• Title/Summary/Keyword: surfaces and interfaces

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Role of Surfaces and Their Analysis in Photovoltaics

  • Opila, Robert L.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.72-72
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    • 2011
  • Surface science is intrinsically related to the performance of solar cells. In solar cells the generation and collection of charge carriers determines their efficiency. Effective transport of charge carriers across interfaces and minimization of their recombination at surfaces and interfaces is of utmost importance. Thus, the chemistry at the surfaces and interfaces of these devices must be determined, and related to their performance. In this talk we will discuss the role of two important interfaces, First, the role of surface passivation is very important in limiting the rate of carrier of recombination. Here we will combine x-ray photoelectron spectroscopy of the surface of a Si device with electrical measurements to ascertain what factors determine the quality of a solar cell passivation. In addition, the quality of the heterojunction interface in a ZnSe/CdTe solar cell affects the output voltage of this device. X-ray photoelectron spectroscopy gives some insight into the composition of the interface, while ultraviolet photoemission yields the relative energy of the two materials' valence bands at the junction, which controls the open circuit voltage of the solar cell. The relative energies of ZnSe and CdTe at the interface is directly affected by the material quality of the interface through processing.

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pH Effects at Doped Si Semiconductor Interfaces (Doping된 Si 반도체 세계에서 pH 효과)

  • 천장호;라극환
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.27 no.12
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    • pp.1859-1864
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    • 1990
  • The effect of H+ and OH- ion concentrations at doped Si semiconductor/pH buffer solution interfaces were investigated in terms of cyclic current-voltage characteristics. The effects of space charge on oppositely doped Si semiconductors, i.e., p-and n-Si semiconductors, can be effectively applied to study the pH effects and the slow surface states at the interfaces. The adsorptions of H+ and OH- inons on the doped Si semiconductor surfaces are physical adsorption rather than chemical adsorption. Adsorptive processes and charging effects of the slow surface states can be explained as the potential barrier variations and the related current-voltage characteristics at the interfaces. Under forward bias, the charged slow surface states on the p-and n-si semiconductor surface are donor and acceptor slow surface states, respectively. The effects of minority carriers on the slow surface states can be neglected at the doped Si semiconductor interfaces.

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The Potential Barrier Scavenging Effects of the Charged Colloidal Semiconductors at the Magnetized SrO${\cdot}6Fe_{2}O_{3}$ Ceramics Interfaces (자화된 SrO${\cdot}6Fe_{2}O_{3}$ Ceramics 계면에서 대전된 colloid 반도체의 전위장벽 청소효과)

  • Jang Ho Chun
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.29A no.4
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    • pp.22-27
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    • 1992
  • The cyclic voltammogram characteristics at the magnetized SrO${\cdot}6Fe_{2}O_{3}$ ceramics/(($10^{-3}$M KCI + p-Si powders) and /(($10^{-4}$M CsNO$_3$ + n-GaAs powders) suspension interfaces have been studied using the microelectrophoresis and the cyclic voltammetric method. The negatively charged ions are specifically absorbed on the virgin and the magnetized SrO${\cdot}6Fe_{2}O_{3}$ ceramics surfaces. The zeta potentials of the p-Si and n-GaAs colloidal semiconductors are + 41mV and -44.8mV, respectively. The magnetization effects act as potential barriers at the magnetized SrO${\cdot}6Fe_{2}O_{3}$ interfaces. The positivelely charged p-Si and the negatively charged n-GaAs colloidal semiconductors act as potential barriers at the virgin SrO${\cdot}6Fe_{2}O_{3}$ interfaces. On the other hand, the charged p-Si and n-GaAs colloidal semiconductors act as potential barrier scavengers at the magnetized SrO${\cdot}6Fe_{2}O_{3}$ interfaces. The magnetization effects and the charged colloidal semiconductor effects are irreversible and interdependent.

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Molecular-scale Structure of Pentacene at Functionalized Electronic Interfaces

  • Seo, Soon-Joo;Peng, Guowen;Mavrikakis, Manos;Ruther, Rose;Hamers, Robert J.;Evans, Paul G.;Kang, Hee-Jae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.299-299
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    • 2011
  • A dipolar interlayer can cause dramatic changes in the device characteristics of organic field-effect transistors (OFETs) or photovoltaics. A shift in the threshold voltage, for example, has been observed in an OFET where the organic semiconductor active layer is deposited on SiO2 modified with a dipolar monolayer. Dipolar molecules can similarly be used to change the current-voltage characteristics of organic-inorganic heterojunctions. We have conducted a series of experiments in which different molecular linkages are placed between a pentacene thin film and a silicon substrate. Interface modifications with different linkages allow us to predict and examine the nature of tunneling through pentacene on modified Si surfaces with different dipole moment. The molecular-scale structure and the tunneling properties of pentacene thin films on modified Si (001) with nitrobenzene and styrene were examined using scanning tunneling spectroscopy. Electronic interfaces using organic surface dipoles can be used to control the band lineups of a semiconductor at organic/inorganic interfaces. Our results can provide insights into the charge transport characteristics of organic thin films at electronic interfaces.

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Friction and Wear of the Vane/Roller Surfaces Depending on Several Sliding Condition for Rotary Compressor (미끄럼 조건에 따른 로터리 압축기 베인/롤러 표면의 마찰 마멸 특성)

  • Oh Se-Doo;Cho Sung-Oug;Lee Young-Ze
    • Tribology and Lubricants
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    • v.20 no.6
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    • pp.337-342
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    • 2004
  • One of the serious challenges in developing rotary compressor with HFC refrigerant is the prediction of scuffing times and wear amounts between vane and roller surfaces. In this study, the tribological characteristics of sliding surfaces using vane-roller geometry of rotary compressor were investigated. The sliding tests were carried out under various sliding speeds, normal loads and surface roughness. During the test, friction force, wear depth, time to failure and surface temperature were monitored. Because severe wear occurred on vane surface, TiN coating was applied on sliding surfaces to prolong the wear life of vane-roller interfaces. From the sliding test it was found that there was the optimum initial surface roughness to break in and to prolong the wear life of sliding surfaces. Depending on the load and speed, the protective layers, which were composed of metallic oxide and organic compound, were formed on sliding surfaces. Those would play an important role in the amounts of friction and wear between roller and vane surfaces.

Friction and Wear of the Vane/Roller Surfaces Depending on Several Sliding Condition for Rotary Compressor (여러 미끄럼 조건에 따른 로터리 압축기 베인/롤러 표면의 마찰 마멸 특성)

  • Lee, Young-Ze;Oh, Se-Doo;Kim, Jong-Woo;Kim, Cheol-Woo;Choi, Jin-Kyu;Cho, Sung-Ook
    • 유체기계공업학회:학술대회논문집
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    • 2002.12a
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    • pp.221-226
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    • 2002
  • One of the serious challenges in developing rotary compressor with HFC refrigerant is the prediction of scuffing times and wear amounts between vane and roller surfaces. In this study, the tribological characteristics of sliding surfaces using vane-roller geometry of rotary compressor were investigated. The sliding tests were carried out under various sliding speeds, normal loads and surface roughness. During the test friction force, wear depth, time to failure and surface temperature were monitored. Because severe wear was occurred on vane surface, TiN coating was applied on sliding surfaces to prolong the wear-life of vane-roller interfaces. From the sliding test it was found that there was the optimum initial surface roughness to break in and to prolong the wear life of sliding surfaces. Depending on the load and speed, the protective layers, which were composed of metallic oxide and organic compound, were formed on sliding surfaces. Those would play an important role in role amounts of friction and wear between miler and vane surfaces.

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Controlled Growth of Layered Silver Stearate on 2D and 3D Surfaces

  • Lee, Seung-Joon;Han, Sang-Woo;Kim, Kwan
    • ETRI Journal
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    • v.25 no.6
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    • pp.517-522
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    • 2003
  • This investigation confirms that silver stearate consists of an infinite-sheet, two-dimensional, nonmolecular layered structure. Scanning electron microscopy, X-ray diffraction, and infrared spectroscopy reveal the following: plate-like morphology is identified from the SEM image, XRD peaks can be indexed to the (0k0) reflections of a layered structure, and infrared peaks show that alkyl chains are present in an all-trans conformational state with little or no significant gauche population. Based on these structural characteristics, we demonstrate that silver stearate, a prototype of layered organic-inorganic hybrid material, can be grown not only in a designed two-dimensional pattern but also in three-dimensionally ordered ways by using carboxyl-group terminated nanoparticles as a template.

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