• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.4
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• pp.2391-2400
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• 2015

Weather proof steels are used for steel bridges due to its high corrosion resistance under atmospheric conditions. However, instead of forming stabilized rust layers, general rust occurs on weather proof steels under high humidity condition close to seawater or shady places. In Japan, therefore, they perform rust stabilization treatment instead of unpainted treatment due to severe atmospheric conditions. However, most of domestic weather proof steels were constructed unpainted in the form of closed box-girder, which makes the periodical repetition of dry and wet hard to occur. For the steel bridges constructed on the Han river, the evaporation of water, dew condensation due to temperature change, and stagnant water due to rain affect harmfully on the formation of passive film on weather proof steels. Thus, in this research, in order to analyze corrosion properties inside the closed box-girder for the unpainted weather proof steel bridge in the waterworks safety zone, multiple ways of analysis such as observation with eyes, cellophane-tape test, steel thickness measurement, surface corrosion potential measurement, electron microscope analysis, and X-ray diffraction analysis of the rust were performed. As a result, unstable rust layer was observed inside the closed box-girder, and severe corrosion was observed on the top and bottom of the flanges due to the effects of stagnant water caused by rain, dew condensation, and de-icing materials.

• Journal of the Korean Society for Marine Environment & Energy
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• v.15 no.3
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• pp.198-207
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• 2012

In this study, we investigated the effect of ocean fertilization by deep sea water, using an ecosystem model which contains not only phytoplankton but also zooplankton. The model is based on NEMURO which consists of eleven compartments - two species of phytoplankton, three species of zooplankton, $NO_3$, $NH_4$, $Si(OH)_4$, particulate organic nitrogen, dissolved organic nitrogen and particulate silicon. We introduced nitrogen cell quota in the both species of phytoplankton, and silicon cell quota in the large phytoplankton in addition to the eleven compartments of NEMURO. We made the experiment at Izu Oshima Island in order to investigate the effect of ocean fertilization. In this experiment, we could not find clear differences between the cases with and without deep sea water. We investigated the causes of the experiment results by the model simulations. One of the causes was high concentrations of nutrients in surface seawater used in the experiment. Another was that the increase of total concentration of inorganic nitrogen does not necessarily accelerate the photosynthetic rate because inorganic nitrogen uptake rate is related to the ratio of $NO_3$ to $NH_4$. Because the model can represent the results of the experiment, we investigated the effect of ocean fertilization by deep sea water using this model. We found that the effect of ocean fertilization hardly appeared when the interval of the addition of deep sea water was too short, or the amount of deep sea water was too much. It is supposed that if the addition of deep sea water is too frequent or too much, the dilution of plankton's concentrations will exceed the effect of promoting phytoplankton's photosynthesis.

• Journal of the Korean Society of Marine Environment & Safety
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• v.13 no.3
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• pp.173-181
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• 2007

A three-dimensional ecological model (EMT-3D) was applied to Tokyo Bay for the simulation of PFOA. EMT-3D was calibrated with seawater analysis data obtained from the study area in 2004. The simulated results of dissolved PFOA were in good agreement with the observed values, with a correlation coefficient(R) of 0.7115${\sim}$0.8759 and a coefficient of determination $(R^2)$ of 0.5062${\sim}$0.7672. The results of sensitivity analysis showed that partition rate, adsorption rate and settling rate were important factors for PFOA in particulate organic matter. In the case of PFOA in phytoplankton, bioconcentration factor, uptake rate and partition rate were important factors. Therefore, the parameters must be carefully considered in the modeling. In the case of 50% and 80% total loads reduction, concentration of dissolved PFOA was shown to be lower than 20ng/L and 10ng/L, respectively. In the case of reduction of loads from rivers in each prefecture, Tokyo prefecture was found to have the most influence on the change of dissolved PFOA in surface water while Chiba prefecture was found to have the most influnce on the change of dissolved PFOA in bottom water.

• Food Science of Animal Resources
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• v.26 no.3
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• pp.402-409
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• 2006

Although microorganisms are, in fact, the most diverse and abundant type of organism on Earth, the ecological functions of microbial populations remains poorly understood. A variety of bacteria including marine Vibrios encounter numerous ecological challenges, such as UV light, predation, competition, and seasonal variations in seawater including pH, salinity, nutrient levels, temperature and so forth. In order to survive and proliferate under variable conditions, they have to develop elaborate means of communication to meet the challenges to which they are exposed. In bacteria, a range of biological functions have recently been found to be regulated by a population density-dependent cell-cell signaling mechanism known as quorum-sensing (QS). In other words, bacterial cells sense population density by monitoring the presence of self-produced extracellular autoinducers (AI). N-acylhomoserine lactone (AHL)-dependent quorum-sensing was first discovered in two luminescent marine bacteria, Vibrio fischeri and Vibrio harveyi. The LuxI/R system of V. fischeriis the paradigm of Gram-negative quorum-sensing systems. At high population density, the accumulated signalstrigger the expression of target genes and thereby initiate a new set of biological activities. Several QS systems have been identified so far. Among them, an AHL-dependent QS system has been found to control biofilm formation in several bacterial species, including Pseudomonas aeruginosa, Aeromonas hydrophila, Burkholderia cepacia, and Serratia liquefaciens. Bacterial biofilm is a structured community of bacterial cells enclosed in a self-produced polymeric matrix that adheres to an inert or living surface. Extracellular signal molecules have been implicated in biofilm formation. Agrobacterium tumefaciens strain NT1(traR, tra::lacZ749) and Chromobacterium violaceum strain CV026 are used as biosensors to detect AHL signals. Quorum sensing in lactic acid bacteria involves peptides that are directly sensed by membrane-located histidine kinases, after which the signal is transmitted to an intracellular regulator. In the nisin autoregulation process in Lactococcus lactis, the NisK protein acts as the sensor for nisin, and NisR protein as the response regulator activatingthe transcription of target genes. For control over growth and survival in bacterial communities, various strategies need to be developed by which receptors of the signal molecules are interfered with or the synthesis and release of the molecules is controlled. However, much is still unknown about the metabolic processes involved in such signal transduction and whether or not various foods and food ingredients may affect communication between spoilage or pathogenic bacteria. In five to ten years, we will be able to discover new signal molecules, some of which may have applications in food preservation to inhibit the growth of pathogens on foods.

• Korean Journal of Microbiology
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• v.33 no.3
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• pp.193-198
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• 1997

Microorganisms capable of producing biosurfactant were isolated from oil-contaminated soils and seawater. Among them, the selected strain SW1 was identified as Pseudomonas sp. by taxonomical characteristic tests, and so tentatively named Pseudomonas sp. SWI. The optimal temperature and initial pH for biosurfactant production were TEX>30^{\circ}C.$ and 7.0, respectively. The optimal medium composilion for the production of biosurfactant by Pseudomonas sp. SW1 were hexadecane of 2.0%, yeast extract of 0.04%, $K_{2}HPO_4$ of 0.02%, $KH_2PO_4$ of 0.03% and $MgSO_4$ center dot $7H_2O$ of 0.04%, respectively. Under the above conditions, minimum wrface tension was 32 mN/m after incubation of 2 days. The biosurfactant was produced during initial stationary phase in the optimal medium. Pseudotnonas sp. SWl utilized various hydrocarbons such as Bunker oils, n-alkanes and branched alkanes as a sole carbon source.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.4
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• pp.679-688
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• 2000

Dispersants, which are used to break water-in-oil emulsions and to remediate oil-spills, are another water pollutants. In this study, magnetic separation technology was applied to remove dispersants from the sea. Magnetite and maghemite were used as magnetic sorbents and SDDBS, an anionic surfactant and Triton X-100, a nonionic surfactant, were employed as dispersants. Batch experiments were undertaken to study the sorption capacity and sorption equilibrium, and water-bath experiments were conducted to simulate the real situation and to describe the recovery of magnetic particles by the permanent magnet or electromagnet. Maghemite has rather constant removal efficiency for dispersants, regardless of surfactant species. On the other hand, removal efficiency by magnetite is higher for anionic surfactant than maghemite and is higher in distilled water than in seawater which contains more ions. The sorption of dispersants to magnetite is explained by electrostatic attraction and that of maghemite is described not only by electrostatic attraction, but also by structural characteristics that provide high sorption ability and surface condition. Water bath experimental results showed that recovery efficiency of magnetic particle after sorption for dispersants is nearly 100%. It is suggested that this magnetic separation technology is an effective way of dispersant removal because of short operating time, high sorption capacity, and high recovery efficiency of sorbents.

• Corrosion Science and Technology
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• v.13 no.1
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• pp.20-27
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• 2014

The structures of reinforced concrete has been extensively increased with rapid development of industrial society. Futhermore, these reinforced concretes are easy to expose to severe corrosive environments such as sea water, contaminated water, acid rain and seashore etc.. Thus, corrosion problem of inner steel bar embedded in concrete is very important in terms of safety and economical point of view. In this study, multiple mortar test specimen(W/C:0.4) with six types having different cover thickness each other was prepared and was immerged in seawater solution for five years to evaluate the effect of cover thickness and immersion years to corrosion property of embedded steel bar. And the polarization characteristics of these embedded steel bars was investigated using electrochemical methods such as measuring corrosion potential, cathodic polarization curve, and cyclic voltammogram. At the beginning of immersion, the corrosion potentials exhibited increasingly nobler values with increasing cover thickness. However, after immersed for 5 years, the thicker cover of thickness, the corrosion potentials shifted in the negative direction, and the relationship between corrosion potential and cover thickness was not in good agreement with each other. Therefore, it is considered that the thinner cover of thickness, corrosive products deposited on the surface of the embedded steel bar plays the role as a resistance polarization which is resulted in decreasing the corrosion rate as well as shifting the corrosion potential in the positive direction. As a result, it seemed that the evaluation which corrosion possibility of the reinforced steel would be estimated by only measuring the corrosion potential may not be a completely desirable method. Therefore, it is suggested that we should take into account various parameters, including cover thickness, passed aged years as well as corrosion potential for more accurate assessment of corrosion possibility of reinforced steel which is exposed to partially or fully in marine environment for long years.

• Corrosion Science and Technology
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• v.13 no.1
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• pp.28-35
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• 2014

Recently, the fuel oil of diesel engines of marine ships has been increasingly changed to heavy oil of low quality as the oil price is getting higher and higher. Therefore, the spiral gear attached at the motor of the oil purifier which plays an important role to purify the heavy oil is also easy to expose at severe environmental condition due to the purification of the heavy oil in higher temperature. Thus, the material of the spiral gear requires a better mechanical strength, wear and corrosion resistance. In this study, the heat treatment(tempering) with various holding time at temperature of $500^{\circ}C$ was carried out to the alloy of Cu-7Al-2.5Si as centrifugal casting, and the properties of both hardness and corrosion resistance with and without heat treatment were investigated with observation of the microstructure and with electrochemical methods, such as measurement of corrosion potential, cathodic and anodic polarization curves, cyclic voltammogram, and a.c. impedance. in natural seawater solution. The ${\alpha}$, ${\beta}^{\prime}$ and ${\gamma}_2$ phases were observed in the material in spite of no heat treatment due to quenching effect of a spin mold. However, their phases, that is, ${\beta}^{\prime}$ and ${\gamma}_2$ phases decreased gradually with increasing the holding time at a constant temperature of $500^{\circ}C$. The hardness more or less decreased with heat treatment, however its corrosion resistance was improved with the heat treatment. Furthermore, the longer holding time, the better corrosion resistance. In addition, when the holding time was 48hrs, its corrosion current density showed the lowest value. The pattern of corroded surface was nearly similar to that of the pitting corrosion, and this morphology was greatly observed in the case of no heat treatment. It is considered that ${\gamma}_2$ phase at the grain boundary was corroded preferentially as an anode. However, the pattern of general corrosion exhibited increasingly due to decreasing the ${\gamma}_2$ phase with heat treatment. Consequently, it is suggested that the corrosion resistance of Cu-7Al-2.5Si alloy can be improved with the heat treatment as a holding time for 48 hrs at $500^{\circ}C$.

• Journal of the Korean Society for Marine Environment & Energy
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• v.8 no.4
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• pp.165-173
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• 2005

Field observations have been conducted to investigate the physical environment around oyster farms in Gamak Bay. Tidal waves near the two channels at the northeast and south of the bay had almost the same amplitudes and phases. Water temperature responded sensibly to the tides, rising at high water and falling at low water, except for the northwest region. The currents more regularly varied in accordance with a tidal period as long as they are at the faster-flowing region. A considerable flow has been found near the seabed of the northwest of the bay, normally known to be a stagnant area, and also the flow was opposite to the surface flow. Average moving speeds and directions of the flow at each station coincided well with patterns of the residual currents computed by Lee ef al. [2004], except for the northwest region. The discrepancy for the northwest region is not clear but it may have resulted from the facts that the computed flow pattern represents only the case of spring tide and in addition, a northwesterly wind prevailed all the observation time.

• Economic and Environmental Geology
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• v.44 no.3
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• pp.239-246
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• 2011

Groundwater in small islands is used as main water resource but the overuse of groundwater may cause seawater intrusion and temperature decrease in geothermal wells. This study aimed to characterize the hydrogeology of Maeum-ri area in Seokmo Island of Ganghwagun using long-term monitoring at groundwater wells and geothermal wells. In the monitoring period seasonal water level change, consistent drop or increase of water levels are not detected. The groundwater temperature about 10m below ground surface shows year cycle variation having two to five months difference with ambient temperature cycle. The storativity was calculated by tidal method. The storativity estimated by adapting tidal efficiency factor showed some larger values than that by using tidal time lag. The result suggested that the tidal method assuming several assumptions on aquifer condition may produce broad ranges but the calculated ranges at this application are reasonable. The similar shape of groundwater level change and tidal effects was observed at several wells clustered east-south-east direction which may implicate the distribution of vertical fracture system strongly related with groundwater flow channels. The applied methodology and study results will bc valuable to evaluate optimal pumping rate for the preservation of groundwater resources, and to manage geothermal development.