• 제목/요약/키워드: sulfur dioxide

검색결과 417건 처리시간 0.026초

사용시약별로 본 이산화연법에 의한 대기중 황산화물의 비교측정및 자동측정 성적과의 비교 (Comparative Experiment to Determine the Activation Factor of Lead dioxide by Kinds in Measuring the Concentration of Sulfur oxides in the Atmosphere by $PbO_2$ Cylinder Method)

  • 최덕일
    • 한국환경보건학회지
    • /
    • 제2권1호
    • /
    • pp.29-31
    • /
    • 1975
  • This experiment Was carried out under two points of view, from May 1st to the end of 1973. One was the comparative determination of the activation factor of Lead dioxide by kinds in measuring of Sulfur oxides concentration by $PbO_2$ cylinder method, and the other was the comparison that result with the record of auto analyzer. Five measuring sites were selected out of Seoul City. Three kinds of Lead dioxide made in Japan (B,C and D) were compared with Standard $PbO_2$ (A for use in Determination of Sulphur in the atmosphere, purity 99% up) made in British Institution, and monthly measuring was conducted at every sampling site. The recording by auto analyzer (Beckman Model 906-A $SO_2$ Analyzer) was conducted once or twice a month for 24 hours at each sampling site during the same period. And some significant results were obtained. 1. In comparative experiments to determine the activation degree of three kinds of Lead dioxide (B,C and D), the obtained correction factor of B reagent was 1.09, 1.16 in C and 1.30 in D against Standard $PbO_2$ (A). Therefore, it should be in need of standardization or clear statement about the reagents for use, in determination sulfur oxides by $PbO_2$ cylinder method. 2. Generally, the concentration of Sulfur dioxide by wilkins' convertion method from $SO_3$ showed about 20-30% higher than those by Auto analyzer.

  • PDF

부산지역 4개 백화점의 공기오염도에 관한 조사연구 (The Study on the Level of Air Pollution at Four Department Stores in Pusan Area)

  • 문덕환;이현우;이채언
    • 한국산업보건학회지
    • /
    • 제1권2호
    • /
    • pp.164-180
    • /
    • 1991
  • For the purpose of contributing to the promotion of health of the employees working at the same kind of department store or similar type of business and the people utilizing them and preparing the basic data for the establishment of mangagement measure by assessing the level of air pollusion at indoor and outodoor of four department store among the distribution service business in Pusan area, authors measured the concentration of sulfur dioxide, nitrogen dioxide, formaldehyde and total suspanded particle according to the measuring height of variable at indoor and outodoor from Aug. 1990. to sep. an. d Jan, 1991 to Feb.: for each two months in summer and winter, and studied by dividing the variable factor into atmospheric factor (temperature, humidity and air velociy) The results are as follows ; 1. The mean concentration of air pollutants at indoor to total subjects was nitrogen dioxide 31.1ppb, sulfur dioxide 51.7ppb, formaldehyde 162.lppb and total suspanded particle $67.7{\mu}g/m^3$, and it was higher in winter than in summer (P>0.05) 2. The mean concentration of formaldehyde to total subjects was higher indoors than outdoors (P<0.001), in case of nitrogen dioxide there was no significant difference and sulfur dioxide and total suspanded particle were higher outdoors than indoors (P<0.05) 3. The concentration of nitrogen dioxide and sulfur dioxide proved to be a adverse correlation, reducing with height. 4. According to the result questioned about the exposure concentration of pollutant and the general symptom caused by the pollutant, nitorgen dioxide and symptom proved to be a positive correlation (P<0.09).

  • PDF

자력선별법에 의한 선탄의 탈황 (COAL DESULFURIZATION BY MAGNETIC SEPARATION METHODS)

  • 전호석;이재장
    • 산업기술연구
    • /
    • 제15권
    • /
    • pp.175-185
    • /
    • 1995
  • Under the new environmental regulations announced by the government, utilities will have to cut their sulfur dioxide emissions by 60% from 1991 levels by the year of 1999. Sulfur dioxide emissions can be reduced prior to combustion by physical, chemical or biological coal cleaning. The new technology of high gradient magnetic separation (HGMS) offers the potential of economic separatoins of a variety of fine, weakly magnetic minerals including inorganic sulfur and many ash-forming minerals from coals. In the present paper, magnetic separation tests have been conducted on Korean anthracite and high-sulfur Chinese coal to investigate the feasibility of these techniques for reducing sulfur content from coals. In wet magnetic separation, the studied operating parameters include particle size, pH, matrix types, feed solids content, feed rate, number of cleaning stages and etc. The results shows that for wet separation, 60~70% of total sulfur was removed from coals with over 80% combustible recovery, on the other hand, for dry separation, 47.6% of total sulfur was removed from coals with 75% recovery.

  • PDF

대기오염물질과 식물환경 -아황산에 의한 영향을 중심으로 (Air Pollutants and Vegetation -With Special Reference to Sulfur Dioxide-)

  • 이미순
    • Journal of Plant Biology
    • /
    • 제18권2호
    • /
    • pp.45-52
    • /
    • 1975
  • Effects of air pollutants on vegetation were reviewed and discussed with special reference to sulfur dioxide. Main contents were on the sources, meteorological factors, injury symptoms, relative sensitivity, growth/yield, indicator/diagnosis, combined effects, injury mechanism and effects on plant metabolism, injury diminishing measures, and future research needs.

  • PDF

황산 공장의 수율 최적화에 관한 연구 (Optimization of conversion of sulfur dioxide in sulfuric acid plant)

  • 원종국;조영상;정태경
    • 제어로봇시스템학회:학술대회논문집
    • /
    • 제어로봇시스템학회 1987년도 한국자동제어학술회의논문집; 한국과학기술대학, 충남; 16-17 Oct. 1987
    • /
    • pp.664-666
    • /
    • 1987
  • In this study, the computation of optimum operating conditions for catalytic oxidation of sulfur dioxide to sulfur trioxide in CONVERTER which determines the yield ultimately in sulfuric acid plant is performed on an IBM/XT computer. The process simulator of rigorous converter model including mass & energy balance equations and supporting equations is linked to optimizer, which produces the desired results successfully.

  • PDF

전탕 전과 후의 중금속, 잔류농약 및 잔류이산화황의 농도변화 - 감기약을 중심으로 - (Concentration of Heavy Metals, Residual Pesticides and Sulfur Dioxide of before/after a Decoction)

  • 서창섭;황대선;이준경;하혜경;천진미;엄영란;장설;신현규
    • 대한본초학회지
    • /
    • 제23권4호
    • /
    • pp.51-58
    • /
    • 2008
  • Objectives: To compare the contents of heavy metals, residual pesticides and sulfur dioxide before/after a decoction. Methods: The heavy metal contents before/after a decoction were measured by Inductively Coupled Plasma Atomic Emission Spectrometer(ICP-AES) and mercury analyzer. In order to analyze pesticides in 5 samples we used simultaneous multi-residue analysis of pesticides by GC/ECD, which was followed by GC/MSD analysis to confirm the identity of the detected pesticide in each sample. In addition, the contents of sulfur dioxide($SO_2$) were performed by Monier-Williams distillation method. Results: 1. The mean values of heavy metal contents(mg/kg) for the samples were as follows: Galgeun-tang(before decoction-Pb; 0.793, Cd; 0.133, As; 0.016 and Hg; 0.005, after decoction-Pb; 0.033, Cd; 0.004, As; 0.002 and Hg; not detected), Gumiganghwal-tang(before decoction-Pb; 0.934, Cd; 0.197, As; 0.046 and Hg; 0.006, after decoction-Pb; 0.062, Cd; 0.007, As; 0.004 and Hg; 0.0001), Sosiho-tang(before decoction-Pb; 0.891, Cd; 0.134, As; 0.091 and Hg; 0.014, after decoction-Pb; 0.036, Cd; 0.002, As; 0.004 and Hg; not detected), Ojuck-san(before decoction-Pb; 0.907, Cd; 0.136, As; 0.084 and Hg; 0.007, after decoction-Pb; 0.074, Cd; 0.007, As; 0.011 and Hg; 0.0005) and Samsoeum(before decoction-Pb; 1.234, Cd; 0.154, As; 0.016 and Hg; 0.007, after decoction-Pb; 0.094, Cd; 0.006, As; 0.002 and Hg; 0.001). 2. Contents(mg/kg) of residual pesticides before/after a decoction in all samples were not detected. 3. Contents(mg/kg) of sulfur dioxide($SO_2$) before a decoction in Galgeun-tang, Gumiganghwal-tang, Sosiho-tang, Ojuck-san and Samsoeum exhibited 1.2, 3.4, 11.1, 12.0 and 5.7, respectively. However, contents of sulfur dioxide after a decoction in all samples were not detected. Conclusions: These results will be used to establish a criterion of heavy metals, residual pesticides and sulfur dioxide.

  • PDF

전탕 전과 후의 중금속, 잔류농약 및 잔류이산화황의 농도변화 - 십전대보탕 구성처방을 중심으로 - (Concentration of Heavy Metals, Residual Pesticides and Sulfur Dioxide before/after a Decoction - In Prescription consist of Sipjeondaebo-tang -)

  • 서창섭;황대선;이준경;하혜경;천진미;엄영란;장설;신현구
    • 대한한의학회지
    • /
    • 제30권4호
    • /
    • pp.108-117
    • /
    • 2009
  • Objective: To compare the contents of heavy metals, residual pesticides and sulfur dioxide before/after a decoction. Methods: The heavy metal contents before/after a decoction were measured by inductively-coupled plasma atomic emission spectrometer (ICP-AES) and mercury analyzer. In order to analyze pesticides in 5 samples we used simultaneous multi-residue analysis of pesticides by GC/ECD, which was followed by GC/MSD analysis to confirm the identity of the detected pesticide in each sample. In addition, the contents of sulfur dioxide ($SO_2$) were performed by Monier-Williams distillation method. Results: 1. The mean values of heavy metal contents (mg/kg) for the samples were as follows: Sipjeondaebo-tang (before decoction - Pb; 1.163, Cd; 0.257, As; 0.080 and Hg; 0.016, after decoction - Pb; 0.059, Cd; 0.007, As; 0.006 and Hg; 0.0003), Palmul-tang (before decoction - Pb; 1.181, Cd; 0.242, As; 0.152 and Hg; 0.014, after decoction - Pb; 0.067, Cd; 0.008, As; 0.008 and Hg; 0.0003), Sagunja-tang (before decoction - Pb; 1.285, Cd; 0.283, As; 0.063 and Hg; 0.012, after decoction - Pb; 0.047, Cd; 0.009, As; 0.004 and Hg; not detected) and Samul-tang (before decoction - Pb; 1.025, Cd; 0.169, As; 0.099 and Hg; 0.013, after decoction - Pb; 0.065, Cd; 0.007, As; 0.010 and Hg; 0.001). 2. Contents (mg/kg) of residual pesticides before/after a decoction were not detected in any samples. 3. Contents (mg/kg) of sulfur dioxide ($SO_2$) before a decoction in Sipjeondaebo-tang, Palmul-tang, Sagunja-tang and Samul-tang exhibited 5.0, 6.0, 14.0 and 6.9, respectively. However, contents of sulfur dioxide after a decoction were not detected in any samples. Conclusion: These results will be used to establish a criterion for heavy metals, residual pesticides and sulfur dioxide.

  • PDF

중금속, 잔류농약 및 잔류이산화황의 전탕 전, 후의 농도 변화 - 다빈도 태음인 사상처방을 중심으로 - (Concentration of Heavy Metals, Residual Pesticides and Sulfur Dioxide of before/after Decoction)

  • 서창섭;황대선;이준경;하혜경;천진미;엄영란;장설;김종열;이시우;신현규
    • 사상체질의학회지
    • /
    • 제21권1호
    • /
    • pp.237-246
    • /
    • 2009
  • 1. Objectives To compare the contents of heavy metals, residual pesticides and sulfur dioxide before/after decoction. 2. Methods The heavy metal contents before/after decoction were measured by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) and mercury analyzer. In order to analyze pesticides in 3 samples we used simultaneous multi-residue analysis of pesticides by GC/ECD, followed by GC/MSD analysis to confirm the identity of the detected pesticide in each sample. In addition, the contents of sulfur dioxide (SO2) were performed by Monier-Williams distillation method. 3. Results 1) The mean values of heavy metal contents (mg/kg) for the samples were as follows: Yuldahanso-tang (before decoction - Pb; 1.85, Cd; 0.148, As; 0.042 and Hg; 0.003, after decoction - Pb; 0.096, Cd; 0.006, As; 0.006 and Hg; 0.002), Chongsimyonja-tang (before decoction - Pb; 1.193, Cd; 0.094, As; 0.084 and Hg; 0.008, after decoction - Pb; 0.053, Cd; 0.007, As; 0.011 and Hg; not detected) and Taeyeumjowee-tang (before decoction - Pb; 0.878, Cd; 0.078, As; 0.302 and Hg; 0.004, after decoction - Pb; 0.079, Cd; 0.005, As; 0.006 and Hg; not dectcted). 2) Contents (mg/kg) of residual pesticides before/after decoction in all samples were not detected. 3) Contents (mg/kg) of sulfur dioxide (SO2) before decoction in Yuldahanso-tang, Chongsimyonja-tang and Taeyeumjowee-tang exhibited 6.1, 37.8, 31.5 and 19.7, respectively. However, contents of sulfur dioxide after decoction in all samples were not detected. 4. Conclusion These results will be used to establish a criterion of heavy metals, residual pesticides and sulfur dioxide.

  • PDF

철강업에 있어서 산성비 원인물질 저감대책평가 모형 구축에 관한 연구 - 아황산가스를 중심으로 - (A Methodological Study on an Assessment Model Developed for the Mitigation of Acid rain Causing Material - Focus on Sulfur Dioxide Emission Reduction Measures -)

  • 이동근;정태용;전성우
    • 환경영향평가
    • /
    • 제7권2호
    • /
    • pp.71-82
    • /
    • 1998
  • This study focuses on one of the most typical energy-intensive industries, the steel industry. The two-fold purpose of the study is to develop a model to assess measures to alleviate sulfur dioxide($SO_2$) emissions from the steel industry and to propose a concrete $SO_2$ emission reduction measure from the steel industry. This study partially employed and modified AIM(Asia-Pacific Integrated Model) developed by Japan National Environmental Research Institute to develop AIM/KOREA SULFUR model for simulation. In the study, a base scenario, which is BAU(Business As Usual) scenario, and mitigation scenarios(a use of low-sulfur contain fuel, fuel conversion to cleaner energy, an induction of desulfurization systems, and energy saving) were employed. The results of the simulation are summarized below: The sulphur dioxide emission from the steel industry in 1992 was estimated to be 252,000 metric tons; however, according to BAU scenario, sulphur dioxide emission is expected to be increased to 586,000 metric tons, which is 2.3 times greater than that in 1992 by year 2020. To alleviate such increasement, simulation results under various 7scenarios proved that some degrees of reduction may be possible by an induction of desulfurization systems although there may be numerous ways to interpretate the simulation results; however, the bottom line is that it appears to be difficult to achieve the Korean Ministry of Environment's policy goal-a mitigation of sulphur dioxide concentration to 0.01ppm.

  • PDF

Passive Sampler를 이용한 $SO_2$ 공간농도분포 조사와 토양오염 상관성 연구 (A Study on Correlations between Distribution of Sulfur Dioxide Concentration and Soil Environments by Using Passive Samplers)

  • 송영배
    • 대한환경공학회지
    • /
    • 제27권10호
    • /
    • pp.1025-1029
    • /
    • 2005
  • 공단지역에서 아황산가스의 오염농도와 공간분포를 조사하기 위해 토지이용 유형별로 약 500 m 격자망을 구성하여 76개의 지점에 패시브샘플러를 설치하여 분석을 수행하였다. 또한 아황산가스를 비롯한 대기오염물질이 공업단지, 주거지 및 녹지지역의 토양에 미치는 오염영향을 파악하기 위해 120개 지점에서 토양시료를 채취하여 토성과 중금속 농도를 분석하였다. 분석결과 아황산가스 농도와 Cu 및 Pb와의 상관도는 0.05 및 0.04로 낮게 도출되었으나, 공업지역만을 대상으로 분석하였을 경우 상관도는 0.17 및 0.08로서 각각 3.3배와 2배 증가한 것으로 분석되었다. 위 연구결과는 대기오염농도의 공간분포 및 토양오염과의 상관성을 파악할 수 있도록 공업지역, 주거지역 및 녹지지역으로 구분하여 도면에 표시하였으며, 연구결과는 인간, 동 식물이 장기간 오염환경에 노출정도와 대기위생 및 공중보건 위험성평가를 위한 자료로 활용될 수 있다.