• 제목/요약/키워드: surface-modification technology

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Surface Modification of Poly(L-lactide-co-ε-caprolactone) Nanofibers by Electron-beam Irradiation (전자선 조사 방법을 통한 생분해성고분자의 표면개질 특성 평가)

  • Kim, Woo-Jin;Shin, Young Min;Park, Jong-Seok;Gwon, Hui-Jeong;Nho, Young-Chang;Lim, Youn-Mook
    • Journal of Radiation Industry
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    • v.5 no.4
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    • pp.365-370
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    • 2011
  • Electrospun nanofibers prepared with synthetic biodegradable polymer have some limitations in regulating adhesion, proliferation, and spreading of cells because of their surface hydrophobicity and absence of cell-interaction. In this study, we functionalized the electrospun poly(L-lactide-co-${\varepsilon}$-caprolactone) (PLCL) nanofibers with acrylic acid (AAc) to modulate their surface hydrophilicity using electron-beam irradiation method and then measured grafting ratio of AAc, water contact angle, and ATR-FTIR of AAc-grafted nanofibers. A grafting ratio of AAc on the nanofibers was increased as irradiation dose and AAc concentration were increased. AAc-grafted nanofibers also have higher wettability than non-modified nanofibers. In conclusion, those surface-modified nanofibers may be an essential candidate to regulate cell attachment in tissue engineering applications.

Preparation of Polypropylene/Clay Nanocomposites Using Aminosilane Treated Clay (아미노실란 개질 클레이를 사용한 폴리프로필렌 클레이 나노복합재료)

  • Hong Chae-Hwan;Bae Jin-Woo;Lee Yong-Bum;Lee Choon-Soo;Jho Jae-Young;Nam Byeong-Uk
    • Polymer(Korea)
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    • v.30 no.4
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    • pp.318-325
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    • 2006
  • Polypropylene-clay nanocomposites were studied by the modification of clay with amino silanes to introduce covalent bonds in nanocomposites, and prepared by melt-compounding with polypropylene, clay modified with amino silanes and maleic anhydride grafted polypropylene. The . .structure and surface properties of modified clay were determined by x-ray diffraction, infrared spectrum, and solid-state $^{29}Si$ nuclear magnetic resonance spectrum. The modification of clay with aminosilanes led to the increase of the silicate interlayers to about $19.8{\AA}$, the weakening effects of hydroxy group at $3650cm^{-1}$ and the signal of amine groups at -69 ppm proved that the modification had taken place.

TENSILE BOND STRENGTH OF ALUNMINA CORE TREATED BY ION ASSISTED REACTION (이온보조반응법으로 처리한 알루미나 코아의 인장결합강도에 관한 연구)

  • Kim, Hyeong-Seob;Woo, Yi-Hyung;Kwon, Kung-Rock;Choi, Boo-Byung;Choi, Won-Kook
    • The Journal of Korean Academy of Prosthodontics
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    • v.38 no.5
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    • pp.704-723
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    • 2000
  • This study was undertaken to evaluate the tensile bond strength of In-Ceram alumina core treat-ed by ion assisted reaction(IAR). Ion assisted reaction is a prospective surface modification technique without damage by a keV low energy ion beam irradiation in reactive gas environments or reactive ion itself. 120 In-Ceram specimens were fabricated according to manufacturer's directions and divided into six groups by surface treatment methods of In-Ceram alumina core. SD group(control group): sandblasting SL group: sandblasting + silane treatment SC group: sandblasting + Siloc treatment IAR I group: sandblasting + Ion assisted reaction with argon ion and oxygen gas IAR II group: sandblasting + Ion assisted reaction with oxygen ion and oxygen gas IAR III group: sandblasting + Ion assisted reaction with oxygen ion only For measuring of tensile bond strength, pairs of specimens within a group were bonded with Panavia 21 resin cement using special device secured that the film thickness was $80{\mu}m$. The results of tensile strength were statistically analyzed with the SPSS release version 8.0 programs. Physical change like surface roughness of In-Ceram alumina core treated by ion assistad reaction was evaluated by Contact Angle Measurement, Scanning Electron Microscopy, Atomic Force Microscopy; chemical surface change was evaluated by X-ray Photoelectron Spectroscopy. The results as follows: 1. In tensile bond strength, there were no statistically significant differences with SC group, IAR groups and SL group except control group(P<0.05). 2. Contact angle measurement showed that wettability of In-Ceram alumina core was enhanced after IAR treatment. 3. SEM and AFM showed that surface roughness of In-Ceram alumina core was not changed after IAR treatment. 4. XPS showed that IAR treatment of In-Ceram alumina core was enabled to create a new functional layer. A keV IAR treatment of In-Ceram alumina core could enhanced tensile bond strength with resin cement. In the future, this ion assisted reaction may be used effectively in various dental materials as well as in In-Ceram to promote the bond strength to natural tooth structure.

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Remediation of Contaminated Ballast Gravels by Blasting Technology (Blasting에 의한 철도오염자갈의 재활용 연구)

  • Cho Young-Min;Park Duckshin;Choi Yoon;Lim Jong-Il;Lee Kyung-Hwan
    • Proceedings of the KSR Conference
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    • 2005.05a
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    • pp.597-603
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    • 2005
  • The remediation of railroad contaminated soil is gaining wide attention, recently. In railroad field, modification of diesel supply field, equipment of roll pad, FRP panel, and iron pannel under diesel locomotive storages are used for the prevention of contamination expansions. However, cheap and efficient remediation technology has not been suggested yet. In this study, the contaminated ballast was remediated by blasting technology. Because the contaminants mainly resides on the surface of ballast, blasting these contaminants make it available to recycle the ballast. We carried out the remediation of oil-contaminated ballasts using the blasting technology, and we could remediate them nicely. This technology is expected to be used for the cheap and quick remediation of contaminated ballast.

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Variation of Rotating Bending Fatigue Characteristics by UNSM on Ti-6Al-4V (Ti-6Al-4V재의 UNSM처리에 의한 회전굽힘피로특성변화)

  • Suh, Chang-Min;Pyoun, Young-Sik;Suh, Min-Soo
    • Journal of Ocean Engineering and Technology
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    • v.25 no.6
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    • pp.49-55
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    • 2011
  • In order to analyze feasibility of replacing a conventional 6-mm Ti bar with a 5-mm bar, a series of rotating bending fatigue tests were carried out on Ti-6Al-4V bars by strengthening the fatigue performance using a special technique called UNSM (Ultrasonic Nanocrystal Surface Modification). The results of S-N curves clearly showed that the performance of the 5-mm titanium specimen was similar to that of the 6-mm specimen when the UNSM treatment was applied. The 5-mm treated specimen converged with small scattering band into the linear line of the non-treated 6-mm one. Below the fatigue life of $10^5$ cycles, the UNSM treatment did not show any significant superiority in the bending stress and fatigue life. However, over the fatigue life of $10^5$ cycles, the effect of UNSM was superior for each fatigue life, and the bending stress became longer and higher than that of the untreated one. In the case of 6-mm Ti-bar with UNSM, the fatigue limit was about 592 MPa, and there was fatigue strength increase of about 30.7% at the fatigue life of $10^4$ cycles compared to the untreated 6-mm bar. Therefore, the compressive residual stress made by the UNSM in Ti-6Al-4V increased the fatigue strength by more than 30%.

Engineered Clay Minerals for Future Industries: Food Packaging and Environmental Remediation (미래산업에 적용가능한 점토 화합물: 식품포장 및 환경개선)

  • Kim, Hyoung-Jun;Oh, Jae-Min
    • Journal of the Mineralogical Society of Korea
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    • v.29 no.2
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    • pp.35-45
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    • 2016
  • Clays, which are abundant in nature and eco-friendly, have been utilized throughout human history due to their characteristic physicochemical properties. Recently, a variety of clays such as montmorillonite, kaolinite, sepiolite and layered double hydroxide with or without chemical modification have been extensively studied for potential application in industries. Clays that possess a large specific surface area, high aspect ratio, nanometer sized layer thickness and controllable surface charge could be utilized as polymer fillers after appropriate chemical modifications. These modified clays can improve mechanical and gas barrier properties of polymer materials but also provide sustained antibacterial activity to polymer films. Furthermore, engineered clays can be utilized as scavengers for chemical or biological pollutants in water or soil, because they have desirable adsorption properties and chemical specificity. In this review, we are going to introduce recent researches on engineered clays for potential applications in future industries such as food packaging and environmental remediation.

Continuous Excavation Type TBM Parts Modification and Control Technology for Improving TBM Performance (TBM 굴진향상을 위한 연속굴착형 TBM 부품개조 및 제어기술 소개)

  • Young-Tae, Choi;Dong-Geon, Lee;Mun-Gyu, Kim;Joo-Young, Oh;Jung-Woo, Cho
    • Tunnel and Underground Space
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    • v.32 no.6
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    • pp.345-352
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    • 2022
  • The existing NATM (New Austrian Tunneling Method) has induced civil compliants due to blasting vibration and noise. Machanized excavation methods such as TBM (Tunnel Boring Machine) are being adopted in the planning and construction of tunneling projects. Shield TBM method is composed of repetition processes of TBM excavation and segment installation, the machine has to be stopped during the later process. Consecutive excavation technology using helical segment is under developing to minimize the stoppage time. The modification of thrust jacks and module are planned to ensure the advance force acting on the inclined surface of helical segment. Also, the integrated system design of hydraulic circuit will be remodeled. This means that the system deactivate the jacks on the installing segment while the others automatically act the thrusting forces on the existing segments. This report briefly introduces the mechanical research part of the current consecutive excavation technological development project of TBM.

Modification of DC Flashover Voltage at High Altitude on the Basis of Molecular Gas Dynamics

  • Liu, Dong-Ming;Guo, Fu-Sheng;Sima, Wen-Xia
    • Journal of Electrical Engineering and Technology
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    • v.10 no.2
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    • pp.625-633
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    • 2015
  • The effect of altitude on thermal conduction, surface temperature, and thermal radiation of partial arc was investigated on the basis of molecular gas dynamics to facilitate a deep understanding of the pollution surface discharge mechanism. The DC flashover model was consequently modified at high altitude. The validity of the modified DC flashover model proposed in this paper was proven through a comparison with the results of high-altitude simulation experiments and earlier models. Moreover, the modified model was found to be better than the earlier modified models in terms of forecasting the flashover voltage. Findings indicated that both the thermal conduction coefficient and the surface thermodynamics temperature of partial arc had a linear decrease tendency with the altitude increasing from 0 m to 3000 m, both of which dropped by approximately 30% and 3.6%, respectively. Meanwhile, the heat conduction and the heat radiation of partial arc both had a similar linear decrease of approximately 15%. The maximum error of DC pollution flashover voltage between the calculation value according to the modified model and the experimental value was within 6.6%, and the pollution flashover voltage exhibited a parabola downtrend with increasing of pollution.

Curcumin-Loaded PLGA Nanoparticles Coating onto Metal Stent by Electrophoretic Deposition Techniques

  • Nam, So-Hee;Nam, Hye-Yeong;Joo, Jae-Ryang;Baek, In-Su;Park, Jong-Sang
    • Bulletin of the Korean Chemical Society
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    • v.28 no.3
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    • pp.397-402
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    • 2007
  • Restenosis after percutaneous coronary intervention (PCI) continues to be a serious problem in clinical cardiology. To solve this problem, drug eluting stents (DES) with antiproliferative agents have been developed. Variable local drug delivery systems in the context of stenting require the development of stent manufacture, drug pharmacology and coating technology. We have worked on a system that integrates electrophoretic deposition (EPD) technology with the polymeric nanoparticles in DES for local drug delivery and a controlled release system. The surface morphology and drug loading amount of DES by EPD have been investigated under different operational conditions, such as operation time, voltage and the composition of media. We prepared poly-D,L-lactide-co-glycolic acid (PLGA) nanoparticles embedded with curcumin, which was done by a modified spontaneous emulsification method and used polyacrylic acid (PAA) as a surfactant because its carboxylic group contribute negative charge to the surface of CPNPs (?53.5 ± 5.8 mV). In the process of ‘trial and error' endeavors, we found that it is easy to control the drug loading amount deposited onto the stent while keeping uniform surface morphology. Accordingly, stent coating by EPD has a wide application to the modification of DES using various kinds of nanoparticles and drugs.