• 제목/요약/키워드: sulfur concentration

검색결과 632건 처리시간 0.026초

평판형 분리막 접촉기를 이용한 이산화황 흡수 분리 (Absorptive Separation of Sulfur Dioxide using Flat Membrane Contactor)

  • 이용택;이영진;송인호;전현수;안효성;이형근
    • 멤브레인
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    • 제16권3호
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    • pp.196-203
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    • 2006
  • 산성비의 한 가지 원인으로 알려진 이산화황($SO_2$)을 포함한 대기 오염물질인 연도 기체의 배출 허용 기준이 엄격해지고 있다. 배연 탈황 기술의 효율을 획기적으로 높일 수 있는 분리막 접촉기의 개발에 필요한 기초 설계 자료를 제공하고자 평판형 분리막 접촉기 실험 장치를 설계 및 설치하여 이산화황 투과 특성 평가를 수행하였다. 평판형 분리막 접촉기를 이용한 이산화황의 제거에 미치는 흡수제 농도와 공급 기체 내의 이산화황 농도의 영향, 공급 기체 유량 및 분리막 재질에 따른 영향을 확인하고자 하였다. 흡수제 농도가 증가할수록 이산화황 제거 효율이 증가하였으며, 이산화황 농도가 증가할수록 제거 효율이 감소하였다. 또한 공급 기체 유량이 증가할수록 제거 효율이 감소하였으며 분리막 재질은 제거 효율에 큰 영향을 끼치지 않음을 확인할 수 있었다.

식물에 미치는 방사성 동위원소 $S^35$의 영향에 대하여 (제2보) 발아호밀의 생장 및 조섬호흡에 미치는 영향 (Effectsof absorbed radioactive sulfur $S^35$ in plant cell. II. Effects of sulfur on the growth and tissue respiration of rye seedlings)

  • 홍순우
    • Journal of Plant Biology
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    • 제8권1_2호
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    • pp.5-10
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    • 1965
  • The effect of radioactive sulfur-35 on the growth and tissue respiration in rye, Secale cereale L., seedlings were studied in this investigation. The growth and respiration rate of the materials treated with the different intensities of radioactivity, represented by the different concentration(${\mu}c$) of radioactive sulfur were shown similar effects in treated groups as those of Gamma-ray or X-ray irradiation on plant materials. However, in the groups of ($0.1{\mu}c$ and ($0.4{\mu}c$ S35-solution, the growth and respiration rate were stimulated somewhat more clearly than in case of control. And the higher concentration groups, $1.6{\mu}c$, $6.4{\mu}c$, and $25.6{\mu}c$ were depressed of the growth and tissue respiration rate. The present data could be explained on the basis that the higher concentration treatments with the radioactive isotope did produce injury to the plant metabolism generally, but the moderate treatment would stimulate to the plant growth and tissue respiration.

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침지형 황 탈질 모듈을 이용한 고속의 질소제거 (High-Rate Nitrogen Removal using a Submerged Module of Sulfur-Utilizing Denitrification)

  • 문진영;황용우;가미선
    • 상하수도학회지
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    • 제21권4호
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    • pp.429-437
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    • 2007
  • This study aims to develop a sulfur-using denitrification process which is possible a renovation to advanced treatment plant submerging a simple module in activated sludge aeration tank. At first, the impact factor of sulfur-using denitrification was appreciated by the batch test. Secondly, reflecting a dissolved oxygen effect of sulfur-using denitrification that was confirmed by the batch test, in a continuous nitrification/sulfur-using denitrification, high-rate nitrogen removal reaction was induced at optimum condition controlling DO concentration according to phases. Also, inside and outside of sulfur-using denitrification module was covered with microfilter and the module was considered as an alternative of clarifier. Result of batch test for sulfur-using denitrification, $NO_2{^-}N$ was lower for consumption of alkalinity and sulfur than that of $NO_3{^-}-N$. These results revealed the accordance of theoretical prediction. In continuous nitrification/sulfur-using denitrification experiment, actual wastewater was used as a influent, and influent nitrogen loading rates were increased 0.04, 0.07, 0.11, $0.14kg\;N/m^3-day$ by changing hydraulic retention times. At this time, nitrogen loading rates of packed sulfur were increased 0.23, 0.46, 0.69, $0.93kg\;N/m^3-day$. As a result, nitrification efficiency was about 100% and denitrification efficiency was 93, 81, 79, 72%. Accordingly, nitrogen removal was a high-rate. Also the module of sulfur-using denitrification covered with microfilter did not make a fouling phenomena according to increased flux. And the module was achieved effluent suspended solids of below 10 mg/L without a clarifier. In conclusion, it is possible a renovation to advanced treatment plant submerging a simple module packed sulfur in activated sludge aeration tank of traditional facilities. And the plant used the module packed sulfur is expected as a effective facilities of high-rate and the smallest.

A Study on the Distribution Characteristics of Sulfur Compounds in Ambient air using Continuous Monitoring Method in Incheon Area

  • Seo, Seok-Jun;Lim, Yong-Jae;Hong, You-deok;Park, Geon-Young
    • 통합자연과학논문집
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    • 제8권2호
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    • pp.128-134
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    • 2015
  • This paper focuses on the applicability of a continuous monitoring method on trace sulfur compounds in the ambient air by TD and GC/PFPD. The target compounds for monitoring include H2S(hydrogen sulfide), Methyl mercaptan, Dimethyl Sulfide, and Dimethyl disulfide. The result of QA/QC on monitoring instruments satisfies all the standards of Odor Measurement and Analysis Method, showing that the reproductivity of the compounds by concentration is within 10%, linearity is above 0.98 of a correlation efficient, method detection limit is 0.16 ppb by MM standard, and recovery rate is over 70%. Monitoring was conducted for two years from March 2006 to February 2008. As a result of the monitoring, the average concentration of H2S was 0.08 ppb, with the maximum concentration at 16.15 ppb. The result indicates that it is reasonable to do continuous monitoring as there appears a spontaneous event of high concentration by the condition of the site during monitoring odor-causing substances. Therefore, it is suggested that the continuous monitoring method used in this paper is appropriate to identify the characteristics of sudden occurrence and concentration variations of sulfur compounds.

초호열성 고세균 Thermococcus sp. DT1331의 유황 화합물 이화 특성

  • 곽이성;김영배
    • 한국미생물·생명공학회지
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    • 제25권4호
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    • pp.354-358
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    • 1997
  • Some sulfur coompounds dissimilation characteristcs of Thermococcus sp. DT1331 were studied. DT1331 had ether-like lipid compounds in addition to esters in the cell membrane. The specific growth rates of DT1331 decreased with increasing head spaces of the cultures. However, when the ratio of head space volume to medium volume was 5.60, the strain showed no growth. DT1331 showed vigo- rous growth with 1% or more elemental sulfur addition. Cystine could substitute elemental sulfur and DT1331 showed moderate growth with 0.1% or more cystine concentration. The specific growth rate and maximum cell concentration of Thermococcus sp. DT1331 in the presence of elemental sulfur were 0.80 hr$^{-1}$ and 2.0 x 10$^{8}$ cells/ml, respectively, while they were 0.67 hr$^{-1}$ and 1.1 x 10$^{8}$ cells/ml, respectively in the presence of cystine.

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염소와 황을 함유한 폐기물의 소각시 생성되는 유해 중금속류 결정에 대한 화학평형 계산 (An Equilibrium Analysis to Determine the Speciation of Metals in the Incineration of Waste Containing Chlorine and Sulfur)

  • 이정진;황정호
    • 한국연소학회지
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    • 제1권1호
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    • pp.31-39
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    • 1996
  • An equilibrium analysis was carried out to determine principal species in the incineration of hazardous waste, which was assumed as a compound of hydrocarbon fuel, chlorine, sulfur, and heavy metals, and their behaviors with variation of temperature, chlorine and sulfur concentrations. Calculated results showed that the most important parameter influencing the principal species was temperature. Chlorine concentration affected on mole fractions of the species, especially at high temperature. Existence of sulfur had a significant effect on the species at low temperature, regardless of surfur concentration. Generally, principal species at high temperature were chlorides and oxides, while the principal species at low temperature were sulfides. As temperature increased, mole fractions of the principal species increased at low temperature, however, mole fractions of some metal species decreased at high temperature.

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홍삼의 법제유황 처리가 당뇨쥐의 혈중지질 및 대사지표물질에 미치는 영향 (Effect of Red Ginseng with Processed Sulfur Extracts on Serum Lipids Concentration and Metabolic Variables in Diabetic Rats)

  • 한현정;김혜자;정명수;조화은;최윤희;이기남
    • 대한본초학회지
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    • 제24권1호
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    • pp.89-98
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    • 2009
  • Objectives : The purpose of this study was to evaluate effects of processed sulfur with red ginseng on streptozotocin(STZ) induced diabetic rats for expansion of processed sulfur internal application. Methods : We prepared red ginseng with non processed sulfur extracts(GS), red ginseng with processed sulfur I extracts(GPS I) and red ginseng with processed sulfur II extracts(GPS II). In the present study, we examined about contents of crdue saponin, antioxidant activity, $\alpha$-glucosidase inhibitory activity, and effects of STZ induced diabetic rats. Results : Contents of crude saponin increased by processed sulfur, and GPS II was shown highest contents in crude saponin and sulfur compared with another groups. Electron donating ability of GPS II was shown highest activity compared with GS and GPS I, SOD-like activity showed same tendency as electron donating ability at 1 $mg/m\ell$ concentration. Inhibitory activity of $\alpha$-glucosidase was approximately same level in acarbose and GPS II. Blood glucose level of GPS II group was decreased 18.34% compared with DC(diabetes control) group and maintained stability range in glucose level. but GS and GPS I showed high level compared to GPS II. Serum triglycerides concentration also showed lowest level in GPS II. The activity of ALT, AST and ALP was shown high level in diabetic induced groups, and lowest level in GPS II. Creatinine was shown non-significantly difference in each groups and GPS II was shown lowest level in BUN. Conclusions : These results suggested that processed sulfur with red ginseng have improvement effects on diabetes and internal application of processed sulfur with red ginseng have no specific toxicity in liver and kidney.

서울시내 가로수목의 수용성유황 및 중금속 함량에 관한 연구 (A Study on the Contents of Soluble Sulfur and Heavy Metals in the Leaves of the Roadside Tree in Seoul Area)

  • 김면섭;이광국
    • 한국대기환경학회지
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    • 제4권1호
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    • pp.1-12
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    • 1988
  • This study was carried out to measure the contents of soluble sulfur and heavy metals in the leaves of roadside tree at 34 sampling sites of Seoul area from the Sep. 1 to Sep. 30 during 1985 and 1986. The results were as follows; 1. Average contents of soluble sulfur at all sampling sites were; Plantanus orientalis 0.474%, Ginkgobioloba 0.562%, and Salix pseudolasiogyne 0.566%. 2. Correlation between sulfur dioxide concentration in the air and soluble sulfur in the leaves by area were; Green belt area R = 0.985, Residential area R = 0.856, Commercial area R = 0.668, Industrial area R = 0.886. Correlation by species were ; Platanus orientalis R = 0.817, Ginkgobiloba R = 0.771, Salix pseudo-lasiogyne R = 0.824. 3. Correlation between $SO_X$ concentration in the air and sulfur contents in the leaves showed positive significance. 4. Contents of soluble sulfur in the heavy traffic area were higher than that of light traffic area. 5. Heavy metal contents of 1986 were higher than that of 1985; Fe> Mn > Zn > Pb > Cu > Cd > Cr. 6. Lead contents in the leaves of 1986 were; Platanus orientalis 16, 701 ppm, Gingobiloba 21,729ppm, Salix Pseudo-lasiogyne 12.418 ppm.

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우리나라 산림지역에서의 이산화황 농도의 시.공간적 분포 (Temporal and Spatial Distribution of Ambient Sulfur Dioxide Concentration in Forest Areas, Korea)

  • 이승우;이충화;지동훈;윤희정
    • 한국토양비료학회지
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    • 제43권6호
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    • pp.1035-1039
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    • 2010
  • 전국 65개 산림지역 조사지를 대상으로 장기확산형 패시브샘플러를 이용하여 1993년에서 2008년까지 월별 이산화황 ($SO_2$) 농도를 측정하고 도시지역과 비교하여 산림지역에서의 이산화황 농도의 시간적 및 공간적 분포 특성을 구명하였다. 산림 내 이산화황 ($SO_2$)의 연평균 농도는 관측 시작년도부터 점차 낮아지다가 1997년 이후에는 뚜렷한 변화가 없었으며, 이는 환경부의 도시지역의 연도별 농도 변화와도 같은 경향이었다. 조사기간 동안 전체 산림지역 조사지의 연평균 이산화황 농도는 5.6 ppb로 환경부의 도시지역 평균치 (10.1 ppb)와 EC (1999)의 생태적 위해 기준치 (7.6 ppb)에 비해 낮은 수준이었다. 계절별로는 산림지역과 도시지역 모두에서 난방 연료 사용량이 많은 겨울과 봄에 농도가 높았으며 강우와 고온의 영향이 큰 여름에 낮게 나타났다. 지역별로는 다른 지역에 비해 경북과 경기지역에서 이산화황 연평균 농도가 높게 나타났다. 황산화물 배출량과 이산화황 농도 간에 유의적인 정의 상관성이 나타남에 따라 황산화물 배출원의 규모와 근접성이 대기 중 이산화황의 농도를 결정짓는 중요한 인자임을 반영하였다.