• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.70-70
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• 2013

As the costs of carbon-footprinetd fuels grow continuously and simultaneously atmospheric carbon dioxide concentration increases, solar fuels are receiving growing attention as alternative clean energy carriers. These fuels include molecular hydrogen and hydrogen peroxide produced from water, and hydrocarbons converted from carbon dioxide. For high efficiency solar fuel production, not only light absorbers (oxide semiconductors, Si, inorganic complexes, etc) should absorb most sunlight, but also charge separation and interfacial charge transfers need to occur efficiently. With this in mind, this talk will introduce the fundamentals of solar fuel production and artificial photosynthesis, and then discuss in detail on photoelectrochemical (PEC) water splitting and CO2 conversion. This talk largely divides into two section: PEC water oxidation and PEC CO2 reduction. The former is very important for proton-coupled electron transfer to CO2. For this oxidation, a variety of oxide semiconductors have been tested including TiO2, ZnO, WO3, BiVO4, and Fe2O3. Although they are essentially capable of oxidizing water into molecular oxygen, the efficiency is very low primarily because of high overpotentials and slow kinetics. This challenge has been overcome by coupling with oxygen evolving catalysts (OECs) and/or doping donor elements. In the latter, surface-modified p-Si electrodes are fabricated to absorb visible light and catalyze the CO2 reduction. For modification, metal nanoparticles are electrodeposited on the p-Si and their PEC performance is compared.

• 한국화재소방학회논문지
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• 제33권5호
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• pp.1-6
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• 2019

최근 다양한 생산기술의 발전을 통해 바이오연료의 생산이 크게 증가하였고, 석유와 같은 기존의 화석연료 등과 혼합연료를 만들어 소비를 장려하고 있다. 이와 같은 새로운 연료의 등장은 기존 에너지 시스템으로의 적용에 있어 화재 및 폭발의 위험성을 크게 증가시킬 수 있다. 따라서 본 연구에서는 대표적인 바이오연료의 소비형태인 휘발유/에탄올 혼합연료를 사용하는 연소장에서 화재 및 폭발의 위험성을 예측할 수 있는 기법을 제시하는 것을 목적으로 하고 있다. 이를 위해 휘발유/에탄올 혼합기의 자연점화온도를 대상으로 수치해석하였고, 반응표면법을 이용하여 다양한 변수조건에 대해서 예측에 대한 유효성과 효율성을 판단해 보았다. 당량비, 압력, 에탄올 분율 등에 대한 자연 발화온도 변화특성은 전체적으로 에탄올 함량과 압력에 큰 의존도를 보였으며, 에탄올 함량이 줄어들수록 압력에 대한 영향이 줄어들었다. 또한 계산을 통한 실험값과 반응표면법을 통해 얻은 기대값이 매우 잘 일치함을 알 수 있었다. 따라서 연료의 혼합 등 다양한 조건에서 운전하는 연소장에서 자연점화온도를 매우 적은 데이터로서 정확하게 예측할 수 있음을 확인하였다.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2012년도 춘계학술발표대회 논문집
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• pp.549-552
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• 2012

Recently the world is trying to reduce carbon emissions for global warming. Reducing use of fossil fuels can decrease carbon emission. In this reason the construction field has tried to reduce the use of fossil fuels relating to heating and cooling of buildings. An energy loss through the window system is about 10 to 30 percent of energy consumption of the whole building. The use of window film insulation is increasing to control the heat loss at the windows. The window film insulation absorbs solar radiation and makes the surface temperature of windows high. In this study, window surface temperature is measured, and an impact on indoor air is identified after attaching window film insulation. Finally, we found that cooling load decreases through simulation.

• 한국압력기기공학회 논문집
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• 제19권2호
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• pp.84-92
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• 2023

As temporary storage facilities for spent nuclear fuels in domestic nuclear power plants are expected to be saturated, external intermediate storage facilities would be required in the future. Spent nuclear fuels are stored in metal canisters and then placed in a dry environment within concrete or metal casing for operation. In the United States, the dry storage method for spent nuclear fuels has been operated for an extended period. Based on the corrosion experiences of dry storage canisters in chloride environments, numerous studies have been conducted to reduce corrosion in welds. With the construction of intermediate storage facilities in Korea for spent nuclear fuels expected near coastal areas adjacent to nuclear power plants, there is a need for research on the corrosion occurrence of welds and mitigation methods for canisters in chloride environments. In this paper, we measured and compared the residual stresses in the Heat-Affected Zones (HAZ) after electron beam welding (EBW) and gas tungsten arc welding (GTAW) processes for candidate materials such as 304L, 316L, and duplex stainless steel(DSS). We investigated the possibility of microstructure control through the application of surface modification processes using friction stir processing (FSP). Corrosion tests on each welded specimen revealed a higher corrosion rate in EBW welds compared to GTAW. Furthermore, it was confirmed that corrosion resistance improved due to phase refinement and redistribution of precipitates when FSP was applied.

• 한국자동차공학회논문집
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• 제12권2호
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• pp.62-68
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• 2004

To comply with stringent exhaust emission standards, it is necessary to reserch on some better quality of automotive fuels. Sulfur in fuels is sulfur compound by DOC and then it caused to the increase of PM on the surface of the catalyst. This research is focused on diesel emission characteristics and poisoning effect on Diesel Oxidation Catalyst when Ultra Low Sulfur Diesel(ULSD) and biodiesel are applied simultaneously. The biodiesel is used to improve viscosity of fuel specially in fuel injection system of engine since the introduction of ULSD may degrade viscosity in the process of desulfurization. Furthermore, this study may provide some basic data for the design of emissions reduction technology.

• 한국입자에어로졸학회지
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• 제9권3호
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• pp.173-185
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• 2013

Oxidations of metal generate large quantity of thermal and light energies but no toxic pollutants, so that metals with high calorific values, such as beryllium, boron, aluminum, magnesium, and lithium, are possible to be used as clean fuels instead of fossil fuels. However, they are so explosive due to very high oxidation rates that they should be stabilized by their surface passivation with oxides, organics and inorganics. For reasonable use of energetic metal particles as solid fuel, therefore, some detail information, such as thermal properties, preparation and passivation methods, and application area, of the energetic metals is introduced in this manuscript.

• 한국분무공학회지
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• 제13권2호
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• pp.65-72
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• 2008

It is recognized that alternative fuel such as dimethyl ether (DME) has better combustion polluting characteristics than diesel fuel, even though the cetane number of DME is almost the same as that of diesel. Characteristics of DME spray were observed experimentally under various ambient conditions using a constant volume chamber and a common-rail injection system. N-dodecane and LPG fuel sprays were also observed under same conditions of DME spray. Using spray images from backlight scattering and Mie scattering, characteristics of fuel sprays such as penetration and spray volume were visualized and quantitatively measured. The measurements showed that the penetration of early period decreased remarkably, because evaporation of alternative fuels became prosperous by the influence of flash boiling phenomenon under the condition of the low temperature and pressure compared with n-dodecane. The penetration of DME and LPG spray received the influence of temperature more largely in comparison with low density, because the specific surface area increased by atomizing in high density.

• 대한기계학회논문집B
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• 제32권4호
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• pp.266-274
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• 2008

The need for more fuel-efficient and lower-emission vehicles has driven the technical development of alternative fuels such as Liquefied Petroleum Gas(LPG) which is able to meet the limits of better emission levels without many modifications to current engine design. LPG has a high vapor pressure and lower viscosity and surface tension than diesel and gasoline fuels. These different fuel characteristics make it difficult to apply it for the conventional gasoline or diesel fuel pump directly. In this study, experiments are performed to get performance and efficiency of the fuel pump at different condition as temperature, rotating speeds, composition of fuel. The characteristics of fuel pump is affected by cavitation due to the variation of temperature and composition.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.478-483
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• 2003

This paper describes spray characteristics of a swirl injector which is intended for use in a HCCI engine. Many optical diagnostics such as laser diffraction methods, and high speed camera photography are applied to measure the spray drop diameter and to investigate the spray development process. The effect of fuel properties on the spray characteristics was investigated using three different fuels because HCCI combustion is tolerant of the chemical composition of various fuels. From these results, the HCCI injector formed a hollow cone sheet spray rather than a liquid jet and the atomization efficiency is high for the low-pressure injector. The SMD of test injector was ranged from $15{\mu}m$ ${\mu}m$ We also found that the spray breakup characteristics were dependent on the fuel properties such as density, viscosity, and surface tension.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2011년도 제36회 춘계학술대회논문집
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• pp.1-2
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• 2011

Hybrid rockets have lately attracted attention as a strong candidate of small, low cost, safe and reliable launch vehicles. A significant topic is that the first commercially sponsored space ship, SpaceShipOne vehicle chose a hybrid rocket. The main factors for the choice were safety of operation, system cost, quick turnaround, and thrust termination. In Japan, five universities including Hokkaido University and three private companies organized "Hybrid Rocket Research Group" from 1998 to 2002. Their main purpose was to downsize the cost and scale of rocket experiments. In 2002, UNISEC (University Space Engineering Consortium) and HASTIC (Hokkaido Aerospace Science and Technology Incubation Center) took over the educational and R&D rocket activities respectively and the research group dissolved. In 2008, JAXA/ISAS and eleven universities formed "Hybrid Rocket Research Working Group" as a subcommittee of the Steering Committee for Space Engineering in ISAS. Their goal is to demonstrate technical feasibility of lowcost and high frequency launches of nano/micro satellites into sun-synchronous orbits. Hybrid rockets use a combination of solid and liquid propellants. Usually the fuel is in a solid phase. A serious problem of hybrid rockets is the low regression rate of the solid fuel. In single port hybrids the low regression rate below 1 mm/s causes large L/D exceeding a hundred and small fuel loading ratio falling below 0.3. Multi-port hybrids are a typical solution to solve this problem. However, this solution is not the mainstream in Japan. Another approach is to use high regression rate fuels. For example, a fuel regression rate of 4 mm/s decreases L/D to around 10 and increases the loading ratio to around 0.75. Liquefying fuels such as paraffins are strong candidates for high regression fuels and subject of active research in Japan too. Nakagawa et al. in Tokai University employed EVA (Ethylene Vinyl Acetate) to modify viscosity of paraffin based fuels and investigated the effect of viscosity on regression rates. Wada et al. in Akita University employed LTP (Low melting ThermoPlastic) as another candidate of liquefying fuels and demonstrated high regression rates comparable to paraffin fuels. Hori et al. in JAXA/ISAS employed glycidylazide-poly(ethylene glycol) (GAP-PEG) copolymers as high regression rate fuels and modified the combustion characteristics by changing the PEG mixing ratio. Regression rate improvement by changing internal ballistics is another stream of research. The author proposed a new fuel configuration named "CAMUI" in 1998. CAMUI comes from an abbreviation of "cascaded multistage impinging-jet" meaning the distinctive flow field. A CAMUI type fuel grain consists of several cylindrical fuel blocks with two ports in axial direction. The port alignment shifts 90 degrees with each other to make jets out of ports impinge on the upstream end face of the downstream fuel block, resulting in intense heat transfer to the fuel. Yuasa et al. in Tokyo Metropolitan University employed swirling injection method and improved regression rates more than three times higher. However, regression rate distribution along the axis is not uniform due to the decay of the swirl strength. Aso et al. in Kyushu University employed multi-swirl injection to solve this problem. Combinations of swirling injection and paraffin based fuel have been tried and some results show very high regression rates exceeding ten times of conventional one. High fuel regression rates by new fuel, new internal ballistics, or combination of them require faster fuel-oxidizer mixing to maintain combustion efficiency. Nakagawa et al. succeeded to improve combustion efficiency of a paraffin-based fuel from 77% to 96% by a baffle plate. Another effective approach some researchers are trying is to use an aft-chamber to increase residence time. Better understanding of the new flow fields is necessary to reveal basic mechanisms of regression enhancement. Yuasa et al. visualized the combustion field in a swirling injection type motor. Nakagawa et al. observed boundary layer combustion of wax-based fuels. To understand detailed flow structures in swirling flow type hybrids, Sawada et al. (Tohoku Univ.), Teramoto et al. (Univ. of Tokyo), Shimada et al. (ISAS), and Tsuboi et al. (Kyushu Inst. Tech.) are trying to simulate the flow field numerically. Main challenges are turbulent reaction, stiffness due to low Mach number flow, fuel regression model, and other non-steady phenomena. Oshima et al. in Hokkaido University simulated CAMUI type flow fields and discussed correspondence relation between regression distribution of a burning surface and the vortex structure over the surface.