• Title/Summary/Keyword: surface protective material

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Concrete crack rehabilitation using biological enzyme

  • Chen, How-Ji;Tai, Pang-Hsu;Peng, Ching-Fang;Yang, Ming-Der
    • Computers and Concrete
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    • v.19 no.4
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    • pp.413-417
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    • 2017
  • Concrete is a material popularly used in construction. Due to the load-bearing and external environmental factors during utilization or manufacturing, its surface is prone to flaws, such as crack and leak. To repair these superficial defects and ultimately and avoid the deterioration of the concrete's durability, numerous concrete surface protective coatings and crack repair products have been developed. Currently, studies are endeavoring to exploit the mineralization property of microbial strains for repairing concrete cracks be the repairing material for crack rehabilitation. This research aims to use bacteria, specifically B. pasteurii, in crack rehabilitation to enhance the flexural and compression strength of the repaired concrete. Serial tests at various bacterial concentrations and the same $Urea-CaCl_2$ medium concentration of 70% for crack rehabilitation were executed. The results prove that the higher the concentration of the bacterial broth, the greater the amount of calcium carbonate precipitate was induced, while using B. pasteurii broth was for crack rehabilitation. The flexural and compression strengths of the repaired concrete test samples were the greatest at 100% bacterial concentration. Compared to the control group (bacterial concentration of 0%), the flexural strength had increased by 32.58% for 1-mm crack samples and 51.01% for 2-mm crack samples, and the compression strength had increased by 28.58% and 23.85%, respectively. From the SEM and XRD test results, a greater quantity of rectangular and polygonal crystals was also found in samples with high bacterial concentrations. These tests all confirm that using bacteria in crack rehabilitation can increase the flexural and compression strength of the repaired concrete.

Properties of Chemical Vapor Deposited ZrC Coating Layer using by Zirconium Sponge Materials (지르코늄 스폰지를 원료로 사용하여 화학증착법으로 제조된 탄화지르코늄 코팅층의 물성)

  • Kim, Jun-Gyu;Choi, Yoo-Youl;Lee, Young-Woo;Park, Ji-Yeon;Choi, Doo-Jin
    • Journal of the Korean Ceramic Society
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    • v.45 no.4
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    • pp.245-249
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    • 2008
  • The SiC and ZrC are critical and essential materials in TRISO coated fuel particles since they act as protective layers against diffusion of metallic and gaseous fission products and provides mechanical strength for the fuel particle. However, SiC and ZrC have critical disadvantage that SiC loses chemical integrity by thermal dissociation at high temperature and mechanical properties of ZrC are weaker than SiC. In order to complement these problems, we made new combinations of the coating layers that the ZrC layers composed of SiC. In this study, after Silicon carbide(SiC) were chemically vapor deposited on graphite substrate, Zirconium carbide(ZrC) were deposited on SiC/graphite substrate by using Zr reaction technology with Zr sponge materials. The different morphologies of sub-deposited SiC layers were correlated with microstructure, chemical composition and mechanical properties of deposited ZrC films. Relationships between deposition pressure and microstructure of deposited ZrC films were discussed. The deposited ZrC films on SiC of faceted structure with smaller grain size has better mechanical properties than deposited ZrC on another structure due to surface growth trend and microstructure of sub-deposited layer.

Effects of Test Temperature on the Reciprocating Wear of Steam Generator Tubes

  • Hong, J.K.;Kim, I.S.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.379-380
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    • 2002
  • Steam generators (S/G) of pressurized water reactors are large heat exchangers that use the heat from the primary reactor coolant to make steam in the secondary side for driving turbine generators. Reciprocating sliding wear experiments have been performed to examine the wear properties of Incoloy 800 and Inconel 690 steam generator tubes in high temperature water. In present study, the test rig was designed to examine the reciprocating and rolling wear properties in high temperature (room temperature - $300^{\circ}C$) water. The test was performed at constant applied load and sliding distance to investigate the effect of test temperature on wear properties of steam generator tube materials. To investigate the wear mechanism of material, the worn surfaces were observed using scanning electron microscopy. At $290^{\circ}C$, wear rate of Inconel 690 was higher than that of Incoloy 800. It was assumed to be resulted from the oxide layer property difference due to the a\loy composition difference. Between 25 and $150^{\circ}C$ the wear loss increased with increasing temperature. Beyond $150^{\circ}C$, the wear loss decreased with increasing temperature. The wear loss change with temperature were due to the formation of wear protective oxide layer. From the worn surface observation, texture patterns and wear particle layers were found. As test temperature increased, the proportion of particle layer increased.

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ANTICORROSION PROPERTIES OF SIOC COATED SUS-316

  • Kim, Su-Ryong;Gwon, U-Taek;Kim, Jeong-Ju;Kim, Jong-Il;Kim, Yeong-Hui;Kim, Jeong-Il;U, Chang-Hyeon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.34.2-34.2
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    • 2009
  • The ceramic coatings on metallic materials have attracted by many researchers due to the chemical inertness of ceramic materials. In such aspect, SiOC is a promising material tobe used as protective coating layer on metallic materials due to its outstanding thermal stability and chemical inertness. In this research, SiOC coating was carried out onto SuS-316 substrate using Cl free preceramic polymers such aspolyphenylcarbosilane. 20% of polymethylphenylsilane in cyclohexane solution was coated onto metal surface by dip coating method. Thermal oxidation was carried out at $200^{\circ}C$ for crosslink of the preceramic polymer and the sample was pyrolysized at $800^{\circ}C$ under argon to convert the preceramic polymer to amorphous SiOCx state. The microstructure of the SiOCx film after pyrolysis was investigated using FE-SEM. Corrosion resistance of SiOC coated SuS-316 substrate has been investigated using 5% HCl solution at 25, 40, 60 and $80^{\circ}C$ for 7days. The data revealed that the corrosion resistance increased with SiOC coating on SuS-316 substrate.

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The Optimal Design Technique for Improving Durability of Spline Shaft of the Self Propelled Artillery' Generator (자주포 발전기 스플라인 축 내구성 향상을 위한 최적 설계 기법)

  • Kim, Byeong Ho;Kang, Hyen Jae;Park, Young Il;Seo, Jae Hyun
    • Journal of the Korea Institute of Military Science and Technology
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    • v.18 no.5
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    • pp.485-491
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    • 2015
  • In this study, the experimental and analytical investigation on structural integrity evaluation of spline shaft of self propelled artillery' generator were carried out. For this work, macro and microstructure fractography of spline shaft were observed. According to the results of the structure analysis and simulation, the shaft was redesigned and optimized. To improve the stiffness and shear stress, the material was changed from the SNCM220 to SNCM439 and surface roughness and protective coating treatment are changed to increase the stress relaxation, respectively. From the result of the torsion test of shaft and accelerated life test of generator, the shaft of a SNCM439 with heat-treatment(Q/T) and electroless nickel plating was superior quality reliability and durability than the others. Therefore, modeling and simulation corresponded well with the experimental result and structural safety was confirmed by generator performing.

Effect of Organic Photosensitizers on the Antimicrobial Property of Polyurethane coated Leather

  • Oh, Kyung Wha;Lim, Ki Sub
    • Fashion & Textile Research Journal
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    • v.15 no.4
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    • pp.630-634
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    • 2013
  • Cow leather coated with polyurethane film that contains various organic photosensitizers was investigated to demonstrate the antimicrobial properties in the application of the material to protective clothing and home appliances. To prepare the antimicrobial coating on leather surfaces with high potency against microbes, photoactive agents, such as benzophenone (BP), 4,4'-bis(dimethylamino) benzophenone (MK), 4,4'-dihydroxybenzophenone (DHBP) and methylene blue (MB), were incorporated into polyurethane-based coating solutions. The photoactive antimicrobial agent treated leather samples were characterized by SEM, color appearance, color fastness against abrasion, and antimicrobial tests. The optical properties of organic photosensitizers indicated that active UV absorbance ranges were different: BP (around 250 nm), MK (around 360 nm), DHBP (around 305 nm) and MB (around 295 nm &570 nm-685 nm). The intensity of the UV absorbance curve at the UVA light wavelength for the antimicrobial test showed the highest value with MK; subsequently, this was followed by MB, DHBP and BP in decreasing order. The treated-leather samples demonstrated excellent antibacterial activity under UVA light. The antimicrobial effects for the Staphylococcus aureus were superior to Escherichia coli. Moreover, the polyurethane finishing showed an effective durability to abrasion. The overall results indicated that DHBP is the most suitable PU coating additive to provide antimicrobial properties to leather as well as color and surface appearance than MK, MB, and BP.

Analysis of Properties Multi-Layered TiN/CrN Thin Films Deposited by AIP Method (AIP법으로 증착된 TiN/CrN 다층박막의 특성 분석)

  • Baek, Min-Sook;Yoon, Dong-Joo;Heo, Ki-Bok;Kim, Byung-Il
    • Korean Journal of Materials Research
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    • v.28 no.7
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    • pp.405-410
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    • 2018
  • TiN and CrN thin films are among the most used coatings in machine and tool steels. TiN and CrN are deposited by arc ion plating(AIP) method. The AIP method inhibits the reaction by depositing a hard, protective coating on the material surface. In this study, the characteristics of multi-layer(TiN/CrN/TiN(TCT), CrN/TiN/CrN(CTC)) are investigated. For comparison, TiN with the same thickness as the multilayer is formed as a single layer and analyzed. Thin films formed as multilayers are well stacked. The characteristics of micro hardness and corrosion resistance are better than those of single layer TiN. The TiN/CrN peak is confirmed because both TCT and CTC are formed of the same component(TiN, CrN), and the phase is first grown in the (111) direction, which is the growth direction. However, the adhesion and abrasion resistance of the multilayer films are somewhat lower.

Acute Hydrofluoric Acid Exposure: Our Clinical Experience at Emergency Centers in Two University Teaching Hospitals (2개 대학병원 응급센터에 내원한 급성 불화수소산 노출 환자에 대한 임상적 경험)

  • Han, Kyu-Hong;Yang, Jung-Il;Jo, Seung-Yook;Cho, Yong-Chul;Ryu, Seung;Lee, Jin-Woong;Kim, Seung-Whan;Yoo, In-Sool;You, Yeon-Ho;Park, Jung-Soo
    • Journal of The Korean Society of Clinical Toxicology
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    • v.7 no.2
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    • pp.121-126
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    • 2009
  • Purpose: We investigated the clinical characteristics and demographics of patients who suffered from hydrofluoric acid chemical injury and the mechanism of damage. Methods: We retrospectively reviewed the medical records of patients who were exposed to hydrofluoric acid from March 2004 to March 2009 and who were seen at the emergency centers in two university teaching hospitals. Results: Forty four patients out of 47 patients suffered from chemical burn, while the injuries of the remaining 3 could not be identified by the medical records. A total of 17 hydrofluoric acid chemical injury patients were enrolled during the study period, and their mean age was $29.6{\pm}7.0$. All the patients were accidentally injured by contact with the material and none of them inhaled or ingested the material. Only 6 patients wore appropriate protective equipments and 5 underwent the water irrigation for more than 10 minutes. The most common exposure area was the hand and forearm (70.5%). Less than 1% of all of the patients had their total body surface (TBS) exposed to hydrofluoric acid (mean=0.35%). The mean time interval from calcium gluconate administration to pain relief was $33.6{\pm}8.8$ hours. Conclusion: When exposed to hydrofluoric acid, it is important to wear protective equipment and undergo water irrigation for more than 10 minutes. Pain and skin damage were observed in all the patients. After treatment, we concluded that administration of calcium gluconate and pain killers was successful in relieving pain, and the prognosis was also positive for the admitted and followed up patients when less than 1% of the TBS was exposed.

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Effect of Cr content on the FAC of pipe material at 150℃ (150℃에서 원전 2차측 배관재료의 Cr함량에 따른 유체가속부식 특성)

  • Park, Tae Jun;Kim, Hong Pyo
    • Corrosion Science and Technology
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    • v.12 no.6
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    • pp.274-279
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    • 2013
  • Flow accelerated corrosion (FAC) of the carbon steel piping in nuclear power plants (NPPs) has been major issue in nuclear industry. During the FAC, a protective oxide layer on carbon steel dissolves into flowing water leading to a thinning of the oxide layer and accelerating corrosion of base material. As a result, severe failures may occur in the piping and equipment of NPPs. Effect of alloying elements on FAC of pipe materials was studied with rotating cylinder FAC test facility at $150^{\circ}C$ and at flow velocity of 4m/s. The facility is equipped with on line monitoring of pH, conductivity, dissolved oxygen(DO) and temperature. Test solution was the demineralized water, and DO concentration was less than 1 ppb. Surface appearance of A 106 Gr. B which is used widely in secondary pipe in NPPs showed orange peel appearance, typical appearance of FAC. The materials with Cr content higher than 0.17wt.% showed pit. The pit is thought to early degradation mode of FAC. The corrosion product within the pit was enriched with Cr, Mo, Cu, Ni and S. But S was not detected in SA336 F22V with 2.25wt.% Cr. The enrichment of Cr and Mo seemed to be related with low, solubility of Cr and Mo compared to Fe. Measured FAC rate was compared with Ducreaux's relationship and showed slightly lower FAC rate than Ducreaux's relationship.

A Study of Bias Draping Design (바이어스 드레이핑 디자인 연구(硏究))

  • Kim, Hee-Kyun;Cho, Kyu-Hwa
    • Journal of Fashion Business
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    • v.4 no.4
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    • pp.1-16
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    • 2000
  • The purpose of this study is to investigate the formative beauty, changes in fashion and aesthetical sense that can be seen in the bias drapings of Madeleine Vionnet and her influences on modern fashion since she used draping as a new fashion means to represent the new feminine images which modernism of the early 20th century and social changes from the two great World War's generated, and to provide proper data to encourage designers' creativity that is wanting in the circle of Korea fashion. Bias draping led women to respect worship their body from the heart with seductive modernism enriching the material's texture to the utmost through geometrical patterns of triangle, quartered plane and quardrants and simple cylindrical cuts and with an attribute adapting itself to the wearer's body. Bias draped wear consisted of light and transparent materials and overall surface decoration revealed women's movements and sought the extension of environmental movements and demonstrated its eroticism. On the other hand, biased daywear gained anonymity through cutting true to body line and psychological protective quality as of cape, and this went well with the independent femininity accepting difference as well as pursuing revolution from the inside. The great inflation and the 2nd World War gave birth to escape from reality like surrealistic artistic tendencies and Hollywood films and increased romanticism. Bias draping once underwent unpopularity except in expensive clothes due to knit wear boom and the utilization of new elastic materials, however, it began to receive lights again from pluralization waves and retro tendencies and to be introduced in many designers' collections. A young genius of England, John Galliano improved functions of Haute Couture through creation of new styles and fantastic shows to promote profits in the fashion markets. Bias draping fitted in human body line provides us comfort and aesthetic qualities through careful choice of material and elegance by delicate cutting.

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