• Korean Journal of Materials Research
• /
• v.5 no.2
• /
• pp.197-202
• /
• 1995

The surface morphology and grain growth of amophous silicon (a-Si) films deposited by low pressure chemical vapor deposition (LPCVD) have been investigated as a function of deposition and in sltu annealing condition. The film deposited at the amorphous to polycrystalline transition temperature has an extra-rough, rugged surface with (311) t.exture. At the same deposition temperature, the grain structure tends to shirr. from the polycrystalline to the amorphous phase with increasing the film thickness. It is found that nucleation of a-Si during in situ annealing at the transition temperature without breaking the vacuum starts to occur from surface Si atom migration in contrast to a heterogeneous nucleation during film deposition.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2007.11a
• /
• pp.97-98
• /
• 2007

In this paper, we analyzed the reset current variation of PRAM device with top electrode using the 3-D finite element analysis tool. As thickness of phase change material thin film decreased, reset current caused by phase transition highly increased. Joule's heat which was generated at the contact surface of phase change material and bottom electrode of PRAM was given off through top electrode to which was transferred phase change material. As thermal conductivity of top electrode decreased, heating temperate was increased.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2002.05b
• /
• pp.94-97
• /
• 2002

Phase transitions of the $Sm_{2}(MoO_{4})_{3}$ single crystal were studied through thermal analysis, x-ray methods and SEM/EDS. $Sm_{2}(MoO_{4})_{3}$ undergoes the ferroelastic and ferroelectric phase transition at $198^{\circ}C$. With increasing temperature, the second phase transition occurs at $928^{\circ}C$. From TG analysis, the mass loss of $Sm_{2}(MoO_{4})_{3}$ exhibits an anomalous behavior at about $650^{\circ}C$ and the curves increased monotonically to $1132^{\circ}C$. SEM and EDS show that the escape of ${MoO_{4}^{2-}$ tetrahedra from the lattice of $Sm_{2}(MoO_{4})_{3}$ increase above $928^{\circ}C$, so $Sm_{2}(MoO_{4})_{3}$ has a very rough surface and internal cracks.

• Korean Journal of Crystallography
• /
• v.12 no.2
• /
• pp.102-112
• /
• 2001

The mechanical properties of silicon crystals are important from the viewpoint of wafer and device fabrication processes. It is now widely recognized that silicon undergoes a series of phase transformations when subjected to high pressures, using conventional high pressure devices, such as diamond anvils or indenters. Diamond tip scratching on a silicon surface in the various conditions introduces various kinds of mechanical damage and stressed states. Micro Raman spectroscopy was used to observe the phase transition of single crystal silicon. As results, different morphologies were observed as functions of scratching speed and loading condition and various phases were observed as functions of scratching speed and loading condition.

• Bulletin of the Korean Chemical Society
• /
• v.16 no.5
• /
• pp.410-416
• /
• 1995

The proton transfer energies of gas phase glycine and alanine and those of hydrated glycine and alanine were calculated both with Hartree-Fock and $M{\Phi}ller-Plesset$ ab initio molecular orbital (MO) calculations with 6-31G** basis set. The transition states of the proton transfer of gas phase glycine was also investigated. For zwitterions, both for glycine and alanine, the water bound to -NH3+ site stabilize the complex more compared with the water bound to -CO2-. The proton transfer energy, ΔEpt, of glycine, alanine, mono-hydrated glycine, mono-hydrated alanine, di-hydrated glycine and di-hydrated alanine were obtained as 30.78 (MP2: 22.57), 31.43, 23.99 (MP2: 17.00), 24.98, 22.87, and 25.63 kcal/mol, respectively. The activation energy for proton transfer from neutral (Nt) glycine to zwitterion (Zw) glycine, Ea, was obtained as 16.13 kcal/mol and that for reverse process, Ear, was obtained as 0.85 kcal/mol. Since the transition state of the proton transfer of gas phase glycine locate near the glycine zwitterion on the potential energy surface and the shape of the potential well of the zwitterion is shallow, the zwitterion easily changed to neutral glycine through the proton transfer.

• Advances in aircraft and spacecraft science
• /
• v.5 no.4
• /
• pp.431-444
• /
• 2018

Numerical simulations have been conducted to study the unstart/restart characteristics of an over-under turbine-based combined-cycle propulsion system (TBCC) inlet during the inlet transition phase. A dual-solution area exists according to the Kantrowitz theory, in which the inlet states may be different even with the same input parameters. The entire transition process was divided into five stages and the unstart/restart hysteresis loop for each stage was also obtained. These loops construct a hysteresis surface which separates the operating space of the engine into three parts: in which a) inlet can maintain a started state; b) inlet keeps an unstarted state; c) inlet state depends on its initial state. During the transition, the operation of the engine follows a certain order with different backpressures and splitter angles, namely control route, which may result in disparate inlet states. Nine control routes with different backpressures and transition stages were designed to illuminate the route-dependent behavior of the inlet. The control routes operating towards the unstart boundary can make the inlet transit from a started state into an unstarted one. But operating backward the same route cannot make the inlet restart, additional effort should be made.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
• /
• v.29 no.9
• /
• pp.685-692
• /
• 2018

Using Babinet's principle and generalized sheet transition conditions(GSTCs), an analysis method for metascreens is proposed. First, the relation of a complementary screen between a metafilm and metascreen with the same dimensions was confirmed using Babinet's principle. These properties were verified by comparing the reflection coefficient of the patch and the transmission coefficient of the mesh. The patch and mesh are the basic structures of metafilms and metascreens, respectively. Based on these findings, it is also confirmed that the reflection coefficient of the patch surface calculated by GSTCs has the same value as the transmission coefficient of the mesh surface. It is expected that the proposed analysis methods can be applied to the magnitude, phase, and polarization of electromagnetic waves in the various unit structures of a given metasurface.

• Journal of the Korean institute of surface engineering
• /
• v.36 no.5
• /
• pp.413-417
• /
• 2003

The effect of 0-0.7 ㏖% addition of $Cr_2$$O_3$on the dielectric, pyroelectric, and piezoelectric properties were studied in the (Mg$0.7Pb_{1}$$3/Nb_{2}$3/)$O_3$-$0.3PbTiO_3$(0.7PMN-0.3PT) ceramics with composition near the morphotropic phase boundary. The dielectric constant and loss of the ceramics samples were measured as a function of temperature at various frequencies (0.1-100 KHz). The pyroelectric coefficient was measured by using the Byer-Roundy method as a function of temperature. Dielectric, pyroelectric, and piezoelectric constant achieved the maximum values of 0.4 ㏖% $Cr_2$$O_3$The transition temperature is continuously shifted to lower temperature with an increase of a small amount of $Cr_2$$O_3$.

• Bulletin of the Korean Chemical Society
• /
• v.12 no.1
• /
• pp.80-85
• /
• 1991

Laser Raman spectroscopy has been used to study the tungsta catalyst supported on titania. The surface tungsten species which forms on titania after calcination appeared to possess a structure that is independent of the initial impregnation condition. The surface polytungstate seemed to be stable only at the interfacial region since the crystalline WO$_3$ phase was observed as long as the tungsta loading was in excess of monolayer coverage. The close intact and strong interaction between the polytungstate and the titania could be evidenced from the inhibition of the phase transition of TiO$_2$ from anatase to rutile.

• Korean Chemical Engineering Research
• /
• v.47 no.4
• /
• pp.481-487
• /
• 2009

In this of study, effects of input air velocity(0.05~0.22 m/sec) and molten carbonate salt temperature ($870{\sim}970^{\circ}C$) on flow regime transition have been studied by adopting a drift-flux model of air holdup and a stochastic analysis of differential pressure fluctuations in an air-molten sodium carbonate salt two-phase system(molten salt oxidation process). Air holdup where the flow regime transition begins was determined by air holdup-drift flux plot. The air holdup value which the flow regime transition begins was increased with increasing molten carbonate salt temperature due to the decrease of viscosity and surface tension of molten carbonate salt. To characterize the flow regime transition more quantitatively, differential pressure fluctuation signals have been analyzed by adopting the stochastic method such as phase space portraits and Kolmogorov entropy, The Kolmogorov entropy decreased with an increasing of molten carbonate salt temperature but increased gradually with an increase in an air velocity, however, it exhibited different tendency with the flow regime and the air velocity value which flow regime transition begins was same to the results of drift-flux analysis.