• 제목/요약/키워드: surface confinement

검색결과 105건 처리시간 0.03초

Influence of Quantum well Thickness Fluctuation on Optical Properties of InGaN/GaN Multi Quantum well Structure Grown by PA-MBE

  • Woo, Hyeonseok;Kim, Jongmin;Cho, Sangeun;Jo, Yongcheol;Roh, Cheong Hyun;Kim, Hyungsang;Hahn, Cheol-Koo;Im, Hyunsik
    • Applied Science and Convergence Technology
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    • 제26권3호
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    • pp.52-54
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    • 2017
  • An InGaN/GaN multiple quantum well (MQW) structure is grown on a GaN/sapphire template using a plasma-assisted molecular beam epitaxy (PA-MBE). The fluctuation of the quantum well thickness formed from roughly-grown InGaN layer results in a disordered photoluminescence (PL) spectrum. The surface morphologies of the InGaN layers with various In compositions are investigated by reflection high energy electron diffraction (RHEED) and atomic force microscopy (AFM). A blurred InGaN/GaN hetero-interface and the non-uniform QW size is confirmed by high resolution transmission electron microscopy (HR-TEM). Inhomogeneity of the quantum confinement results in a degradation of the quantum efficiency even though the InGaN layer has a uniform In composition.

One-dimensional Bi-Te core/shell structure grown by a stress-induced method for the enhanced thermoelectric properties

  • Kang, Joo-Hoon;Ham, Jin-Hee;Lee, Woo-Young
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 춘계학술대회 논문집
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    • pp.47-47
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    • 2009
  • The formation of variable one-dimensional structures including core/shell structure is of particular significance with respect to potential applications for thermoelectric devices with the enhanced figure of merit ($ZT=S2{\sigma}T/{\kappa}$). We report the fabrication of Bi-Te core/shell nanowire based on a novel stress induced method. Fig. 1 schematically shows the nanowire fabrication process. Bi nanowires are grown on the Si substrate by the stress-induced method, and then Te is evaporated on the Bi nanowires. Fig. 2 is a transmission electron microscopy image clearly showing a core/shell structure for which effective phonon scattering and quantum confinement effect are expected. Electrical conductivity of the core/shell nanowire was measured at the temperatures from 4K to 300K, respectively. Our results demonstrate that Bi-Te core/shell nanowire can be grown successfully by the stress-induced method. Based on the result of electrical transport measurement and characteristic morphology of rough surface, Seebeck coefficient and thermal conductivity of Bi-Te core/shell nanowires are presented.

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Investigation of Photoluminescence and Annealing Effect of PS Layers

  • Han, Chang-Suk;Park, Kyoung-Woo;Kim, Sang-Wook
    • 한국재료학회지
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    • 제28권2호
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    • pp.124-128
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    • 2018
  • N-type porous silicon (PS) layers and thermally oxidized PS layers have been characterized by various measuring techniques such as photoluminescence (PL), Raman spectroscopy, IR, HRSEM and transmittance measurements. The top surface of PS layer shows a stronger photoluminescence peak than its bottom part, and this is ascribed to the difference in number of fine silicon particles of 2~3 nm in diameter. Observed characteristics of PL spectra are explained in terms of microstructures in the n-type PS layers. Common features for both p-type and n-type PS layers are as follows: the parts which can emit visible photoluminescence are not amorphous, but crystalline, and such parts are composed of nanocrystallites of several nm's whose orientations are slightly different from Si substrate, and such fine silicon particles absorb much hydrogen atoms near the surfaces. Light emission is strongly dependent on such fine silicon particles. Photoluminescence is due to charge carrier confinement in such three dimensional structure (sponge-like structure). Characteristics of visible light emission from n-type PS can be explained in terms of modification of band structure accompanied by bandgap widening and localized levels in bandstructure. It is also shown that hydrogen and oxygen atoms existing on residual silicon parts play an important role on emission stability.

고성능 콘크리트의 Mock-Up 시험에 의한 수축특성 분석 (Analysis on Shrinkage Properties of High Performance Concrete According to Mock-Up Test)

  • 고경택;김호림;류금성;황인성;김도겸;한천구
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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    • pp.545-548
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    • 2004
  • This paper is to investigate the shrinkage properties of high performance concrete (HPC) with mixture adjustment by using mock-up specimens. HPC with mixture adjustment needed a higher dosage of SP agent due to fluidity reduction and a larger dosage of AE agent due to the reduction of air content. Setting time of HPC with mixture adjustment exhibited earlier than that of control HPC by as much as 6 hours. HPC with mixture adjustment gained more than 70MPa of compressive strength. Autogenous shrinkage of Control HPC was found to be $-340\times40^{-6}$ at 49days when the expansion value by thermal effect was excluded and HPC with mixture adjustment $-175\times10^{-6}$, which was the half of the value of control HPC. Drying shrinkage of center section of HPC with mixture adjustment showed similar tendency with autogenous shrinkage because of no internal moisture movement, while surface section had larger drying shrinkage. The specimen embedded with reinforcing bar had smaller deformation caused by confinement of reinforcing bar.

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Vertically-Aligned Nanowire Arrays for Cellular Interfaces

  • 김성민;이세영;강동희;윤명한
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.90.2-90.2
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    • 2013
  • Vertically-aligned silicon nanostructure arrays (SNAs) have been drawing much attention due to their useful electrical properties, large surface area, and quantum confinement effect. SNAs are typically fabricated by chemical vapor deposition, reactive ion etching, or wet chemical etching. Recently, metal-assisted chemical etching process, which is relatively simple and cost-effective, in combination with nanosphere lithography was recently demonstrated for vertical SNA fabrication with controlled SNA diameters, lengths, and densities. However, this method exhibits limitations in terms of large-area preparation of unperiodic nanostructures and SNA geometry tuning independent of inter-structure separation. In this work, we introduced the layerby- layer deposition of polyelectrolytes for holding uniformly dispersed polystyrene beads as mask and demonstrated the fabrication of well-dispersed vertical SNAs with controlled geometric parameters on large substrates. Additionally, we present a new means of building in vitro neuronal networks using vertical nanowire arrays. Primary culture of rat hippocampal neurons were deposited on the bare and conducting polymer-coated SNAs and maintained for several weeks while their viability remains for several weeks. Combined with the recently-developed transfection method via nanowire internalization, the patterned vertical nanostructures will contribute to understanding how synaptic connectivity and site-specific perturbation will affect global neuronal network function in an extant in vitro neuronal circuit.

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Experimental study on circular CFST short columns with intermittently welded stiffeners

  • Thomas, Job;Sandeep, T.N.
    • Steel and Composite Structures
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    • 제29권5호
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    • pp.659-667
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    • 2018
  • This paper deals with the experimental study on strength the strength and deformation characteristics of short circular Concrete Filled Steel Tube (CFST) columns. Effect of vertical stiffeners on the behavior of the column is studied under axial compressive loading. Intermittently welded vertical stiffeners are used to strengthen the tubes. Stiffeners are attached to the inner surface of tube by welding through pre drilled holes on the tube. The variable of the study is the spacing of the weld between stiffeners and circular tube. A total of 5 specimens with different weld spacing (60 mm, 75 mm, 100 mm, 150 mm and 350 mm) were prepared and tested. Short CFST columns of height 350 mm, outer tube diameter of 165 mm and thickness of 4.5 mm were used in the study. Concrete of cube compressive strength $41N/mm^2$ and steel tubes with yield strength $310N/mm^2$ are adopted. The test results indicate that the strength and deformation of the circular CFST column is found to be significantly influenced by the weld spacing. The ultimate axial load carrying capacity was found to increase by 11% when the spacing of weld is reduced from 350 mm to 60 mm. The vertical stiffeners are found to effective in enhancing the initial stiffness and ductility of CFST columns. The prediction models were developed for strength and deformation of CFST columns. The prediction is found to be in good agreement with the corresponding test data.

Debonding strain for steel-concrete composite slabs with trapezoidal metal deck

  • Claudio Bernuzzi;Marco A. Pisani;Marco Simoncelli
    • Steel and Composite Structures
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    • 제49권1호
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    • pp.19-30
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    • 2023
  • Steel-concrete composite slabs represent a very efficient floor solution combining the key performance of two different materials: the steel and the concrete. Composite slab response is governed by the degree of the interaction between these two materials, mainly depending by chemical and mechanical bond. The latter is characterized by a limited degree of confinement if compared with the one of the rebars in reinforced concrete members while the former is remarkably influenced by the type of concrete and the roughness of the profiled surface, frequently lubricated during the cold-forming manufacturing processes. Indeed, owing to the impossibility to guarantee a full interaction between the two materials, a key parameter governing slab design is represented by the horizontal shear-bond strength, which should be always experimentally estimated. According to EC4, the design of the slab bending resistance, is based on the simplified assumption that the decking sheet is totally yielded, i.e., always in plastic range, despite experimental and numerical researches demonstrate that a large part of the steel deck resists in elastic range when longitudinal shear collapse is achieved. In the paper, the limit strain for composite slab, which corresponds to the slip, i.e., the debonding between the two materials, has been appraised by means of a refined numerical method used for the simulation of experimental results obtained on 8 different composite slab types. In total, 71 specimens have been considered, differing for the properties of the materials, cross-section of the trapezoidal profiled metal sheets and specimen lengths.

Energy separation and carrier-phonon scattering in CdZnTe/ZnTe quantum dots on Si substrate

  • 만민탄;이홍석
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.191.2-191.2
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    • 2015
  • Details of carrier dynamics in self-assembled quantum dots (QDs) with a particular attention to nonradiative processes are not only interesting for fundamental physics, but it is also relevant to performance of optoelectronic devices and the exploitation of nanocrystals in practical applications. In general, the possible processes in such systems can be considered as radiative relaxation, carrier transfer between dots of different dimensions, Auger nonradiactive scattering, thermal escape from the dot, and trapping in surface and/or defects states. Authors of recent studies have proposed a mechanism for the carrier dynamics of time-resolved photoluminescence CdTe (a type II-VI QDs) systems. This mechanism involves the activation of phonons mediated by electron-phonon interactions. Confinement of both electrons and holes is strongly dependent on the thermal escape process, which can include multi-longitudinal optical phonon absorption resulting from carriers trapped in QD surface defects. Furthermore, the discrete quantized energies in the QD density of states (1S, 2S, 1P, etc.) arise mainly from ${\delta}$-functions in the QDs, which are related to different orbitals. Multiple discrete transitions between well separated energy states may play a critical role in carrier dynamics at low temperature when the thermal escape processes is not available. The decay time in QD structures slightly increases with temperature due to the redistribution of the QDs into discrete levels. Among II-VI QDs, wide-gap CdZnTe QD structures characterized by large excitonic binding energies are of great interest because of their potential use in optoelectronic devices that operate in the green spectral range. Furthermore, CdZnTe layers have emerged as excellent candidates for possible fabrication of ferroelectric non-volatile flash memory. In this study, we investigated the optical properties of CdZnTe/ZnTe QDs on Si substrate grown using molecular beam epitaxy. Time-resolved and temperature-dependent PL measurements were carried out in order to investigate the temperature-dependent carrier dynamics and the activation energy of CdZnTe/ZnTe QDs on Si substrate.

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토목섬유로 보강된 다짐토 공시체의 구속효과 관한 연구 (A Study on the Confining Effect Due to Geosynthetics Wrapping Compacted Soil Specimen)

  • Kim, Eun Ra;Iizuka, Atsushi;Kim, You-Seong;Park, Hong
    • 한국지반공학회논문집
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    • 제20권5호
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    • pp.5-16
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    • 2004
  • 본 연구에서는 토목섬유로 보강된 다짐토의 보강 메카니즘이 제시되며, 이러한 보강 메카니즘은 다짐토의 체적팽창(부의 다일러탄시)을 토목섬유에 의해 구속 억제하는 과정에서 생성되는 효과로 간주된다. 먼저, 실내실험을 위한 구체적인 방법으로서, 토목섬유의 보강효과를 정량적으로 파악하기 위하여 사질토를 다짐하여 공시체를 만들어 그 주위에 토목섬유를 설치한 후 전체적으로 압축전단시험을 실시하였다. 실험에서 초기 다짐도는 각각의 종류에 대하여 다일러탄시의 특성이 다르기 때문에 각각의 공시체에 대하여 변화시켰다. 여기서 전단시험 도중에 다짐토의 다일러탄시 변형을 방지하기 위한 토목섬유에 작용하는 축방향 힘들(axial forces)이 조사되었다. 또한 다짐토의 탄소성 모델과 이러한 모델에 필요한 초기 입력치 값의 결정 방법들이 제시된다. 마지막으로, 탄소성 구성 모델에서 항복 이전의 탄성 영역의 거동을 모사하기 위하여 Hashiguch(1989)가 제안한 subloading surface의 개념을 도입하여, 유한요소(FEM) 해석을 통해 얻어진 결과들을 실내시험의 결과와 비교 분석하였다.

토목섬유로 보강된 다짐토 공시체의 구속효과에 관한 수치계산 (Numerical Analysis of Confining Effect Due to Geosynthetics Wrapping Compacted Soil Specimen)

  • Kim, Eun-Ra;Kang, Ho-Keun
    • 한국지반공학회논문집
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    • 제20권2호
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    • pp.37-46
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    • 2004
  • 본 연구에서는 토목섬유로 보강된 다짐토의 메카니즘이 제시되며, 이러한 메카니즘은 다짐토의 체적팽창(다일러턴시)을 토목섬유에 의해 구속 억제하는 과정에서 생성되는 효과로 간주된다. 먼저, 실내실험을 위한 구체적인 방법으로서, 토목섬유의 보강효과를 정량적으로 파악하기 위하여 사질토를 다짐하여 공시체를 만들어 그 주위에 토목섬유를 설치한 후 전체적으로 압축전단시험을 실시하였다. 실험에서 초기 다짐도는 각각의 종류에 대하여 다일러턴시의 특성이 다르기 때문에 각각의 공시체에 대하여 변화시켰다. 여기서 전단시험 도중에 다짐토의 다일러턴시 변형을 방지하기 위한 토목섬유에 작용하는 축방향 힘들(axial farces)이 조사되었다. 또한 다짐토의 탄소성 모델과 이러한 모델에 필요한 초기 입력치 값의 결정 방법들이 제시된다. 마지막으로, 탄소성 구성 모델에서 항복 이전의 탄성영역의 거동을 모사하기 위하여 Hashiguch(1989)가 제안한 subloading surface의 개념을 도입하여, 유한요소(FEM)해석을 통해 얻어진 결과들을 실내시험의 결과와 비교 분석하였다.