• Corrosion Science and Technology
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• v.7 no.4
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• pp.237-242
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• 2008

Physical properties of water, such as dielectric constant and ionic product, significantly vary with the density of water. In the supercritical conditions, since density of water widely varies with pressure, pressure has a strong influence on physical properties of water. Dielectric constant represents a character of water as a solvent, which determines solubility of an inorganic compound including metal oxides. Dissociation equilibrium of an acid is also strongly dependent on water density. Dissociation constant of acid rises with increased density of water, resulting in drop of pH. Density of water and the density-related physical properties of water, therefore, are the major governing factors of corrosion and environmentally assisted cracking of metals in supercritical aqueous solutions. This paper discusses importance of "physical properties of water" in understanding corrosion and cracking behavior of alloys in supercritical water environments, based on experimental data and estimated solubility of metal oxides. It has been pointed out that the water density can have significant effects on stress corrosion cracking (SCC) susceptibility of metals in supercritical water, when dissolution of metal plays the key role in the cracking phenomena.

• Nuclear Engineering and Technology
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• v.52 no.7
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• pp.1409-1416
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• 2020

The study of heat transfer coefficient of supercritical water plays an important role in improving the heat transfer efficiency of the reactor. Taking the supercritical natural circulation experimental bench as the research object, the effects of power, flow, pipe diameter and mainstream temperature on the heat transfer coefficient of supercritical water were studied. At the same time, the experimental data of Chen Yuzhou's supercritical water heat transfer coefficient was collected. Through the factorial design method, the influence of different factors and their interactions on the heat transfer coefficient of supercritical water is analyzed. Through the corresponding analysis method, the influencing factors of different levels of heat transfer coefficient are analyzed. It can be found: Except for the effects of flow rate, power, power-temperature and temperature, the influence of other factors on the natural circulation heat transfer coefficient of supercritical water is negligible. When the heat transfer coefficient is low, it is mainly affected by the pipe diameter. As the heat transfer coefficient is further increased, it is mainly affected by temperature and power. When the heat transfer coefficient is at a large level, the influence of the flow rate is the largest at this time.

• Nuclear Engineering and Technology
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• v.55 no.11
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• pp.4102-4111
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• 2023

In order to better perform thermal hydraulic calculation and analysis of supercritical water reactor, based on the experimental data of supercritical water, the model training and predictive analysis of the heat transfer coefficient of supercritical water were carried out by using the support vector machine (SVM) algorithm. The changes in the prediction accuracy of the supercritical water heat transfer coefficient are analyzed by the changes of the regularization penalty parameter C, the slack variable epsilon and the Gaussian kernel function parameter gamma. The predicted value of the SVM model obtained after parameter optimization and the actual experimental test data are analyzed for data verification. The research results show that: the normalization of the data has a great influence on the prediction results. The slack variable has a relatively small influence on the accuracy change range of the predicted heat transfer coefficient. The change of gamma has the greatest impact on the accuracy of the heat transfer coefficient. Compared with the calculation results of traditional empirical formula methods, the trained algorithm model using SVM has smaller average error and standard deviations. Using the SVM trained algorithm model, the heat transfer coefficient of supercritical water can be effectively predicted and analyzed.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.206-209
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• 2008

The modified supercritical water treatment method is adopted for hydrolysis of wood powder, Populus alba$\times$glandulosa. This modified method is containing 0.05% HCl or $HNO_3$ as acid catalyst. The supercritical water treatment(SCW) was performed for 1 min. with $350^{\circ}C$, $380^{\circ}C$, $400^{\circ}C$ and $425^{\circ}C$, respectively, under 230 $\pm$ 10 atm using continuous flow system. When acid was added to powder prepared for SCW treatment, the yields of monomeric sugars were significantly increased. The lignin remained after supercritical treatment was applied to gel permeation chromatography(GPC) for molecular weight distribution analysis. Compared to the lignin produced from SCW treatment without acid catalyst, the average molecular weight of lignin compounds treated with acid was clearly decreased. Particularly, Mn/Mw ratio is decreased. This result shows supercritical water treatment of wood powder can change the molecular weight of lignin to small size. However, it is necessary to be further studied for exactly characterizing the lignin produced from supercritical water treatment.

• Korean Chemical Engineering Research
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• v.45 no.1
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• pp.46-51
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• 2007

In this study, computer simulations have been performed for the removal of the transformer oil contaminated with polychlorinated biphenyls (PCBs) in supercritical water through complete combustion reaction. We regarded n-decane as a main material of transformer oil, and it is assumed to be 3.0 wt％ of transformer oil in supercritical water. We used Peng-Robinson equation of state to estimate the physical properties of components in supercritical water. Throughout the computer simulation done in this work, we could explain the solubilities of 3.0 wt% of transformer oil and excess oxygen in supercritical water.

• Journal of the Korea Institute of Military Science and Technology
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• v.10 no.1
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• pp.123-129
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• 2007

A 2-step process for the safe destruction of chemical wafare agents(agent hydrolysis followed by supercritical water oxidation) was studied to obtain kinetic data for the pilot plant design. This process is simple to operate by using commercial equipments and could be applied as an alternative technology to incineration. Sarin(GB) and sulfur mustard(HD) were hydrolysed in sodium hydroxide and water respectively and their hydrolysates and OPA, which is binary agent for GB were oxidized in a continuous flow supercritical water oxidation system. Destruction efficiencies of the materials were above 99.99% in supercritical water.

• Applied Chemistry for Engineering
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• v.10 no.1
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• pp.173-176
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• 1999

The production of fine metal oxide particles in supercritical water has been studied. Cobalt nitrate solution and manganese nitrate solution have been selected as model solutions for metal salt aqueous solution and the particles of cobalt oxide and manganese oxide have been produced. It was observed that the production of fine metal oxide particles in supercritical water was feasible and the dehydration rate was remarkably high in supercritical water. In spite of a short residence time (3~100 seconds), fine particles ($0.5{\sim}2{\mu}m$) have been produced. In the supercritical water process, the temperature of mixer had a significant effect on particle size and size distribution. It was observed that a change in reaction temperature resulted in the control of particle size.

• Nuclear Engineering and Technology
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• v.50 no.7
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• pp.1079-1087
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• 2018

There are many parameters that affect the natural circulation flow, such as height difference, heating power size, pipe diameter, system pressure and inlet temperature and so on. In general analysis the heating power is often regarded as a uniform distribution. The ANSYS-CFX numerical analysis software was used to analyze the flow heat transfer of supercritical water under different heating power distribution conditions. The distribution types of uniform, power increasing, power decreasing and sine function are investigated. Through the analysis, it can be concluded that different power distribution has a great influence on the flow of natural circulation if the total power of heating is constant. It was found that the peak flow of supercritical water natural circulation is maximal when the distribution of heating power is monotonically decreasing, minimal when it is monotonically increasing, and moderate at uniform or the sine type of heating. The simulation results further reveal the supercritical water under different heat transfer conditions on its flow characteristics. It can provide certain theory reference and system design for passive residual heat removal system about supercritical water.

• New & Renewable Energy
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• v.3 no.1 s.9
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• pp.38-45
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• 2007

To characterize thermo-chemical feature of sugar conversion of woody biomass, poplar wood ($Populus\;alba{\times}glandulosa$) powder was treated with supercritical water system. Supercritical water treatment (SCWT) was performed for 60 seconds at different temperatures (subcritical zone 350; supercritical zone $300,\;400,\;425^{\circ}C$) under two pressures $230{\pm}10atm$ as well as $330{\pm}10atm$, respectively, using flow type system. After separation of solid residues from SCWT products, the monomeric sugars in aqueous part converted from poplar wood powder were quantitatively determined by high performance anionic exchange chromatography [HPAEC] equipped with PAD detector and Carbo Pac PA10 column. As the temperature treated increased, the degradation of poplar wood powder was enhanced and ca 83% of woody biomass was dissolved into the water at $425^{\circ}C$. However, the pressure didn't help the degradation of biomass components. At subcritical temperature range, xylose was first formed by degradation of xylan, which is main hemicellulose component in hardwood species, while cellulose degradation started at the transition zone between sub and supercritical conditions and was remarkably accelerated at the supercritical temperature. In the supercritical water system the maximum yield of monomeric sugars amounts to ca. 7.3% based on oven dried wood weight at $425^{\circ}C$.

• Nuclear Engineering and Technology
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• v.49 no.1
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• pp.103-112
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• 2017

Application of the supercritical condition in reactor core cooling needs to be properly justified based on the extreme level of parameters involved. Therefore, a numerical study is presented to compare the thermalhydraulic performance of supercritical and single-phase natural circulation loops under low-to-intermediate power levels. Carbon dioxide and water are selected as respective working fluids, operating under an identical set of conditions. Accordingly, a three-dimensional computational model was developed, and solved with an appropriate turbulence model and equations of state. Large asymmetry in velocity and temperature profiles was observed in a single cross section due to local buoyancy effect, which is more prominent for supercritical fluids. Mass flow rate in a supercritical loop increases with power until a maximum is reached, which subsequently corresponds to a rapid deterioration in heat transfer coefficient. That can be identified as the limit of operation for such loops to avoid a high temperature, and therefore, the use of a supercritical loop is suggested only until the appearance of such maxima. Flow-induced heat transfer deterioration can be delayed by increasing system pressure or lowering sink temperature. Bulk temperature level throughout the loop with water as working fluid is higher than supercritical carbon dioxide. This is until the heat transfer deterioration, and hence the use of a single-phase loop is prescribed beyond that limit.