• Bulletin of the Korean Chemical Society
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• v.21 no.6
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• pp.604-610
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• 2000

Drying-step in sol-gel processing was bypassed by exchanging alcoholic solvent in forsterite alcogel directly with MMA. By in-situ polymerization of the MMA, organic-inorganic nano-composite of PMMA-forsterite was prepared. As porous nature of inorganic networks in the gel was preserved and fixated in the composite, spherical morphology of PMMA was resulted. The PMMA-forsterite composite was optically transparent, machinable,mechanically sustainable, and thermally more stable than pristine PMMA. When doped with $Eu^{+3}$, inorganic moiety in the composite provided site environment that is very different from that in pristine PMMA. Prominent $^{5}D_0$ → $^{7}F_0$ transition at 578 nm, broken degeneracy in $^{5}D_0$ → $^{7}F_1$ and $^{5}D_0$ →$^{7}F_2$ transitions suggested that $Eu^{+3}$ was exclusively doped in the inorganic moiety of the composite, which had lower symmetry than the organic counterpart.

• Analytical Science and Technology
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• v.37 no.1
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• pp.39-46
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• 2024

Alizarin dye, a persistent and hazardous contaminant in aquatic environments, presents a pressing environmental concern. In the quest for efficient removal methods, adsorption has emerged as a versatile and sustainable approach. This study focuses on the development and application of Zinc Oxide/Nickel Oxide (ZnO/NiO) nano-composites as adsorbents for alizarin dye removal. These semiconducting metal oxide nano-composites exhibit synergistic properties, offering enhanced adsorption capabilities. Key parameters affecting alizarin removal, such as contact time, adsorbent dosage, pH, and temperature, were systematically investigated. Notably, the ZnO/NiO nano-composite demonstrated superior performance, with a maximum alizarin removal percentage of 76.9 % at pH 6. The adsorption process followed a monolayer pattern, as suggested by the Langmuir model. The pseudo-second-order kinetics model provided a good fit to the experimental data. Thermodynamic analysis indicated that the process is endothermic and thermodynamically favorable. These findings underscore the potential of ZnO/NiO nano-composites as effective and sustainable adsorbents for alizarin dye removal, with promising applications in wastewater treatment and environmental remediation.

• Steel and Composite Structures
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• v.4 no.4
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• pp.265-280
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• 2004

In view of the mounting cost of rehabilitating deteriorating infrastructure, further compounded by intensified environmental concerns, it is now obvious that the evolvement and application of advanced composite structural materials to complement conventional construction materials is a necessity for sustainable construction. This study seeks alternative fill materials (polymer-based) to the much-limited cement concrete used in concrete-filled steel tubular structures. Polymers have been successfully used in other industries and are known to be much lighter, possess high tensile strength, durable and resistant to aggressive environments. Findings of this study relating to elasto-plastic characteristics of polymer concrete filled steel composite beams subjected to uniform bending highlight the enormous increase in stiffness, strength and ductility of the composite beams, over the empty steel tube. Moreover, polymer based materials were noted to present a wide array of properties that could be tailored to meet specific design requirements e.g., ductility based design or strength based design. Analytical formulations for design are also considered.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.6
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• pp.780-786
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• 2011

Mg hydride had high hydrogen capacity (7.6%), lightweight and low cost materials and it was promising hydrogen storage material at high temperature. However, commercial applications of the Mg hydride are currently hindered by its high absorption/desorption temperature, and very slow reaction kinetics. one of the approaches to improve the kinetic is $MgH_x$ intermixed with carbon. And it shows that carbon and carbon allotropes have a beneficial effect on hydrogen sorption in Mg. The graphene is a kind of carbon allotropes which is easily desorbed reaction at low temperatures because its reaction is exothermic. In this work, the effect of graphene concentration on the kinetics of Mg hydrogen absorption reaction was investigated. The $MgH_x$-Graphene composites has been prepared by hydrogen induced mechanical alloy (HIMA). The synthesized powder was characterized by XRD and simultaneous TG, DSC analysis. The hydrogenation behaviors were evaluated by using a sievert's type automatic PCT apparatus. In this research, results of kinetic profiles exhibit hydrogen absorption rate of $MgH_x$-5wt.% and 10wt.% graphene composite, as 1.25wt.%/ms, 10.33wt.%/ms against 0.88wt.%/ms for $MgH_x$ alone at 473K.

• International Journal of High-Rise Buildings
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• v.4 no.2
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• pp.153-160
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• 2015

As the predominant mode of vertical urban development in China, mixed-use complexes provide the optimal case for the research of sustainable and vertical urbanism. This paper reviews three typical mixed-use complexes with various vertical space systems in Shanghai via the combination of field observation, questionnaires and software analysis. It then proceeds to determine which vertical space system is most effective for encouraging sustainable vertical urban development from the perspective of spatial efficiency. Finally, it concludes with an evaluation of the relative capabilities of the design features of a mixed-use complex: to create external dimensional-connections, to create multiple internal connections, and to organize overall composite functions.

• Steel and Composite Structures
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• v.33 no.1
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• pp.143-162
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• 2019

A number of desirable characteristics concerning excellent durability, aesthetics, recyclability, high ductility and fire resistance have made stainless steel a preferred option in engineering practice. However, the relatively high initial cost has greatly restricted the application of stainless steel as a major structural material in general construction. This drawback can be partially overcome by introducing composite stainless steel-concrete structures, which provides a cost-efficient and sustainable solution for future stainless steel construction. This paper presents a preliminary numerical study on stainless steel-concrete composite beam-to-column joints with bolted flush endplates. In order to ensure a consistent corrosion resistance within the whole structural system, all structural steel components were designed with austenitic stainless steel, including beams, columns, endplates, bolts, reinforcing bars and shear connectors. A finite element model was developed using ABAQUS software for composite beam-to-column joints under monotonic and symmetric hogging moments, while validation was performed based on independent test results. A parametric study was subsequently conducted to investigate the effects of several critical factors on the behaviour of composite stainless steel joints. Finally, comparisons were made between the numerical results and the predictions by current design codes regarding the plastic moment capacity and the rotational stiffness of the joints. It was concluded that the present codes of practice generally overestimate the rotational stiffness and underestimate the plastic moment resistance of stainless steel-concrete composite joints.

• Advances in concrete construction
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• v.11 no.5
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• pp.409-417
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• 2021

The incorporation of non-biodegradable tyre waste in cement-based material has gained more interest towards sustainable construction these days. Crumb rubber (CR) from waste tyre is an alternative for sand replacement in low strength applications. Many researchers have studied CR cement-based materials produced by normal mixing (NM) method and reported a significant decrease in compressive strength due to CR. To compensate this strength loss, this research aims to study the innovative incorporation of CR in cement composite via the preplaced mixing (PM) method. In this investigation, cement composite was produced with NM and PM methods by replacing sand with 0%, 50%, and 100% CR by volume. The test results showed no significant difference in terms of densities of cement composite prepared with both mixing methods. However, cement composite prepared with PM method had lower strength reduction (about 10%) and lowered drying shrinkage (about 20%). In addition, the sound absorption coefficient and noise reduction coefficient of CR cement composite prepared by PM method were in similar range as those prepared with NM method. Overall, the results demonstrate that the PM method is promising, and the maximum replacement level of 50% is recommended for CR in the cement composite.

• Steel and Composite Structures
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• v.22 no.2
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• pp.387-398
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• 2016

In order to evaluate the effects of U shape ultra high performance concrete (UHPC) permanent form on the behaviors of Reinforced Concrete (RC) beam, a full scale RC composite beam is designed and tested with U shape UHPC permanent form and a reference RC beam with same parameters is tested simultaneously for comparison. The effects of the permanent form on the failure mode, cracking strength, ultimate capacity and deformation are studied. Test results shows that the contributions of the U shape UHPC permanent form to the flexural cracking behaviors of RC beam are significant. This study may provide a reference for the design of sustainable RC beam with high durable UHPC permanent form.

• Steel and Composite Structures
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• v.48 no.4
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• pp.475-483
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• 2023

In this paper, a new energy-efficient semi-active hybrid bulk damper is developed that is cost-effective for use in structural applications. In this work, the possibility of active and semi-active component configurations combined with suitable control algorithms, especially vibration control methods, is explored. The equations of motion for a container bridge equipped with an MDOF Mass Tuned Damper (M-TMD) system are established, and the combination of excitation, adhesion, and control effects are performed by a proprietary package and commercial custom submodel software. Systematic methods for the synthesis of structural components and active systems have been used in many applications because of the main interest in designing efficient devices and high-performance structural systems. A rational strategy can be established by properly controlling the master injection frequency parameter. Simulation results show that the multiscale model approach is achieved and meets accuracy with high computational efficiency. The M-TMD system can significantly improve the overall response of constrained structures by modestly reducing the critical stress amplitude of the frame. This design can be believed to build affordable, safe, environmentally friendly, resilient, sustainable infrastructure and transportation.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.11a
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• pp.169-170
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• 2022

Due to the higher use of nonrenewable fossil fuel energy, environment friendly sustainable energy from waste materials is attracting attention of the researchers. Considering that, jute stick (JS) biochar has been considered for this study for ecofriendly and sustainable thermal energy storage application. Waste jute sticks (JS), which are being mainly used as a fuel for cooking purpose, have been pyrolyzed to produce porous biochar and have been used for shape stabilization of stearic acid (SA) as phase change material (PCM). SA at 1:1 ratio has been incorporated into the activated JS biochar to concoct shape-stabilized phase change composite (SAJS). The SAJS has been evaluated by different techniques such as Fourier transform-infrared spectroscope (FT-IR), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). The obtained composite PCM has shown excellent shape stability with a high latent heat storage, suggesting its suitability for thermal energy storage applications.