• Title/Summary/Keyword: surface characteristic

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Fabrication of K-PHI Zeolite Coated Alumina Hollow Fiber Membrane and Study on Removal Characteristics of Metal Ions in Lignin Wastewater

  • Zhuang, XueLong;Shin, Min Chang;Jeong, Byeong Jun;Lee, Seung Hwan;Park, Jung Hoon
    • Korean Chemical Engineering Research
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    • v.59 no.2
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    • pp.174-179
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    • 2021
  • Recently, hybrid coal research is underway to upgrade low-grade coal. The hybrid coal is made by mixing low-grade coal with bioliquids such as molasses, sugar cane, and lignin. In the case of lignin used here, a large amount of lignin is included in the wastewater of the papermaking process, and thus, research on hybrid coal production using the same is attracting attention. However, since a large amount of metal ions are contained in the lignin wastewater from the papermaking process, substances that corrode the generator are generated during combustion, and the amount of fly ash is increased. To solve this problem, it is essential to remove metal ions in the lignin wastewater. In this study, metal ions were removed by ion exchange with a alumina hollow fiber membrane coated with K-Phillipsite (K-PHI) zeolite. The alumina hollow fiber membrane used as the support was prepared by the nonsolvent induced phase separation (NIPS) method, and K-PHI seeds were prepared by hydrothermal synthesis. The prepared K-PHI seed was seeded on the surface of the support and coated by secondary growth hydrothermal synthesis. The characteristic of prepared coating membrane was analyzed by Scanning Electron Microscope (SEM), X-Ray Diffraction (XRD), Energy Dispersive Spectroscopy (EDX), and the concentration of metal ions before and after ion exchange was measured by Inductively Coupled Plasma Optical Emission Spectrometer (ICP-OES). The extraction amount of K+ is 86 mg/kg, and the extraction amount of Na+ is 54.9 mg/kg. Therefore, K-PHI zeolite membrane has the potential to remove potassium and sodium ions from the solution and can be used in acidic lignin wastewater.

Ammonia Adsorption Characteristic of Reusable PAN/zeolite Fibers Made by Electrospinning (전기방사로 제작된 재이용 가능한 PAN/제올라이트 섬유의 암모니아 흡착 특성)

  • Ro, Yeon Hee;Chung, Woo Jin;Chang, Soon Woong
    • Korean Journal of Environmental Agriculture
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    • v.39 no.4
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    • pp.281-288
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    • 2020
  • BACKGROUND: Generally, ammonia occurs from agricultural waste disposal. Ammonia is known as a harmful substance to the human body and has a bad influence such as eutrophication on the ecosystem. It is possible to remove the ammonia by ammonia adsorption method using natural zeolite, without external influence. However, due to the natural zeolite shape, it is hard to reuse. METHODS AND RESULTS: Electrospinning method can produce fiber with constant diameter. Moreover, electrospinning method has no limitation for selecting the material to make the fiber, and thus, it is valuable to reform the surface of adsorbent. In this study, reusable membrane was made by electrospinning method. The highest removal efficiency was shown from the membrane with 20% of zeolite included, and it has been verified that it is possible to reuse the membrane through chemical treatment. The highest ammonia removal efficiency was about 92.4%. CONCLUSION: In this study, ammonia adsorption characteristics of zeolite fibers were studied. Electrospinning method can produce zeolite fiber with even distribution. Ammonia can be removed efficiently from ion exchange ability of the natural zeolite. The result of adsorption isotherm indicated that both Freundlich model and Langmuir model provided the best fit for equilibrium data. And study on desorption has demonstrated that the ion exchange from zeolite was reversible when 0.01 M NaCl and KCl solution were used.

Preparation and PTC Characteristics of Silicone Modified Maleated PE/HDPE/CNT (Silicone 변성 말레화 PE/HDPE/CNT Composite의 제조와 PTC 특성)

  • Kang, Doo Whan;Park, Seung Woo
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.109-113
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    • 2011
  • ${\alpha},{\omega}$-Hydroxypropylpoly(dimethylsiloxane) was prepared from the reaction of a ${\alpha},{\omega}$-hydrogen polydimethylsiloxane with an allyl alcohol. MPE-g-poly(dimethylsiloxane) copolymer (MPES) was prepared from the graft copolymerization of MPE with ${\alpha},{\omega}$-hydroxypropyl group terminated PDMS. MPES/HDPE/EtO-CNT need to varify was prepared from the compounding of MPES, HDPE, and surface treated MWCNT with 4-ethoxybenzoic acid at $180^{\circ}C$. Melting point of the MPES/HDPE/EtO-CNT composite was decreased from 130 to $129^{\circ}C$ as increasing the content of MWCNT 10 to 20 wt% in the composite PTC characteristic of the MPES/HDPE/EtO-CNT composite was appeared at $120^{\circ}C$ as abruptly increasing the electrical resistivity at this temperature. The heighest PTC intensity of MPES/HDPE/EtO-CNT compsite at 10 wt% loading of EtO-CNT was 1.9.

Analysis of Road-to-Stream Linkage Characteristics in a Mountain Catchment using the Discriminant Analysis (판별분석을 이용한 산악지역 도로-하천 연결 특성 분석)

  • Park, Sang-Hyoung;Park, Changyeol;Yoo, Chulsang
    • Journal of Korean Society on Water Environment
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    • v.27 no.2
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    • pp.147-158
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    • 2011
  • This study analyzed the linkage characteristics between road runoff and the nearest streams in mountain regions using a discriminant analysis. The road-to-stream linkage is an important characteristic to evaluate whether the contaminant on road surface is transported directly into the nearby channel system. This study evaluated a total of 51 drainage outlets of mountain roads near the Soyanggang Dam. The linkage between road and stream, slope and width of road, and other information necessary for the discriminant analysis have been collected by in situ investigation and by analyzing the Digital Elevation Model. Finally, as independent variables in the discriminant analysis, the contributing road representing the road characteristics (similar to the runoff from the road drainage outlet) and the distance and slope of the connecting channel between road and nearest stream were selected. Among these three, the distance was found to have the highest discriminant power, the contributing road the lowest. Using the discriminant function derived, 40 out of 51 cases (78.4%) were correctly discriminated and the remaining 11 cases (21.6%) were wrongly discriminated. Reasons of wrongly discriminated cases were mainly due to change in drainage outlet direction, excessive runoff, change in road-to-stream path, etc. This result also indicates that the road-to-stream linkage can be introduced or prohibited by exactly the same way.

Thematic and geometric analysis of Bangpo beach based on UAV Remote Sensing (무인항공기반 태안반도 방포해빈의 지형분석)

  • Bae, Sungji;Yu, Jaehyung;Jeong, Yong-Sik;Yang, Dongyoon;Han, Min
    • Journal of The Geomorphological Association of Korea
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    • v.23 no.1
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    • pp.117-128
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    • 2016
  • High resolution aerial photographs and digital elevation models for Bangpo beach using UAV were generated in this study to analyze the thematic and geometric characteristics of coastal features. Based on 728 aerial images acquired on September 10, 2016 by the UAV, a image mosaic at 2.2 cm spatial resolution and a digital elevation model at 4.4 cm spatial resolution were developed. This study found out that Bangpo beach consisted of intertidal zone and supratidal zone. The intertidal zone can be subdivided into lower part and upper part with distinctive geomorphological characteristics. While the lower part included sand bars and ripple marks along the coastline, the cusps and sand dunes were the major coastal features of the upper part. Part of the intertidal zone was occupied by shore platform with average slope of 0.9 degree containing various sizes of gravels. The supratidal zone slanted toward ocean with berms on the surface with an interval of 15 m. These coastal features indicated the flow intensity towards to the land and tidal effect. It validated that the UAV application in coastal research was very effective analyzing to examine coastal processes.

Evaluation of Resistance Spot Weld Interfacial Fractures in Tensile-Shear Tests of TRIP 590 Steels (저항 점 용접된 TRIP590강의 계면파단특성에 관한 평가)

  • Park, Sang-Soon;Lee, Sang-Min;Cho, Yongjoon;Kang, Nam-Hyun;Yu, Ji-Hun;Kim, Young-Seok;Park, Yeong-Do
    • Korean Journal of Metals and Materials
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    • v.46 no.10
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    • pp.672-682
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    • 2008
  • The resistance spot welding of TRIP590 steels was investigated to enhance understanding of weld fracture during tensile-shear strength (TSS) test. The main failure modes for spot welds of TRIP590 steels were nugget pullout and interfacial fracture. The peak load to cause a weld interfacial failure was found to be related to fracture toughness of the weld and the weld diameter. Although interfacial fracture occurred in the samples, the load carrying capacity of the weld was high and not significantly affected by the fracture mode. Substantial part of the weld exhibits the characteristic dimple (or elongated dimple) fractures on interfacial fractured surface, in spite of the high hardness values associated with the martensite microstructures. The high load-bearing ability of the weld is directly associated with the area of ductile fracture occurred in weld. Therefore, the judgment of the quality of resistance spot welds in TRIP590 steels, the load carrying capacity of the weld should be considered as an important factor than fracture mode.

Performance of selective combining according to channel selection decision method of frequency diversity in underwater frequency selective channel (수중 주파수 선택적 채널에서 주파수 다이버시티의 채널 선택 판정법에 따른 선택 합성법의 성능)

  • Lee, Chaehui;Jeong, Hyunsoo;Park, Kyu-Chil;Park, Jihyun
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.26 no.3
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    • pp.436-442
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    • 2022
  • In this paper, the performance of the selective combining according to the channel selection decision method of frequency diversity is evaluated in the underwater frequency selective channel. The underwater acoustic channel in the shallow sea has a complex multipath characteristic by combining various environmental factors such as boundary surface reflection and sound wave refraction according to the water temperature layer. In particular, frequency selectivity due to multipath causes energy fluctuation in a communication channel, which reduces SNR (Signal to Noise Ratio) and deteriorates communication performance. In this paper, we applied the frequency diversity technique using multiple channels to secure the communication performance according to the frequency selectivity by multipath. For each channel, 4-FSK (Frequency Shift Keying) and selective combining were applied, the performance was evaluated by applying the maximum value, average value, and majority decision of the signal in order to decide the demodulation channel selection of the selective combining.

Characteristics of organic design in Alexander McQueen's collections (알렉산더 맥퀸 컬렉션에 나타난 유기적 디자인 특성)

  • Kim, Dana;Lee, Younhee
    • The Research Journal of the Costume Culture
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    • v.30 no.2
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    • pp.262-280
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    • 2022
  • The purpose of this study is to analyze the organic forms, expressions, and characteristics of Alexander McQueen's fashion design and to present various materials for understanding and utilizing this organic design style. The criteria for organic design expressions and characteristics were classified through a literature review, and the organic design characteristics of Alexander McQueen's fashion were then analyzed. The results are as follows: First, the morphological characteristics of nature's forms are used as objects in Alexander McQueen's fashions to represent organic characteristics. Second, abstraction through the application of organic forms means creating an abstract representation of the object being represented. Abstracting organic forms occurs by partially modifying the structural features of the human body to show characteristics or by visualizing these characteristics within the surface of the natural object. Third, continuity through the expression of the formation process of organisms is characteristic of the expression of the gradual growth of organisms; this reinterpretation is based on the concept that the internal elements of natural objects affect their external forms. Fourth, the structure of using natural materials, as well as regional and cultural characteristics, is shown in the designs through use of the physical characteristics of expressions and materials that use natural elements. Fifth, symbolism through subjective thinking implies that the element of nature that an object expresses is the element that appears in nature; this includes created organisms along with environmental factors. These characteristics are best demonstrated in fashion designs that express themselves through creativity.

Classification and Characteristic Comparison of Groundwater Level Variation in Jeju Island Using Principal Component Analysis and Cluster Analysis (주성분분석 및 군집분석을 이용한 제주도 지하수위 변동 유형 분류 및 특성 비교)

  • Lim, Woo-Ri;Hamm, Se-Yeong;Lee, Chung-Mo
    • Journal of Soil and Groundwater Environment
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    • v.27 no.6
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    • pp.22-36
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    • 2022
  • Water resources in Jeju Island are dependent virtually entirely on groundwater. For groundwater resources, drought damage can cause environmental and economic losses because it progresses slowly and occurs for a long time in a large area. Therefore, this study quantitatively evaluated groundwater level fluctuations using principal component and cluster analyses for 42 monitoring wells in Jeju Island, and further identified the types of groundwater fluctuations caused by drought. As a result of principal component analysis for the monthly average groundwater level during 2005-2019 and the daily average groundwater level during the dry season, it was found that the first three principal components account for most of the variance 74.5-93.5% of the total data. In the cluster analysis using these three principal components, most of wells belong to Cluster 1, and seasonal characteristics have a significant impact on groundwater fluctuations. However, wells belonging to Cluster 2 with high factor loadings of components 2 and 3 affected by groundwater pumping, tide levels, and nearby surface water are mainly distributed on the west coast. Based on these results, it is expected that groundwater in the western area will be more vulnerable to saltwater intrusion and groundwater depletion caused by drought.

The development of the photoreflectance program for the analysis of semiconductor optical properties

  • Shin, Sang-Hoon;Kim, Geun-Hyeong
    • Journal of the Korea Society of Computer and Information
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    • v.27 no.8
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    • pp.211-218
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    • 2022
  • In this paper, a computer simulation program was developed to interpret the results measured by photoreflectance spectroscopy. The developed program is implemented so that the user can easily change the factors required for optical modulation characteristic interpretation, and the result of the value can be checked simultaneously with the actual measurement result. The results obtained by photoreflectance spectroscopy are obtained by mixing a third derivative function form (TDFF) modulated around a bandgap with a Franz-Keldysh oscillation (FKO) signal due to an electric field at a surface and an interface higher than the bandgap. Through the computer simulation program, the optical characteristics that appear in the GaSb Epi layer formed as a single layer were analyzed, and very useful results were obtained by specializing in optical modulation analysis. In addition, a Fast Fourier Transform (FFT) analysis tool was added to facilitate frequency characteristics analysis of FKO.