DOI QR코드

DOI QR Code

Photografting of PET Fabrics with Vinyl Pyrrolidone and Acryloyl Morpholine Monomers

  • Huang, Weiwei (Dept. of Nano-Bio Textile Engineering, Kumoh National Institute of Technology) ;
  • Jang, Jin-Ho (Dept. of Nano-Bio Textile Engineering, Kumoh National Institute of Technology)
  • Published : 2008.10.27

Abstract

PET fabrics were photografted under continuous UV irradiation with vinyl pyrrolidone (VP) and acryloylmorpholine(ACMO) as monomers and benzophenone as a hydrogen-abstractable photoinitiator. ACMO can be grafted onto the PET fabrics more efficiently than VP. The grafted PET surfaces were characterized by ATR, ESCA, SEM and zeta potential measurement. ATR and ESCA analysis indicated significant alterations on chemical structure and atomic composition on the surface of the grafted fabrics, where nitrogen content increased with increasing grafting yield. SEM images showed that the fabric surface was covered with the grafted polymers. The zeta potentials and the water wettability of the grafted PET increased with grafting. Also the photografted fabrics showed an increased dyeablity to reactive dyes and increased affinity to various iodine species which imparted anti-bacterial properties.

Keywords

References

  1. E. Uchida, H. Iwata, and Y. Ikada, Surface Structure of Poly(ethyleneerephthalate) Film Grafted with Poly(methacrylic acid), Polymer, 41, 3609-3614 (2000) https://doi.org/10.1016/S0032-3861(99)00581-9
  2. C. He, and Z. Gu, Studies on Acrylic acid-grafted Polyester Fabrics by Electron Beam Preirradiation Method. I. Effects of Process Parameters on Graft Ratio and Characterization of Grafting Products, J. Appl. Polym. Sci., 89, 3931-3938(2003) https://doi.org/10.1002/app.12646
  3. H. Mirzadeh, M. Dadsetan, and N. Sharifi-Sanjani, Platelet Adhesion on Laser-Induced Acrylic acid-grafted Polyethylene Terephthalate, J. Appl. Polym. Sci., 86, 3191-3196(2002) https://doi.org/10.1002/app.10775
  4. B. Gupta, C. Plummer, I. Bisson, P. Frey, and J. Hilborn, Plasma-induced Graft Polymerization of Acrylic acid onto Poly(ethyleneterephthalate) Films: Characterization and Human Smooth Muscle Cell Growth on Grafted Films, Biomaterials, 23, 863-871(2002) https://doi.org/10.1016/S0142-9612(01)00195-8
  5. Y. C. Nho, and O. H. Kwon, Blood Compatibility of AAc, HEMA, and Cellulose Film, Radiation Physics and Chemistry, 66, 299-307(2003) https://doi.org/10.1016/S0969-806X(02)00387-0
  6. L. M. Ferreiraa, A. N. Falcao, and M. H. Gilb, Elemental and Topographic Characterization of LDPE Based Copolymeric Films Obtained by Gammairradiation, Nucl. Instr. and Meth. in Phys. Res B, 265, 193-197(2007) https://doi.org/10.1016/j.nimb.2007.08.047
  7. M. X. Hua, Q. Yang, and Z. K. Xua, Enhancing the Hydrophilicity of Polypropylene Microporous Membranes by the Grafting of 2-Hydroxyethyl Methacrylate via a Synergistic Effect of Photoinitiators, J. Membr. Sci., 285, 196-205(2006) https://doi.org/10.1016/j.memsci.2006.08.023
  8. G. M. Kline, Polyvinylpyrrolidone, Mod Plast. November, 157-161(1945)
  9. E. Senogles, and R. Thomas, Polymerization Kinetics of N-vinyl Pyrrolidone, J. Polym. Sci. Symp., 49, 203-210(1975)
  10. M. Chaimberg, R. Pamas, and Y. Cohen, Graft Polymerization of Polyvinylpyrrolidone onto Silica, J. Appl. Polym. Sci., 37, 2921-2931(1989) https://doi.org/10.1002/app.1989.070371011
  11. K. Ishihara, Y. Iwasaki, S. Ebihara, Y. I. Shindo and N. Nakabayashi, Photoinduced Graft Polymerization of 2-Methacryloyloxyethyl Phosphorylcholine on Polyethylene Membrane Surface for Obtaining Blood Cell Adhesion Resistance, Colloids Surf B, 18, 325-335(2000) https://doi.org/10.1016/S0927-7765(99)00158-7
  12. C. M. Xing, J. P. Deng, and W. T. Yang, Surface Functionalization of Polypropylene Film via UV-Induced Photografting of N-Vinylpyrrolidone/Maleic Anhydride Binary Monomers, Macromol Chem. Phys., 206, 1106-1113(2005) https://doi.org/10.1002/macp.200400534
  13. J. A. Dougherty, L. I. Lynch, and L. Mahamoud, Acryloyl Morpholine for UV Curing, Radtech Report, May/June, 2007
  14. B. L. Rivas, A. Maureira and K. E. Geckeler, Novel Water-soluble Acryloylmorpholine Copolylmers: Synthesis, Characterization, and Metal Ion Binding Properties, J. Appl. Polym. Sci., 101, 180-185(2006) https://doi.org/10.1002/app.23163
  15. R. Schwalm, UV coating, pp.117-118, 2007
  16. Z. M. Liu, Z. K. Xu, J. Q. Wang, J. Wu, and J. J. Fu, Surface Modification of Polypropylene Microfiltration Membranes by Graft Polymerization of N-vinyl-2-pyrrolidone, Euro. Polym. J., 40, 2077-2087(2004) https://doi.org/10.1016/j.eurpolymj.2004.05.020
  17. J. Z. Yi, and S. H. Goh, Interactions in Miscible Blends and Complexes of Poly(N-acryloylmorpholine) with Poly(p-vinylphenol), Polymer, 43, 4515-4522 (2002) https://doi.org/10.1016/S0032-3861(02)00291-4
  18. J. Jang and J. A. Son, Cationization of PET Fabrics via Continuous Photografting of [3-(Methacryloylamino)propyl]trirnethylammonium Chloride, Text. Sci. Eng., 44, 312-318(2007)
  19. N. N. Kazantseva, A. Emepesova, A. Khodjamamedov, O. A. Geldyev, and B. S. Krumgalz, Spectrophotometric Analysis of Iodide Oxidation by Chlorine in HigWy Mineralized Solutions, Anal. Chim. Acta, 456, 105-119(2002) https://doi.org/10.1016/S0003-2670(01)01625-7