• Title/Summary/Keyword: system decomposition

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Noninteracting Feedbeck Control of Multivariable Nonlinear Systems (다변수 비선형시스템의 noninteracting 되먹임 제어)

  • 하인중;고명삼
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.36 no.7
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    • pp.501-513
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    • 1987
  • Conditions for achieving noninteraction in nonlinear multivariable systems via the decomposition of state space are well established. The main contribution of this paper is to fully characterize the class of decomposing control laws. The characterization corresponds to a family of simple control laws which are applied to a standard decomposed system(SDS). The SDS is similar to the decomposed systems of Isidori, Krener, Gori-Giorgi, and Monaco but has a finer structure. The finer structure parallels the one used by Gilbert for linear systems. A weaker form of noninteraction, based on input-output behaviour, is decoupling. Some connections between decomposition and decoupling are also established. An example illustrating the importance of the results is given.

A Study on the Decomposition Rate of Phenol in the Batch Type Ozonation (회분식 오존 공정에서 페놀의 분해 속도에 관한 연구)

  • 안재동;강동수
    • Journal of Environmental Health Sciences
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    • v.23 no.4
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    • pp.127-132
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    • 1997
  • The characteristics of the ozone treatments of phenol were studied in a laboratory scale wastewater treatment system. The ozone treatment of wastewater was carried out in a batch-type reactor. The initial pH of wastewater(7-10), volumetric flow rate(1-2l/min) and ozone concentration(20~30 mg/l) of aerating gas were considereal as experimental variables in the ozone treatment. Phenol was decomposed easily by the ozone in a batch treatment, where the rate determining step was the COD removal that is decomposition of intermediates formed by the ozonation of phenol. Phenol decomposition and COD removal could be expressed by the first order reaction for the phenol concentration and COD, respectively. Rate constants of phenol decomposition and COD removal increased with the initial pH, volumetric flow rate and ozone concentration of aeration gas. Under the present experimental condition, their relationships could be given by for the phenol decomposition $k'=4.46\times 10^{-9}[pH]_o ^{3.94}[O_3]^{1.42}Q_{O3}^{1.57}$ for the COD removal $k=2.46\times 10^{-10}[pH]_o ^{5.19}[O_3]^{1.15}Q_{O3}^{1.19}$

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A Study on the Thermal Decomposition Characteristics of Nitrophenylhydrazine (니트로페닐하이드라진의 열분해 특성에 관한 연구)

  • 김관응;이근원
    • Journal of the Korean Society of Safety
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    • v.16 no.2
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    • pp.75-79
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    • 2001
  • For handling and storage of reactive chemicals, the hazard evaluations have been extremely important. In the chemical industry, the most concerns are focused on the thermal harzards such as runaway reactions and thermal decompositions, which are mostly governed by thermodynamics and reaction kinetics or these reactive chemical in the system. This study no investigated the thermal decomposition characteristics of nitrophenylhydrazine isomers by using differential scanning calorimeter(DSC) and accelerating rate calorimeter(ARC). Experimental results showed that exothermic onset-temperatures in nitrophenylhydrazine(NPH) isomers were about 160-$210^{\circ}C$ by DSC and 100-$150^{\circ}C$ by ARC. The decomposition temperature acquired by ARC was about 50-$60^{\circ}C$ lower than that by DSC. Reaction heats were about 40-100cal/g by DSC and 330-750ca1/g by ARC. While ortho isomer of NPH show two distinct exothermic peaks, para isomer shows a single peak in DSC curves. The first exothermic peak for 2-NPH is mainly due to intramolecular dehydration forming 1-hydroxybenzotriazole(HOBT) and the second exothermic peak is mainly due to the decomposition of HOBT formed in the first step of decomposition. The exothermin peak in the DSC curve for 4-NPH is mainly due to dissociation of hydrazino and nitro groups.

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A Study on the Condition Diagnosis for A Gas-insulated Transformer using Decomposition Gas Analysis (가스분해 분석기법을 활용한 가스 전열 변압기의 상태 진단 연구)

  • Ah-Reum, Kim;Byeong Sub, Kwak;Tae-Hyun, Jun;Hyun-joo, Park
    • KEPCO Journal on Electric Power and Energy
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    • v.8 no.2
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    • pp.119-126
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    • 2022
  • A growing number of gas-insulated transformers in underground power substations in urban areas are approaching 20 years of operation, the time when failures begin to occur. It is thus essential to prevent failure through accurate condition diagnosis of the given facility. Various solid insulation materials exist inside of the transformers, and the generated decomposition gas may differ for each gas-insulated equipment. In this study, a simulation system was designed to analyze the deterioration characteristics of SF6 decomposition gas and insulation materials under the conditions of partial discharge and thermal fault for diagnosis of gas-insulated transformers. Degradation characteristics of the insulation materials was determined using an automatic viscometer and FT-IR. The analysis results showed that the pattern of decomposition gas generation under partial discharge and thermal fault was different. In particular, acetaldehyde was detected under a thermal fault in all types of insulation, but not under partial discharge or an arc condition. In addition, in the case of insulation materials, deterioration of the insulation itself rapidly progressed as the experimental temperature increased. It was confirmed that it was possible to diagnose the internal discharge or thermal fault occurrence of the transformer through the ratio and type of decomposition gas generated in the gas-insulated transformer.

Optimization of Ammonia Decomposition and Hydrogen Purification Process Focusing on Ammonia Decomposition Rate (암모니아 반응기의 분해 효율 최적화를 통한 암모니아 분해 및 수소 정제 공정 모델 연구)

  • DAEMYEONG CHO;JONGHWA PARK;DONSANG YU
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.6
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    • pp.594-600
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    • 2023
  • In this study, a process model and optimization design direction for a hydrogen production plant through ammonia decomposition are presented. If the reactor decomposition rate is designed to approach 100%, the amount of catalyst increases and the devices that make up the entire system also have a large design capacity. However, if the characteristics of the hydrogen regeneration process are reflected in the design of the reactor, it becomes possible to satisfy the total flow rate of fuel gas with the discharged tail gas flow rate. Analyzing the plant process simulation results, it was confirmed that when an appropriate decomposition rate is maintained in the reactor, the phenomenon of excess or shortage of fuel gas disappears. In addition, it became possible to reduce the amount of catalyst required and design the optimized capacity of the relevant processes.

Development of Membrane Strip Assay System for Lipoprotein Cholesterol Based on Liquid-Phase Enzyme Reactions (액상 효소반응을 이용한 Membrane Strip 형 Cholesterol 측정시스템의 개발)

  • 신인수;목락선;장미라;백세환
    • KSBB Journal
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    • v.13 no.5
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    • pp.577-584
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    • 1998
  • A sensitive membrane strip assay for plasma lipoprotein cholesterol that can be performed without handling reagents has been investigated. We previously developed an assay system with immobilized enzymes (cholesterol esterase and cholesterol oxidase) on the surfaces of nitrocellulose membrane(1). In such a case, the amount of enzymes present on the membrane was limited by its surface area and, thus, the detection capability was relatively poor (> 50 mg/dL cholesterol). To overcome this problem, we devised a new system with non-immobilized enzymes by placing them within interstitial spaces of a celullose membrane pad in a dry state. Upon contact with sample medium, the enzymes were immediately dissolved and participated in the reactions with cholesterol in a liquid phase. We constructed a user-friendly system consisting of four membrane pads fro sample application, cholesterol decomposition, color development as signal, and medium absorption to invoke a continuous flow (sequential location from the bottom). A sample containing lipoproteins was added into the application pad by capillary action and transferred to the next pad for decomposition. The decomposition pad (namely, enzyme pad) contained a detergent (sodium cholate) for the destruction of lipoprotein particles, the two enzymes for cholesterol decomposition, and a chromogen (3,3'-diaminobenzidine). As a consequence of the enzyme reactions, hydrogen peroxide was produced, and then reacted in the presence of the chromogen with horseradish peroxidase immobilized on the signal generation pad. Finally, a colorimetric signal directly proportional to the cholesterol concentration was produced. The detection limit determined from this system under optimal conditions was at least 2 times lower than of the enzyme-immobilized system.

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Mechanically Driven Decomposition of Intermetallics

  • Kwon, Young-Soon;Kim, Hyun-Sik;Gerasimov, Konstantin B.
    • Journal of Powder Materials
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    • v.9 no.6
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    • pp.422-432
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    • 2002
  • Mechanically driven decomposition of intermetallics during mechanical milling(MM 1 was investigated. This process for Fe-Ce and Fe-Sn system was studied using conventional XRD, DSC, magnetization and alternative current susceptibility measurements. Mechanical alloying and milling form products of the following composition (in sequence of increasing Gecontent): $\alpha$(${\alpha}_1$) bcc solid solution, $\alpha$+$\beta$-phase ($Fe_{2-x}Ge$), $\beta$-phase, $\beta$+FeGe(B20), FeGE(B20), FeGe(B20)+$FeGe_2$,$FeGe_2$,$FeGe_2$+Ge, Ge. Incongruently melting intermetallics $Fe_6Ge_5$ and $Fe_2Ge_3$ decompose under milling. $Fe_6Ge_5$ produces mixture of $\hat{a}$-phase and FeGe(B20), $Fe_2Ge_3$ produces mixture of FeGe(B20) and $FeGe_2$ phases. These facts are in good agreement with the model that implies local melting as a mechanism of new phase for-mation during medchanical alloying. Stability of FeGe(B20) phase, which is also incongruently melting compound, is explained as a result of highest density of this phase in Fe-Ge system. Under mechanical milling (MM) in planetary ball mill, FeSn intermetallic decomposes with formation $Fe_5Sn_3$ and $FeSn_2$ phases, which have the biggest density among the phases of Fe-Sn system. If decomposition degree of FeSn is relatively small(<60%), milled powder shows superparamagnetic behavior at room temperature. For this case, magnetization curves can be fitted by superposition of two Langevin functions. particle sizes for ferromagnetic $Fe_5Sn_3$ phase determined from fitting parameters are in good agreement with crystalline sizes determined from XRD data and remiain approximately chageless during MM. The decomposition of FeSn is attributed to the effects of local temperature and local pressure produced by ball collisions.

Wavelet Filter Evaluation for Speech Recognition System (음성인식을 위한 웨이블릿 필터 평가)

  • 김기대;이철희
    • Proceedings of the IEEK Conference
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    • 2000.06d
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    • pp.127-130
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    • 2000
  • In this paper, we explore the possibility to use wavelet decomposition based on modified octave structured 5-level filter banks as a set of features for speech recognition. The HMM (Hidden Markov Model) is used as a recognizer 〔l〕. We compared the performance of the wavelet decomposition with the mel-cepstrum and LPC cepstrum. Experimental results show favorable results.

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A Review on Major Foreign Research Trend of Monomethylhydrazine Reaction for Space Propulsion Part I : Thermal Decomposition Reaction of Monomethylhydrazine (우주추진용 모노메틸하이드라진 반응에 대한 주요 해외연구 동향 조사 Part I : 모노메틸하이드라진의 열분해 반응)

  • Jang, Yohan;Lee, Kyun Ho
    • Journal of Aerospace System Engineering
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    • v.10 no.1
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    • pp.66-73
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    • 2016
  • Space propulsion system produces required thrust for satellites and space launch vehicles by using chemical reactions of a liquid fuel and a liquid oxidizer typically. For example, monomethylhydrazine-dinitrogen tetroxide, liquid hydrogen-liquid oxygen and RP-1-liquid oxygen are conventional combinations of liquid propellants used for the liquid propulsion system. Among several liquid propellants, the monomethylhydrazine is expecially preferred for a satellite fuel due to its better storability in liquid phase during a relatively long mission period under a space environment. Thus, a development importance of a bipropellant system using the monomethylhydrazine fuel is recognized recently as the national space program proceeds on a large scale. The objective of the present study is to review a foreign research trend of a thermal decomposition reaction of monomethyhydrazine to understand a fundamental basis of its chemical reaction to prepare for domestic development in future.

PARAFAC Tensor Reconstruction for Recommender System based on Apache Spark (아파치 스파크에서의 PARAFAC 분해 기반 텐서 재구성을 이용한 추천 시스템)

  • Im, Eo-Jin;Yong, Hwan-Seung
    • Journal of Korea Multimedia Society
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    • v.22 no.4
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    • pp.443-454
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    • 2019
  • In recent years, there has been active research on a recommender system that considers three or more inputs in addition to users and goods, making it a multi-dimensional array, also known as a tensor. The main issue with using tensor is that there are a lot of missing values, making it sparse. In order to solve this, the tensor can be shrunk using the tensor decomposition algorithm into a lower dimensional array called a factor matrix. Then, the tensor is reconstructed by calculating factor matrices to fill original empty cells with predicted values. This is called tensor reconstruction. In this paper, we propose a user-based Top-K recommender system by normalized PARAFAC tensor reconstruction. This method involves factorization of a tensor into factor matrices and reconstructs the tensor again. Before decomposition, the original tensor is normalized based on each dimension to reduce overfitting. Using the real world dataset, this paper shows the processing of a large amount of data and implements a recommender system based on Apache Spark. In addition, this study has confirmed that the recommender performance is improved through normalization of the tensor.