• Title/Summary/Keyword: surface-modification technology

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Pulsed laser surface modification for heat treatment and nano-texturing on biometal surface

  • Jeon, Hojeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.118.1-118.1
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    • 2016
  • The laser surface modification has been reported for its functional applications for improving tribological performance, wear resistance, hardness, and corrosion property. In most of these applications, continuous wave lasers and pulsed lasers were used for surface melting, cladding, alloying. Since flexibility in processing, refinement of microstructure and controlling the surface properties, technology utilizing lasers has been used in a number of fields. Especially, femtosecond laser has great benefits compared with other lasers because its pulsed width is much shorter than characteristic time of thermal diffusion, which leads to diminish heat affected zone. Moreover, laser surface engineering has been highlighted as an effective tool for micro/nano structuring of materials in the bio application field. In this study, we applied femtosecond and nanosecond pulsed laser to treat biometals, such as Mg, Mg alloy, and NiTi alloy, by heating to improve corrosion properties and functionalize their surface controlling cell response as implantable biomedical devices.

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Performance Enhancement of Biofuel Cell by Surface Modification of Glucose Oxidase using Ferrocene Carboxylic acid (페로신카르복시산을 이용한 글루코스 산화효소의 표면개질에 의한 바이오 연료전지 성능향상)

  • JI, JUNGYEON;CHRISTWARDANA, MARCELINUS;CHUNG, YONGJIN;KWON, YONGCHAI
    • Journal of Hydrogen and New Energy
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    • v.27 no.5
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    • pp.526-532
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    • 2016
  • In this study, we synthesized a mediator immobilized biocatalyst([FCA/GOx]/PEI/CNT) by surface modification using ferrocene carboxylic acid(FCA), and evaluated its performance as anode catalyst for biofuel cell. Through the application of FCA on glucose oxidase (GOx), the free amine groups on the lysine residue of GOx surface reacted with carboxylic acid of FCA and make amide bond between GOx and FCA. As the result of that, the electron transfer of catalyst was increased up to 1.91 times($0.468mA{\cdot}cm^{-2}$) than the catalyst without surface modification (GOx/PEI/CNT), and high maxium power density of $1.79mA{\cdot}cm^{-2}$ was gained.

Formation Mechanism of Mesoporous Aluminum Hydroxide Film by Alkali Surface Modification (알칼리 표면개질을 통한 메조포러스 알루미늄 하이드록사이드 필름 형성 기구)

  • Seo, Young-Ik;Jeon, Yong-Jin;Lee, Young-Jung;Kim, Dae-Gun;Lee, Kyu-Hwan;Kim, Young-Do
    • Korean Journal of Materials Research
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    • v.20 no.2
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    • pp.97-103
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    • 2010
  • In this study, a new, relatively simple fabrication method for forming a mesoporous $Al(OH)_3$ film on Al substrates was demonstrated. This method, i.e., alkali surface modification, was simply comprised of dipping the substrate in a $5\times10^{-3}$ M NaOH solution at $80^{\circ}C$ for one minute and then immersing it in boiling water for 30 minutes. After alkali surface modification, a mesoporous $Al(OH)_3$ film was formed on the Al substrate, and its chemical state and crystal structure were confirmed by XPS and TEM. According to the results of the XPS analysis, the flake-like morphology after the alkali surface modification was mainly composed of $Al(OH)_3$, with a small amount of $Al_2O_3$. The mesoporous $Al(OH)_3$ layer was composed of three regions: an amorphousrich region, a region of mixed amorphous and crystal domains, and a crystalline-rich region near the $Al(OH)_3$ layer surface. It was confirmed that the stabilization process in the alkali surface modification strongly influenced the crystallization of the mesoporous $Al(OH)_3$ layer.

MEVVA ion Source And Filtered Thin-Film Deposition System

  • Liu, A.D.;Zhang, H.X.;Zhang, T.H.;Zhang, X.Y.;Wu, X.Y.;Zhang, S.J.;Li, Q.
    • Journal of Korean Vacuum Science & Technology
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    • v.6 no.2
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    • pp.55-57
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    • 2002
  • Metal-vapor-vacuum-arc ion source is an ideal source for both high current metal ion implanter and high current plasma thin-film deposition systems. It uses the direct evaporation of metal from surface of cathode by vacuum arc to produce a very high flux of ion plasmas. The MEVVA ion source, the high-current metal-ion implanter and high-current magnetic-field-filtered plasma thin-film deposition systems developed in Beijing Normal University are introduced in this paper.

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A Study on Wear Characteristics of Machine Structural Steel by Surface Modification (표면개질에 의한 기계구조용강의 마멸특성에 관한 연구)

  • Park Heung-Sik;Woo Kyu-Sung
    • Tribology and Lubricants
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    • v.22 no.2
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    • pp.73-78
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    • 2006
  • The surface modification of automobile parts is of great technological importance for the improvement of corrosion resistance, wear resistance, fatigue strength and so on. Recently, research on the development of the technology of surface modification substituting 6-balance chrome process has progressively been achieved in automobile parts. Although the innovation technology for the improvement of the corrosion-resisting and wear resistant properties through post oxidation after nitrocarburising process had attracted a great attention. For this, anodically potentiodynamic polarisation testing was carried out to corrosion resistance and friction and wear experiment according to applied load and sliding distance was carried out to evaluate the wear resistance of machine structural steel with nitrocarburising and non-nitrocarburising SM45C. The presumed wear volume was calculated with the image processing far evaluation of wear resistance of two materials. The results show that the nitrocarburising had a distinguished corrosion resistance and wear resistance than non-nitrocarburising.

Modification of Polyimide Surface for Photo-Alignment in LCD (액정의 광배향을 위한 폴리이미드의 표면 변형)

  • Shin, Dong-Muyng;Song, Dong-Mee;Shon, Byoung-Choung;Kang, Dou-Yol
    • Journal of the Korean Applied Science and Technology
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    • v.15 no.3
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    • pp.47-53
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    • 1998
  • The polyimide film surface was modified with KOH aqueous solutions or sulfuric acid. The film thickness was increased by about 10% through the modification of film surface. Hydrolysis of amide bonds and hydration of water induced the increase. The polarity of the film surface increased and identified by contact angle measurement. The depth and roughness of modified was increased. After treatment of surface with water, alkyl and 4-pentyloxyaniline were introduced on the film surface by complex formation between anionic species formed on the imide surface and ammonium ion. The newly introduced alkyl group was identified by FT-IR spectroscopy. Surface polarity reduced dramatically and the roughness was increased after introduction of ammonium salt.

Effects of Ultraviolet Surface Treatment on Adhesion Strength of Carbon/Epoxy Composite

  • Kim, Jong-Min;Lee, Dai-Gil
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.15-19
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    • 2002
  • In this work, the surface modification of carbon/epoxy composites was investigated using UV (ultraviolet ray) surface treatment to increase adhesion strength between the carbon/epoxy composites and adhesives. After UV surface treatment, XPS (X-ray photoelectron spectroscopy) tests were performed to analyze the surface characteristics of the carbon/epoxy composites. Comparing adhesion strengths with the surface characteristics, the effects of the surface modification of carbon/epoxy composites by UV surface treatments on the adhesion strengths were investigated.

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Effects of Surface Modification with Amino Terminated Polydimethylsiloxane(ATP) on the Corrosion Protection of Epoxy Coating

  • Shon, MinYoung
    • Corrosion Science and Technology
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    • v.8 no.3
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    • pp.103-109
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    • 2009
  • An epoxy coating was designed to give a hydrophobic property on its surface by modifying it with three types of Amino Terminated Polydimethylsiloxane (ATP), and then effects of the modification on the structure, surface hydrophobic tendency, water transport behavior and hence corrosion protectiveness of the modified epoxy coating were examined using FT-IR spectroscopy, hydrothermal cyclic test, and impedance test. The surface of epoxy coating was changed from hydrophilic to hydrophobic property due primarily to a phase separation tendency between epoxy and modifier by the modification. The phase separation tendency is more appreciable when modified by ATP with higher molecular weight ATP at higher content. Water transport behavior of the modified epoxy coating decreased more in that with higher hydrophobic surface property. The resistance to localized corrosion of the modified epoxy coated carbon steel was well agreed with its water transport behavior and hydrophobic tendency.

Effect of Laser Surface Modification of Cemented Carbide Substrates on the Adhesion of Diamond Films (Cemented Carbide기판의 레이저 표면 개질이 다이아몬드 박막의 접합력에 미치는 영향)

  • Lee, Dong-Gu
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.3
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    • pp.170-176
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    • 2000
  • A novel method for improving the adhesion of diamond films on cemented carbide tool inserts has been investigated. This method is based on the formation of a compositionally graded interface by developing a microrough surface structure using a pulsed laser process. Residual stresses of diamond films deposited on laser modified cemented carbides were measured as a function of substrate roughness using micro-Raman spectroscopy. The surface morphology and roughness of diamond films and cemented carbides were also investigated at different laser modification conditions. It was found that the increasing interface roughness reduced the average residual stress of diamond films, resulting in improved adhesion of diamond films on cemented carbides.

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Polydopamine Coating Behaviors on the Acrylic Acid Grafted-Nanofibers (아크릴산이 그라프트된 나노섬유에서의 폴리도파민 코팅)

  • Shin, Young Min;Kim, Woo-Jin;Park, Jong-Seok;Gwon, Hui-Jeong;Nho, Young-Chang;Lim, Youn-Mook
    • Journal of Radiation Industry
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    • v.5 no.4
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    • pp.371-376
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    • 2011
  • The surface property of the materials used in tissue engineering application has been essential to regulate cellular behaviors by directing their adhesion on the materials. To modulate surface property of the synthetic biodegradable materials, a variety of surface modification techniques have used to introduced surface functional groups or bioactive molecules, recently polydopamine coating method have been introduce as a facile modification method which can be coated on various materials such as polymers, metals, and ceramics regardless of their surface property. However, there are no reports about the degree of polydopamine coating on the materials with different hydrophilicity. In the present study, we prepared acrylic acid grafted nanofibrous meshes using electron-beam irradiation, and then coated meshes with polydopamine. Polydopamine successfully coated on the all meshes, both properties of acrylic acid and polydopamine were detected on the meshes. In addition, the degree of polydopamine deposition on the materials has been altered according to surface hydrophilicity, which was approximately 8-times greater than those on the non-modified materials. In conclusion, dual effect from the acrylic acid grafting and polydopamine may give a chance as a alternative tool in tissue engineering application.