• Journal of the Society of Cosmetic Scientists of Korea
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• v.42 no.1
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• pp.15-28
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• 2016

Water-in-oil emulsions including water-in-ester oil and water-in-silicone oil (W/O+S) have various advantages such as blocking moisture evaporation and forming air permeable membrane. However, their applications have been limited due to the poor stability under low viscosity condition. In this study, we investigated the effect of synergistic interaction between nonionic surfactant, micro-size particles and cationic surfactant on the stability of W/O+S formulation. The stability of W/O+S emulsions was changed as a function of cationic surfactant concentration where it increased at lower concentration and then started to decrease above a critical point. Finally, emulsion phase inversion occurred at a high concentration. The results suggest that W/O+S emulsions of low viscosity ranging from 2000 to 5000 cps can be stabilized under the conditions where a nonionic surfactant, micro-size particles and a cationic surfactant are used in the range of 1.0 ~ 4.0 wt%, 2.5 wt% and 0.1 ~ 0.5 wt%, respectively.

• Korean Journal of Materials Research
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• v.8 no.2
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• pp.135-140
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• 1998

Drag reduction produced by dilute solution of water soluble ionic polymer-surfactant complex under turbulent flow in a rotating disk apparatus(RDA) was investigated in this study. Three different molecular weights of polyacrylic acid(PAA) were adopted as drag reducing additives, and distilled water was used as a solvent. Experiments were undertaken to observe the dependence of drag reduction on various factors such as polymer molecular weight, molecular expansions and flexibility, rotating speed of the disk and polymer concentration. Specific considerations were put on conformational difference between surfactant and polymer, and effect of pH on ionic polymer possessing various molecular conformation through pH. The complex of ionic polymer and surfactant(Sodium Dodecyl Sulfate) behaves like a large polyelectrolyte. Surfactant changes the polymer conformation and then increases the dimension of the polymer. The radius of gyration, hydrodynamic volume and relative viscosity of the polymer-surfactant system are observed to be greater than those of polymer itself. Such surfactant-polymer complex has enhanced drag reduction properties.

• Archives of Pharmacal Research
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• v.28 no.9
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• pp.1097-1102
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• 2005

An O/W microemulsion system was developed to enhance the skin permeability of ace-clofenac. Of the oils studied, Labrafil? M 1944 CS was chosen as the oil phase: of the microemulson, as it showed a good solubilizing capacity. Pseudo-ternary phase diagrams were constructed to obtain the concentration range of oil, surfactant, Cremophor ELP, and co-surfactant, ethanol, for micoemulsion formation. Eight different formulations with various values of oil of $6-30\%$, water of $0-80\%$, and the mixture of surfactant and co-surfactant (at the ratio of 2) of $14-70\%$. The in vitro transdermal permeability of aceclofenac from the microemulsions was evaluated using Franz diffusion cells mounted with rat skin. The level of aceclofenac permeated was analyzed by HPLC and the droplet size' of the microemulsions was characterized using a Zetasizer Nano-ZS. Terpenes were added to the microemulsions at a level of $5\%$, and their effects on the skin permeation of aceclofenac were investigated. The mean diameters of the microemulsions ranged between approximately $10\~100nm$, and the skin permeability of the aceclofenac incorporated into the microemulsion systems was 5-fold higher than that of the ethanol vehicle. Of the various terpenes added, limonene had the best enhancing ability. These results indicate that the microemulsion pystem studied is a promising tool for the percutaneous delivery of aceclofenac.

• Journal of the Microelectronics and Packaging Society
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• v.16 no.1
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• pp.45-50
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• 2009

By Laser Through-Silicon-Via process, debris and particles occur when you are forming. Therefore the research of TSV cleaning become important to remove those particles and debris. Both chemical cleaning method that uses a surfactant and physical cleaning method that uses a brush were studied with the via of $30{\mu}m$ diameter and $100{\mu}m$ depth on the 8 inch CMOS Image Sensor wafer. On the DI water and a surfactant in mixture ratio of 2:1, debris show $73{\mu}m^2$ per $0.054mm^2$. Cleaning is superior by lower mixture ratio of DI water and surfactant. In addition, It is less than 5% of debris distribution in the laser condition changed by Laser's frequency and its speed and cleaning had no effect. In the physical cleaning, there are no crack and damage when the system condition is set by $1000{\sim}3000rpm$ strip, $50{\sim}3000rpm$ rinsing, and $200{\sim}300rpm$ brushing Therefore, debris and particles can be removed by enforced chemical method and physical method.

• Journal of the Korean Graphic Arts Communication Society
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• v.4 no.1
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• pp.37-42
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• 1986

This study was made to determine the furctions of I.P.A(iso-Prophyl alchohl)an it is used in lithographic fountais solution. Alcohol acts as a wetting agent, an evaporant, a dilutent, a lubricant and reduces Surface tension and emulsification of link/water mixture/ From many studies, the function of the I.P.A appeurs to be that of a surfactant Cowbined with evaporative and diluent ProPerties.

• Applied Chemistry for Engineering
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• v.32 no.3
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• pp.357-360
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• 2021

Emulsions were prepared using a mixture of bio-oil obtained from the pyrolysis of sawdust in an N₂ environment and Quercus mongolica in a CH₄ environment for both non-catalytic and catalytic cases. Both prepared emulsions were examined by measuring the physical stability and Fourier transform infrared spectroscopy. The emulsion with HLB 5.8 (Span 80 and Atlox 4916) for the ratio of bio-oil (B-oil and C-oil): surfactant: diesel = 10% : 3% : 87% showed stability for 15 days. Combining oils produced in N₂ and CH₄ environments could be a potential solution for generating high-quality emulsions with a high heating value.

• Journal of the Korean Applied Science and Technology
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• v.36 no.4
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• pp.1208-1218
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• 2019

The study is on the cosmetic solubilizing power of organic plant surfactants. The blended high purity polyglyceryl-10 oleate and polyglyceryl-10 stearate mixtures were synthesized using organically certified raw materials to develop surfactants having excellent solubilizing power. The mixture is called "Solubil ORG-1300". The appearance of this material is a pale yellowish paste, with a specific odor. The specific gravity was 1.12 and it was high purity that acid value was 0.072±0.1. The HLB value of this natural surfactant was averaged = 15.1 and calculated through the Griffin equation. Mechanically it is explained how organic surfactant are available with fragrance and oils. The solubilizing test was determined by eye evaluation method through the dissolving performance test for the two oils and measured the transmittance at 890 nm using a UV spectrophotometer to measure the transparency. The results showed that the concentration of surfactant needed to make Bergamot oil available requires approximately more 2 times. It was also found that the concentration of surfactant needed to make the tocoperyl acetate available was about 8 times higher. Experiments on the solubility resulting from pH changes showed stabilized usable solubilizing power even in acidic areas of pH=3.5, neutral areas of pH=7.2, and alkaline areas of pH=1.5. Experiments on the solubility according to pH variation showed good solubility stabilized in acidic areas of pH=3.5, neutral areas of pH=7.2, and alkaline areas of pH=11.5. As an application of cosmetics, the company successfully developed a prescription for moisturizing activity based on these results, it is expected that a wide range of applications will be available for skin care, baby lotion, sensitivity or atopic skin cosmetics.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.44 no.3
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• pp.285-293
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• 2018

A structure of coacervate affects the adsorption of oil and polymer as a conditioning ingredient. This study aims to elucidate a structural characterization of the coacervate of which is a mixture of alkyl cellulose and guar gum. It is well known that the guar gum supports stiffness to the hair when it is adsorbed on the hair. However, addition of guar gum in the formulation composed of alkyl cellulose tremendously increased flexibility in hair. The stable complex system is induced by an electrostatic force between a head group of anionic surfactant and an quarternary ammonium at the alkyl cellulose, and the affinity of alkyl chain to the oil inside the micelle of surfactant by hydrophobic interactions. Taken together, amount of the coacervate increased oil-delivery upon hair in shampooing and these caused a low bending rigidity and calming on the hair swatch.

• Journal of the Korean Applied Science and Technology
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• v.41 no.2
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• pp.318-328
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• 2024

In this study, we enhanced the emulsifying power and solubilization of sucrose stearate (SS) by creating mixtures with sodium deoxycholate (SDOC) and PEG-40 hydrogenated castor oil (HCO). We employed the design of mixture experiments (DOME) methodology to identify the optimal composition of the mixture, and the impact of varying the mixture composition on its characteristics was examined through regression analysis of the experimental data. It was revealed that the emulsifying power for coconut oil was most improved when only SDOC was added to SS, and solubilization was most improved when only HCO was added, while the emulsifying power for cetyl ethylhexanoate (CEH) was most significantly improved when SDOC and HCO were added together. As a result of simultaneous optimization of three characteristics, emulsifying power for each of coconut oil and CEH, and solubilization, the optimal surfactant mixture composition was determined as SS 0.7939, SDOC 0.0586, and HCO 0.1475.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.21 no.2
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• pp.129-139
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• 1995

To confirm the usefulness of partial least-squares(PLS) and multiple scattering correction(MSC) method for quantitation of surfactants in [quantitative methods using FT-lR, reconsitituted mixtures of LAS, MES and ELA-9 were tested. Each mixture was dissolved in 50% EtOH, dried, and applied to the KBr cell. From the IR spectra of these mixture, the variance spectrum was obtained. After repeated calibrations for the various regios of this spectrum, we found that 1245-1130cm-1 and 1070-1010cm-1 showed the strong correlation with each component of the sample mixture: all the correlation coefficients were 1.000 and quantitative errors did not exceed 0.32%. From this result, we concluded that PLS method and MSC method are very useful and can be successfully applied to Quality control.