• Proceedings of the KIEE Conference
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• 2005.07c
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• pp.2193-2195
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• 2005

The hybrid discharge reactor was designed for the application of wastewater treatment and the removal of hazardous volatile organic substances in water. This discharge type was similar to the barrier discharge, and the surface discharge on the dielectric surface was propagated to the water surface. That caused the heterogeneous chemical reaction strongly at the interface between the working gases and the water surface. Changes of the conductivity, acidity, and the dissolved ozone with respect to the treatment time and water quantities were studied as the fundamental experiment. The concentration of hydrogen ions largely increased with increasing the treatment time and the conductivity increased with respect to the increase of water quantities under the constant other discharge parameters.

• Journal of Korean Society for Atmospheric Environment
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• v.15 no.6
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• pp.779-789
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• 1999

To support daily ground-level $O_3$ forecasting in Seoul, a transfer function model(TFM) has been developed by using surface meteorological data and pollutant data(previous-day [$O_3$] and [$NO_2$]) from 1 May to 31 August in 1997. The forecast performance of the TFM was evaluated by statistical comparison with $O_3$ concentration observed during September it is shown that correlation coefficient(R), root mean squared error(RMSE), normalized mean squared error(NMSE) and mean relative error(MRE) were 0.73, 15.64, 0.006 and 0.101, respectively. The TFM appeared to have some difficulty forecasting very high $O_3$ concentrations. To compare with this model, multiple regression model(MRM) was developed for the same period. According to statistical comparison between the TFM and MRM. two models had similar predictive capability but TFM based on $O_3$ concentration higher than 60 ppb provided more accurate forecast than MRM. It was concluded that statistical model based on TFM can be useful for improving the accuracy of local $O_3$ forecast.

• Journal of Korean Society for Atmospheric Environment
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• v.30 no.6
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• pp.531-537
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• 2014

Terrestrial vegetation has been known as a main source of biogenic volatile organic compounds (BVOCs). Isoprene and monoterpene among the BVOCs are most abundant species emitted by forests, and have a significant impact on atmospheric chemistry. Abundancy of these species could lead to an increase or decrease in the production of natural tropospheric ozone in forests, depending on the nitric oxide (NO) concentration. Soil is the most significant source of natural NO. Understanding of NO emission from forest soil could be critical in evaluation of air quality in the forest area. Flux-gradient similarity theory (FGST) was applied for practical use to estimate forest soil NO emission at Mt. Taewha where is available micro-meteorological data near surface monitoring from flux tower. NO fluxes calculated by FGST were compared to flux results by flow-through dynamic chamber (FDC) measurement. Surface NO emission trends were shown between two different techniques, however their magnitudes were found to be different. NO emissions measured from FDC technique were relatively higher than those from theoretical results. Daily mean NO emissions resulted from FGST during Aug. 13, 14 and 15 were $0.28{\pm}8.45$, $2.17{\pm}15.55$, and $-3.18{\pm}13.65{\mu}gm^{-2}hr^{-1}$, respectively, while results from FDC were $2.26{\pm}1.44$, $5.11{\pm}3.85$, and $2.23{\pm}6.45{\mu}gm^{-2}hr^{-1}$. Trends of daily means were shown in similar pattern, which NO emissions were increasing during late afternoon ($r^2$=0.04). These emission trends could be because soil temperature and moisture influence importantly soil microbiology.

• Journal of Wellbeing Management and Applied Psychology
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• v.6 no.1
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• pp.17-22
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• 2023

Purpose: VOCs (volatile organic compounds) are all the organic compounds that react with solar rays and increase the concentration of ozone in the troposphere and are partially also known as carcinogens. The adsorption using activated carbon is usually applied to remove VOCs. Research design, data and methodology: The 20 places of surface coating facilities were selected to evaluate the emission amount of VOCs in Seoul. In addition, the removal efficiency of VOCs in 25 places of automobile coating facilities was evaluated. Results: The average emission amount of VOCs was 10.903 kg/hr from automobile coating facilities, while 3.520 kg/hr from other surface coating facilities. The removal efficiency in adsorption with the combustion catalytic process has the mean value of 87.9% and the regeneration efficiency of activated carbon has the mean value of 95.0%. Conclusions: The removal efficiency in adsorption with the biofiltration process has the mean value of 89.8% and the regeneration efficiency of activated carbon has the mean value of 94.8%. The removal efficiency in the plasma catalyst process has the mean value of 79.3%.

• Journal of Korean Society for Atmospheric Environment
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• v.11 no.2
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• pp.185-190
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• 1995

Recently, because of the worse of the air pollution, the excessive airtught of building and the inferiority of air conditioning system, the development of high efficiency air purification technology was enlarged to the environmental improvement of an indoor or a harmful working condition. The air purification technology has used chemical filters or charcoal filters or charcoal to remove hazardouse gaseous pollutants (SO$_{x}$, NO$_{x}$, NH$_{3}$, etc.) by air pollutant control technology, but they have many problems of high pressure loss, short life, wide space possession, and treatment of secondary wastes. For these reason, the object of reasearch shall be hazardous gaseous pollutants removal by the surface discharge induced plasma chemical process that is A.C. discharge of multistreams applied A.C. voltage and frequency between plane induced eletrode and line discharge eletrode of tungsten, platinum or titanium with a high purified alumina sheet having a film-like plane. As a result, the control performance for hazardous gaseous pollutants showed very high efficiency in the normal temperature and pressure. Also, after comtact oxidation decomposition of harmful gaseous pollutants, the remainded ozone concentration was found much lower than that of ACGIH or air pollution criteria in Korea.rea.

• Journal of Korean Society for Atmospheric Environment
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• v.25 no.5
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• pp.369-381
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• 2009

The objective of this study was to simulate surface air pollutants and to examine reliability of mobile emission for CMAQ system using an observation-based approach in the Seoul Metropolitan Area. Accurate assessment of emissions from mobile source is one of the most debatable parts in the entire emissions inventory process. For this study, we evaluated the official emission inventories of Volatile Organic Compounds (VOCs) and nitrogen oxides ($NO_x$) using an observation-based approach. In this paper, we achieved VOCs/CO and $NO_x$/CO ratios derived from ambient measurements taken from June to August of 2005 in early morning (07:00~08:00). And we compared them with those derived from the emission inventory. Based on these ratios and on the assumption that official inventory of CO emissions is reasonably accurate, mobile emissions of $NO_x$ seem to be slightly overestimated and VOCs emissions significantly underestimated. The results of simulations using modified emission of mobile source were in closer agreement with the observation results except NO. Predicted NO values based on revised $NO_x$ emissions were considerably lower than the observed values. Using modified emission inventories brings the modeled values into closer agreement with observed ozone levels in Seoul. Especially in case of CO, $NO_x$ and VOCs emission, the modified values were suitable for simulating ozone levels in Seoul and Gyeonggi. However, ozone values predicted using the modified emissions were higher than the observed and predicted values based on original emissions. According to the 95 percentile ozone concentrations, emission revised by CO, $NO_x$ and VOCs from mobile source was the best for predicting high concentration.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.1
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• pp.14-28
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• 2007

This study presented the selection of ozone ($O_3$) potential factors and designed and assessed its potential prediction model using multiple-linear regression equations in Ulsan area during the springtime from April to June, $2000{\sim}2004$. $O_3$ potential factors were selected by analyzing the relationship between meterological parameters and surface $O_3$ concentrations. In addition, cluster analysis (e.g., average linkage and K-means clustering techniques) was performed to identify three major synoptic patterns (e.g., $P1{\sim}P3$) for an $O_3$ potential prediction model. P1 is characterized by a presence of a low-pressure system over northeastern Korea, the Ulsan was influenced by the northwesterly synoptic flow leading to a retarded sea breeze development. P2 is characterized by a weakening high-pressure system over Korea, and P3 is clearly associated with a migratory anticyclone. The stepwise linear regression was performed to develop models for prediction of the highest 1-h $O_3$ occurring in the Ulsan. The results of the models were rather satisfactory, and the high $O_3$ simulation accuracy for $P1{\sim}P3$ synoptic patterns was found to be 79, 85, and 95%, respectively ($2000{\sim}2004$). The $O_3$ potential prediction model for $P1{\sim}P3$ using the predicted meteorological data in 2005 showed good high $O_3$ prediction performance with 78, 75, and 70%, respectively. Therefore the regression models can be a useful tool for forecasting of local $O_3$ concentration.

• Korean Journal of Materials Research
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• v.18 no.6
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• pp.307-312
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• 2008

In this study, a new cleaning process with a low cost of ownership (CoO) was developed with ozonated DI water ($DIO_3$). An ozone concentration of 40 ppm at room temperature was used to remove organic wax film and particles. Wax residues thicker than $200\;{\AA}$ remained after only a commercial dewaxer treatment. A $DIO_3$ treatment in place of a dewaxer showed a low removal rate on a thick wax layer of $8000\;{\AA}$ due to the diffusion-limited reaction of ozone. A dewaxer was combined with a $DIO_3$ rinse to reduce the wax removal time and remove wax residue completely. Replacing DI rinse with the $DIO_3$ rinse resulted in a surface with a contact angle of less than $5^{\circ}$, which indicates no further cleaning steps would be required. The particle removal efficiency (PRE) was further improved by combining a SC-1 cleaning step with the $DIO_3$ rinsing process. A reduction in the process time was obtained by introducing $DIO_3$ cleaning with a dewaxing process.

• 보존과학연구
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• s.23
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• pp.95-112
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• 2002

Seoul City built a facility for conservation of the Wongaksajisipcheungseoktap (Ten storied stone pagoda of Wongaksa Temple site, National treasure No. 2). It has speciality glass(thickness 21.5㎜) between steel-frames(8.4m, length 8.4m, height 15.4m). So we investigated the inside of facility to know whether the environment alvariation exists. We measured continuously the temperature and relative humidity, twice for the particulate, once for the $SO_2$(sulfur dioxide), $NO_2$(nitrogen dioxide)and $O_3$(ozone) from September $1_st$, 2000 to August $31_st$, 2001.The temperature and relative humidity, have a tendency to vary, and they have no difference between the inside and the outside. As dewy phenomenon doesn appear on the surface of the Pagoda and facility we know that the inside air is moving. As a result of the particulate is $64\mug$/$m_3$ of average concentration, the particulate fluxed inside don’t flow out because air-velocity of the outside is faster than that of the inside. The air pollutants are 0.036ppm/hr of SO$_2$average concentration, 0.028ppm/hr of $NO_2$ average concentration and 0.008ppm/hr of $O_3$ average concentration which are lower than the Environmental Air Quality Standards($SO_2$ : 0.15ppm/hr, $NO_2$ : 0.25ppm/hr,O3 : 0.1ppm/hr).

• Journal of Korean Society of Environmental Engineers
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• v.22 no.4
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• pp.775-784
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• 2000

Nitrate dry deposition fluxes were directly measured using knife-leading-edge surrogate surface (KSS) covered with greased strips and a water surface sampler (WSS). The average gaseous flux ($8.3mg/m^2/day$) was much higher than the average particulate one ($3.0mg/m^2/day$). The best fit gas phase mass transfer coefficient (MTC) of $HNO_3$ was obtained by linear regression analysis between measured gaseous flux containing nitrogen compounds and measured ambient $HNO_3$ concentration. The result showed that the MTCs of $HNO_3$ were approximately two times higher than those of $SO_2$. Especially, during the ozone action day, measured gaseous fluxes containing nitrogen compounds were much higher than those ones calculated as the product of measured ambient $HNO_3$ concentration and gas phase MTC of $HNO_3$, which is calculated from MTC of $SO_2$ using Graham's diffusion law. This result indicated that other nitrogen compounds except $HNO_3$ contributed to gaseous flux containing nitrogen compounds into the water surface sampler. The theoretical calculations suggest the contributions of nitrous acid ($HNO_2$) and PAN to the gaseous dry deposition flux of nitrogen containing compounds to the WSS.