• Bulletin of the Korean Chemical Society
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• 제15권7호
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• pp.545-549
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• 1994

Using the extended Hackel molecular orbital method in connection with the tight binding model, we have studied electronic structure and related properties of the charged cluster models relating to superconducting $YBa_{2}Cu_{3}O_{7-x}$, crystals in which O-atoms in regular sites were selectively replaced with Se atoms. In analogy to the isomorphism problem with molecules, we discuss all possible combinations of Se-substitutions in O-sites with one, two, and four Se atoms. The calculations are carried out within charged cluster models for analogues of YBa-copper oxide. Our results suggest that the electronic structure of the symmetrically Se-substituted or Se-added compound is closer to that of the YBCO superconducting compound than that obtained from the unsymmetrical substitution. This applies in particular if O is replaced with Se around the Cu(1) site. Symmetrical substitutions in the $CuO_2$ layers give rise to large variations in the electronic structure of $YBa_{2}Cu_{3}O_{7}$. This is consistent with the fact that superconductivity is very sensitive to the electronic population of the $CuO_2$ layers.

• 한국초전도ㆍ저온공학회논문지
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• 제22권4호
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• pp.14-19
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• 2020

Here we present the comparative experimental study of the stability of the superconducting state in 4 mm YBCO tapes with copper lamination against local heat disturbances at 77 K. The samples are either directly cooled by immersing a bare YBCO tape into a liquid nitrogen pool or operate in nearly-adiabatic conditions when the tape is covered by a 0.6 mm layer of Kapton insulation. Main quench characteristics, i.e. minimum quench energies (MQEs) and normal zone propagation (NZP) velocities for both samples are measured and compared. Minimum NZP currents are determined by a low ohmic resistor technique eligible for obtaining V - I curves with a negative differential resistance. The region of transport currents satisfying the stationary stability criterion is found for the different cooling conditions. Finally, we use the critical temperature margin as a universal scaling parameter to compare the MQEs obtained in this work for YBCO tapes at 77 K with those taken from literature for low-temperature superconductors in vacuum at 4.2 K, as well as for MgB2 wires cooled with a cryocooler down to 20 K.

• 한국초전도ㆍ저온공학회논문지
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• 제22권4호
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• pp.20-23
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• 2020

Among many variables in processing the high performance MgB2 bulk superconductors, simple and important approach is to optimize the size dependence of the Mg & B raw powders. The present study is dedicated towards the variation in superconducting properties of MgB2 depending upon the various combination of Mg & B powders with the two different particle sizes respectively. From morphological investigation of the MgB2 samples, narrow and long pores are observed when the larger Mg powders are used, whereas it is rather like the oval shapes with the smaller Mg powders. Also, it can be seen that the connectivity of the MgB2 samples is much enhanced with the smaller size of the B powders. Jc-H properties of the MgB2 samples also indicate that the highest Jc can be obtained when using the smaller size of the B powder with the combination of the smaller Mg powders than that of the larger Mg powders. If the cases with the larger B powers, it is more favorable to select the larger Mg powders with the better Jc-H properties considering shorter diffusion length of Mg and more homogeneous mixture between the Mg & B powders.

• 한국초전도ㆍ저온공학회논문지
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• 제22권4호
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• pp.31-39
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• 2020

Power cables made of high temperature superconductors (HTS) are considered as most advanced applications of superconductivity for electro-energetics. Several cables made of the First Generation (1G) HTS wires have been produced and installed to electrical grids worldwide. Power cables made of the Second Generation HTS wires (2G or Coated Conductors) are in active development. Most basic principles of HTS power cables development have been published in many works since 90-ties. In this Review we would like to present our new developments mostly directed to 2G HTS compact power cables. We are presenting the methods to optimize a design of 2G AC compact power cable providing uniform current distribution among cable layers and the production technology approaches to implement such a design. AC losses measurements in such cables and other test methods are described. Some problems of the development 2G HTS power cables with small diameters are discussed. We presented as examples designs, developments and test results of two major coaxial cables designs: single-phase (cable core and a shield) and three-phase (triaxial: with three coaxial phases).

• 한국전기전자재료학회논문지
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• 제35권6호
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• pp.622-625
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• 2022

YBa₂Cu₃O_7-y bulk as a high temperature oxide superconducting conductor has the high critical temperature of 92 K. YBa₂Cu₃O_7-y bulk superconductors have been fabricated by a seeded melting growth. Magnetic properties were studied by using superconductor of melted YBa₂Cu₃O_7-y oxides. It was demonstrated that Y₂BaCuO₅ particles acts as a pinning center which plays an important role on the magnetic properties. The thickness of the upper and lower pellets of the YBa₂Cu₃O_7-y bulk was formed at 40 mm with 55 g of the composition, and the YBa₂Cu₃O_7-y superconductor was manufactured through a heat treatment process. Manufacturing the superconducting bulk, it is possible to improve the pore density of the superconducting bulk by providing a path through which oxygen could be emitted.

• 한국초전도ㆍ저온공학회논문지
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• 제12권4호
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• pp.8-12
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• 2010

The properties of the conductor.mechanical, thermal, and electrical-are the key information in the design and optimization of superconducting coils. Particularly, in devices using second generation (2G) high temperature superconductors (HTS), whose base materials (for example, the substrate or stabilizer) and dimensions are adjustable, a design process for conductor optimization is one of the most important factors to enhance the electrical and thermal performance of the superconducting system while reducing the cost of the conductor. Recently, we developed a numerical program that can be used for 2G HTS conductor optimization. Focusing on the five major properties, viz. the electrical resistivity, heat capacity, thermal conductivity, Z-value, and enthalpy, the program includes an electronic database of the major base materials and calculates the equivalent properties of the 2G HTS conductors using the dimensions of the base materials as the input values. In this study, the developed program is introduced and its validity is verified by comparing the experimental and simulated results obtained with several 2G HTS conductors.

• 한국재료학회지
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• 제7권2호
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• pp.157-161
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• 1997

$Bi_{2}Sr_{2}Ca_{0.8}Y_{0.2}Cu_{2}^{16}O_{8+\delta}$의 $^{16}O$이 $^{18}O$으로 치환되는 $^{16}O-^{18}O$ 교환반응의 결정학적 위치 의존성에 대하여 고찰하였다. $Bi_{2}Sr_{2}Ca_{0.8}Y_{0.2}Cu_{2}^{16}O_{8+\delta}$의 라만스펙트럼 측정결과 297, 464, $623cm^{-1}$에서 라만밴드가 관찰되었으며 이들은 모두 시료중의 $^{16}O$이 $^{18}O$으로 치환됨에 따라 저파수측으로 이동하였다. 이러한 동위체 치환에 따른 저파수측으로의 이동속도는 297, $464cm^{-1}$ 라만밴드의 경우 거의 같았지만 $623cm^{-1}$ 라만밴드의 경우 두 라만밴드보다 현저히 늦었다. 이는 $^{16}O-^{18}O$ 교환반응이 산소의 결정학적 위치에 의존한다는 사실을 시사한다. 이로부터 정방정계를 가정하고 623, 464, $297cm^{-1}$ 라만밴드를 각각 $O_{pl}(A_{g}),\;O_{ap}O_{Bi}$의 모드로 귀속하였다.

• 한국재료학회지
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• 제24권9호
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• pp.465-468
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• 2014

The crystallization effects of boron (B) powder on the phase, full width at half maximum (FWHM) values, and critical properties were investigated for in-situ reacted $MgB_2$ bulk superconductors. The semi-crystalline B powder was heat-treated at different temperatures of 1000, 1300 and $1500^{\circ}C$ for 5 hours in an Ar atmosphere. Then, using as-received and heat-treated B powders, the $MgB_2$ samples were prepared at $600^{\circ}C$ for 40 hours in an Ar atmosphere. As the heat-treatment temperature of the B powder increased, both the particle size of the B powder and crystalline phase increased. In the case of $MgB_2$ samples using B powders heat-treated at above $1300^{\circ}C$, unreacted magnesium (Mg) and B remained due to the improved crystallinity of the B powder. As the heat-treatment temperature of B powder increased, the critical current density of $MgB_2$ decreased continuously due to the reduction of grain boundary density and superconducting volume caused by unreacted Mg and B.

• 한국초전도ㆍ저온공학회논문지
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• 제19권4호
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• pp.1-11
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• 2017

This article reviews the recent activities of field testing and application of superconducting fault current limiters (SFCL) based on high-temperature superconductors (HTS). The review particularly focuses on the trends in the field tests in terms of the technical aspects and commercial activities of the SFCLs. Stimulated by the discovery of HTS, numerous research and development activities have been conducted worldwide for SFCLs operating from distribution voltages to transmission voltages. Different types of SFCLs have been developed and field-tested. Consequently, more than 20 field tests and applications have been performed on real grids worldwide while supplying electric power to the customers. These field tests have not only provided the track records of the operation experiences including the problems and maintenance during operation, but also proved their current limiting capabilities against real faults, rendering this new technology highly viable. Through these activities, the following trends in the status of field testing and application are observed. Resistive-type SFCLs with HTS-coated conductors were dominantly used in the most recent field tests. This implies that the resistive type is technically more mature than the other types. Bus-bar coupling and transformer feeders were the major application locations. It is of importance that most of the field applications were conducted as R&D projects. A relevant change from the R&D stage to the application stage is shown as recently deployed SFCLs are expected to be under long-term operation and commercial service. Here, we review the installation of these SFCLs by substation. This review also discusses the recent activities for their commercial applications.

• 한국초전도저온공학회:학술대회논문집
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• 한국초전도저온공학회 2002년도 학술대회 논문집
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• pp.346-350
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• 2002

The effect of Ca-doping on the superconducting properties of Nd-Ba-Cu-O bulk superconductors, fabricated by the oxygen-controlled melt growth process, has been systematically investigated. Various c-axis textured bulk samples were grown using precursors with the nominal compositions of N $d_{1.8-x}$C $a_{x}$B $a_{2.4}$C $u_{3.4}$ $O_{y}$ (x = 0.00, 0.02, 0.05, 0.10, 0.15) in a reduced oxygen atmosphere of 1% $O_2$ in Ar. Magnetization measurements revealed that the critical temperatures( $T_{c}$) were almost linearly depressed from 95K to 86K with increasing the Ca dopant from x = 0.0 to 0.15, respectively, and thus critical current densities( $J_{c}$) at 77K and for H//c-axis of specimens were gradually degraded with increasing x. Compositional analyses revealed that although the amounts of the Ca dopant both in NdB $a_2$C $u_3$ $O_{y}$(Nd123) and N $d_4$B $a_2$C $u_2$ $O_{10}$(Nd422) were increased with increasing x, only less than half of the initial Ca compositions were detected in melt-grown Ca-doped Nd-Ba-Cu-O bulk crystals. The supression of $T_{c}$ is attributed to an increased Nd substitution for the Ba site in the Nd123 superconducting matrix with increasing the amount of the Ca dopant.t.opant.t.t.t.t.t.