• Title/Summary/Keyword: sulfur oxides

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Comparison of Sulfate Reduction Rates Associated with Geochemical Characteristics at the Continental Slope and Basin Sediments in the Ulleung Basin, East Sea (동해 울릉분지에서 대륙사면과 분지 퇴적물의 지화학적 특성에 따른 황산염 환원 비교)

  • You, Ok-Rye;Mok, Jin-Sook;Kim, Sung-Han;Choi, Dong-Lim;Hyun, Jung-Ho
    • Ocean and Polar Research
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    • v.32 no.3
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    • pp.299-307
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    • 2010
  • In conjunction with geochemical characteristics, rate of sulfate reduction was investigated at two sediment sites in the continental slope and rise (basin) of the Ulleung Basin in the East Sea. Geochemical sediment analysis revealed that the surface sediments of the basin site (D2) were enriched with manganese oxides (348 ${\mu}mol$ $cm^{-3}$) and iron oxides (133 ${\mu}mol$ $cm^{-3}$), whereas total reduced sulfur (TRS) in the solid phase was nearly depleted. Sulfate reduction rates (SRRs) ranged from 20.96 to 92.87 nmol $cm^{-3}$ $d^{-1}$ at the slope site (M1) and from 0.65 to 22.32 nmol $cm^{-3}$ $d^{-1}$ at the basin site (D2). Depth integrated SRR within the top 10 cm depth of the slope site (M1; 5.25 mmol $m^{-2}$ $d^{-1}$) was approximately 6 times higher than that at the basin site (D2; 0.94 mmol $m^{-2}$ $d^{-1}$) despite high organic content (>2.0% dry wt.) in the sediment of both sites. The results indicate that the spatial variations of sulfate reduction are affected by the distribution of manganese oxide and iron oxide-enriched surface sediment of the Ulleung Basin.

A Study on the Annual Increase of Air Pollutant Emissions in Korea (대기오염물질(大氣汚染物質) 배출량(排出量)의 연도별추세(年度別趨勢)에 관(關)한 연구(硏究))

  • Cho, Moon-Whan
    • Journal of Preventive Medicine and Public Health
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    • v.9 no.1
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    • pp.49-54
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    • 1976
  • In order to provide bases for the control of air pollutants in Korea, the author figured out the trend on the annual increase of air pollutants emitted in the process of combustions, and estimated the amounts of air pollutants of the future years from 1975 to 1981. 1) In 1973 the consumption rate of coal was 1.2 times of that of fuel oil. The consumption rate of them would be same in 1975 and 1977. However, the rate of fuel oil would exceed that of coal in 1979. Incontrast with the rate in 1979. The one of coal would be increased faster and faster to show reverse trend of consumption in 1981. 2) The estimated amounts of air pollutant emissions in the years of 1973, 1975, 1977, 1979 ana 1981 were 1,561,800, 1,921,700, 2,253,300, 2,769,000, and 3,145,700 tons respectively. These indicated that the amount of air pollutants in 1981 would be about 2 times of that in 1973. 3) The amounts of sulfur oxides emissions in 1981 would be 2.3 times of that in 1973, nitrogen oxides 2.2 times, carbon monoxide 1.7 times, particulate 2.0 times and hydrocarbon 2.0 times. 4) The estimated amounts of air pollutant emissions per unit area($km^2$) in the years of 1965, 1971, 1975 and 1980 were 5.2, 14.5, 19.5 and 28.7 tons respectively. These indicated that the amount of air pollutant emissions per unit area would increase 5.5 times in 1980 comparing the one in 1965.

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Experimental Analysis of Boil-Off Gas Occurrence in Independent Liquefied Gas Storage Tank (독립형 액화가스 저장탱크의 BOG 발생에 대한 실험적 분석)

  • Cha, Seung-Joo;Bae, Jin-Ho;Lee, Dong-Ha;Kim, Tae-Wook;Kim, Seul-Kee;Lee, Jae-Myung
    • Journal of Ocean Engineering and Technology
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    • v.32 no.5
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    • pp.380-385
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    • 2018
  • With the tightening of environmental regulations (i.e., IMO Tier III), natural gas (NG) has been spotlighted as an eco-friendly fuel with few air pollutants other than nitrogen oxides (NOx) and sulfur oxides (SOx). For reasons of economic efficiency, it is mainly stored and transported in a liquid state at $-163^{\circ}C$, which is a cryogenic temperature, using a liquefied gas storage tank. Accordingly, it is necessary to reduce the boil-off gas (BOG) occurrence due to the heat flow according to the temperature difference between the inside and outside of the storage tank. Therefore, in this study, a BOG measurement test on an independent-type storage tank made up of SUS304L was carried out. The test results showed the tendency for BOG occurrence according to the temperature under different filling ratios.

Emission Characteristics of Air Pollutants and Black Carbon from Wood-pellet Stove and Boiler (목재 펠릿 난로와 보일러 사용에 의한 대기오염물질과 블랙카본의 배출 특성)

  • Park, Sung Kyu;Lyu, Kun Jung;Kim, Daekeun;Kim, Dong Young;Jang, Young Kee;Jeon, Eui Chan
    • Journal of Climate Change Research
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    • v.6 no.1
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    • pp.41-47
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    • 2015
  • This study was carried out simulating domestic utilization conditions of a wood pellet stove and a wood pellet boiler in order to determine emission factors (EFs) of macro-pollutants, i.e., carbon monoxide, nitrogen oxides, sulfur oxides, ammonia, particulate matters (total suspended particulate, $PM_{10}$, $PM_{2.5}$, black carbon) and trace pollutants (i.e., ten different volatile organic compounds). The composite pollutants EFs for the pellet stove were: for TSP 4.58 g/kg, for $PM_{10}$ 3.35 g/kg, for $PM_{2.5}$ 2.48 g/kg, CO 119.23 g/kg, NO 14.40 g/kg, $SO_2$ 0.17 g/kg, TVOC 37.73 g/kg, $NH_3$ 0.02 g/kg and emissions were similar to the pellet boiler appliance: for TSP 4.73 g/kg, for $PM_{10}$ 3.41 g/kg, for $PM_{2.5}$ 2.63 g/kg, CO 161.51 g/kg, NO 13.67 g/kg, $SO_2$ 0.19 g/kg, TVOC 45.22 g/kg, $NH_3$ 0.02 g/kg.

Emission Characteristics of Air Pollutants and Black Carbon from Wood Stove and Boiler (화목 난로와 보일러 사용에 의한 대기오염물질과 블랙카본의 배출 특성)

  • Park, Sung Kyu;Choi, Sang Jin;Kim, Dae keun;Kim, Dong Young;Jang, Young Kee;Jeon, Eui Chan
    • Journal of Climate Change Research
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    • v.6 no.1
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    • pp.49-54
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    • 2015
  • Manually fed firewood burning appliances, i.e., stove and boiler, were tested in order to determine emission factors (EFs) of macro-pollutants, i.e., carbon monoxide, nitrogen oxides, sulfur oxides, ammonia, particulate matters (total suspended particulate, $PM_{10}$, $PM_{2.5}$, black carbon) and trace pollutants (i.e., ten different volatile organic compounds). The composite pollutants EFs for the wood stove were: for TSP 15.45 g/kg, for $PM_{10}$ 6.53 g/kg, $PM_{2.5}$ 4.16 g/kg, CO 175.49 g/kg, NO 1.58 g/kg, $SO_2$ 0.15 g/kg, TVOC 48.02 g/kg, $NH_3$ 0.02 g/kg and emissions were similar to the wood boiler appliance: for TSP 12.23 g/kg, for $PM_{10}$ 5.84 g/kg, $PM_{2.5}$ 3.66 g/kg, CO 146.74 g/kg, NO 1.42 g/kg, $SO_2$ 0.15 g/kg, TVOC 47.78 g/kg, $NH_3$ 0.01 g/kg.

Evaluation of ammonia (NH3) emissions from soil amended with rice hull biochar

  • Park, Seong-Yong;Choi, Ha-Yeon;Kang, Yun-Gu;Park, Seong-Jin;Luyima, Deogratius;Lee, Jae-Han;Oh, Taek-Keun
    • Korean Journal of Agricultural Science
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    • v.47 no.4
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    • pp.1049-1056
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    • 2020
  • Ultrafine dust causes asthma and respiratory and cardiovascular diseases when inhaled. Ammonia (NH3) plays a big role in ultrafine dust formation in the atmosphere by reacting with nitrogen oxides (NOx) and sulfur oxides (SOx) emitted from various sources. The agricultural sector is the single largest contributor of NH3, with the vast majority of emissions ensuing from fertilizers and livestock sector. Interest in using biochar to attenuate these NH3 emissions has grown. This experiment was conducted to study the effects of using rice hull biochar pyrolyzed at three different temperatures of 250℃ (BP 4.6, biochar pH 4.6), 350℃ (BP 6.8), and 450℃ (BP 10.3) on the emission of ammonia from soil fertilized with urea. The emissions of NH3 initially increased as the experiment progressed but decreased after peaking at the 84th hour. The amount of emitted NH3 was lower in soil with biochar amendments than in that without biochar. Emissions amongst biochar-amended soils were lowest for the BP 6.8 treatment, followed in an ascending order by BP 10.3 and BP 4.6. Since BP 6.8 biochar with neutral pH resulted in the lowest amount of NH3 emitted, it can be concluded that biochar's pH has an effect on the emissions of NH3. The results of this study, therefore, indicate that biochar can abate NH3 emissions and that a neutral pH biochar is more effective at reducing gaseous emissions than either alkaline or acidic biochar.

Computational Study on the Application of Porous Media to Fluid Flow in Exhaust Gas Scrubbers (배기가스 세정장치내 유체 유동에 대한 다공성 매질 적용 기반의 전산해석적 연구)

  • Hong, Jin-pyo;Yoon, Sang-hwan;Yoon, Hyeon-kyu;Kim, Lae-sung;An, Jun-tae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.2
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    • pp.1-10
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    • 2022
  • Exhaust gases emitted from internal combustion engines contain nitrogen oxides (NOx) and sulfur oxides (SOx), which are major air pollutants causing acid rain, respiratory diseases, and photochemical smog. As a countermeasure, scrubber systems are being studied extensively. In this study, the pressure drop characteristics were analyzed by changing the exhaust gas inflow velocity using a scrubber for a 700 kW engine as a model. In addition, the fluid flow inside the scrubber and the behavioral characteristics of the droplets were studied using CFD, and the design compatibility of the cleaning device was verified. Flow analysis was performed using inertial and viscous resistances by applying porous media to the complex shape of the scrubber. The speed of the exhaust passing through the outlet nozzle from the inlet was determined through the droplet behavior analysis by spraying, and the flow characteristics for the pressure drop were studied. In addition, it was confirmed through computational analysis whether there was a stagnation section in the exhaust gas flow in the scrubber or the sprayed droplets were in good contact with the exhaust gas.

A Study on Technology Status and Project of Hydrogen Production from Coal Gasificiation (석탄가스화를 이용한 수소생산 기술현황 및 프로젝트 분석)

  • Seungmo Ko;Hochang Jang
    • Journal of the Korean Institute of Gas
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    • v.27 no.1
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    • pp.1-12
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    • 2023
  • Coal gasification is a process of incomplete coal combustion to produce a syngas composed of hydrogen and carbon monoxide. It is one of methods to utilize coal cleanly because the process does not emits nitrogen oxides or sulfur oxides and particulate matters. In addition, chemicals can be produced using syngas. Coal gasification is classified as IGCC (Integrated Gasification Combined Cycle), Plasma coal gasification and UCG (Underground Coal Gasification). Recently, WGS (Water Gas Shift) reactor and carbon capture system have been combined to gasifier to produce hydrogen from coal. In this study, the coal gasification and method of hydrogen production from syngas was summarized, and the hydrogen production from coal gasification project was investigated.

Study on Wet Scrubber for SOX/NOX Treatment in Ship Flue Gas (선박 배가스내 SOX/NOX 처리용 습식 스크러버에 대한 연구)

  • Choi, Jin-Sik;Kim, Jae-Gang;Park, Byung Hyun;Lee, Ju-Yeol
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.1
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    • pp.183-188
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    • 2017
  • This study deals with $de-SO_X$ and $de-NO_X$ process of a wet scrubber for small size ship engines. The experiment was conducted according to the E3 mode of the $NO_X$ technical code. In order to discharge the sulfur containing flue gas, ditertiarybutyldusulfide was added to the diesel fuel to increase the sulfur content. NO gas, which occupies most of the nitrogen oxides in the exhaust gas, was oxidized into $NO_2$ and absorbed by a wet scrubber. The developed equipment of this work achieved 100% of removal efficiency for highly soluble $SO_2$ gas in an aqueous solution.

Characteristics of Acidic Gas Emissions from Combustion with Preblending of Coal and Sludge (석탄과 슬러지의 예혼합연소에 따른 산성가스 배출특성)

  • Shim, Sung-Hoon;Jeong, Sang-Hyun;Min, Hyo-Ki;Lee, Sang-Sup
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.2
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    • pp.103-108
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    • 2014
  • Using dried sludge as a secondary fuel of a coal-fired power plant is proposed as an alternative option for sludge disposal. Because elemental contents of sludge are different from those of coal, different levels of acidic gas emissions are expected from the co-combustion of sludge with coal. In this study, sludge samples were obtained from 7 sewage treatment plants in Korea. Each sludge sample was combusted together with coal in a lab-scale combustor, and the concentrations of nitrogen oxides ($NO_x$), sulfur dioxide ($SO_2$), hydrogen chloride (HCl), chlorine ($Cl_2$) in the flue gas were analyzed. Compared to the combustion of coal only, $NO_x$ concentration was slightly higher in the flue gas from the co-combustion of coal and sludge. $SO_2$ emission increased with the combustion of sludge due to the higher content of sulfur in sludge than in coal. For most of the tested samples, the concentrations of HCl and $Cl_2$ were varied depending on the chlorine content in the sludge sample.