• Title/Summary/Keyword: surface film

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Analysis of Surface Properties of PVC Thin Film according to Addition of Non-solvent to PVC-THF Solution (PVC-THF 용액에 비용매 첨가에 따른 PVC 박막의 표면 특성 분석)

  • Lee, Seung Gyu;Moon, Je Cheol;Lee, Won Gyu
    • Applied Chemistry for Engineering
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    • v.33 no.4
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    • pp.367-372
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    • 2022
  • The effect of the addition of a polyvinylchloride (PVC) non-solvent to a PVC-tetrahydrofuran (THF) solution on the surface properties of the PVC thin film was analyzed. The non-solvents used were composed of alcohol-based and non-alcoholic ones. Surface morphologies of PVC thin films according to the addition of the non-solvent were compared. In addition, the hydrophobic properties relying on the surface characteristics were compared. The micro-bubbles generated in the preparation of PVC-THF solution affected the surface morphology of the thin film. In order to implement the normal surface physical properties of the coating thin film at the relatively high concentration of PVC-THF solution, the selection of appropriate drying method was required. When an alcohol-based non-solvent was added, a PVC thin film having a granular porous surface was obtained and exhibited super hydrophobic properties. The volume ratio of the PVC-THF solution to the non-solvent affects the surface shape of the coating thin film. The larger the amount of non-solvent was added, the more advantageous it was to form a super hydrophobic PVC thin film.

Enhancement of the surface plasmon-polariton excitation in nanometer metal films

  • Kukushkin, Vladimir A.;Baidus, Nikoly V.
    • Advances in nano research
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    • v.2 no.3
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    • pp.173-177
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    • 2014
  • This study is aimed to the numerical modeling of the surface plasmon-polariton excitation by a layer of active (electrically pumped) quantum dots embedded in a semiconductor, covered with a metal. It is shown that this excitation becomes much more efficient if the metal has a form of a thin (with thickness of several nanometers) film. The cause of this enhancement in comparison with a thick covering metal film is the partial surface plasmon-polariton localized at the metal-semiconductor interface penetration into air. In result the real part of the metal+air half-space effective dielectric function becomes closer (in absolute value) to the real part of the semiconductor dielectric function than in the case of a thick covering metal film. This leads to approaching the point of the surface plasmon-polariton resonance (where absolute values of these parts coincide) and, therefore, the enhancement of the surface plasmon-polariton excitation. The calculations were made for a particular example of InAs quantum dot layer embedded in GaAs matrix covered with an Au film. Its results indicate that for the 10 nm Au film the rate of this excitation becomes by 2.5 times, and for the 5 nm Au film - by 6-7 times larger than in the case of a thick (40 nm or more) Au film.

Corrosion Behavior of Hard Coated Ti-Zr-N Film on the Tool Steels

  • Eun, Sang-Won;Choe, Han-Cheol
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.289-293
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    • 2010
  • To investigate the corrosion behavior of tools steel surface in various coating film, the surface of hard coated Ti-Zr-N film on the tool steel by using magnetron-sputtering methods was researched using various experimental methods. STD 61 steels were manufactured by using vacuum furnace and solutionized for 1hr at $1050^{\circ}C$. Steel surface was coated with Ti-Zr-N film at $150^{\circ}C$ and 100W for 1h by using DC-sputtering equipment. Surface characteristics of Ti-Zr-N film coated specimens were investigated by OM, XRD, FE-SEM and nano-scratch tester. And corrosion behaviors of the coated specimen were investigated by polarization test and electrochemical impedance spectroscopy(EG&G Co, PARSTAT 2273. USA). It was found that Ti-Zr-N film coated sample had a thick coated layer and showed a good wear resistance and corrosion resistance of surface compared with ZrN and TiN coated sample. The corrosion resistance and mechanical property of Ti-Zr-N film coated STD 61 alloy increased as sputtering time increased.

Disinfection Effect of Film Cassettes by Ultraviolet Irradiation (자외선을 이용한 Film Cassette의 소독 효과)

  • Kweon, Dae-Cheol;Park, Peom
    • Journal of Radiation Protection and Research
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    • v.26 no.4
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    • pp.425-432
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    • 2001
  • A bacteria infection on film cassette contact surface was examined at the diagnostic radiology department. Studies have demonstrated a bactericidal effect of ultraviolet irradiation, and to assess the contamination level on film cassette contact surface as a predictor of patient prevent from nosocomial infection. The study showed that the laboratory result was identified non-pathologic and pathologic bacterial in the five different cassette size of the contact surface. Film cassettes were exposed to ultraviolet light for 1, 2 and 3 minutes. Ultraviolet light disinfection practices suitable for bacteria. The study concludes that presence of a bacterial infection will prevent a using antiseptic technique on film cassette contact surface. In conclusion, ultraviolet irradiate on film cassette over the surface more than 2 minutes. Ultraviolet dose of $1565 {\mu}W{\codt}s/cm^2$ Win in 30 second relative to ultraviolet dose in time.

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3D modeling of a surface acoustic wave for wireless sensors (무선 센서용 표면탄성파의 3 차원 모델링)

  • Cuong, Tran Ngoc;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.111-111
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    • 2009
  • In this work, we discuss simulation of surface acoustic wave device using Comsol Multiphysics. The structure SAW device based on piezoelectric thin film aluminum-nitride (AlN) on silicon was simulated. Some parameters of SAW device such as surface velocity, displacement of piezoelectric thin film were evaluated by software. Many modes and shapes of wave are also discussed in this paper. For evaluation physical parameters of AlN piezoelectric layer, the SAW resonator was modeled and simulation results were also compared with experiment results. we simulated arid evaluated the surface Rayleigh wave of AlN thin film on silicon substrate. Results simulation and experiment showed the surface velocity of AlN thin film was about 5200 m/s and shape of surface wave was also displayed. This paper has also proposed as method to study SAW characteristic of piezoelectric thin film and found out measurement values accurately of film such as stiffness matrix, piezoelectric matrix. These values are very important in calculation and design SAW device or MEMS device based on AlN piezoelectric layer.

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Effect of Micro Casting and Plasma-etching on Polycaprolactone Film for Bone (뼈 재생을위한 폴리카프로락톤 필름에 대한 마이크로 캐스팅 및 플라즈마 에칭)

  • Lee, Jae-Yun;Yang, Ji-Hun;Kim, Geun-Hyeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.24-24
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    • 2018
  • One of the challenges in tissue engineering is the design of optimal biomedical scaffolds, which can be governed by topographical surface characteristics, such as size, shape, and direction. Of these properties, we focus on the effects of nano - to micro - sized hierarchical surface. To fabricate the hierarchical surface structure on poly(${\varepsilon}$-caprolactone) (PCL) film, we employed a nano/micro-casting technique (NCT) and modified plasma process. The micro size topography of PCL film was controlled by sizes of the micro structures on lotus leaf. Also, the nano-size topography and hydrophilicity of PCL film were controlled by modified plasma process. After the plasma treatment, the hydrophobic property of the PCL film was significantly changed into hydrophilic property, and the nano-sized structure was well developed, as increasing the plasma exposure time and applied power. The surface properties of the modified PCL film were investigated in terms of initial cell morphology, attachment, and proliferation using osteoblast-like-cells (MG63). In particular, initial cell attachment, proliferation and osteogenic differentiation in the hierarchical structure were enhanced dramatically compared to those of the smooth surface.

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A Study on Applicability of Low-Density Surface Film Copper Mesh for Aircraft (저밀도 표면필름 구리망의 비행체 적용 가능성 연구)

  • Hyun, Se-Young;Kim, Yong-Tae;Kim, Sang-Yong;Kim, Bong-Gyu
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.49 no.10
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    • pp.841-847
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    • 2021
  • In this paper, the applicability of the low-density surface film copper mesh for aircraft applications have been analyzed. Recently, low-density surface film copper mesh is developed to reduce weight and cost compared with traditional surface film copper mesh. In order to apply low-density surface film copper mesh to aircraft, it is needed to analyze its electromagnetic effects as well as structural integrity with sandwich panels to prevent pinholes. The structural integrity and electromagnetic characteristics have been analyzed for 2 samples of low-density surface film copper mesh and 1 sample of surface film copper mesh. To review the applicability of the low-density surface film, it is combined with sandwich composite panel to confirm pinhole effects. The low-density surface film has been modeled as a periodic structure and analyzed with 3D electromagnetic simulation tool. The simulation results has been verified through measured electromagnetic transmission results using free space measurements. From the results, it will be possible to use these results for the analysis and the applicability of low-density surface film copper mesh for aircraft.

Thermal Stability of Surface Film Formed on a Graphite Negative Electrode in Lithium Secondary Batteries (리튬 이차전지의 흑연 음극에 형성된 표면피막의 열적 안정성)

  • Jeong, Soon-Ki;Lee, Ha-Na;Kim, Yang-Soo
    • Journal of the Korean Electrochemical Society
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    • v.14 no.3
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    • pp.157-162
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    • 2011
  • The stability at elevated temperatures of a surface film formed on a graphite electrode in lithium secondary batteries was investigated by transmission electron microscopy (TEM) and electrochemical AC impedance spectroscopy (EIS). TEM analysis revealed that the surface film partly dissolved in the electrolyte solution during storage at $60^{\circ}C$, resulting in a decrease in the thickness of the surface film and a change in its morphology to a porous structure. On the other hand, an increase in the impedance of the surface film which is attributable to a change in composition of the surface film was confirmed by EIS analysis during the storage at $60^{\circ}C$. It was also shown that the addition of vinylene carbonate or 1,3-propane sultone or etylene sulfite, even if limited, improves the stability of the surface film at elevated temperatures.

Physical properties of TiN thin films deposited by grid-assisted magnetron sputtering

  • Jung, Min J.;Nam, Kyung-H.;Han, Jeon-G.;Shaginyan, Leonid-R.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2002.05a
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    • pp.46-46
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    • 2002
  • It is well known that thin film growth and surface morphology can be substantially modified by ion-bombardment during the deposition. This is particularly important in case of thin-film deposition at low temperatures where the film growth occurs under highly nonequilibrium conditions. An attractive way to promote crystalline growth and surface morphology is deposition of additional energy in to the surface of the growing film by bombardment with hyperthermal particles. We were deposited crystalline Ti and TiN thin films on Si substrate by magnetron sputtering method with grid. Its thin films were highly smoothed and dense as increasing grid bias. In order explore the benefits of a bombardment of the growing film with high energetic particles. Ti and TiN films were deposited on Si substrates by an unbalanced magnetron sputter source with attached grid assembly for energetic ion extraction. Also, we have studied the variation of the plasma states by Langmuir probe and Optical Emission Spectroscopy (OES). The epitaxial orientation. microstructual characteristics. electrical and surface properties of the films were analyzed by XRD. SEM. Four point probe and AFM.

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Study on the Ag Thin Film Layer Deposition of the YBCO Coated Conductor Using a Plasma Surface Treatment (플라즈마 표면처리를 이용한 YBCO Coated Conductor의 Ag 박막층 증착에 관한 연구)

  • Jeong, Hyun-Gi;Yang, Sung-Chae;Choi, Byoung-Jung;Du, Ho-Ik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.1
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    • pp.32-36
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    • 2017
  • The Ag thin film of YBCO (yttrium barium copper oxide) CC (coated conductor) protect the YBCO layer and, at the same time, affects the electrical characteristics of the YBCO CC. Therefore, YBCO CC with the commercialization of the Ag thin film layers makes it easy to establish a process, it can lead to a variety of characteristic changes in YBCO CC. In this paper, plasma surface treatment was carried out to facilitate the deposition of the Ag thin film and the deposition process of YBCO CC. Surface roughness from the test results was increased as the time of the plasma surface treatment increased from 5 to 20 minutes. On the other hand, the surface roughness was decreased for the time of the plasma surface treatment over 20 minutes. Furthermore, after depositing, the increasing of deposit amount and reduced lifting phenomenon showed a similar tendency with the rise time of surface roughness.