• 제목/요약/키워드: surface composition

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Fe-Co-Ni합금박막의 조성 및 자기적 성질 (Composition and Coercivity of Fe-Co-Ni Alloy Electrodeposits)

  • 예길촌;김용웅;문근호
    • 한국표면공학회지
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    • 제29권3호
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    • pp.195-202
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    • 1996
  • The composition, the microstructure and the magnetic properties(HC and Hk) of Fe-Co-Ni alloy electrodeposits were investigated according to the electrolysis conditions using sulfate bath paddle agitated. The current efficiency of the alloys electrodeposition was considerably low in the range of 16∼50%. The Fe content(wt.%) of the alloy increased from 20% to 57% with current density, while Ni content of them decreased in the range of 70∼24% respectively, and Co content was nearly constant. As a result, Fe/Ni ratio of the alloy increased from 0.3 to 2.0 showing the anomalous codeposition. The structure of the alloy changed from fcc to the mixed one of fcc+bcc with the increase of Fe/Ni ratio. The preferred orientation of the alloy with fcc and bcc structure were (220) and (110) respectively. The alloy with Fe/Ni ratio(0.3∼l.2) had the lowest coercivity of 0.4∼0.8 Oe.

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MICROSTRUCTURE AND ELECTROCHEMICAL CHARACTERISTICS OF ELECTRODEPOSITED Zn-Ni ALLOY COATINGS

  • Short, N.R.;Hui, Wen-Hua;Dennis, J.K.
    • 한국표면공학회지
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    • 제32권3호
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    • pp.281-288
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    • 1999
  • Electrodeposited Zn-Ni alloy coatings are of particular interest for improving the corrosion resistance of steel in a number of enviornments. Of particular interest is the relationship between composition, structure and corrosion rate. This paper firstly reviews the literature regarding composition-structure relationships of Zn-Ni electrodeposits and compares them with the equilibrium phase diagram. Secondly, research was carried out on a wide range of coatings which were produced in the laboratory and their structure and corrosion rates determined. It was found that unambiguous identification of phases from XRD data can be difficult. Maximum corrosion resistance of deposits is obtained at 12-13% Ni, with a $\gamma$ phase structure and predomination of (600) and (411) reflections. Compatibility is important with regard to chromate conversion coatings.

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실내디자인의 해체주의적 구성 경향에 관한 연구 (A Study on the Tendency of Deconstructivism in Interior Design)

  • 윤도근;김홍기
    • 한국실내디자인학회논문집
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    • 제1호
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    • pp.22-25
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    • 1992
  • The purpose of this study is to understand spatial composition techniques and character on the tendency of Deconstructivisim in interior design. Interior space is basically surrounded by architectural surface and influenced by architectural shape. Therefore, the main point of this study is based on the inter relationship of interior design and the trend of contemporary architectural design. This viewpoint is to comment upon current events in Korean situation some degree, but allow the new feeling to interior design and can be enlarge the concepts of spatial composition.

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동지나해의 두 해역에 있어서 미세플랑크톤의 분포(예보) (A PRELIMINARY REPORT ON THE DISTRIBUTION, OF MICROPLANKTON IN TWO DIFFERENT AREAS OF THE EAST CHINA SEA)

  • 최정신
    • 한국수산과학회지
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    • 제11권3호
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    • pp.123-127
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    • 1978
  • Distributions of microplankton in two different regions of the East China Sea were studied based on the plankton samples collected by R. V. Umitaka Maru of Fisheries University of Tokyo, Japan in September, 1975. The abundance distribution and species composition of the two areas were interpreted with their temperature-salinity properties. The two areas aye characterized by differences in the depth of thermocline, the nature of surface and bottom waters, and the abundance and species composition of microplankton.

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BIOLOGICAL RESPONSES OF OSTEOBLAST-LIKE CELLS TO DIFFERENT TITANIUM SURFACE BY ANODIZING MODIFICATION

  • Kim Myung-Joo;Kim Chang-Whe;Lim Young-Jun;Park Hyun-Joo
    • 대한치과보철학회지
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    • 제43권6호
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    • pp.751-763
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    • 2005
  • Statement of problem. To improve a direct implant fixation to the bone, various strategies have been developed focusing on the surface of materials. The surface quality of the implant depends on the chemical, physical, mechanical and topographical properties of the surface. The different properties will interact with each other and a change in thickness of the oxide layer may also result in a change in surface energy, the surface topography and surface, chemical composition. However, there is limited the comprehensive study with regard to changed surface and biologic behavior of osteoblast by anodization. Purpose of study. The aim of this study was to analyze the characteristics of an oxide layer formed and to evaluate the cellular biologic behaviors on titanium by anodic oxidation (anodization) by cellular proliferation, differentiation, ECM formation and gene expression. And the phospholipase activity was measured on the anodized surface as preliminary study to understand how surface properties of Ti implant are transduced into downstream cellular events. Methods and Materials. The surface of a commercially pure titanium(Grade 2) was modified by anodic oxidation. The group 1 samples had a machined surface and other three experimental specimens were anodized under a constant voltage of 270 V(Group 2), 350 V(Group 3), and 450 V(Group 4). The specimen characteristics were inspected using the following five categories; the surface morphology, the surface roughness, the thickness of oxide layer, the crystallinity, and the chemical composition of the oxide layer. Cell numbers were taken as a marker for cell proliferation. While the expression of alkaline phosphatase and Runx2 (Cbfa1) was used as early differentiation marker for osteoblast. The type I collagen production was determined, which constitutes the main structural protein of the extracellular matrix. Phospholipase $A_2$ and D activity were detected. Results. (1) The anodized titanium had a porous oxide layer, and there was increase in both the size and number of pores with increasing anodizing voltage. (2) With increasing voltage, the surface roughness and thickness of the oxide film increased significantly (p<0.01), the $TiO_2$phase changed from anatase to rutile. During the anodic oxidization, Ca and P ions were more incorporated into the oxide layer. (3) The in vitro cell responses of the specimen were also dependant on the oxidation conditions. With increasing voltage, the ALP activity, type I collagen production, and Cbfa 1 gene expression increased significantly (p<0.01), while the cell proliferation decreased. (4) In preliminary study on the relation of surface property and phospholipase, PLD activity was increased but $PLA_2$ activity did not changed according to applied voltage. Conclusion. The anodized titanium shows improved surface characteristics than the machined titanium. The surface properties acquired by anodization appear to give rise more mature osteoblast characteristics and might result in increased bone growth, and contribute to the achievement of a tight fixation. The precise mechanism of surface property signaling is not known, may be related to phospholipase D.

표면분석용 인증표준물질의 개발 I : 표면조성분석용 합금박막 표준물질 (Development of certified reference material (CRM)s for surface analysis I : alloy thin film for surface compositional analysis)

  • 김경중;박용섭;문대원
    • 한국진공학회지
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    • 제8권3B호
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    • pp.276-282
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    • 1999
  • For the quantitative surface analysis of multicomponent materials, algorithms for the compensation of the matrix effect and surface compositional change by ion beam sputtering must be established and reference materials having certified compositions are necessary. These certified reference material (CRM)s are needed for the improvement of instrument performance, inter-laboratory comparison and quantitative surface analysis. Surface analysis group of KRISS developed alloy thin film CRMs by and ion beam sputter deposition system and in-situ surface analysis system to control the composition of alloy thin films The real compositions of the CRMs were certified by inductively coupled plasma-atomic emission spectroscopy (ICP-AES).

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Chromate-free Hybrid Coating for Corrosion Protection of Electrogalvanized Steel Sheets

  • Jo, Du-Hwan;Kwon, Moonjae;Kim, Jong-Sang
    • Corrosion Science and Technology
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    • 제11권1호
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    • pp.15-19
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    • 2012
  • Both electrogalvanized and hot-dip galvanized steel sheets have been finally produced via organic-inorganic surface coating process on the zinc surface to enhance corrosion resistance and afford additional functional properties. Recently, POSCO has been developed a variety of chromate-free coated steels that are widely used in household, construction and automotive applications. New organic-inorganic hybrid coating solutions as chromate alternatives are comprised of surface modified silicate with silane coupling agent and inorganic corrosion inhibitors as an aqueous formulation. In this paper we have prepared new type of hybrid coatings and evaluated quality performances such as corrosion resistance, spot weldability, thermal tolerance, and paint adhesion property etc. The electrogalvanized steels with these coating solutions exhibit good anti-corrosion property compared to those of chromate coated steels. Detailed components composition of coating solutions and experimental results suggest that strong binding between organic-inorganic hybrid coating layer and zinc surface plays a key role in the advanced quality performances.

Design of an Algorithm to Simulate Surface Roughness in a Turning for an Integrated Virtual Machine Tool

  • Jang, Dong-Young
    • 한국시뮬레이션학회:학술대회논문집
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    • 한국시뮬레이션학회 1998년도 추계학술대회 및 정기총회
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    • pp.204-208
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    • 1998
  • The fundamental issues to evaluate machine tool's performance through simulation pertain to the physical models of the machine tool itself and of process while the practical problems are related to the development of the modular software structure. It allows the composition of arbitrary machine/process models along with the development of programs to evaluate each state of machining process. Surface roughness is one of the fundamental factors to evaluate machining process and performance of machine tool, but it is not easy to evaluate surface roughness due to its tribological complexity. This paper presents an algorithm to calculate surface roughness considering cutting geometry, cutting parameters, and contact dynamics of cutting between tool and workpiece as well as tool wear in turning process. The designed virtual machining system can be used to evaluate the surface integrity of a turned surface during the design and process planning phase for the design for manufacturability analysis of the concurrent engineering.

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통합절삭 시뮬레이션 시스템용 선삭표면조도 시뮬레이션 알고리즘의 설계 (Design of an Algorithm to Simulate Surface Roughness in a Turning for an Integrated Machining Simulation System)

  • 장동영
    • 한국시뮬레이션학회논문지
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    • 제8권1호
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    • pp.19-33
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    • 1999
  • The fundamental issues to evaluate machine tools performance through simulation pertain to the physical models of the machine tool itself and of process while the practical problems are related to the development of the modular software structure. It allows the composition of arbitrary machine/process models along with the development of programs to evaluate each state of machining process. Surface roughness is one of the fundamental factors to evaluate machining process and performance of machine tool, but it is not easy to evaluate surface roughness due to its tribological complexity. This paper presents an algorithm to calculate surface roughness considering cutting geometry, cutting parameters, and contact dynamics of cutting between tool and workpiece as well as tool wear in turning process. This proposed algorithm could be used in the designed virtual machining system. The system can be used to evaluate the surface integrity of a turned surface during the design and process planning phase for the design for manufacturability analysis of the concurrent engineering.

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Formation of Superhydrophobic Surfaces on Fluoropolymer Films Using Ion Implantation

  • Park, Yong-Woon;Jo, Yong-Jun;Jung, Chan-Hee;Hwang, In-Tae;Choi, Jae-Hak
    • 방사선산업학회지
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    • 제6권4호
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    • pp.323-328
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    • 2012
  • In this study, a facile method to fabricate superhydrophobic surfaces on perfluoroalkoxy (PFA) films using ion implantation was developed. PFA films were implanted at 100 keV with a fluence ranging from $4{\times}10^{16}$ to $7{\times}10^{16}ions\;cm^{-2}$. The surface properties of the implanted films were investigated in terms of their surface morphology, wettability, and chemical composition. As the fluence increased to $6{\times}10^{16}ions\;cm^{-2}$, the surface morphology and surface roughness of the PFA films were dramatically changed. The PFA surface implanted at a fluence of $6{\times}10^{16}ions\;cm^{-2}$ showed a maximum contact angle (CA) of $157.1^{\circ}$, while the control CA of the smooth PFA surface was $103.6^{\circ}$. Thus, the superhydrophobic surface was successfully fabricated by ion implantation.