• Title/Summary/Keyword: super high refractive index

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Synthesis of Ultra High Refractive Index Monomer for Plastic Optical Lens and Its Ophthalmic Lens Preparation (플라스틱 안경렌즈용 초고굴절 모노머 합성 및 이를 이용한 안경렌즈 제조)

  • Jang, Dong Gyu;Kim, Jong Hyo;Lee, Soo Min;Roh, Soo Gyun
    • Journal of Korean Ophthalmic Optics Society
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    • v.13 no.3
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    • pp.1-6
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    • 2008
  • Purpose: Plastic optical monomer materials having ultra high refractive index have an income of the whole quantity from advanced nations to domestic companies which are related to plastic optical lens. It is necessary to develop novel plastic optical lens materials in order to overcome a FTA provision and revitalize a stagnating optical lens industry in the interior optical lens industries. The new plastic optical lens materials against the substitution effect of income should be gradually demanded. This work will be synthesized novel super high refractive monomer resin materials of urethane lens series and studied the properties of optical lens using it. Methods: ETS-4 (2-(2-mercaptoethylthio)-3-{2-[3-mercapto-2-(2-mercaptoethylthio)propyl thio]ethylthio}propane -1-thiol), which is optical lens monomer resin having super high refractive index, was synthesized and identified its structure and property by elemental analysis, EI-MS, TGA, FT-IR spectroscopy, $^1H$ and $^{13}C$ NMR spectroscopies. After mixing evenly from mixed monomer resin and diisocyanate series, it was casting in glass mold. After thermal curing, the obtained optical lenses were measured and compared with the refractive index and Abbe number for studies of their optical properties. Results: We have synthesized the novel ultra high refractive index monomer resin, ETS-4, and have identified its structure and property by elemental analysis, EI-MS, TGA, FT-IR spectroscopy, $^1H$ and $^{13}C$ NMR spectroscopies. The existence of three isomers for EST-4 was identified by $^{13}C$ NMR spectroscopy. The refractive index ($N_d$ at $25^{\circ}C$) of monomer resin in liquid state obtained from the Abbe refractometer was 1.647. The refractive indexes of raw plastic optical lenses prepared from the mixed ETS-4 monomer and diisocyanate series were in the range of 1.656~1.680. Conclusions: Novel super high refractive index plastic optical lens monomer was synthesized and analysed, the optical lenses prepared using it were colorless transparency and excellent properties. It is of utility for the industrialization.

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The process optimization for development of super deep black fiber (고심색용 폴리에스테르 섬유제품의 개발을 위한 공정최적화 연구)

  • Kim, Tae-Kyeong;Jeon, Jun-Hyung;Kim, Eun-Cheol
    • Textile Coloration and Finishing
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    • v.19 no.1 s.92
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    • pp.53-60
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    • 2007
  • In order to optimize the process for development of super deep black fiber, the silica-containing polyester fabric, SN2000, was investigated in terms of mass reduction process by sodium hydroxide, selection of high color strength dyes, and resin treatment. As the results, the mass reduction condition which used 15g/L of sodium hydroxide at $120^{\circ}C$ was determined and Dianix Deep Black Plus was selected for the best deep coloration at around 5% owf. Contrary to the prevailed understanding that the additional use of chromatic dyes would enhance the deep coloration, four kinds of chromatic dyes such as yellow, red, blue, and green dyes did not make great effect on the deep coloration. To increase the effect, the commercial resin that has low refractive index was used additionally and the resin made it possible to lower the lightness of the fabrics down to 8.7 which was generally accepted for super highly deep black fabric.

Solid-immersion lens based confocal microscopy using super-continuum generation effect (Super-continuum generation 현상을 이용한 Solid-immersion lens 기반 공초점 현미경)

  • Lee, Won-Sup;Moon, Hyungbae;Lim, Geon;Choi, Guk-Jong;Park, No-Cheol
    • Transactions of the Society of Information Storage Systems
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    • v.11 no.2
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    • pp.22-25
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    • 2015
  • In this paper, we demonstrate solid-immersion lens based confocal microscopy using super-continuum generation effect. Using super-continuum generation effect, we could diversify the excitation wavelength of confocal microscopy. Further, high refractive index of solid-immersion lens would increase the resolution of confocal microscopy. As a result, by applying the super-continuum generation effect and solid-immersion lens to confocal microscopy, some problems of confocal fluorescent microscopy, the excitation wavelength and the resolution, could be overcome. To verify it, we made home-built solid-immersion lens based confocal microscopy using super-continuum generation effect, and evaluate the performance of the system.