performed on 53 normal male subjects under three different experimental conditions. 1. Group 1 Mean $^{51}Cr$ red cell half survival by ACD wash method was 29.7 days. $T\frac{1}{2}$ of Ascorbic acid method was 29.0 days in group with 100 mg dose and 29.1 days in group with 50 mg dose respectively. There was no difference between these two methods in regards to red cell half survival. No difference were noted in amount of ascorbic acid administered. 2. Group 2 As daily amount of blood loss is increased the shortening of red cell half survival was noted. Rapid phase was seen when blood loss ranged 10 to 25 ml per day, while slow phase noted when more loss amounted 25 ml or more daily. Thus, it was clear that there was more than an exponential relation between $T\frac{1}{2}$ and the amount of blood loss. 3. Group 3 $T\frac{1}{2}$ measured by cpm per whole blood was within normal range and $T\frac{1}{2}$ measured by cpm per red cell mass showed shortening tendency when compared with the former in the group measured after blood loss (from 25 ml daily up to 100 ml daily in 10 days). In the group with rather constant blood loss of 100 ml daily for 10 consecutive days revealed the significant difference in two measurements (P<0.01). 4. $T\frac{1}{2}$ in non-steady state When red cell production is increased compared with red cell destruction, $T\frac{1}{2}$ measured by cpm per red cell mass being shorter than that by cpm per whole blood. Shortening of $T\frac{1}{2}$ measured by cpm per whole blood is more prominent. if red cell destrction is enhanced and exceeds production. 5. It is clear that when expressing red cell destruction rate, $T\frac{1}{2}$ measured by cpm per whole blood is more adequate and production more consistent with cpm red cell mass. 6. $T\frac{1}{2}$ measured during blood-letting, when corrected by amount of blood loss, it remains normal. It is erroneous to use conventional equational when measuring $T\frac{1}{2}$ in non-steady. $T\frac{1}{2}$ measured by cpm per whole blood is considred more applicable in clinical evaluation.

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Clinical Applications of 3T MR Spectroscopy

  • Choe, Bo-Young;Baik, Hyun-Man;Chu, Myung-Ja;Jeun, Sin-Soo;Kang, Sei-Kwon;Chung, Sung-Taek;Park, Chi-Bong;Oh, Chang-Hyun;Lee, Hyoung-Koo
    • Proceedings of the Korean Society of Medical Physics Conference
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    • 2002.09a
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    • pp.345-351
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    • 2002
  • The purpose of this study was to assess clinical proton MR spectroscopy (MRS) as a noninvasive method for evaluating brain tumor malignancy at 3T high field system. Using 3T MRI/MRS system, localized water-suppressed single-voxe1 technique in patients with brain tumors was employed to evaluate spectra with peaks of N-acetyl aspartate (NAA), choline-containing compounds (Cho), creatine/phosphocreatine (Cr) and lactate. On the basis of Cr, these peak areas were quantificated as a relative ratio. The variation of metabolites measurements of the designated region in 10 normal volunteers was less than 10%. Normal ranges of NAA/Cr and Cho/Cr ratios were 1.67${\pm}$018 and 1.16${\pm}$0.15, respectively. NAA/Cr ratio of all tumor tissues was significantly lower than that of the normal tissues (p=0.005), but Cho/Cr ratio of all tumor tissue was significantly higher (p=0.001). Cho/Cr ratio of high-grade gliomas was significantly higher than that of low-grade gliomas (P=0.001). Except 4 menigiomas, lactate signal was observed in all tumor cases. The present study demonstrated that the neuronal degradation or loss was observed in all tumor tissues. Higher grade of brain tumors was correlated with higher Cho/Cr ratio, indicating a significant dependence of Cho levels on malignancy of gliomas. Our results suggest that clinical proton MR spectroscopy could be useful to predict tumor malignancy.

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Evaluation of biological treatment of cutting-oil wastes using sequencing batch reactor (SBR) process (연속 회분식 반응조 (SBR) 공정을 이용한 폐절삭유의 생물학적 처리능 평가)

  • Baek, Byung-Do;Kim, Chang-Seop;Kim, Jun-Young;Chang, In-Soung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.7
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    • pp.1654-1660
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    • 2009
  • Two different cutting-oils from H and B companies which are sold as an eco-friendly cutting-oils were selected and the biodegradability of these commercially available cutting-oils was evaluated by the sequencing batch reactor (SBR) processes. The cutting-oil wastes ($H_1$) pre-treated by coagulation/flocculation was used as an influent to SBR. When the F/M ratio was operated 0.04 to 0.08kgCOD/kgMLSS d, removals of $BOD_5$and $COD_{Cr}$were above 97% and 91%, respectively. T-N and T-P removals were above 76% and 81%, respectively. If the diluted cutting-oil wastes ($B_1$) was used as an influent of the SBR, $COD_{Cr}$removals were above 77% at the F/M ratio of 0.01-0.02kgCOD/kgMLSS d. After the cutting-oil wastes was treated by coagulation/ flocculation ($B_2$), $COD_{Cr}$removals was above 85%. If the pre-treated cutting-oil wastes were mixed with a synthetic wastewater ($B_3$) and fed into the SBR in order to mimic the real wastewater treatment plant situation, $BOD_5$and $COD_{Cr}$removals were above 97%, 91%, respectively. T-N and T-P removals were above 79% and 76%. The ratio between $BOD_5$and $COD_{Cr}$, ($COD_{Cr}$-$BOD_5$)/$COD_{Cr}$, indicating the biodegradability of effluent of the SBR, was calculated to 85% and 61%. This means that significant amounts of non-readily-biodegradable organic compounds in the effluent of $H_1$, $B_3$are still present.

The Effect of Sputtering Conditions on Magnetic Properties of CoCrMo/Cr Magnetic Thin Film (CoCrMo/Cr 자성박막의 제조조건이 자기적성질에 미치는 영향)

  • 박정용;남인탁;홍양기
    • Journal of the Korean Magnetics Society
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    • v.3 no.4
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    • pp.320-324
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    • 1993
  • The effect of sputtering conditions on magnetic properties of CoCrMo/Cr magnetic thin film was investigated. Substrate temperature were controlled from R. T to $250^{\circ}C$. The thickness changes of Cr underlayer and CoCrMo magnetic layer were in the range of $1000-2500\AA$ and $300-800\AA$, respectively. Grain size was found to be decreased with increasing magnetic layer thickness(from $500\AA$ to $800\AA$). CoCrMo magnetic layer microstructure showed relatively small dependence on Cr underlayer thickness, substrate temperature. Coercivity increased with increasing Cr underlayer, magnetic layer thickness and substrate temperature. CoCrMo/Cr thin film showed a coercivity of 880 Oe in $700\AA$ magnetic layer thickness and $1000\AA$ Cr underalyer thickness.

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Crystallinity of CrOx/TiO2 Catalysts and Their Activity in TCE Oxidation (CrOx/TiO2 촉매의 결정성과 TCE 산화반응 활성)

  • Kim, Moon-Hyeon;Lee, Hyo-Sang
    • Journal of Environmental Science International
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    • v.23 no.5
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    • pp.829-837
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    • 2014
  • Titania-supported chromium oxides with different loadings have been embarked in catalytic oxidation of trichloroethylene (TCE) to inquire association of the formation of crystalline $Cr_2O_3$ with catalytic performances. A better activity in the oxidative TCE decomposition at chosen temperatures was represented when chromium oxides ($CrO_x$) had been dispersed on pure anatase-type $TiO_2$ (DT51D) rather than on phase-mixed and sulfur-contained ones such as P25 and DT51. The extent of TCE oxidation at temperatures below $350^{\circ}C$ was a strong function of $CrO_x$ content in $CrO_x$/DT51D $TiO_2$, and a noticeable point was that the catalyst has two optimal $CrO_x$ loadings in which the lowest $T_{50}$ and $T_{90}$ values were measured for the TCE oxidation. This behavior in the activity with respect to $CrO_x$ amounts could be associated with the formation of crystalline $Cr_2O_3$ on the support surface, that is less active for the oxidation reaction, and an easier mobility of the surface oxygen existing in noncrystalline $CrO_x$ species with higher oxidation states, such as $Cr_2O_8$ and $CrO_3$.