• 제목/요약/키워드: surface impregnation

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Preparation and Structural Characterization of Silver-Deposited Activated Carbons (은도금 활성탄소의 제조 및 기공구조 분석)

  • Jung, Woo-Young;Park, Soo-Jin;Pak, Pyong-Ki
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.173-174
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    • 2003
  • Activated carbons (ACs) are widely used in adsorption for the removal of gaseous and aqueous pollutants[1,2]. The microbicidal property of ACs is also very important, in order to decrease the risk of water and air contamination with microorganisms. For this purpose, ACs have impregnated with silver or with metallic oxides[2]. However, in the case of Ag supported ACs prepared by impregnation, there are some problem, such as, heat-treatment, highly decrease in specific surface area and pore volume by deposited Ag, and rapidly elution of Ag at the initial stage of usage[3]. (omitted)

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Rotational Design of the Superconductor Flywheel Energy Storage System (플라이휠 에너지 저장시스템의 회전 설계)

  • Nam, Gueng-Hyun;Choi, Hyo-Sang;Sung, Tae-Hyun;Han, Young-Hee;Lee, Jeong-Pill;Han, Sang-Chul
    • Proceedings of the KIEE Conference
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    • 2006.07b
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    • pp.907-908
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    • 2006
  • The energy storage systems are being widely researched for the electric power. The operations running in a vacuum chamber mainly consists of a composite flywheel rotor, superconductor bearings, a motor/generator and its controller. Among composed the apparatus, the floating magnet bearing consists of the ring-type permanent magnets with epoxy resin impregnation for reinforcement and surface protection. In order to storage as much energy as possible, the flywheel is supposed to be rotated with very high speed. The magnetic field is analyzed by using the Maxwell 2D/3D for the simulations.

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Radiation-Induced Graft Copolymerization of Hydrophilic Monomers to Polyester

  • Lee, Chong-Kwang;Park, Jae-Ho
    • Nuclear Engineering and Technology
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    • v.4 no.2
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    • pp.90-101
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    • 1972
  • Radiation grafting of acrylic acid to Polyester fabric has been studied by an impregnation method to render its surface more hydrophilic. Impregnated fabric was irradiated under nitrogen with gamma-ray from Co-60. The homopolymer formed usually could be extracted with water at 10$0^{\circ}C$. Graft-fabric exhibited a good acceptability to acid, basic or disperse dyes in conventional aqueous dye bath at moderate temperature.

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Characterization by Solid-State $^51V$ NMRand X-ray Diffraction of Vanadium Oxide Supported on ZrO₂

  • 손종락;박만영;배영일
    • Bulletin of the Korean Chemical Society
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    • v.17 no.3
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    • pp.274-278
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    • 1996
  • Vanadium oxide-zirconia catalysts were prepared by dry impregnation of powdered Zr(OH)4 with aqueous solution of NH4VO3. The characterization of prepared catalysts was performed using 51V solid state NMR, XRD, and DSC. The addition of vanadium oxide up to 9 mol% to zirconia shifted the phase transitions of ZrO2 from amorphous to tetragonal toward higher temperatures due to the interaction between vanadium oxide and zirconia. On the basis of results of XRD and DSC, it is concluded that the content of V2O5 monolayer covering most of the available zirconia was 9 mol%. The crystalline V2O5 was observed only with the samples containing V2O5 content exceeding the formation of complete monolayer (9 mol%) on the surface of ZrO2.

Ceramic barrier coated Pd hydrogen membrane on a porous nickel support (수소 분리용 팔라듐계 분리막의 세라믹 코팅 영향)

  • Lee, Chun-Boo;Lee, Sung-Wook;Park, Jin-Woo;Kim, Kwang-Ho;Hwang, Kyung-Ran;Park, Jong-Soo;Kim, Sung-Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.114.1-114.1
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    • 2010
  • A highly performed Pd-based hydrogen membrane has prepared successfully on a modified porous nickel support. The porous nickel support modified by impregnation method of $Al(NO_3)_3{\cdot}9H_2O$ (Aldrich Co.) over the nickel powder showed a strong resistance to hydrogen embrittlement and thermal stability. Plasma surface modification treatment was introduced as a pre-treatment process instead of conventional HCl wet activation. Ceramic barrier was coated on the external surface of the prepared nickel supports to prevent intermetallic diffusion and to enhance the affinity between the support and membrane. Palladium and copper were deposited at thicknesses of $4\mu}m$ and $0.5{\mu}m$, respectively, on a barrier-coated support by DC sputtering process. The permeation measurement was performed in pure hydrogen at $400^{\circ}C$. The single gas permeation of our membrane was two times higher than that of the previous membrane which do not have ceramic barrier.

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Caffeine as a source for nitrogen doped graphene, and its functionalization with silver nanowires in-situ

  • Ramirez-Gonzalez, Daniel;Cruz-Rivera, Jose de J.;Tiznado, Hugo;Rodriguez, Angel G.;Guillen-Escamilla, Ivan;Zamudio-Ojeda, Adalberto
    • Advances in nano research
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    • v.9 no.1
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    • pp.25-32
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    • 2020
  • In this work, we report the use of caffeine as an alternative source of nitrogen to successfully dope graphene (quaternary 400.6 eV and pyridinic at 398 eV according XPS), as well as the growth of silver nanowires (in-situ) in the surface of nitrogen doped graphene (NG) sheets. We used the improved graphene oxide method (IGO), chemical reduction of graphene oxide (GOx), and impregnation with caffeine as source of nitrogen for doping and subsequently, silver nanowires (NW) grow in the surface by the reduction of silver salts in the presence of NG, achieving a numerous of growth of NW in the graphene sheets. As supporting experimental evidence, the samples were analyzed using conventional characterization techniques: SEM-EDX, XRD, FT-IR, micro RAMAN, TEM, and XPS.

A Study on Ultrasonic Evaluation of Material Defects in Carbon/carbon Composites

  • Im, Kwang-Hee;David K. Hsu;Cha, Cheon-Seok;Sim, Jae-Ki;Yang, In-Young
    • Journal of Mechanical Science and Technology
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    • v.16 no.12
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    • pp.1652-1663
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    • 2002
  • It is desirable to perform nondestructive evaluation to assess material properties and part homogeneity because manufacturing of carbon/carbon (C/C) composites requires complicated and costly processes. In this work several ultrasonic techniques were applied to carbon/carbon composites for the evaluation of spatial variations in material properties that are attributable to the manufacturing process. In a large carbon/carbon composite manufactured by chemical vapor infiltration (CVI) method, the spatial variation of ultrasonic velocity was measured and found to be consistent with the densification behavior in CVI process in order to increase the density of C/C composites. Ultrasonic velocity and attenuation depend on a density variation of materials. Low frequency through-transmission scans based on both amplitude and time-of-flight of the ultrasonic pulse were used for mapping out the material property inhomogeneity These results were compared with that obtained by dry-coupling ultrasonics. Pulse-echo C-scans was used to image near-surface material property anomalies such as the placement of spacers between disks during CVI. Also, optical micrograph had been examined on the surface of C/C composites using a destructive way.

Adsorption of CO2 on Amine-impregnated Mesorporous Silica (아민계 함침 메조포러스 실리카를 이용한 CO2 흡착)

  • Choi, Sung-Woo
    • Journal of Environmental Science International
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    • v.20 no.7
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    • pp.873-879
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    • 2011
  • Adsorption experiment of carbon dioxide was performed on MCM41 silica impregnated with two kinds of EDA(ethylenediamine) and MEA(monoethanolamine). The prepared adsorbents were characterized by BET surface area, X-ray diffraction and FT-IR. The $CO_2$ capture study was investigated in a U type packed column with GC/TCD. The results of XRD for MCM-41 and amine-impregnated MCM41 showed typical the hexagonal pore system. BET results showed the MCM 41 impregnated amine to have a surface area of 141 $m^2/g$ to 595 $m^2/g$ and FT-IR revealed a N-H functional group at about 1400$cm^{-1}$ to 1600$cm^{-1}$. The $CO_2$ adsorption capacity on EDA and MEA was as follow: MCM41-EDA30 > MCM41 -EDA40 >MCM41-EDA20 >MCM-EDA10 and MCM41-MEA40 >MCM41-MEA30 > MCM41-MEA20> MCM41-MEA10. The MCM41-EDA30 showed the highest adsorption capacity due to physical adsorption and chemical adsorption by amino-group content. The results suggest that mesoporous media with EDA is effective adsorbent for $CO_2$ capture from flue gases.

Effect of Chemical Treatment on Performance Behaviors of PtRu/GNFs Catalysts for DMFCs (직접 메탄올 연료전지용 PtRu/GNF 성능에 대한 화학적 처리의 영향)

  • Park, Soo-Jin;Park, Jeong-Min
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.369-372
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    • 2009
  • In the present study, the effect of chemical treatment on graphite nanofibers (GNFs) supports with various concentrated nitric acids was investigated for methanol oxidation. To optimize the electrocatalytic activity, PtRu catalysts were deposited on GNF supports by impregnation method. The surface and structural properties of the GNF supports were characterized by X-ray photoelectron spectroscopy (XPS), element analyzer (EA), and X-ray diffraction (XRD). The morphology of the catalysts was observed by means of transmission electron microscopy (TEM). The electrocatalytic activity of PtRu/GNF catalysts was investigated by cyclic voltammetry measurement. As a result, the oxygen functional groups were introduced on the GNF supports and were gradually increased with increasing of concentrated nitric acid, causing the smaller particle size and higher loading level. And the electrocatalytic activity of the catalysts for methanol oxidation was gradually improved. Consequently, it was found that chemical treatments could influence on surface properties of the carbon supports, resulting in enhancing the electrocatalytic activity of the catalysts for DMFCs.

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Three Freshwater Lembadion Ciliates (Peniculida, Lembadionidae) Newly Reported from Korea

  • Kim, Sung Hoon;Yoon, Jae Sool;Yoon, Seong Myeong;Shin, Mann Kyoon
    • Animal Systematics, Evolution and Diversity
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    • v.33 no.4
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    • pp.246-255
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    • 2017
  • Three freshwater ciliates, Lembadion lucens (Maskell, 1887) Kahl, 1931, L. bullinum ($M{\ddot{u}}ller$, 1786) Perty, 1849, and L. magnum (Stokes, 1887) Kahl, 1931, belonging to the genus Lembadion Perty, 1849 are newly reported from Korea with detailed descriptions and illustrations based on live observation and protargol impregnation. Lembadion lucens is characterized by following characteristics: $52-91{\times}33-64{\mu}m$ body size in vivo; ovoid and slightly asymmetric body shape; 27-49 somatic kineties; and 55-80% of whole pellicle covered with meridional lines with rectangular meshes in posterior portion. Lembadion bullinum is distinguishable from its congeners by its body size of $110-130{\times}60-73{\mu}m$ in vivo; ovoid body shape; oral aperture occupying about four-fifths of ventral side; 48-55 somatic ciliary rows; meridional lines with rectangular meshes except anterior portion (about 16% of body) on pellicle. Lembadion magnum is also characterized by its body size of $70-90{\times}37-50{\mu}m$ in vivo; obliquely asymmetric anterior end of body; oral aperture occupying about more than four-fifths of ventral surface, and opened longitudinally entire ventral surface; 45-61 somatic ciliary rows; meridional lines without rectangular meshes on whole pellicle of body. The present study is the first description of the genus Lembadion from Korea.