• 제목/요약/키워드: surface zeta-potential

검색결과 260건 처리시간 0.029초

해수담수화 공정에서 역삼투막의 거동에 영향을 주는 요인 (Factors related to Performance of Reverse Osmosis Membrane in Seawater Desalination Process)

  • 박준영;홍성호;김지훈;정우원;남종우;김영훈;이창하;김형수
    • 상하수도학회지
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    • 제25권2호
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    • pp.171-176
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    • 2011
  • Organic matters that comprise a tiny part of seawater generally occur over 50% of membrane fouling in Reverse Osmosis Process. This study evaluates Foundation efficiency of reverse osmosis membranes under brackish and seawater conditions and resistance of organic fouling. Moreover, analyzing the membrane surface through roughness, contact angle and zeta potential results in roughness and contact angle are proportional to flux decline rate (FDR), yet FDR has high value when zeta potential is low level. Furthermore, with various membrane fouling of different raw water conditions, the flux tends to improve when pH value is high and raw water which is complex with organic and cation pollutes membrane faster than organic separated raw water condition.

Post-CMP Cleaning에서 PVA 브러시 오염이 세정 효율에 미치는 영향 (Effect of PVA Brush Contamination on Post-CMP Cleaning Performance)

  • 조한철;유민종;김석주;정해도
    • 한국전기전자재료학회논문지
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    • 제22권2호
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    • pp.114-118
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    • 2009
  • PVA (polyvinyl alcohol) brush cleaning method is a typical cleaning method for semiconductor cleaning process especially post-CMP cleaning. PVA brush contacts with the wafer surface and abrasive particle, generating the contact rotational torque of the brush, which is the removal mechanism. The brush rotational torque can overcome theoretically the adhesion force generated between the abrasive particle and wafer by zeta potential. However, after CMP (chemical mechanical polishing) process, many particles remained on the wafer because the brush was contaminated in previous post-CMP cleaning step. The abrasive particle on the brush redeposits to the wafer. The level of the brush contamination increased according to the cleaning run time. After cleaning the brush, the level of wafer contamination dramatically decreased. Therefore, the brush cleanliness effect on the cleaning performance and it is important for the brush to be maintained clearly.

Effect of the PC, diatomite and zeolite on the performance of concrete composites

  • Kocak, Yilmaz;Savas, Muhsin
    • Computers and Concrete
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    • 제17권6호
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    • pp.815-829
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    • 2016
  • This study has been carried out to investigate the effect of the surface properties of Portland cement, diatomite and zeolite on the performance of concrete composites. In this context, to describe the materials used in this study and determine the properties of them, chemical, physical, mineralogical, molecular, thermal, and zeta potential analysis have been applied. In the study, reference (Portland cement), 10%-20% diatomite, 10%-20% zeolite, 5+5%-10+10% diatomite and zeolite were substituted for Portland cement, a total of 7 different cements were obtained. Ultrasonic pulse velocity, capillary water absorption and compressive strength tests were performed on the hardened concrete specimens. Hardened concrete tests have been done on seven different types of concrete, for 28, 56 and 90 days. As a result of experiments it has been identified that both the zeolite and diatomite substitution has a positive effect on the performance of concrete.

거푸집 종류에 따른 콘크리트 표면 특성 (Surface Characteristics of Concrete According to Types of Formworks)

  • 박세언;최정일;이봉기;이방연
    • 한국건설순환자원학회논문집
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    • 제9권4호
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    • pp.499-505
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    • 2021
  • 이 연구의 목적은 거푸집 종류별로 콘크리트 표면의 물리/화학적 특성을 실험적으로 조사하는 것이다. 이를 위하여 건설공사에 일반적으로 사용되는 합판 거푸집과 코팅된 합판 거푸집을 준비하였고, 추가로 콘크리트 표면 열화나 거친 표면을 모사하기 위해 사포를 부착한 합판 거푸집을 준비하였다. 콘크리트는 일반 콘크리트를 사용하였다. 콘크리트 표면 특성은 육안관찰, 주사전자현미경 관찰, 성분 이미지 맵핑, 화학성분 분석, 2차원과 3차원 표면 형상 분석, 그리고 제타 전위 측정을 통해 조사하였다. 실험결과 코팅된 거푸집과 접한 콘크리트 표면이 가장 매끄럽고, 사포를 부착한 거푸집과 접한 콘크리트 표면이 가장 거친 것으로 나타났다. 이외에도 거푸집 종류별로 표면 특성에 뚜렷한 차이가 나타났다. 다만 표면 거칠기가 화학 성분이나 제타 전위에 비하여 차이가 크게 나타났다.

Poly-Si, TEOS, SiN 막질의 CMP 공정 중의 연마입자 오염 특성 평가. (The Adhesion of Abrasive Particle during Poly-Si, TEOS and SiN CMP)

  • 김진영;홍의관;박진구
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.561-562
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    • 2006
  • The purpose of this study was to investigate the root cause of adhesion of silica and ceria particles during Poly-Si, TEOS, and SiN CMP process, respectively. The zeta-potentials of abrasive particles and wafers were observed negative surface charges in the alkaline solutions. SAC and STI patterned wafers have intermediate values of their composition surface's zeta potentials. The theoretical interaction force and adhesion force of silica and ceria particle were calculated in solution with acidic, neutral and alkaline pH. A stronger attractive force was calculated for silica and ceria particles on wafers in acidic solutions than in alkaline solutions. The theoretical interaction forces of the SAC and STI patterned wafers have intermediate values of their constitution wafer's values. The adhesion forces is observed lower values in alkaline solutions than in acidic solutions. And the ceria particle has lower adhesion than that of the silica particle.

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Photografting of PET Fabrics with Vinyl Pyrrolidone and Acryloyl Morpholine Monomers

  • Huang, Weiwei;Jang, Jin-Ho
    • 한국염색가공학회지
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    • 제20권5호
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    • pp.28-34
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    • 2008
  • PET fabrics were photografted under continuous UV irradiation with vinyl pyrrolidone (VP) and acryloylmorpholine(ACMO) as monomers and benzophenone as a hydrogen-abstractable photoinitiator. ACMO can be grafted onto the PET fabrics more efficiently than VP. The grafted PET surfaces were characterized by ATR, ESCA, SEM and zeta potential measurement. ATR and ESCA analysis indicated significant alterations on chemical structure and atomic composition on the surface of the grafted fabrics, where nitrogen content increased with increasing grafting yield. SEM images showed that the fabric surface was covered with the grafted polymers. The zeta potentials and the water wettability of the grafted PET increased with grafting. Also the photografted fabrics showed an increased dyeablity to reactive dyes and increased affinity to various iodine species which imparted anti-bacterial properties.

충전제-탄성체 상호작용 4. 플라즈마 처리가 카본블랙 표면 특성에 미치는 영향 (Filler-Elastomer Interactions : 4. Effect of Plasma Treatment on Surface Properties of Carbon Blacks)

  • 김정순;최경은;박수진
    • Elastomers and Composites
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    • 제36권2호
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    • pp.94-101
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    • 2001
  • 본 연구에서는 RF-plasma를 사용하여 카본블랙을 $N_2$ 분위기에서 표면처리 하였을 때 카본블랙의 표면 산도 및 염기도와 이온 흡착 특성, 그리고 표면 자유에너지를 통한 물리-화학적변화를 관찰하였다. 그 결과 카본블랙을 플라즈마 표면처리 하였을 경우 표면 자유에너지의 비극성 요소 (${\gamma}s^L$)가 크게 증가함을 고찰하였다. 또한 표면 산도 및 표면 염기도와 이온 교환특성, 제타 전위, 그리고 이온 이동도의 향상 등에 의한 표면 관능기의 발달로 표면처리 시간이 증가됨에 따라 극성요소 (${\gamma}s^{sp}$)인 전자 받게 (${\gamma}s^+$)와 전자 주게 (${\gamma}s^-$) 인자도 증가하는 것을 볼 수 있었다.

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Electrokinetic flow and electroviscous effect in a charged slit-like microfluidic channel with nonlinear Poisson-Boltzmann field

  • Chun, Myung-Suk;Kwak, Hyun-Wook
    • Korea-Australia Rheology Journal
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    • 제15권2호
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    • pp.83-90
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    • 2003
  • In cases of the microfluidic channel, the electrokinetic influence on the transport behavior can be found. The externally applied body force originated from the electrostatic interaction between the nonlinear Poisson-Boltzmann field and the flow-induced electrical field is applied in the equation of motion. The electrostatic potential profile is computed a priori by applying the finite difference scheme, and an analytical solution to the Navier-Stokes equation of motion for slit-like microchannel is obtained via the Green's function. An explicit analytical expression for the induced electrokinetic potential is derived as functions of relevant physicochemical parameters. The effects of the electric double layer, the zeta potential of the solid surface, and the charge condition of the channel wall on the velocity profile as well as the electroviscous behavior are examined. With increases in either electric double layer or zeta potential, the average fluid velocity in the channel of same charge is entirely reduced, whereas the electroviscous effect becomes stronger. We observed an opposite behavior in the channel of opposite charge, where the attractive electrostatic interactions are presented.

콜로이드 실리카의 제조 및 계면특성 (Preparation and Interface Properties of Colloidal Silica)

  • 이한철;김종협;장윤호
    • 공업화학
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    • 제17권4호
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    • pp.386-390
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    • 2006
  • 콜로이드형 실리카는 화학적으로 안정한 무기소재로 비표면적과 표면물성이 우수하여 산업적으로 다양한 용도로 사용하고 있다. 본 연구에서는 sodium silicate로부터 이온교환방법 및 산-중화법을 이용하여 colloidal silica를 제조하고 입자성장인자인 온도, pH, 농도와 aging time을 조절하여 크기를 조정하는 방법을 조사하여 균일한 크기분포를 가진 colloidal silica를 제조하였다. 실리카 졸의 크기와 모양은 TEM 및 dynamic scattering method를 이용하여 측정하였다. 또한 콜로이드의 입자크기에 따른 제타 전위값의 변화, 겔화현상과 그 유변학적 특성을 연구하였다.

The Influence of Functionalization of the Fe3O4 Nanoparticle on its Dispersion Property

  • Han, Jin Soon;An, Gye Seok;Park, Bong Geun;Choi, Sung-Churl
    • 한국세라믹학회지
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    • 제55권1호
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    • pp.80-84
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    • 2018
  • In this study, to improve the dispersity of $Fe_3O_4$ nanoparticles, dispersion properties were considered with various types of functionalization of $Fe_3O_4$ nanoparticles. Due to its high surface area, the electrically neutral state of its surfaces, and its magnetic momentum, $Fe_3O_4$ nanoparticles are easily aggregated in solution. In order to prevent aggregation, $Fe_3O_4$ nanoparticles were functionalized with carboxyl and amine groups in the form of a polymer compound. Carboxyl and amine groups were attached to the surface of $Fe_3O_4$ nanoparticles and the absolute value of the zeta potential was found to be enhanced by nearly 40 eV. Furthermore, the morphology and the magnetic property were analyzed for the application of $Fe_3O_4$ nanoparticles as a magnetic fluid.