• Korean Journal of Fisheries and Aquatic Sciences
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• v.34 no.3
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• pp.268-278
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• 2001

To investigate sedimentary facies and environmental changes of the Nakdong River Estuary and its adjacent coastal area, the grain size analysis and measurement of organic matter, calcium carbonate, clay mineral and metallic elements were carried out for forty surface sediment samples. Based on regional distribution pattern and characteristics of the surface sediments, sedimentary facies in the study area can be divided into sand facies (TYPE I), mud facies (TYPE II) and sand-mud mixed facies (TYPE III). TYPE III is the transition of TYPE I and TYPE II in every aspects of sediment characteristics. It suggests that TYPE III may have been formed by the mixture of two different source of sediment : one derived from Nakdong River and the other resuspended fine-grained sediments from the Jinhae Bay by winnowing action during floods or storms. Among many aspects of environmental change after the construction of the Nakdong Barrage, the most significant is the increase of sand content off the sand barrier region. It could be explained by several reasons including decreased input of fine-grained sediment from river, increased hydrodynamic energy level off the sand barrier region and artificial effects such as dredging and dumping.

• Bulletin of the Korean Chemical Society
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• v.32 no.1
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• pp.263-272
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• 2011

Highly luminescent and monodisperse InP quantum dots (QDs) were prepared by a non-organometallic approach in a non-coordinating solvent. Fatty acids with well-defined chain lengths as the ligand, a non coordinating solvent, and a thorough degassing process are all important factors for the formation of high quality InP QDs. By varying the molar concentration of indium to ligand, QDs of different size were prepared and their absorption and emission behaviors studied. By spin-coating a colloidal solution of InP QD onto a silicon wafer, InP QD thin films were obtained. The thickness of the thin films cured at 60 and $200^{\circ}C$ were nearly identical (approximately 860 nm), whereas at $300^{\circ}C$, the thickness of the thin film was found to be 760 nm. Different contrast regions (A, B, C) were observed in the TEM images, which were found to be unreacted precursors, InP QDs, and indium-rich phases, respectively, through EDX analysis. The optical properties of the thin films were measured at three different curing temperatures (60, 200, $300^{\circ}C$), which showed a blue shift with an increase in temperature. It was proposed that this blue shift may be due to a decrease in the core diameter of the InP QD by oxidation, as confirmed by the XPS studies. Oxidation also passivates the QD surface by reducing the amount of P dangling bonds, thereby increasing luminescence intensity. The dielectric properties of the thin films were also investigated by capacitance-voltage (C-V) measurements in a metal-insulator-semiconductor (MIS) device. At 60 and $300^{\circ}C$, negative flat band shifts (${\Delta}V_{fb}$) were observed, which were explained by the presence of P dangling bonds on the InP QD surface. At $300^{\circ}C$, clockwise hysteresis was observed due to trapping and detrapping of positive charges on the thin film, which was explained by proposing the existence of deep energy levels due to the indium-rich phases.

• Clean Technology
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• v.18 no.4
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• pp.446-450
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• 2012

Strong alkaline electrolyzed water which is produced in cathode by electrolyzing the solution where electrolytes (NaCl, $K_2CO_3$ etc.) are added in diaphragm electrolytic cell, is eco-friendly and has cleaning effects. So, it is viewed as a substitution of chemical cleaner. In addition, strong alkaline electrolyzed water is being used by some Japanese automobile and precision parts manufacturing industries. When strong alkaline electrolyzed water is produced by using diaphragm electrolytic cell, it is necessarily produced at the anode side. Since strong acidic electrolyzed water produced is discarded when its utilization cannot be found, production efficiency of electrolyzed water is consequently decreased. Also, there is a weakness electrolytic efficiency is decreasing due to the pollution of diaphragm. In order to overcome this, non-diaphragm all-in-one electrolytic cell integrated with electrode reaction chamber and dilution chamber was applied. Strong alkaline electrolyzed water was produced for different composition of electrolytes, and their properties and characteristics were identified. In comparing the properties between strong alkaline electrolyzed water produced in diaphragm electrolytic cell and that produced in all-in-one electrolytic cell, the differences in ORP and chlorine concentration were found. In emulsification test to confirm surface-active capability, similar results were obtained and strong alkaline electrolyzed water produced in non-diaphragm all-in-one electrolytic cell was identified to be useable as a cleaner like strong alkaline electrolyzed water produced in diaphragm electrolytic cell. Strong alkaline electrolyzed water produced in non-diaphragm all-in-one electrolytic cell is thought to have sterilizing power because it has active chlorine which is different from strong alkaline electrolyzed water produced in diaphragm electrolytic cell.

• Journal of Radiation Protection and Research
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• v.16 no.2
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• pp.27-39
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• 1991

The diffusion of Sr-85, Cs-137, Co-60 and Am-241 in compacted domestic bentonite was studied, using a diffusion cell unit in which diffusion took place axially from the center of cylindrical bentonite sample body. The effects of compaction density and heat-treated bentonite on diffusion were analysed. And the diffusion mechanism of radionuclide was also analysed by evaluating the measured diffusivity of anion Cl-36. The apparent diffusivities obtained for Sr-85, Cs-137, Co-60 and Am-241 were $l.07{\times}10^{-11},\;6.705{\times}10^{-13},\;l.226{\times}10^{-13}\;and\; l.310{\times}10^{-14}m^2/sec$, respectively. When the as-pressed density of bentonite increased from $1.8\;to\;2.0g/cm^3$, the apparent diffusivity of Cs-137 decreased by quarter. In the case of bentonite heat-treated to $150^{\circ}C$, no significant change in diffusivity was observed, which showed the possibility that the domestic bentonite could be used as a chemical barrier to retard the radionuclide migration at below $150^{\circ}C$. From the calculated pore and surface diffusivity, the surface diffusion due to the concentration gradient of radionuclide sorbed on the solid phase was found to dominate greatly in total transport process.

• The Journal of The Korea Institute of Intelligent Transport Systems
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• v.17 no.6
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• pp.185-201
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• 2018

Road lighting is highly preferred as the major nighttime road safety countermeasures. When it comes to the pole-type road lighting, as it's installed at a certain height from the road surface, the driver is dazzled by the light source, interrupting the driver's visibility and furthermore, the light leaks to the area outside the road boundary, worsening the energy efficiency as well as generating the light pollution to the surrounding environment including the animals and plants. The study developed the low-level lighting systems, so it is possible to prevent the lights from being strayed, so there is no any side effects in terms of the sleep deprivation. The study compared the performance as the lightings between low-level lightings and conventional pole based lighting systems. As the results, the low-level lighting systems showed the higher performance in terms of average surface luminance, uniformity, glare compared to the conventional lighting systems.

• Journal of the Korean earth science society
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• v.40 no.1
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• pp.37-45
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• 2019

In spite of continued nourishments, Haeundae Beach in Busan has been suffering from erosion, this being caused by the increased wave energy due to global warming and intermittent typhoon reported by previous works. In the meantime, the typhoon Chaba hit Basan in October 2016. In order to investigate the effects of the typhoon in beach erosion and how fast the beach recovered after the typhoon, repeated beach profiling using a VRS-GPS system was carried out, and the grain size analyses for surface sediments sampled on the beach were conducted. Immediately after the typhoon invasion, Haeundae beach was eroded by 1.4 m in average height. The mean high tide lines were retreated back by 12 m, and beach slope became gentler from $3.8^{\circ}$ to $1.7^{\circ}$. The mean grain sizes of surface sediments became coarser from $1.6{\Phi}$ to $1.2{\Phi}$ after two months, and the sorting well sorted. After two months of typhoon landfall, the mean high tide lines have recovered by 85%, and the beach topography almost recovered. This suggests that the impact of typhoons on Haeundae beach erosion is negligible, and the relaxation time is shorter than that of other beaches.

• Ecology and Resilient Infrastructure
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• v.6 no.2
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• pp.109-119
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• 2019

Eutrophication has occurred due to the inflow of various water pollutants in many Korean reservoirs with low depth, and algal blooms of surface layer and low oxygenation of deep layer have repeated every year. There are several existing technologies to alleviate the stratification of reservoirs, but it is difficult to apply them in field sites due to the necessity of electric power and low economic efficiency. In this study, a non-powered water circulation system using natural energy of wind and water flow has been developed, and two test-beds constructed in the reservoirs with different conditions and examined its field applicability. Through computational fluid dynamics (CFD) simulation, it has been shown that the water circulation system could induce the downward flow to mitigate the stratification between surface and deep layers, and its influence radius could reach about 30 m. As a result of long-term monitoring of the test-beds, various water quality improvement effects have been observed such as moderation of DO fluctuation by water circulation, reduction of DO supersaturation and prevention of excessive pH rising. In order to improve the applicability of the water circulation system, it is considered necessary to review countermeasures against flood and depth conditions of each reservoir.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.9
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• pp.532-540
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• 2019

PET microfibers with various diameters (0.5, 0.2, 0.06, and 0.01 dpf) were dyed with a dispersed dye (C.I. Disperse Blue 56) at various temperatures. The dyeing process was conducted under infinite dyebath conditions at constant temperatures. The effects of the dyeing temperature and diameter on the partition coefficient, affinity, and diffusion coefficient of disperse dyes were studied. The curve of isotherms was fitted well to Nernst-type model in a large range of initial dye concentrations. At the same temperature, the partition coefficient and affinity decreased with increasing sample diameter due to the increase in surface area. At all deniers, the partition coefficient and affinity decreased with increasing temperature because the dyeing process is an exothermic reaction. In addition, the decrease in radius of the sample gives rise to a decrease in the heat of dyeing. The fine diameter of the sample resulted in an increased surface area but decreased space between the microfibers. Consequently, decreasing the diameter of the microfibers leads to a decrease in the diffusion coefficient. At the same diameter, the diffusion coefficient increased with increasing temperature because of rapid dye movement and the large free volume of the sample inside. In addition, thermal dependence of the diffusion coefficient increased when the diameter of the sample increased.

• Applied Chemistry for Engineering
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• v.33 no.2
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• pp.202-209
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• 2022

Effects of the support and amount of NiCl₂ on ammonia adsorption capacity were investigated to improve the ammonia adsorption performance. NiCl₂ was impregnated onto the surface of various supports under ultrasonic irradiation. The physicochemical properties and ammonia adsorption performance of NiCl₂-impregnated adsorbents were investigated. Among the various supports, it was found that the adsorption capacity of ammonia was the best when NiCl₂ was impregnated on activated carbon (AC) with the highest specific surface area. As a result of changing the amount of NiCl₂ impregnated on AC, the NiCl₂(2.0)/AC adsorbent impregnated with 2 mmol·g^-1 of NiCl₂ showed the highest ammonia adsorption capacity of 5.977 mmol·g^-1. In addition, the adsorption capacity was found to be maintained at an almost constant level in five repeated cycle tests under the condition that low-temperature heat could be utilized. This indicates that the adsorbent has excellent regeneration ability.

• Resources Recycling
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• v.28 no.6
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• pp.96-105
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• 2019

Automobile shredder residue (ASR) is the final waste produced when end-of-life vehicles (ELVs) are shredded. ASR can be separated using mineral-processing operations such as comminution, air classification, magnetic separation, and/or electrostatic separation. In this work, trajectory analyses of conductors (copper) and non-conductors (glass) in the ASR have been carried out using induction electrostatic separator for predicting or improving the ASR-separation efficiency. From results of trajectory analysis for conductors, the trajectories of copper wire by observation versus simulation for coarse particles of 0.5 and 0.25 mm showed consistent congruity. The observed 0.06 mm fine-particles trajectory was deflected toward the (-) attractive electrode owing to the charge-density effects due to the particle characteristics and relative humidity. In the case of non-conductors, the actual trajectory of dielectric glass deflected toward the (-) electrode, showing characteristics similar to those of conductive particles. The analyses of stereoscopic microscope and SEM & EDS found heterologous materials (fine ferrous particles and conductive organics) on the glass surface. This demonstrates the glass decreasing separation efficiency for non-ferrous metals during electrostatic separation for the recycling of ASR. Future work will require a pretreatment process for eliminating impurities from the glass and advanced trajectory-simulation processes.