• Journal of Radiation Industry
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• v.6 no.4
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• pp.323-328
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• 2012

In this study, a facile method to fabricate superhydrophobic surfaces on perfluoroalkoxy (PFA) films using ion implantation was developed. PFA films were implanted at 100 keV with a fluence ranging from $4{\times}10^{16}$ to $7{\times}10^{16}ions\;cm^{-2}$. The surface properties of the implanted films were investigated in terms of their surface morphology, wettability, and chemical composition. As the fluence increased to $6{\times}10^{16}ions\;cm^{-2}$, the surface morphology and surface roughness of the PFA films were dramatically changed. The PFA surface implanted at a fluence of $6{\times}10^{16}ions\;cm^{-2}$ showed a maximum contact angle (CA) of $157.1^{\circ}$, while the control CA of the smooth PFA surface was $103.6^{\circ}$. Thus, the superhydrophobic surface was successfully fabricated by ion implantation.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.157.2-157.2
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• 2016

Water repellent surfaces may enhance the condensation by efficiently removing the condensed droplets. However, such surfaces may lose their original performance as they are exposed to external mechanical stresses. In this work, we fabricated spray-coated mechanically robust superhydrophobic surfaces using treated titanium dioxide (Type 1) or silica particles (Type 2). Then we compared the mechanical robustness of such surfaces with the silane-coated superhydrophobic surface and PEEK coated surface using a controlled-sand blasting method. The results show that the spray-coated samples can maintain the same level of the contact angle hysteresis than silane-coated superhydorphobic surface after sand blasting at 2 bar. The spray-coating method was applied to the tube type condenser and the condensation behaviors were observed within the environmental chamber with controlled pressure, humidity and non-condensable gas. Previously-reported droplet jumping was observed in the early stage of the condensation event, but soon the droplet jumping stopped and only dropwise condensation was observed since the condensed droplets were pinned on the cracks at spray-coated surfaces. The static contact angle decreases from $158.0^{\circ}$ to $133.2^{\circ}$, and hysteresis increases from $3.0^{\circ}$ to $23.5^{\circ}$ when active condensation occurs on such surfaces. This work suggests the benefits and limitation of spray-coated superhydrophobic condensers and help develop advanced condensers for practical use.

• Proceedings of the Materials Research Society of Korea Conference
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• 2010.05a
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• pp.24.1-24.1
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• 2010

In practical operation, the exposed surfaces may get dirty thus degrade the performance of devices. So the combination of self cleaning and antireflection is very desirable for use in outdoor photovoltaic and displaying devices, self cleaning windows and car windshields. For the purpose of self cleaning, the surface needs to be either superhydrophobic or superhydrophilic. However, in practice AR in the visible region and self cleaning are a pair of competitive properties. To satisfy the requirements for superhydrophobic or superhydrophilic surfaces, high surface roughness is required. But it usually cause severely light scattering. Photo-responsive coatings (TiO2, ZnO etc.) can lead to superhydrophilic. However, the refractive indices are high. Thus for porous structure, controlling pore size in the underwavelength scale to reduce the light scattering is very crucial for highly transparent and self cleaning antireflection coating. Herein, we demonstrate a simple method to make high performance broadband antireflection layer on the glass surface, by "carving" the surface by hot alkali solution. Etched glass has superhydrophilic surface. By chemical modification, it turns to superhydrophobic. Enhanced transparency (up to 97%) in a broad wavelength range was obtained by short time etching. Also antifogging effect has been demonstrated, which may offer advantage for devices working at high humidity environment or underwater. Compositional dependence of the properties was observed by comparing three different commercially available glasses.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.384.2-384.2
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• 2016

Recent publications reported the self-propelled jumping of coalescing dew droplets on superhydrophobic surfaces [1-2]. We further investigated the initial growth, coalescence, and removal by self-propelled ejection of nano and microscopic water droplets on the superhydrophobic surface of lotus leaves under condensing conditions. By using a high-speed digital camera mounted on an optical microscope, we have found: (1) sub-micrometer droplets form and grow on nanoscale waxy hairs; (2) growing droplets coalesce rapidly upon contact, but never jump off the surface unless the diameter of merged droplets exceeds ${\sim}15{\mu}m$; (3) the diameter and direction of jumping droplets are very narrowly distributed, centered at $20-30{\mu}m$ and ${\sim}20$ degrees from the surface normal, respectively. We present a rationale for these observations on the basis of: (a) the hierarchically rough surface structure on nano- and micro-scales; (b) its chemical composition; and (c) the balance among competing forces of cohesion (surface tension), adhesion and gravity.

• Bulletin of the Korean Chemical Society
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• v.31 no.7
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• pp.1833-1834
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• 2010

• Bulletin of the Korean Chemical Society
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• v.35 no.5
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• pp.1545-1548
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• 2014

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2013.05a
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• pp.157-158
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• 2013

• Bulletin of the Korean Chemical Society
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• v.34 no.10
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• pp.3141-3142
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• 2013

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2013.05a
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• pp.611-612
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• 2013

• Proceedings of the KSME Conference
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• 2008.11a
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• pp.1582-1584
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• 2008

This paper reports a simple fabrication method for creating the superhydrophobic polymer surface using a plasma etching. Generally, it is necessary for the superhydrophobic surfaces to have a rough structure on surface with the composition of the low surface energy. In this study, Poly(methyl methacrylate) (PMMA), poly(ethylene terephthalate) (PET), acrylonitrile butadiene styrene (ABS) with superhydrophobic surface were fabricated using $O_2$ plasma etching and vapor deposition with the fluoroalkylsilane self-assembled monolayers. The plasma treated polymer surfaces are covered with the nano-pillar shaped structures after treatment for $1{\sim}2min$. And these samples with FOTS SAMs coating are showed the superhydrophobicity having the water contact angle of around $150^{\circ}$ and sometimes around $180^{\circ}$ depending on the treatment time. Furthermore the nanostructured polymer is transparent for the visible light.