• Title/Summary/Keyword: surface confinement

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Influence of Quantum well Thickness Fluctuation on Optical Properties of InGaN/GaN Multi Quantum well Structure Grown by PA-MBE

  • Woo, Hyeonseok;Kim, Jongmin;Cho, Sangeun;Jo, Yongcheol;Roh, Cheong Hyun;Kim, Hyungsang;Hahn, Cheol-Koo;Im, Hyunsik
    • Applied Science and Convergence Technology
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    • v.26 no.3
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    • pp.52-54
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    • 2017
  • An InGaN/GaN multiple quantum well (MQW) structure is grown on a GaN/sapphire template using a plasma-assisted molecular beam epitaxy (PA-MBE). The fluctuation of the quantum well thickness formed from roughly-grown InGaN layer results in a disordered photoluminescence (PL) spectrum. The surface morphologies of the InGaN layers with various In compositions are investigated by reflection high energy electron diffraction (RHEED) and atomic force microscopy (AFM). A blurred InGaN/GaN hetero-interface and the non-uniform QW size is confirmed by high resolution transmission electron microscopy (HR-TEM). Inhomogeneity of the quantum confinement results in a degradation of the quantum efficiency even though the InGaN layer has a uniform In composition.

One-dimensional Bi-Te core/shell structure grown by a stress-induced method for the enhanced thermoelectric properties

  • Kang, Joo-Hoon;Ham, Jin-Hee;Lee, Woo-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.04b
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    • pp.47-47
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    • 2009
  • The formation of variable one-dimensional structures including core/shell structure is of particular significance with respect to potential applications for thermoelectric devices with the enhanced figure of merit ($ZT=S2{\sigma}T/{\kappa}$). We report the fabrication of Bi-Te core/shell nanowire based on a novel stress induced method. Fig. 1 schematically shows the nanowire fabrication process. Bi nanowires are grown on the Si substrate by the stress-induced method, and then Te is evaporated on the Bi nanowires. Fig. 2 is a transmission electron microscopy image clearly showing a core/shell structure for which effective phonon scattering and quantum confinement effect are expected. Electrical conductivity of the core/shell nanowire was measured at the temperatures from 4K to 300K, respectively. Our results demonstrate that Bi-Te core/shell nanowire can be grown successfully by the stress-induced method. Based on the result of electrical transport measurement and characteristic morphology of rough surface, Seebeck coefficient and thermal conductivity of Bi-Te core/shell nanowires are presented.

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Investigation of Photoluminescence and Annealing Effect of PS Layers

  • Han, Chang-Suk;Park, Kyoung-Woo;Kim, Sang-Wook
    • Korean Journal of Materials Research
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    • v.28 no.2
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    • pp.124-128
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    • 2018
  • N-type porous silicon (PS) layers and thermally oxidized PS layers have been characterized by various measuring techniques such as photoluminescence (PL), Raman spectroscopy, IR, HRSEM and transmittance measurements. The top surface of PS layer shows a stronger photoluminescence peak than its bottom part, and this is ascribed to the difference in number of fine silicon particles of 2~3 nm in diameter. Observed characteristics of PL spectra are explained in terms of microstructures in the n-type PS layers. Common features for both p-type and n-type PS layers are as follows: the parts which can emit visible photoluminescence are not amorphous, but crystalline, and such parts are composed of nanocrystallites of several nm's whose orientations are slightly different from Si substrate, and such fine silicon particles absorb much hydrogen atoms near the surfaces. Light emission is strongly dependent on such fine silicon particles. Photoluminescence is due to charge carrier confinement in such three dimensional structure (sponge-like structure). Characteristics of visible light emission from n-type PS can be explained in terms of modification of band structure accompanied by bandgap widening and localized levels in bandstructure. It is also shown that hydrogen and oxygen atoms existing on residual silicon parts play an important role on emission stability.

Analysis on Shrinkage Properties of High Performance Concrete According to Mock-Up Test (고성능 콘크리트의 Mock-Up 시험에 의한 수축특성 분석)

  • Koh Kyoung Taek;Jin Hu Lin;Ryu Gum Sung;Hwang Yin Seong;Kim Do Gyum;Han Cheon Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.545-548
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    • 2004
  • This paper is to investigate the shrinkage properties of high performance concrete (HPC) with mixture adjustment by using mock-up specimens. HPC with mixture adjustment needed a higher dosage of SP agent due to fluidity reduction and a larger dosage of AE agent due to the reduction of air content. Setting time of HPC with mixture adjustment exhibited earlier than that of control HPC by as much as 6 hours. HPC with mixture adjustment gained more than 70MPa of compressive strength. Autogenous shrinkage of Control HPC was found to be $-340\times40^{-6}$ at 49days when the expansion value by thermal effect was excluded and HPC with mixture adjustment $-175\times10^{-6}$, which was the half of the value of control HPC. Drying shrinkage of center section of HPC with mixture adjustment showed similar tendency with autogenous shrinkage because of no internal moisture movement, while surface section had larger drying shrinkage. The specimen embedded with reinforcing bar had smaller deformation caused by confinement of reinforcing bar.

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Vertically-Aligned Nanowire Arrays for Cellular Interfaces

  • Kim, Seong-Min;Lee, Se-Yeong;Gang, Dong-Hui;Yun, Myeong-Han
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.90.2-90.2
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    • 2013
  • Vertically-aligned silicon nanostructure arrays (SNAs) have been drawing much attention due to their useful electrical properties, large surface area, and quantum confinement effect. SNAs are typically fabricated by chemical vapor deposition, reactive ion etching, or wet chemical etching. Recently, metal-assisted chemical etching process, which is relatively simple and cost-effective, in combination with nanosphere lithography was recently demonstrated for vertical SNA fabrication with controlled SNA diameters, lengths, and densities. However, this method exhibits limitations in terms of large-area preparation of unperiodic nanostructures and SNA geometry tuning independent of inter-structure separation. In this work, we introduced the layerby- layer deposition of polyelectrolytes for holding uniformly dispersed polystyrene beads as mask and demonstrated the fabrication of well-dispersed vertical SNAs with controlled geometric parameters on large substrates. Additionally, we present a new means of building in vitro neuronal networks using vertical nanowire arrays. Primary culture of rat hippocampal neurons were deposited on the bare and conducting polymer-coated SNAs and maintained for several weeks while their viability remains for several weeks. Combined with the recently-developed transfection method via nanowire internalization, the patterned vertical nanostructures will contribute to understanding how synaptic connectivity and site-specific perturbation will affect global neuronal network function in an extant in vitro neuronal circuit.

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Experimental study on circular CFST short columns with intermittently welded stiffeners

  • Thomas, Job;Sandeep, T.N.
    • Steel and Composite Structures
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    • v.29 no.5
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    • pp.659-667
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    • 2018
  • This paper deals with the experimental study on strength the strength and deformation characteristics of short circular Concrete Filled Steel Tube (CFST) columns. Effect of vertical stiffeners on the behavior of the column is studied under axial compressive loading. Intermittently welded vertical stiffeners are used to strengthen the tubes. Stiffeners are attached to the inner surface of tube by welding through pre drilled holes on the tube. The variable of the study is the spacing of the weld between stiffeners and circular tube. A total of 5 specimens with different weld spacing (60 mm, 75 mm, 100 mm, 150 mm and 350 mm) were prepared and tested. Short CFST columns of height 350 mm, outer tube diameter of 165 mm and thickness of 4.5 mm were used in the study. Concrete of cube compressive strength $41N/mm^2$ and steel tubes with yield strength $310N/mm^2$ are adopted. The test results indicate that the strength and deformation of the circular CFST column is found to be significantly influenced by the weld spacing. The ultimate axial load carrying capacity was found to increase by 11% when the spacing of weld is reduced from 350 mm to 60 mm. The vertical stiffeners are found to effective in enhancing the initial stiffness and ductility of CFST columns. The prediction models were developed for strength and deformation of CFST columns. The prediction is found to be in good agreement with the corresponding test data.

Debonding strain for steel-concrete composite slabs with trapezoidal metal deck

  • Claudio Bernuzzi;Marco A. Pisani;Marco Simoncelli
    • Steel and Composite Structures
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    • v.49 no.1
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    • pp.19-30
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    • 2023
  • Steel-concrete composite slabs represent a very efficient floor solution combining the key performance of two different materials: the steel and the concrete. Composite slab response is governed by the degree of the interaction between these two materials, mainly depending by chemical and mechanical bond. The latter is characterized by a limited degree of confinement if compared with the one of the rebars in reinforced concrete members while the former is remarkably influenced by the type of concrete and the roughness of the profiled surface, frequently lubricated during the cold-forming manufacturing processes. Indeed, owing to the impossibility to guarantee a full interaction between the two materials, a key parameter governing slab design is represented by the horizontal shear-bond strength, which should be always experimentally estimated. According to EC4, the design of the slab bending resistance, is based on the simplified assumption that the decking sheet is totally yielded, i.e., always in plastic range, despite experimental and numerical researches demonstrate that a large part of the steel deck resists in elastic range when longitudinal shear collapse is achieved. In the paper, the limit strain for composite slab, which corresponds to the slip, i.e., the debonding between the two materials, has been appraised by means of a refined numerical method used for the simulation of experimental results obtained on 8 different composite slab types. In total, 71 specimens have been considered, differing for the properties of the materials, cross-section of the trapezoidal profiled metal sheets and specimen lengths.

Energy separation and carrier-phonon scattering in CdZnTe/ZnTe quantum dots on Si substrate

  • Man, Min-Tan;Lee, Hong-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.191.2-191.2
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    • 2015
  • Details of carrier dynamics in self-assembled quantum dots (QDs) with a particular attention to nonradiative processes are not only interesting for fundamental physics, but it is also relevant to performance of optoelectronic devices and the exploitation of nanocrystals in practical applications. In general, the possible processes in such systems can be considered as radiative relaxation, carrier transfer between dots of different dimensions, Auger nonradiactive scattering, thermal escape from the dot, and trapping in surface and/or defects states. Authors of recent studies have proposed a mechanism for the carrier dynamics of time-resolved photoluminescence CdTe (a type II-VI QDs) systems. This mechanism involves the activation of phonons mediated by electron-phonon interactions. Confinement of both electrons and holes is strongly dependent on the thermal escape process, which can include multi-longitudinal optical phonon absorption resulting from carriers trapped in QD surface defects. Furthermore, the discrete quantized energies in the QD density of states (1S, 2S, 1P, etc.) arise mainly from ${\delta}$-functions in the QDs, which are related to different orbitals. Multiple discrete transitions between well separated energy states may play a critical role in carrier dynamics at low temperature when the thermal escape processes is not available. The decay time in QD structures slightly increases with temperature due to the redistribution of the QDs into discrete levels. Among II-VI QDs, wide-gap CdZnTe QD structures characterized by large excitonic binding energies are of great interest because of their potential use in optoelectronic devices that operate in the green spectral range. Furthermore, CdZnTe layers have emerged as excellent candidates for possible fabrication of ferroelectric non-volatile flash memory. In this study, we investigated the optical properties of CdZnTe/ZnTe QDs on Si substrate grown using molecular beam epitaxy. Time-resolved and temperature-dependent PL measurements were carried out in order to investigate the temperature-dependent carrier dynamics and the activation energy of CdZnTe/ZnTe QDs on Si substrate.

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A Study on the Confining Effect Due to Geosynthetics Wrapping Compacted Soil Specimen (토목섬유로 보강된 다짐토 공시체의 구속효과 관한 연구)

  • Kim, Eun Ra;Iizuka, Atsushi;Kim, You-Seong;Park, Hong
    • Journal of the Korean Geotechnical Society
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    • v.20 no.5
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    • pp.5-16
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    • 2004
  • This paper presents the modeling of geosynthetic-reinforced compacted soils and discusses the reinforcement effect arising from confining the dilatancy deformation of the soil by geosynthetics. A series of compressive shear tests for compacted sandy soil specimens wrapped by geosynthetics are carried out by quantitatively examining the geosynthetic-reinforcement effect, occurring from a confinement of the dilative deformation in compacted soils during shearing. In the test, the initial degree of compaction is changed for each series of sandy soil specimens so that each series has different degree of dilatancy characteristics. Herein, the axial forces working on the geosynthetics so as to prevent dilative deformation of compacted soils during shearing are measured. Furthermore, the elasto-plastic modeling of compacted soils and a rational determination procedure for input parameters needed in the elasto-plastic modeling are presented. And to describe the irreversible deformation characteristics of compacted soils during shearing, the subloading yielding surface (Hashiguchi (1989)) to the elasto-plastic modeling is introduced. Finally, the elasto-plastic finite element simulation is carried out and the geosynthetic-reinforcement effect is discussed.

Numerical Analysis of Confining Effect Due to Geosynthetics Wrapping Compacted Soil Specimen (토목섬유로 보강된 다짐토 공시체의 구속효과에 관한 수치계산)

  • Kim, Eun-Ra;Kang, Ho-Keun
    • Journal of the Korean Geotechnical Society
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    • v.20 no.2
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    • pp.37-46
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    • 2004
  • This paper presents the modeling of geosynthetic-reinforced soils and discusses the reinforcement effect arising from confining the dilatancy deformation of the soil by geosynthetics. A series of compressive shear tests for compacted sandy soil specimens wrapped by geosynthetics are carried out by quantitatively examining the geosynthetic-reinforcement effect, and it occurred from the confinement of the dilative deformation of compacted soils during shearing. In the test, the initial degree of compaction is changed for each series of sandy soil specimens so that each series has different degree of dilatancy characteristics. Herein, the axial forces working to the geosynthetics so as to prevent dilative deformation of compacted soils during shearing are measured. Furthermore, the elasto-plastic modeling of compacted soils and a rational determination procedure of input parameters needed in the elasto-plastic modeling are presented. In this paper, the subloading yielding surface(Hashiguchi(1989)) is introduced to the elasto-plastic modeling which could describe the irreversible deformation characteristics of compacted soils during shearing. Finally, the elasto-plastic finite element simulation is carried out and the geosynthetic-reinforcement effect is discussed.