• Title/Summary/Keyword: sulphur

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A Study on the electron energy diffusion function of the sulphur hexaflouride (SF_6 가스의 전자에너지 분포함수에 관한 연구)

  • ;金相南
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.13 no.2
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    • pp.227-227
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    • 1999
  • The electron energy distributions function were analysed in sulphur hexaflouride at E/N : 500~800(Td) for a case of non-equilibrium region in the mean electron energy. This paper describes the electron transport characteristics in $SF_6$ gas calculated for range of E/N values from 150~800(Td) by the Monte Carlo simulation and Boltzmann equation method using a set of electron collision cross sections determined by the authors and the values of electron swarm parameters. The results gained that the value of ane1ctron swarm parameter such as the e1ectron drift velocity, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients agree with the experimental and theoretical for a range of E/N. The properties of electron avalanches in an electron energy non-equilibrium region.

Identify the Quality Characteristic of Low Sulphur Fuel Oil to Implement IMO Regulation on SOx (IMO 황산화물 규제 이행을 위한 저유황유 품질 특성)

  • Lee, Boram;Kim, Min
    • Prospectives of Industrial Chemistry
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    • v.22 no.5
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    • pp.41-50
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    • 2019
  • 2020년 1월 1일부터 이행되는 연료유의 황 함유량 규제에 따른 대응 현황을 보면, 약 60% 이상의 선사들이 저유황유 사용을 고려하고 있다. 이처럼 높은 저유황유 선택에 따라 저유황유의 안정적인 공급에 대한 사전 검토 및 대비책을 통한 구체적인 방안이 요구되고 있으며, 저유황유의 품질 보증이 무엇보다도 중요한 사안이라 판단된다. 저유황유의 품질에 따라 예상되는 문제점을 미리 파악하고 이에 대한 적절한 대응 방안을 수립하여 선박 기관 운영에 차질이 없도록 대비하여야 한다. 그래서 선박에 공급되는 저유황유의 품질 특성 시 고려사항을 전달하고자 한다.

Dyeing Properties of Ultra-fine Nylon Suede Non-woven Fabric with Sulphur Black Dye by Pad-steam Process (흑색 황화염료와 초극세사 나일론 스웨이드 부직포 직물의 Pad-steam 염색 및 염색성 평가)

  • Kim, Min Seok;Jung, Dae-Ho;Lee, Mikyung;Ko, Jae Wang;Lee, Jeong Hoon;Lee, Seung Geol
    • Textile Coloration and Finishing
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    • v.29 no.4
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    • pp.211-222
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    • 2017
  • In this study, we investigated the dyeing properties of the ultra-fine nylon suede non-woven fabric with Sulphur black dye regarding to the effect of dye concentrations, reducing agent contents, sodium carbonate contents, antioxidant contents, immersion temperature and exposure time in air by pad-steam process. The optimal conditions of dyeing for the ultra-fine nylon suede non-woven fabric were determined with dye concentration of 30% o.w.f., reducing agent content of $9{\sim}13g/{\ell}$, sodium carbonate content of $1{\sim}4g/{\ell}$, antioxidant content of $1{\sim}5g/{\ell}$, immersion temperature of $70^{\circ}C$, exposure time of 20 minutes in air and immersion time of 1 minute, respectively. Meanwhile, the colorfastness to washing, the colorfastness to light, and the colorfastness to perspiration for dyed ultra-fine nylon suede non-woven fabric were achieved in the range of 4-5 grades. The formaldehyde and arylamine were not detected on the ultra-fine nylon suede non-woven fabric by KC tests.

Impact of Sulphur and Nitrogen Application on Seed and Xanthotoxin Yield in Ammi majus L.

  • Ahmad, Saif;Jamal, Arshad;Fazili, Inayat Saleem;Alam, Tanweer;Khan, Mather Ali;Kamaluddin, Kamaluddin;Iqbal, Mohd;Abdin, Malik Zainul
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.52 no.2
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    • pp.153-161
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    • 2007
  • Field experiments were conducted to determine the physiological and biochemical basis of the interactive effect of sulphur (S) and nitrogen (N) application on seed and xanthotoxin yield of Ammi majus L. Six treatments were tested ($T_1$ = control-without manure and fertilizers, $T_2$ = manure @ 9 kg $plot^{-1}-10\;t\;ha^{-1},\;T_3=A_0N_{50}K_{25}P_{25},\;T_4=S_{40}N_{50}K_{25}P_{25},\;T_5=S_{40}N_{100}K_{25}P_{25}\;T_6=S_{20+20}N_{50+50}K_{25}P_{25})$). Nitrate reductase (NR) activity and ATP-sulphurylase activity in the leaves were measured at various phonological stages, as the two enzymes catalyze rate-limiting steps of the assimilatory pathways of nitrate and sulphate, respectively. The activities of these two enzymes were strongly correlated with seed and xanthotoxin yield. The highest nitrate reductase activity, ATP-sulphurylase activity and xanthotoxin yield were achieved with the treatment $T_4$. Any variation from this treatment decreased the activity of these enzymes, resulting in a reduction of the seed and xanthotoxin yield in Ammi majus L. The higher seed and xanthotoxin yield achieved in Ammi majus L. at treatment $T_4$ could be due to optimization of leaf soluble protein and photosynthetic rate, as these parameters are Influenced by S and N assimilation.

Simulating reactive distillation of HIx (HI-H2O-I2) system in Sulphur-Iodine cycle for hydrogen production

  • Mandal, Subhasis;Jana, Amiya K.
    • Nuclear Engineering and Technology
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    • v.52 no.2
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    • pp.279-286
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    • 2020
  • In this article, we develop a reactive distillation (RD) column configuration for the production of hydrogen. This RD column is in the HI decomposition section of the sulphur - iodine (SI) thermochemical cycle, in which HI decomposition and H2 separation take place simultaneously. The section plays a major role in high hydrogen production efficiency (that depends on reaction conversion and separation efficiency) of the SI cycle. In the column simulation, the rigorous thermodynamic phase equilibrium and reaction kinetic model are used. The tuning parameters involved in phase equilibrium model are dependent on interactive components and system temperature. For kinetic model, parameter values are adopted from the Aspen flowsheet simulator. Interestingly, there is no side reaction (e.g., solvation reaction, electrolyte decomposition and polyiodide formation) considered aiming to make the proposed model simple that leads to a challenging prediction. The process parameters are determined on the basis of optimal hydrogen production as reflux ratio = 0.87, total number of stages = 19 and feeding point at 8th stage. With this, the column operates at a reasonably low pressure (i.e., 8 bar) and produces hydrogen in the distillate with a desired composition (H2 = 9.18 mol%, H2O = 88.27 mol% and HI = 2.54 mol%). Finally, the results are compared with other model simulations. It is observed that the proposed scheme leads to consume a reasonably low energy requirement of 327 MJ/kmol of H2.

Development of transgenic potato with high content of sulphur-containing essential amino acids (황 함유 필수아미노산이 증대된 기능성 형질전환 감자 개발 현황)

  • Goo, Young-Min;Kim, Tae-Won;Lee, Min-Kyung;Lee, Shin-Woo
    • Journal of Plant Biotechnology
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    • v.40 no.1
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    • pp.1-8
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    • 2013
  • Potato is the 4th important crop along with rice, wheat and maize. It contains high quality of starch with relatively high content of vitamin C and protein. However, there is a nutritionally limiting factor due to a low level of sulphur-containing essential amino acid including methionine and cysteine. Recently, recombinant DNA technology and metabolic engineering with genes involved in the bio-synthetic pathway have been applied to enhance the level of these essential amino acids. In this report, it has been discussed about the current status and bottleneck on the development of transgenic potato containing high level of sulphur-containing essential amino acids.

Properties of SPE-Based Cement Grout for Semi-Rigid Pavements (Sulfur Polymer Emulsion을 활용한 반강성 포장용 시멘트 주입재의 특성)

  • Lee, Byung-Jae;Lee, Jun;Hyun, Jung-Hwan;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.4
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    • pp.57-65
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    • 2013
  • The development of the oil refining industry has resulted in an annual 120 million tons of sulphur, which is a by-product of the desulphurization process. To exploit this abundance, the applications of sulphur must be expanded. as excellent durability of reuse of leftover sulphur which has high potential for utilization in construction materials, the study is actively in progress. Meanwhile, there has been active research on semi-rigid pavements that draw on the strengths and overcome the weaknesses of asphalt and concrete pavements. Acrylate is used to prevent cracking but involves a high cost, thus, an alternative material is required. As such, this study presents methods on the reuse of leftover sulphur and examines the engineering performance of grout containing sulfur polymer emulsion (SPE) for use in semi-rigid pavements. Our analysis shows that grout in which 30% of acrylate is replaced with SPE has superior properties in terms of time of flow and strength compared to regular grout. However, performance declined when more than 50% of acrylate was replaced by SPE, indicating that the optimum replacement level is 30%. Through SEM analysis, we found that grout with utra harding cement in this study at three hours had similar hydration properties to that of Type 1 Ordinary Portland Cement (OPC) at seven days, and maintained the properties regardless of grout containing SPE. OPC and grout with a replacement level of 30% displayed similar levels of chloride invasion resistance, whereas grout without SPE was far less resistant. Within the scope of this paper, the optimum replacement level of acrylate with SPE was found to be 30% in consideration of various properties such as time of flow, strength, and chloride invasion resistance.

Fundamental Study on the Cause of Efflorescence in Calciumsilicate Brick (고압벽돌의 백화원인에 대한 기초적 연구)

  • Han, Sang-Mok;Shin, Kun-Chul
    • Journal of Industrial Technology
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    • v.2
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    • pp.61-67
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    • 1982
  • The cause of efflorescence originated from calciumsilicate hydrate brick was studied and some reports on efflorescence were reviewed. The main ingredient of undesirable efflorescence powder was sodium sulphate. It was found that influx of sodium and sulphur components was resulted from hydration water and fine sand.

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