• Macromolecular Research
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• v.15 no.1
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• pp.51-58
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• 2007

The approach studied in the present work produced an exfoliated state of clay layers via confinement of the charged nano-sized polystyrene (PS) beads within the gallery of swollen pristine clay. It was demonstrated that adsorption of the polymer nanobeads dramatically promotes expansion of the clay gallery. A comparative study of incorporation was conducted by employing organo-modified clay along with two different colloid polymer systems: electrostatically stabilized PS nanobeads and cationic monomer-grafted PS nanobeads. The mechanism of adsorption of the monomer-grafted polymer beads onto clay via cationic exchange between the alkyl ammonium group of the polymer nanobeads and the interlayer sodium cation of the layered silicate was verified by using several techniques. As distinct from the polymer nanobeads formed using conventional miniemulsion polymerization method, competitive adsorption of stabilizing surfactant molecules was be prevented by grafting the surface functional groups into the polymer chain, thereby supporting the observed effective adsorption of the polymer beads. The presence of surface functional groups that support the establishment of strong polymer-clay interactions was suggested to improve the compatibility of the clay with the polymer matrix and eventually play a crucial role in the performance of the final nanocomposites.

• KCI Concrete Journal
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• v.13 no.1
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• pp.19-25
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• 2001

Based on the orthotropic hypoelasticity formulation, a constitutive material model of concrete taking account of triaxial stress state is presented. In this model, the ultimate strength surface of concrete in triaxial stress space is described by the Hsieh's four-parameter surface. On the other hand, the different ultimate strength surface of concrete in strain space is proposed in order to account for increasing ductility in high confinement pressure. Compressive ascending and descending behavior of concrete is considered. Concrete cracking behavior is considered as a smeared crack model, and after cracking, the tensile strain-softening behavior and the shear mechanism of cracked concrete are considered. The proposed constitutive model of concrete is compared with some results obtained from tests under the states of uniaxial, biaxial, and triaxial stresses. In triaxial compressive tests, the peak compressive stress from the predicted results agrees well with the experimental results, and ductility response under high confining pressure matches well the experimental result. The reinforcing bars embedded in concrete are considered as an isoparametric line element which could be easily incorporated into the isoparametric solid element of concrete, and the average stress - average strain relationship of the bar embedded in concrete is considered. From numerical examples for a reinforced concrete simple beam and a structural beam type member, the stress state of concrete in the vicinity of talc critical region is investigated.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2012.05a
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• pp.349-350
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• 2012

Porous silicon (PS) was prepared by electrochemical anodization. Ultra-thin zinc oxide (ZnO) capping layers were deposited on the PS by plasma-assisted molecular beam epitaxy (PA-MBE). The effects of the ZnO capping layers on the properties of the as-prepared PS were investigated using scanning electron microscopy (SEM) and photoluminescence (PL). The as-prepared PS has circular pores over the entire surface. Its structure is similar to a sponge where the quantum confinement effect (QCE) plays a fundamental role. It was found that the dominant red emission of the porous silicon was tuned to white light emission by simple deposition of the ultra-thin ZnO capping layers. Specifically, the intensity of white light emission was observed to be enhanced by increasing the growth time from 1 to 3 min.

• Journal of Korean Tunnelling and Underground Space Association
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• v.5 no.4
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• pp.323-336
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• 2003

Recently, the development of tunnel reinforcement method has been required relating to the shallow tunnelling in soft ground. In this study, the improvement method on tunnel stability is proposed by evaluating the efficiency of face reinforcement which enables to control extrusion of advance core, however, it is often neglected in urban tunnelling under the poor ground conditions. Systematic pre-confinement ahead of the face improves the tunnel stability, subsequently, displacement of the crown and surface settlement can be restrained by proper method. 3-dimensional numerical analysis including horizontal reinforcement modelling on a face is applied to estimate the behaviour of a tunnel in relation to the ground and reinforcement conditions. Consequently, extrusion at the face decreases significantly after using the horizontal reinforcement and the effect of reinforcement is much increased in case of applying the supplemental reinforcement ahead of the face together. Especially, confinement effect around the tunnel and the core is proved by means of the core reinforcement in poor ground conditions.

• Journal of the Korea Concrete Institute
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• v.16 no.4 s.82
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• pp.501-509
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• 2004

The proposed model can predict the compressive behaviors of concrete confined with fiber reinforced polymer (FRP) jacket. To model confining concrete by FRP jackets, the hypoelasticity-based constitutive law of concrete In tri-axial stress states has been presented. The increment of strength of concrete has been determined by the failure surface of concrete in tri-axial states, and its corresponding peak strain is computed by the strain enhancement factor that is proposed in the present study, Therefore, the newly proposed model is a load-dependent confinement model of concrete wrapped by FRP jackets to compare the previous models which are load-independent confinement models. The behavior of FRP jackets has been modeled using the mechanics of orthotropic laminated composite materials in two-dimension. The developed model is implemented into the incremental analysis of compressive tests. The verification study with several different experiments shows that the model is able to adequately capture the behavior of the compression test by including better estimations of the axial responses as well as the lateral response of FRP-confined concrete cylinders.

• Structural Engineering and Mechanics
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• v.64 no.6
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• pp.703-721
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• 2017

The experimental study of the behavior of dry medium and loose sandy soil under the action of a single impulsive load is carried out. Different falling masses from different heights were conducted using the falling weight deflectometer (FWD) to provide the single pulse energy. The responses of soils were evaluated at different locations (vertically below the impact plate and horizontally away from it). These responses include; displacements, velocities, and accelerations that are developed due to the impact acting at top and different depth ratios within the soil using the falling weight deflectometer (FWD) and accelerometers (ARH-500A Waterproof, and Low capacity Acceleration Transducer) that are embedded in the soil and then recorded using the multi-recorder TMR-200. The behavior of medium and loose sandy soil was evaluated with different parameters, these are; footing embedment, depth ratios (D/B), diameter of the impact plate (B), and the applied energy. It was found that increasing footing embedment depth results in: amplitude of the force-time history increases by about 10-30%. due to increase in the degree of confinement with the increasing in the embedment, the displacement response of the soil will decrease by about 25-35% for loose sand, 35-40% for medium sand due to increase in the overburden pressure when the embedment depth increased. For surface foundation, the foundation is free to oscillate in vertical, horizontal and rocking modes. But, when embedding a footing, the surrounding soil restricts oscillation due to confinement which leads to increasing the natural frequency, moreover, soil density increases with depth because of compaction, that is, tendency to behave as a solid medium.

• Geomechanics and Engineering
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• v.16 no.3
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• pp.295-308
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• 2018

The excavation of twin tunnels is a process that destabilizes the ground. The stability of the tunnel lining, the control of ground displacements around the tunnel resulting from each excavation and the interaction between them must be controlled. This paper provides a new approach for replacing the costly 3D analyses with the equivalent 2D analyses that closely reflects the in-situ measurements when excavating twin tunnels. The modeling was performed in two dimensions using the FLAC2D finite difference code. The three-dimensional effect of excavation is taken into account through the deconfinement rate ${\lambda}$ of the soil surrounding the excavation by applying the convergence-confinement method. A comparison between settlements derived by the proposed 2D analysis and the settlements measured in a real project in Algeria shows an acceptable agreement. Also, this paper reports the investigation into the changes in deformations on tunnel linings and surface settlements which may be expected if the twin tunnels of T4 El-Harouche Skikda were constructed with a tunneling machine. Special attention was paid to the influence of the excavation phase shift distance between the two mechanized tunnel faces. It is revealed that the ground movements and the lining deformations during tunnel excavation depend on the distance between the tunnels' axis and the excavation phase shift.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.23 no.11
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• pp.848-853
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• 2010

We have grown GaN nanowires by the low pressure MOCVD method on Ni deposited oxidized Si surface and have established optimum conditions by observing surface microstructure and its photoluminescence. Optimum growth temperature of $880^{\circ}C$, growth time of 30 min, TMG source flow rate of 10 sccm have resulted in dense nanowires on the surface, however further increase of growth time or TMG flow rate has not increased the length of nanowire but has formed nanocrystals. On the contrary, the increase of ammonia flow has increased the length of nanowires and the coverage of nanowire over the surface. The shape of nanowire is needle-like with a Ni droplet at its tip; the length is tens of micron with more than 40 nm in diameter. Low temperature photoluminescence obtained from the sample at optimum growth condition has revealed several peaks related to exciton decay near band-edge, but does not show any characteristic originated from one dimensional quantum confinement. Strong and broad luminescence at 2.2 eV is observed from dense nanowire samples and this suggests that the broad band is related to e-h recombination at the surface state in a nanowire. The current result is implemented to the nanowire device fabrication by nanowire bridging between micro-patterned neighboring Ni catalysis islands.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.75-75
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• 2015

Strong interactions between electromagnetic radiation and electrons at metallic interfaces or in metallic nanostructures lead to resonant oscillations called surface plasmon resonance with fascinating properties: light confinement in subwavelength dimensions and enhancement of optical near fields, just to name a few [1,2]. By utilizing the properties enabled by geometry dependent localization of surface plasmons, metal photonics or plasmonics offers a promise of enabling novel photonic components and systems for integrated photonics or sensing applications [3-5]. The versatility of the nanoplasmonic platform is described in this talk on three folds: our findings on an enhanced ultracompact photodetector based on nanoridge plasmonics for photonic integrated circuit applications [3], a colorimetric sensing of miRNA based on a nanoplasmonic core-satellite assembly for label-free and on-chip sensing applications [4], and a controlled fabrication of plasmonic nanostructures on a flexible substrate based on a transfer printing process for ultra-sensitive and noise free flexible bio-sensing applications [5]. For integrated photonics, nanoplasmonics offers interesting opportunities providing the material and dimensional compatibility with ultra-small silicon electronics and the integrative functionality using hybrid photonic and electronic nanostructures. For sensing applications, remarkable changes in scattering colors stemming from a plasmonic coupling effect of gold nanoplasmonic particles have been utilized to demonstrate a detection of microRNAs at the femtomolar level with selectivity. As top-down or bottom-up fabrication of such nanoscale structures is limited to more conventional substrates, we have approached the controlled fabrication of highly ordered nanostructures using a transfer printing of pre-functionalized nanodisks on flexible substrates for more enabling applications of nanoplasmonics.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.11
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• pp.992-998
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• 2009

We investigated the influence of organic solvents on the droplet properties of 6,13-bis (triisopropylsilylethynyl) pentacene (TIPS-pentacene), which was used for semiconductor of organic thin film transistors (OTFTs) and deposited by ink jet printing. From the result of the investigation, the conditions of a suitable solvent is that boiling point should be above $200^{\circ}C$ to reduce coffee stain and the surface tension above 32 dyn/cm to decrease the droplet size. Consequently, we selected tetralin which have a high boiling point ($207^{\circ}C$) and high surface tension (34.3 dyn/cm) as the solvent for TIPS-pentacene, and applied it to OTFTs. In fabrication process the conventional bank process employing photolithography and etching process was replaced by ink jet printed bank process, resulting in simplifying the process. Especially, polyvinylphenol was used for the bank, and the high hydrophobicity could improve the confinement of TIPS molecules inside the bank, enhancing the performance over the conventional hydrophilic polyvinylalcohol bank. The mobility was $0.18\;cm^2/Vs$, current on/off ratio $2.09{\times}10^5$, subthreshold slope 0.42 V/dec, and off state current $0.049\;pA/{\mu}m$.