• 한국염색가공학회지
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• 제3권2호
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• pp.16-24
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• 1991

The textile fabric have the functions of sanitation, decoration, wearing style and washing in the practical use. Among various texitle fiber, silk has less utilities than synthetic fiber in practical use although silk has good benefits of the high quality. Thus no textile fiber, neither natural nor synthetic, has all the functions. In this sence, many blend yarns have been improved various functions of fabric. However, this has been disturbed with the problem of dyeing, especially in the case of blend fabric of silk. In this study, we dyed silk/PET blend fabric in one step useing one bath dyeing method by acid dyes/disperse dyes. The results of the experiments can be summarized as follows; 1) Yellow index of silk fabric treated at $130^{\circ}C$ increased about 7.8 (color difference 4.5 NBS) and whiteness decrease about 5%. 2) Both elongation and tensile strength of silk fabric treated at $130^{\circ}C$ of pH 5-6 decreased about 10% and tensile strength of silk spun yarn treated at $60^{\circ}C$ of pH 10 have little changed. 3) While silk/PET blend frbric dyeing, silk soiling of disperse dyes causes from difference of dyeing rate and degree of silk soiling with dyes. 4) Fastness and soiling of silk/PET blend fabric dyed by one bath dyeing method of acid dyes/disperse dyes was same as two bath dyeing method.

• 한국전기전자재료학회논문지
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• 제29권1호
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• pp.35-39
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• 2016

In this research, we focused on the improvement of cy3 dye's characteristics for LCD color filter. Solubility and thermal stability are main characteristics of dyes for LCD color filter. We performed experiment to change counter cation of cy3 dyes with alkoxy substituent for these purposes. These cy3 dyes (1b~5b) were prepared through the synthetic procedure of three steps. The synthesized new cy3 dyes were charaterized by using NMR, FT-IR, UV/Vis spectroscopy, and TGA. These cy3 dyes showed purple color and maximum absorption wavelength (${\lambda}_{max}$) in the range of 578~590 nm in UV/Vis spectrum. We confirmed that solubility and thermal stability of cy3 dyes were dependent on the structure of counter cation. Cy3 dyes with alkoxy substituent have good solubility in organic solvents such as dichloromethane, methanol, and acetone. Especially, Cy3 dye with 4-nitrobenzyl counter cation (5b) gave excellent solubility characteristics.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2003년도 봄 학술발표회 논문집
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• pp.214-217
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• 2003

In recent years the focus of research in dye chemistry has largely changed from involvement in the traditional chemistry of dyes and pigments to investigations of functional dyes. With the development of the elcetronics and information industries, the importance of functional dyes has increased. Many research papers have been published concerning new synthetic methods and mechanicsm of functional dyes. Highly functionalized dicyanopyrazine derivatives can be used as fluorescent dyestuffs, emitters for electroluminescent devices tec. (omitted)

• 한국염색가공학회지
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• 제28권2호
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• pp.118-123
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• 2016

The use of natural organic dyes obtained from renewable resources such as plants and trees has the potential for not only preserving petrochemicals but also all-endangered environment for coming next generations. In spite of inferior fastness, natural dyes can be employed in the colouration of natural as well as synthetic fibers. Recently, the potentiality of using natural dyes in colouration with additional UV-protection and antimicrobial properties has been reported. This study is aimed to investigate the effect of Zinc compounds compared to another metallic compounds as mordants on the dyeing properties of natural dye extracted from mulberry leaves and coffee. In this study, the results showed Zinc compounds was expose that is more similar than other mordants in washing fastness through a repeated experiment. Also, Zinc is the environmental impact is less material compared with other mordants, essential edibility minerals ingredient that is necessary in human body.

• 한국염색가공학회지
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• 제15권1호
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• pp.23-29
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• 2003

Dyeings of the most widely used to the synthetic fibers, namely polyamide and polyester, have been carried out using acid dyes and disperse dyes. The above mentioned dye types, and indeed all dyes onto substrates, rely on the reaction properties between the substrates and dye molecules. In terms of fastness properties, however, especially to washings, the satisfactory levels are not present in the results from acid and disperse dyeings. Thus, vat dyeings leaves a feasibility and are an alternative way to overcome the problem. Although attempts and works have been reported in early years, with little if any commercial achievement and success. In this context, to meet increased demands towards a high level of wash fastness from consumers and retailers, an attempt using vat dyes has been carried out in this work.

• 한국염색가공학회지
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• 제12권5호
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• pp.280-287
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• 2000

For thousands of years, dyes were obtained from natural sources, such as plants and animals. Although synthetic dyes have replaced many natural dyes for commercial use but natural dyes with their fascinating color are still used extensively by some people. To investigate the dyeing properties of chestnut bur, which is most widely found in our country, some experiments were performed under the several dyeing conditions with silk and cotton fabrics. It was found that $\lambda_{max}$ of chestnut but extract was 410nm and the color of the fabric dyed is Yellow Red. The K/S value of silk and cotton fabrics increased when the dyeing temperature was higher than $60^\circ{C}$ and the dyeing time was more than 30 minutes. Optimal dyeing pH was between 5 and 6, and repetition of dyeing increased K/S value of the sample fabrics. K/S value of silk fabric dyed with chestnut bur extract was higher than that of cotton. Post-mordanting method showed higher color yield compared with pre-mordanting, and higher temperature and increased time in mordanting increased the dye-uptake.

• Membrane and Water Treatment
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• 제10권5호
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• pp.373-379
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• 2019

One of the real issues of the recent years is water contamination because of harmful synthetic dyes. Liquid Membranes (LM) resemble a promising alternative to the current separation processes, demonstrating various points of interest as far as effectiveness, selectivity, and operational expenses. The improvement of various Liquid Membranes designs has been a matter of examination by few researchers, particularly for the expulsion of dyes from aqueous solutions. The choice of organic surfactants plays an essential role in the efficiency of the dye removal. In LM design, the most significant step towards productivity is the decision of the surfactant type and its concentration. Liquid emulsion membrane (LEM) was used to remove safranin from aqueous solutions in which the emulsion was made with the help of D2EHPA as carrier, kerosene was used as a diluent and Span 80 (Sorbiton monooleate) was used as an emulsifying agent or surfactant. Various sorts of internal stages were utilized, to be specific sulphuric acid and sodium hydroxide. The impact of parameters influencing extraction efficiency such as pH of feed solution, concentrations of surfactant and emulsifying agent in membrane phase, volume ratio of internal phase to membrane phase, internal phase concentration, agitation speed and time of extraction were analyzed.

• 대한화학회지
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• 제50권4호
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• pp.321-327
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• 2006

M78과 일본산 KJ, 2개의 점토를 사용하여 계면활성제 CTMA(M-1, KJ-1), DSDMA(M-2, KJ-2) 그리고 TMSA(M-3, KJ-3)를 이용하여 변성된 점토광물을 합성하였다. 이러한 변성된 점토광물을 사용하여 염색 폐수의 주원인인 염료 중의 하나이며 대구 염색 공단 등에서 많이 사용되고 있는 염료인 acid blue 92와 acid red 1의 흡착 제거 실험을 통해 M-1, M-3, KJ-1 KJ-3의 경우 아주 좋은 흡착능력을 보인다는 결과를 얻었으며 이러한 결과는 점토 M과 KJ의 거의 0%에 가까운 흡착능력과 아주 좋은 비교가 될 수 있을 것이다. 또한 M-1과 KJ-3의 경우에는 이러한 염료 제거율이 거의 100%에 근접해 이러한 변성 점토가 실제 염색공단에서 배출되는 유해성 잔류 유기 염료 성분의 제거 방법으로 사용될 수 있는 충분한 가능성을 보였다고 할 수 있겠다.

• 한국염색가공학회지
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• 제17권6호
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• pp.1-10
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• 2005

Disperse dyes derived from heterocyclic compounds such as phenylindole, pyridone, diaminopyridine, and carbazole have been known to exhibit high light fastness and bathochromic shift compared to the coursponding aminoazobenzene. The synthetic method to obtain diaminopyridine derivatives, which can be used as coupling components, was chlorination of pyridone with phosphorous oxychloride, followed by substitution with various primary amines. Four azo disperse dyes were synthesized by coupling four diaminopyridines with 2-cyano-4-nitroaniline as a diazo component. Structures of these dyes were confirmed by $^1H$ NMR spectroscopy. The wavelengths of maximum absorption of the synthesized disperse dyes were in the range of $517\~528nm$, and molar extinction coefficients were $45,700\~50,100$. The dyeability of four disperse dyes toward PET fiber was generally good. Wash and rubbing fastnesses were excellent, while light and dry heat fastness were good.

• Bulletin of the Korean Chemical Society
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• 제27권10호
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• pp.1567-1571
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• 2006

Synthetic color additives approved for general food use are sixteen in European Union, seven in U. S. A. and twelve in Japan. Twelve food dyes were examined for their inhibitory potency against human protein tyrosine phosphatases (PTPases). Half of the food colorants inhibited PTPases significantly and three of them were potent inhibitors with low micromolar IC50 values. Also examined were the synthetic dyes structurally similar but not allowed in food. Some of them were potent inhibitors of PTPases. Considering the importance of PTPases in cellular signal transduction, inhibition of PTPases by food colorants might cause harmful effects in human health.