• Title/Summary/Keyword: swollen fibers

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Study on Pulp Fibers and Paper Morphology by ESEM and LTSEM

  • Kim, Chul-Hwan;Yang, Jae-Kyung;Park, Chong-Yawl
    • Journal of the Korean Wood Science and Technology
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    • v.29 no.3
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    • pp.73-82
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    • 2001
  • The ESEM could be used in investigating the fibrous networks developed during handsheet-forming processes with the exception of the stages relating to the actual dispersion of the fibers and the drying of formed sheets. Also the cross-sectional images of swollen fibers were generated with the ESEM but the information given by the images was rarely fresh compared to the CLSM images. The LTSEM was extremely useful in generating images of the microfibrillar structure of a wet fiber with great resolution. However, pretreatment required in the LTSEM chamber was somewhat tedious due to the time consumed in sublimation of ice and sputter coating. For observation of lamellar structure of a hydrated fiber, the LTSEM exhibited greatly detailed structure with high resolution. Finally ESEM and LTSEM should be used in a finite field such as observation of surface morphology in detail.

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Alkali-Swollen Structures of Native Cellulose Fibers by X-ray Diffraction Methods (X선회절법(線回折法)에 의한 천연 셀룰로오스 섬유의 알칼리 팽윤구조(膨潤構造))

  • Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.1
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    • pp.38-45
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    • 1992
  • Fine and alkali-swollen structures of native cellulose fibers were investigated by x-ray diffraction methods. The results of fine structures are shown in Table 1. In meridional x-ray diffractograms, the relative intensity ratio R of (002) to (004) for cellulose I was ca. 0.05 and for regenerated cellulose it was ca. 0.45. It was considered that the transformation from cellulose I to cellulose II resulted from the packing or conformational change of cellulose chain. Finally. although cellulose I was not detected in the alkali-swollen celluloses treated for 1 hr to 24 hrs, washing and drying them resulted in the generation of considerable amounts of cellulose I and the amount decreased with increasing alkali duration.

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Swelling and Shrinking Behavior of Lyocell Fibers

  • Donkai, Nobuo;Sasaki, Hiroari;Kasahara, Katsuji
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.17-18
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    • 2003
  • Swelling behaviors of Lyocell and Polynosic fibers are investigated by measuring fiber sizes in ferric sodium tartrate complex (FeTNa) and NaOH solution. They showed an anisotropic swelling behavior, i.e., a large expansion in a radius and small shrinking in a longitudinal direction. Birefringent structure was maintained in Lyocell fibers in the swollen state but not in Polynosic fibers for both solvent systems.

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Alkali-Swollen Morphology of Native Cellulose Fibers

  • Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.2
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    • pp.16-22
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    • 2007
  • The behavior of ramie fibers and some wood elements in the early stage of alkali swelling was examined. When the fibers were treated with alkali solution, they significantly shrank in length and swelled in wall thickness. Ramie fibers showed a shrinkage averaging 23% in length and a swelling averaging 92% in width in 100 seconds treating time. Dimensional changes showed different fashion in each element of woods. The tracheids of latewood especially in Pinus densiflora and Larix kaempferi woods swelled intensively and showed balloon swelling, but in the case of Cryptomeria japonica, it was hardly observed. The swelling morphology of libriform fibers was similar to that of tracheids. The walls of vessel elements and parenchyma cells also swelled considerably in thickness but, no balloon swelling was found in both elements. The differences of swelling in different elements can be interpreted in terms of the differences of organization and/or chemical components of the cell walls.

A Histopathological Observation on the Local Side Reaction following the Intramuscular Injection of Iron Preparations in Guinea pigs (철분근육주사후에 일어나는 국소자극반응에 관한 병리조직학적 관찰)

  • Kim, Soon-Bok
    • Korean Journal of Veterinary Research
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    • v.23 no.2
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    • pp.179-182
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    • 1983
  • This study was conducted to observe the local irritation histopathologically following the intramuscular injection of iron preparations in guinea pigs. Necropsy findings were edema, hemorrhage and darkish brown pigmentation around the injection sites. On the microscopic examination, the muscle fibers near the injection sites became pale staining or uniformly eosinophilic, indicating necrosis of the fibers, which were occasionally filled with granular bluish-staining material. The nuclei were swollen or pyknotic. Infiltrations of heterophils and macrophages containing iron were evident around the necrotized tissues and the injected iron compounds. Fibrosis was often seen between the affected muscle fibers, and this change was considered as secondary inflammatory process.

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Studies on Silk Contraction Treated with Neutral Salts (중성염에 의한 견사의 수축작용)

  • Lee, Gwang-Gil;Lee, Yong-U;Nam, Jung-Hui
    • Journal of Sericultural and Entomological Science
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    • v.39 no.1
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    • pp.44-55
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    • 1997
  • This study was carried out to find out the relationship between qualities and contraction phenomenon of silk fibers by treatment of concentrated neutral salts. The contraction effects of silk fibers showed the critical point on the treatment conditions of concentration, temperature and time, among three kinds of neutral salts such as calcium nitrate, calcium chloride and lithium bromide. But, The silk fibers, pretreated with bromide and/or formaldehyde, did not show the contraction upon treating with calcium nitrate. This indicates that tyrosine and serine can be correlated with the contraction reaction because of coupling these amino acids with bromide and formaldehyde. In conclusion, a mechanism for the contraction of silk fiber with highly concentrated calcium nitrate solution is supposed as follows. At the initial stage of ration, the water was penetrated into the amorphous regions and fibers swollen, therefore, the contraction took place mainly in amorphous regions, which have plenty of functional groups with hydroxyl residues. Then, as the calcium nitrate is penetrated into the microfibril, the gydrogen bonds of tyrosine and serine residues and broken and crystalline regions are more and more influenced by increasing concentration of calcium nitrate solution. Microgibrils of crystalline regions become entangled, contracted to linear direction and rearranged to form new stable hydrogen bonds.

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Effects of Fiber Wall Thickness on Paper Properties Using CLSM (CLSM을 이용한 고해과정 중 섬유벽 두께 변화의 종이 특성 영향 분석)

  • 김서환;박종문;김철환
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.1
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    • pp.39-45
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    • 1999
  • Refining in papermaking plays an important role in changing fiber properties as well as paper properties. The major effects of refining on pulp fibers are internal and external fibrillation, fiber shortening, and fines formation. Many workers showed that internal fibrillation of the primary refining effects was most influential in improving paper properties. In particular, refining produces separation of fiber walls into several lamellae, thus causing fiber wall swelling with water penetration. This leads to the increase of fiber flexibility and of fiber-to-fiber contact during drying. If the fibers are very flexible, they will be drawn into close contact with each other by the force of surface tension as the water is removed during the drainage process and drying stages. In order to study the effect of fiber wall delamination on paper properties, cross-sectional image of fibers in a natural condition had to be generated without distortion. Finally, it was well recognized that confocal laser scanning microscope (CLSM) could be one of the most efficient tool for creating and quantifying fiber wall delamination in combination with image analysis technique. In this study, the CLSM could be used not only to observe morphological features of transverse views of swollen fibers refined under low and high intensity, but also to investigate the sequence of fiber wall delamination and fiber wall breakage. From the CLSM images, increasing the specific energy or refining decreased the degree of fiber collapse, fiber cross-sectional area, fiber wall thickness and lumen area. High intensity refining produced more external fibrillation.

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A Study on the Tension and Slack Mercerization of Cotton Fabrics (견직물의 긴장과 무긴장머어서화 가공에 관한 연구)

  • Chul-Ho, Choi;Chan-Min, Lee
    • Textile Coloration and Finishing
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    • v.2 no.3
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    • pp.51-58
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    • 1990
  • Cotton fabrics were mercerized in ammonia water, sodium hydroxide and mixture of ammonia/sodium hydroxide, slack and under tension. X-ray and infrared spectra analyses were used to measure crystallinity of treated cottons. Changes due to swelling, which took place in the accessible regions were determined by moisture regain and dye adsorption. In addition to that crease recovery was compared mutually, and breaking strength-elongation compared, too. Both ammonia water and caustic treatments produced changes in morphology (swollen fibers, decrease in convolutions) and in fine structure of the cellulose (increase accessibility as measured by increased moisture regain, dye adsorption). X-ray diffraction showed partial recrystallization into cellulose III lattic after tension treatment with ammonia water. Both reagents produced increased cotton elongation-at-break with slack mercerization, increased cotton breaking strength with tension mercerization, and increased moisture regain or dye adsorption with slack mercerization.

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Effect of Wet Cleaning on Shrinkage and Detergency of Wool and Rayon Fabrics (웨트클리닝이 양모, 레이온 직물의 치수 안정성과 세탁성능에 미치는 영향)

  • Chung, Seung-Eun;Yun, Chang-Sang;Park, Chung-Hee;Kim, Hyun-Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.36 no.2
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    • pp.127-137
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    • 2012
  • This study focuses on the optimal washing conditions for dry cleaning recommended fabrics to minimize dimensional changes using wet cleaning. We suggest water-based alternatives to a perchloroethylene based cleaning process. Wool and rayon fabrics were laundered under various washing conditions and then air-dried for 24hrs. All specimens were extended after spinning and shrunk after drying. This is probably because the fibers were swollen and extended by wetting. The wool fabrics were shown to be acutely influenced by washing temperature and mechanical force. The optimal washing conditions for wool fabric to minimize the dimensional change implied a normal washing temperature and minimized mechanical force. For rayon specimens, dimensional change by a hand wash showed a remarkable decrease compared with a machine wash. Rayon fabric seemed to be influenced by the quantity of water contained in the fabric after spinning and washing time. Therefore, the desirable washing conditions for rayon fabric are to reduce the time required for washing and to increase the spin speed.

Effect of Carrageenan-Induced Pain on Lower Limb Muscle and Ligament of Rat (Carrageenan에 의한 근통유발이 백서의 하지근과 인대에 미치는 영향)

  • Lee Gun-Hyee;Hwang Byung-Chun;Choi Jeong-Son;Kim Yang-Jung;Yun Ju-Young;Lee Geon-Mok
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.19 no.5
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    • pp.1356-1362
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    • 2005
  • The purpose of this study os to investigative the effect of Carrageenan-Induced Pain on lower limb muscle and ligament of rat. To evaluate pain mechanism in muscle and ligament, pain was induced by the injection of 2% $0.1m{\ell}$ carrageenan into the left lower limb muscle of rats after rats were anesthesized with 3% enflurane. Rats were killed on 72 hours after pain induction under the anesthesia. anterior rectus femoris muscle and its ligament were removed from rat hind limb. Morphological changes of them were peformed by the observation of light and electron microscopes. In the light microscopic findings, the muscle cells were polyheadral and situated with each other without small gap in control group. nucleus of cell was seen along the cell margin, and muscle cell groups were divided by regular narrow gap in cross section. In the pain-induced group, muscle cell groups were divided each other by the irregular gap, and some of groups formed larger than other cell groups by the fusion. Intercellular gap of most cell groups were increased compared with control groups. And also, perimysium of muscle cell groups was swollen in cross section. In control group, muscle cells contacted each other closely and each cell was divided by perimysium. The intracellular gaps were not seen between myofibrills, and also striations were well defined between muscle cells in longitudinal section. In pain-induced group, muscle cells were divided by the small intracellular gaps. And also, muscle cell showed many a short cross or longitudinal intercellular gaps in longitudinal section. In light microscopic findings of control group, tendon was composed with many tendon fibers contacted each other closely without gap. The free margin of tendon was fused, and apso the tendon fibers did not invaded between muscles. In pain-induced group, tendon was divided small groups by intertendinous gap, and also the margin of tendon divided by small groups. In the free margin, tendon invaded into muscle cells, and also fibroblasts between tendon fibers were long and lance-shaped. From these results, it is suggested that pain induction by carrageenan injured rat skeletal muscle and ligament by the morphological changes.