• 제목/요약/키워드: surface protective material

검색결과 91건 처리시간 0.034초

기계적 표면 처리된 TITANIUM PLASMA SPRAYED IMPLANT에 대한 치은섬유아세포전개양상의 형태학적 관찰 (THE MORPHOLOGICAL OBSERVATION OF HUMAN GINGIVAL FIBROBLASTS ATTACHMENT AND SPREADING ON THE MECHANICAL TREATED TITANIUM PLASMA SPRAYED IMPLANT SURFACE)

  • 황연희;이재목;서조영
    • Journal of Periodontal and Implant Science
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    • 제25권3호
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    • pp.741-755
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    • 1995
  • 구강내 매식된 임프란트가 과도한 교합력이나 염증등의 이유로 구강내로 노출되었을 때 세균독소에 이완된 면을 제거하고 평활한 면을 형성하여 주위의 연조직, 경조직에 적합한 상태로 만들어 건강한 상태로 구강내에 유지하기 위해서 임프란트 매식체 표면을 기계적인 표면처리방법으로 처치하여 이러한 방법이 임프란트 표면성분, 치은섬유아세포의 전개양상에 미치는 영향을 알아보고자 본 실험을 실행하였다. IMZ사에서 제작한 직경 10mm, 높이 2mm의 원판 타이타늄을 이용하여 피막되지 않은 타이타늄면과 TPS면을 대조군으로 하고 기계적인 표면처리방법인 low speed stone bur처치면을 실험군으로 설정한 후 EDX로 타이타늄 표면성분을 분석하였고 주사전자현미경으로 치은섬유아세포의 전개양상을 관찰하였다. EDX에 의한 타이타늄 표면성분분석 결과 모든 실험군에서 titanium peak, 소량의 aluminum이 나타났으며 그외의 성분은 나타나지 않았다. 치은섬유아세포의 전개양상에 대한 주사전자현미경 관찰결과 평활한 타이타늄면에서 접종 30분 후 세사상돌기와 박판엽상으로 확장된 세포가 많이 관찰되며 6시간 후 신장된 치은섬유아세포가 시편에 밀착된 양상을 보였고 24시간 후 치은섬유아세포는 시편의 모든 면을 피개하며 가공시의 평행한 선을 따라 방향성을 띄었다. TPS가 잔존한 stone처치군에서 세포 접종 30분 후 세사상돌기가 적게 관찰되어 평활한 타이타늄면에 비해 초기부착이 늦은 것을 알 수 있었고 6, 24시간후 치은섬유아세포는 거친면으로 인해 시편에 밀착되지 못한 양상을 보였으나 평활한 타이타늄면과 연결되며 시편의 모든면을 피개하였다. TPS군에서 치은섬유아세포는 세포 접종 30분후 세사상돌기를 거의 찾아 볼 수 없어 초기부착이 다른군에 비해 늦으며 세포배양 6, 24시간후에도 시편에 밀착되지 못하고 박판상돌기가 가늘고 길게 돌출되어 여러면에 부착된 양상을 보였으며 세포가 부착되지 않은 TPS면이 관찰되었다.

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3D 프린팅용 금속 입자 필라멘트의 물성 및 차폐 능력 평가 (Evaluation of Metal Composite Filaments for 3D Printing)

  • 박기석;최우전;김동현
    • 한국방사선학회논문지
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    • 제15권5호
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    • pp.697-704
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    • 2021
  • 3D 프린팅 FDM방식의 재료인 필라멘트 중 차폐성능을 지닌 필라멘트는 국내에 판매되지 않고 있으며 관련 연구도 미비하다. 이에 본 연구는 금속 입자가 함유된 필라멘트의 물성과 방사선의 차폐능력을 평가하여 3D 프린트를 이용한 방사선 차폐체 개발의 기초자료를 제공하고자 한다. 금속입자 강화재가 함유된 금속 필라멘트 5가지를 선정 후 ASTM의 평가방법을 이용하여 인장강도, 밀도, XRD, 무게측정 등 물성을 평가하고 방사선 차폐능력을 알아보기 위하여 한국산업표준의 방호용구류 시험방법에 따라서 방사선 차폐율을 구하였다. 인장강도는 PLA + SS가 가장 높았고 ABS + W가 가장 낮았으며 밀도는 ABS + W 가 3.13 g/cm3으로 가장 높게 나타났다. XRD결과 시편의 표면의 입자의 XRD peak 패턴이 각 입자 강화재 분말 금속의 패턴과 일치함을 확인 할 수 있어 프린트된 시편이 분말금속이 함유 되었음을 확인하였다. 3D 프린트 복합 필라멘트별 차폐효과는 ABS + W, ABS + Bi, PLA + SS, PLA + Cu, PLA + Al의 순서로 실효원자번호와 밀도에 비례하여 차폐율이 높게 나타났다. 본 연구에서는 강화재로 금속 분말이 함유된 금속입자 복합 필라멘트는 방사선의 차폐능력을 가지는 것이 확인되었으며 향후 방사선 차폐용 필라멘트의 사용가능성을 확인하였다.

Revealing the Spatial Distribution of Inorganic Elements in Rice Grains

  • Jeon, Ji Suk;Choi, Sung Hwa;Lee, Ji Yeon;Kim, Ji A;Yang, Young Mi;Song, Eun Ji;Kim, Jae Sung;Yang, Jung Seok;Kim, Kyong Su;Yoo, Jong Hyun;Kim, Hai Dong;Park, Kyung Su
    • Bulletin of the Korean Chemical Society
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    • 제35권11호
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    • pp.3289-3293
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    • 2014
  • Femtosecond laser ablation (fs LA) was used in this study to identify pollution by heavy metals and the distribution of elemental nutrients at different rice milling ratios. Polished rice (degrees of milling of 3, 5, 7, 9, and 11) was collected from major Korean supermarkets and one sample thereof was selected. An internal quality control experiment was conducted using a rice flour certified reference material from the Korea Research Institute of Standards and Science (KRISS CRM) for the evaluation of the efficacy. To assess the effectiveness of the analysis method, the reliability was validated using a food analysis performance assessment scheme (FAPAS), with chili powder serving as an external quality control. The results of the analysis of the inorganic elements Ti, Ca, Al, Fe and Mn in white and brown rice with degrees of milling of 3, 5, 7, 9 and 11 using ICP-MS, ICP-OES and AAS revealed contents of 0.40, 49.2, 2.43, 5.36 and 10.3 mg/kg in white rice and 0.59, 78.0, 7.52, 11.0 and 18.5 mg/kg in brown rice, respectively. Among the elements, there were remarkable differences in the measured contents. By comparing the contents of the elements at different degrees of milling, Ti, Co, As, Ca, Al, Cu, Fe, and Mn were determined to be distributed on the surface of the rice grains, whereas the contents of Cd and Pb increased toward the center of the rice grains, and Si was evenly distributed. After the quantitative analysis of rice samples polished to different degrees of milling, Ca and Al, which were contained in large amounts, and Si were analyzed with specificity by fs LA. The results show that Ca and Al were distributed in the rice husk (protective covering of rice) and Si was distributed in all parts of the rice.

선체외판부 3.2T 박판에 대한 SAW 용접 적용에 관한 연구 (A Study on the Application of SAW Process for Thin Plate of 3.2 Thickness in Ship Structure)

  • 오종인;윤진오;임동용;정상훈;이정수
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2010년도 춘계학술발표대회 초록집
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    • pp.51-51
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    • 2010
  • Recently just as in the automobile industry, shipbuilders also try to reduce material consumption and weight in order to keep operating costs as low as possible and improve the speed of production. Naturally industry is ever searching for welding techniques offering higher power, higher productivity and a better quality. Therefore it is important to have a details research based on the various welding process applied to steel and other materials, and to have the ability both to counsel interested companies and to evaluate the feasibility of implementation of this process. Submerged-arc welding (SAW) process is usually used about 20% of shipbuilding. Similar to gas metal arc welding(GMAW), SAW involves formation of an arc between a continuously-fed bare wire electrode and the work-piece. The process uses a flux to generate protective gases and slag, and to add alloying elements to the weld pool and a shielding gas is not required. Prior to welding, a thin layer of flux powder is placed on the work-piece surface. The arc moves along the joint line and as it does so, excess flux is recycled via a hopper. Remaining fused slag layers can be easily removed after welding. As the arc is completely covered by the flux layer, heat loss is extremely low. This produces a thermal efficiency as high as 60% (compared with 25% for manual metal arc). SAW process offers many advantages compared to conventional CO2 welding process. The main advantages of SAW are higher welding speed, facility of workers, less deformation and better than bead shape & strength of welded joint because there is no visible arc light, welding is spatter-free, fully-mechanized or automatic process, high travel speed, and depth of penetration and chemical composition of the deposited weld metal. However it is difficult to application of thin plate according to high heat input. So this paper has been focused on application of the field according to SAW process for thin plate in ship-structures. For this purpose, It has been decided to optimized welding condition by experiments, relationship between welding parameters and bead shapes, mechanical test such as tensile and bending. Also finite element(FE) based numerical comparison of thermal history and welding residual stress in A-grade 3.2 thickness steel of SAW been made in this study. From the result of this study, It makes substantial saving of time and manufacturing cost and raises the quality of product.

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Hexagonal Boron Nitride Monolayer Growth without Aminoborane Nanoparticles by Chemical Vapor Deposition

  • Han, Jaehyu;Yeo, Jong-Souk
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.409-409
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    • 2014
  • Recently hexagonal boron nitride (h-BN), III-V compound of boron and nitrogen with strong covalent $sp^2$ bond, is a 2 dimensional insulating material with a large direct band gap up to 6 eV. Its outstanding properties such as strong mechanical strength, high thermal conductivity, and chemical stability have been reported to be similar or superior to graphene. Because of these excellent properties, h-BN can potentially be used for variety of applications such as dielectric layer, deep UV optoelectronic device, and protective transparent substrate. Ultra flat and charge impurity-free surface of h-BN is also an ideal substrate to maintain electrical properties of 2 dimensional materials such as graphene. To synthesize a single or a few layered h-BN, chemical vapor deposition method (CVD) has been widely used by using an ammonia borane as a precursor. Ammonia borane decomposes into hydrogen (gas), monomeric aminoborane (solid), and borazine (gas) that is used for growing h-BN layer. However, very active monomeric aminoborane forms polymeric aminoborane nanoparticles that are white non-crystalline BN nanoparticles of 50~100 nm in diameter. The presence of these BN nanoparticles following the synthesis has been hampering the implementation of h-BN to various applications. Therefore, it is quite important to grow a clean and high quality h-BN layer free of BN particles without having to introduce complicated process steps. We have demonstrated a synthesis of a high quality h-BN monolayer free of BN nanoparticles in wafer-scale size of $7{\times}7cm^2$ by using CVD method incorporating a simple filter system. The measured results have shown that the filter can effectively remove BN nanoparticles by restricting them from reaching to Cu substrate. Layer thickness of about 0.48 nm measured by AFM, a Raman shift of $1,371{\sim}1,372cm^{-1}$ measured by micro Raman spectroscopy along with optical band gap of 6.06 eV estimated from UV-Vis Spectrophotometer confirm the formation of monolayer h-BN. Quantitative XPS analysis for the ratio of boron and nitrogen and CS-corrected HRTEM image of atomic resolution hexagonal lattices indicate a high quality stoichiometric h-BN. The method presented here provides a promising technique for the synthesis of high quality monolayer h-BN free of BN nanoparticles.

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하이알로매트릭스를 이용한, 두개골결손을 동반한 선천성피부무형성증의 치료: 1례 보고 (Treatment of Aplasia Cutis Congenita on Scalp using Hyalomatix$^{(R)}$: A Case Report)

  • 이석현;홍종원;노태석;김영석;나동균
    • Archives of Plastic Surgery
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    • 제37권4호
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    • pp.469-472
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    • 2010
  • Purpose: Aplasia Cutis Congenita (ACC) is a rare disease characterized by the focal defect of the skin at birth, frequently involving scalp, but it may affect any region of the body. There are no etiology known but some conditions such as intrauterine vascular ischemia, amniotic adherences and viral infections are associated. The ideal treatment for the ACC is not known. Superficial and relatively small sized defects (< $3{\times}5\;cm$) may heal spontaneously and large defects related with risks of infection and bleeding may require aggressive surgical treatment. Hyalomatrix$^{(R)}$ is a bilayer of an esterified hyaluronan scaffold beneath a silicone membrane. It has been used as a temporary dermal substitute to cover deep thickness skin defect and has physiological functions derive from the structural role in extracellular matrix and interaction with cell surface receptor. This material has been used for the wound bed pre-treatment for skin graft to follow and especially in uncooperative patient, like a newborn, this could be a efficient and aseptic way of promoting granulation without daily irritative wound care. For this reason, using Hyalomatrix$^{(R)}$ for the treatment of ACC was preferred in this paper. Methods: We report a case of a newborn with ACC of the vertex scalp and non-ossified partial skull defect. The large sized skin and skull defect ($6{\times}6\;cm$) was found with intact dura mater. No other complications such as bleeding or abnormal neurologic sign were accompanied. Escharectomy was performed and Hyalomatrix$^{(R)}$ was applied for the protection and the induction of acute wound healing for 3 months before the split-thickness skin graft. During the 3 months period, the dressing was renewed in aseptic technique for every 3 weeks. The skin graft was achieved on the healthy granulation bed. Results: The operative procedure was uneventful without necessity of blood transfusion. Postoperative physical examination revealed no additional abnormalities. Regular wound management was performed in out-patient clinic and the grafted skin was taken completely. No other problems developed during follow-up. Conclusion: Hyalomatrix$^{(R)}$ provides protective and favorable environment for wound healing. The combination of the use of Hyalomatrix$^{(R)}$ and the skin graft will be a good alternative for the ACC patients with relatively large defect on vertex.

창녕 관룡사 약사전 단청안료의 과학적 분석 (A Scientific Analysis of Dancheong Pigments at Yaksajeon Hall in Gwallyoungsa Temple)

  • 한민수;김진형;이장존
    • 헤리티지:역사와 과학
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    • 제47권1호
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    • pp.18-31
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    • 2014
  • 관룡사 약사전에 사용된 단청안료에 대해 과학적 분석을 실시하여 사용안료의 종류와 특성을 밝혀내고, 이를 약사전 벽화 뿐만아니라 대웅전 단청에 사용된 안료와도 비교하고자 하였다. 분석결과, 적색과 녹색, 백색계열의 안료는 채색 부위에 따라 전혀 다른 종류의 안료를 사용한 것으로 나타났으며, 여러 가지 색상구현을 위해 2종류 이상의 안료를 혼합하여 일부 사용하였다. 확인된 안료의 색상별 원료광물은 적색계열의 경우, 진사(Cinnaba)와 연단(Minium), 석간주(Hematite)이며, 백색계열은 합분(Oyster shell white)과 백토(White Clay), 녹색계열은 녹염동광(Atacamite)과 뇌록석(Celadonite)이었다. 또한 흑색계열은 먹(Carbon)이나 카본블랙(Carbon Black), 황색은 황토(Yellow Ocher)이며, 청색계열은 청람석(Lazulite)으로 확인되었다. 이러한 분석결과를 관룡사 내 약사전 벽화나 대웅전 단청에 사용된 안료의 연구결과와 서로 비교했을 때, 전체적으로는 비슷한 원료광물을 사용했으나 녹색이나 백색, 황색 등의 안료들에서 서로 다른 원료광물이 가감되어 사용되었음을 일부 확인하였다. 결국 같은 시기, 같은 사찰내에서도 회화의 종류나 대상건물에 따라 안료의 원료광물은 선택적으로 사용될 수 있다는 것을 보여주는 결과이다.

운영중인 지하구조물의 누수처리를 위한 유도배수공법의 개선 (Improvement of existing drainage system for leakage treatment in exiting underground structures)

  • 김동규;임민진
    • 한국터널지하공간학회 논문집
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    • 제19권4호
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    • pp.669-683
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    • 2017
  • 본 연구의 목적은 지하 콘크리트 구조물에서 부분적으로 발생하는 누수를 처리하기 위하여 기존에 제안된 전단면 유도배수시스템을 수정하여 제안하는 것이다. 누수된 부분에만 유도배수시스템을 적용하기 위하여 누수된 지하수를 유도배수시스템내에서 집수 지점으로 유도하는 기술과 집수된 지하수를 지하 콘크리트 구조물의 배수 시설로 이동시키기 위한 기술을 추가 제안하였다. 유도배수시스템내로 누수된 지하수를 집수 지점으로 유도하기 위한 4가지 방수 재료들, 즉, 다공질의 고무 재료인 Durkflex, 초강력 접착력을 가진 KE-45 실리콘 접착제, 폴리머 계열 재료인 Hotty-gel 및 일반 실리콘 접착제에 대한 성능 평가를 수행하였다. 방수 재료 Hotty-gel만 완벽한 방수 성능을 보였고 나머지 3가지 방수 재료들에서는 누수가 발생하였다. 선정된 방수 재료 Hotty-gel과 집수 지점에서 배수시설로 누수된 지하수를 이동시키기 위한 배수관 및 고정 새들(saddle)을 추가한 유도배수시스템을 콘크리트 옹벽에서 시험 시공하였다. 재령 7일, 14일, 21일, 28일, 2개월, 및 3개월에 수정된 유도배수시스템 배면에 1,000 ml의 물을 주입하여 방수 성능과 유도배수 성능을 평가하였다. 재령 3개월까지 방수 성능 및 유도배수 성능에는 전혀 이상이 없는 것으로 확인되었다. 수정된 유도배수시스템의 총 공사 기간 및 공사비에 대한 평가를 위하여 표면 정리 단계, 누수 처리 단계 및 단면 복구 단계별로 기존 누수 보수 공법과 비교하였다. 작업 내용, 보수 재료, 시공 장비, 작업 시간, 작업 인원 등을 고려한 개략적인 총 공사 시간 및 공사비에 대하여 비교하였다. 각 시공 단계별로 비교 분석한 결과 수정된 유도배수시스템은 기존의 누수 처리 공법보다 총 공사 기간 및 공사비를 절감할 수 있을 것으로 판단되었다.

마오리族 傳統 服飾과 文身 考察 (A Study on the Traditional Costumes and Tattoo of the Maori)

  • 황춘섭;정현주
    • 복식문화연구
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    • 제3권2호
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    • pp.241-260
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    • 1995
  • The Maori's traditional clothing materials, basic forms of dress, and the pattern and technique of tatoo were examined in the present study in order to deepen the appreciation of the cultural heritage of the Maori. The research method employed was the analysis of written materials. And a fild-trip was also made for the study. The study was limitted to the traditional culture of body adornment of the Maori including the clothing which is preserved and practicing by them at the present day, and the origin and the process of the historical development of those are not included in the scope of the present study. Followings are the results of the study: (1) By far the most widely used fiber for Maori clothing is abtained from what is commonly called New Zealand Flax. The fiber of kiekie(Freycinetia baueriana) and cabbage trees(Cordyline spp.) may also be used. The strong, long-lasting fiber of toi(cordyline indivisa) is used for a prestige warrior's cloak. Flat strips of ti kauka(Cordyline australi) are also used as thatch on rain cloaks. (2) Regardless of technique used, Maori weaving is always worked horizontally from left to right. Traditionally the work was suspended between two upright turuturu or weaving sticks. As the work progressed a second pair of uprights was used to keep the work off the ground. These uprights were moved forward as required. Because the weaver sat on the ground, the working edge was kept at a height that was comfortable to reach. No weaving tools are used, the wefts(aho) being manipulated by the fingers. The two main Maori weaving techniques are whatu aho patahi(single-pair twining) and whatu aho rua(double-pair twining). (3) The Maori wore two basic garments - a waist met and a cloak. The cloth of commoners were of plain manufacture, while those of people of rank were superior, sometimes being decorated with feather or dyed tags and decorated borders. Children ran more-or-less naked until puberty, being dressed only for special events. Some working dress consisted of nothing more than belts with leaves thrust under them. Chiefs and commoners usually went barefoot, using rough sandals on journeys over rough country (4) The adornment of men and women of rank was an important matter of tribal concern as it was in chiefly persons that prestige of the group was centred, The durable items of Maori persons adornment were either worn or carried. Ornaments of various kinds were draped about the neck or suspended from pierced earlobes. Combs decorated the head. Personal decorations not only enhanced the appearance of men and women, but many had protective magical function. The most evident personal ornament was the hei-tiki made of jade or other material. Maori weapons were treasured by their owners. They served on bottle and were also personal regalia. A man of rank was not fully dressed without a weapon in hand. Also weapons were essential to effective oratory. (5) No man or woman of rank went without some tattoo adornment except in extremely rare instances when a person was too sacred to have any blood shed. The untattooed were marked as beeing commoners of no social standing. This indelible mark of rank was begun, with appropriate rite and ritual, at puberty. And tattoo marked the person as being of a marriageable age. Maori tattoo was unlike most traditional tattoo in that its main line were 'engraved' on the face with deep cuts made by miniature bone chisels. The fill-in areas were not tattooed with cuts but with the multiple pricks of small bone 'combs' that only lightly penetrated the skin surface. The instrument of tattoo consisted of small pots of pumice or wood into which was placed a wetted black pigment made from burnt kauri gum, burnt vegetable caterpillars or other sooty materials. A bird bone chisel or comb set at right angles on a short wooden handle was dipped into the gigment, that a rod or stick was used to tap head of this miniature adze, causing penetration of the skin surface. Black pigment lodged under the skin took on a bluish tinge. A full made facial tattoo consisted of major spirals with smaller spirals on each side of the nose and sweeping curved lines radiating out from between the brows over the forehead and from the nose to the chin. The major patterns were cut deep, while the secondary koru patterns were lightly pricked into the skin.

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화순 운주사 석조불감의 재질특성과 풍화훼손도 평가 (Material Characteristics and Deterioration Assessment of the Stone Buddhas and Shrine in Unjusa Temple, Hwasun, Korea)

  • 박성미;이명성;최석원;이찬희
    • 보존과학회지
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    • 제24권
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    • pp.23-36
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    • 2008
  • 화순 운주사 석조불감(보물 제797호)은 고려시대 양식을 갖추고 있는 석조문화재로서 아주 독특한 형식적 특징을 보여준다. 남북의 감실 내부에는 각각의 불상이 등을 맞대고 있는 쌍배 좌상의 형태를 보이고 있어 역사적, 미술사적 및 학술적으로 높은 평가를 받고 있다. 그러나 이 석조불감은 특별한 보호시설 없이 옥외에 노출되어 장기간의 풍화작용으로 다양한 훼손양상이 복합적으로 나타나고 있다. 이 석조불감은 총 47매의 암석으로 구성되어 있으며, 총 하중은 약 56.6톤이다. 구성 재질은 주로 회백색의 유리질 조직을 갖는 화산력 응회암류로 암편질 응회암과 유문암질 각력응회암이다. 또한 이들의 보수과정에서 부분적으로 흑운모 화강암을 사용하였다. 이들 응회암질암의 화학적 풍화지수는 52.1~59.4이나, 대체적인 화강암은 보다 신선한 50.0~51.0을 보인다. 이 연구에서는 석조불감에 나타나는 손상유형을 크게 물리적, 화학적 및 생물학적 풍화로 구분하여 훼손양상에 따라 종합훼손지도를 작성하였고, 표면적 대비 점유율을 산출하였다. 이 결과, 물리적 풍화양상 중 박리박락이 모든 방위에서 가장 높은 점유율을 보였으며, 방위로는 석감의 남측 면이 39.1%로 가장 높은 풍화도를 보였다. 화학적 풍화는 흑색 변색, 황갈색 변색, 백화현상 순으로 나타났으며 석감의 서측 면에서 61.2%의 높은 점유율을 보인다. 육안으로 볼 때, 가장 심각한 훼손을 보이는 생물학적 풍화는 회색지의류가 압도적으로 높으며, 석조불감 북측 면이 38.3%로 가장 높게 나타났다. 따라서 균열과 박리박락이 심한 부재의 접합 및 보강이 선행되어야 하며, 이차적 오염물질과 생물들은 정기적인 세정을 통해 제거하는 등 각각의 손상도에 적합한 보존방안의 수립과 임상실험을 통한 과학적 처리가 필요하다.

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