• Journal of the Korean Applied Science and Technology
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• v.3 no.2
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• pp.29-34
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• 1986

The sulfuric acid sulfonation of 2-aminonaphthalene was preformed at $30^{\circ}C{\sim}200^{\circ}C$ for $1{\sim}15$ hours, using $4{\sim}10$ parts of 90% sulfuric acid${\sim}$20% oleum. This reaction was influenced by many factory such as reaction temperature, reaction time, strength of sulfuric acid and amount of sulfuric acid and among these factors, the effect of the reaction temperature was considerable. The main products of this reaction were Dahl's acid (2-aminonaphthalene-5-sulfonic acid, Broenner's-acid (2-aminonaphthalene-6-sulfonic acid), amnio-F-acid(2-aminonapthalene-7-sulfonic acid), and Baden acid (2-aminonaphthalene-7-sulfonic acid) and another isomers such as Tobia's acid (2-aminonaphthalene-1-sulfonic acid) and 2-aminonaphthalene-4-sulfonic acid were not formed. Of these isomeric acids, those containing the sulfonic acid group in an ${\alpha}-position$, namely, Dahl's acid and Baden acid, are simultaneously formed by sulfonation at low-temperature ($30{\sim}100^{\circ}C$), whilst those containing the sulfonic acid group in a ${\beta}$-position, namely, Broenner's acid and amino-F-acid, are formed simultaneously by sulfonation at high temperatures($150^{\circ}{\sim}200^{\circ}$).

• Journal of the Korean Chemical Society
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• v.35 no.5
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• pp.520-526
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• 1991

Retention behavior of lanthanides was studied on the dynamic system using dinonylnaphthalene sulfonic acid cation exchanger and tartaric acid as a complexing agent. The relations between logk' and log$[NH^{4+}]$/log[tartarate], and between logk' and logR showed good linearity in isocratic and gradient elution, respectively. In gradient elution of tartaric acid the slopes were increased as the initial concentrations were decreased. Column efficiencies and resolution of lanthanides on dinonylnaphthalene sulfonic acid equilibrated cation exchanger were found to be better in ${\alpha}$-hydroxyisobutyric acid eluent than in tartaric acid.

• Polymer(Korea)
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• v.35 no.5
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• pp.438-443
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• 2011

In order to enhance water permeability through the improvement of fouling phenomena and wettability of hydrophobic porous membranes, various adsorption materials, i.e., poly(vinyl amine), poly (styrene sulfonic acid), poly(vinyl sulfonic acid), and poly(acrylamide-co-acrylic acid) were adsorbed onto the surface of polyethylene (PE) porous membrane. The concentration of adsorption solutions, adsorption time, the sort of salts and their ionic strength were varied, and the pure water permeability of their resulting adsorbed membranes was measured. In general, water permeability increased with an initial increase in the concentration of adsorption solution, adsorption time, and ionic strength and then decreased with a further increase. The pure water permeability of 375 $L/m^2h$(LMH), 35% enhancement, was obtained at a condition of poly(vinyl sulfonic acid) 1000 ppm, $Mg(NO_3)_2$ ionic strength(IS) 0.1, and adsorption time 150 sec, while the 50% (411 LMH) and 35% (374 LMH) enhancements were obtained at conditions of poly(styrene sulfonic acid) 1000 ppm, adsorption time 60 sec, and NaCl IS 0.1 and 0.2, respectively.

• Journal of Korea Foresty Energy
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• v.21 no.3
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• pp.18-27
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• 2002

Pine bark was liquefied in the presence of phenol using organic sulfonic acids as catalysts, and the liquefied barks were characterized. It was found that the organic sulfonic acids were more effective catalysts than hydrochloric acid for complete liquefaction of pine bark. The liquefied barks prepared from phenol-organic sulfonic acid liquefaction were highly phenolated, and the amounts of combined phenol were 2-3 times greater than that of the liquefied bark obtained from phenol-hydrochloric acid liquefaction. The glass transition points (Tg) were lower than that of the liquefied barks prepared from phenol-hydrochloric acid. It can be concluded that by using the organic sulfonic acids, the phenol used as a liquefying reagent is highly introduced into the bark, resulting in the phenolated bark preventing further condensation reactions, which may occur during the liquefaction. The carbohydrates such as cellulose and hemicellulose in the liquefied barks were almost decomposed during the liquefaction, from the results of IR spectra and neutral sugar analyses. Energy dispersive X-ray spectromery (EDS) results from the residues and the liquefied barks showed that the organic sulfonic acid catalysts did not lead to serious corrosion of the reactor compared with the hydrochloric acid catalyst.

• Journal of the Korean Chemical Society
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• v.5 no.1
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• pp.38-41
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• 1961

By varying groups on biologically active molecules, it is possible to produce analogues which sometimes inhibit the action of the parent compound. Such is true of taurine(${\beta}$-amino-ethane sulfonic acid)as an analogue of ${\beta}$-alanine and of pantoyl taurine for pantothenic acid. It seemed possible that the sulfonic acid analogues of amino acids built into peptides might possibly produce inhibition of the parent peptide. Tauryl-L-histidine was selected to prepare as an analogue of carnosine(${\beta}$-alanyl-L-histidine). There were several reasons for this choice. Camosine causes a slight contraction of isolated uterine muscle and inhibition of this action can be easily tested. Also, taurine, being a ${\beta}$-amino sulfonic acid, is much more stable than the ${\beta}$-amino sulfonic acids. Phthalyl tauryl-L-histidine methyl ester was prepared by condensing phthalyl tauryl chloride with histidine methyl ester in chloroform. The yields were quite low possibly due to reaction between the acid chloride and the imidazole of histidine. Approximately 50 per cent yield of crude amorphous product was obtained, but upon purification by crystallization they yielded only 25 percent of a pure product. The methyl ester was removed by acid hydrolysis to prevent partial cleavage of the phthalyl group. Crystalline tauryl histidine was then obtained from this acid by removal of the phthalyl group by hydrazinolysis. Tests for inhibition were carried out by comparing the action of camosine on isolated uterine muscle before and after tauryl histidine had been added to the bath surrounding the muscle strip. Only in very high relative concentrations of tauryl histidine was there any demonstrable inhibition.

• Bulletin of the Korean Chemical Society
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• v.31 no.7
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• pp.1887-1890
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• 2010

Cross-linked polystyrene supported aluminium triflate (Ps-Al(OTf)$_3$) was found to be an efficient and chemoselective heterogeneous Lewis acid catalyst for the direct conversion of arenes to sulfones using sulfonic acids as sulfonylating agents. The solid acid catalyst is stable (as a bench top catalyst) and can be easily recovered and reused without appreciable change in its efficiency.

• Journal of Sericultural and Entomological Science
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• v.31 no.1
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• pp.45-54
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• 1989

본 연구에서는 견에 대한 산성염료의 염착기구를 규명하기 위하여 전하수가 다른 산성염료에 의한 흡착실험을 수행하여, 견섬유와 피브로인막의 구조와 염료의 구조를 관련시켜서 산성염료의 흡착거동에 관한 해석을 하였다. 산성염료에 sulfonic acid group이 도입됨에 따라서 partition coefficient(Kp)는 감소하였지만 Langmuir type sorption constant(KL)는 증가하였고, 염욕의 pH와 온도의 증가에 따라서도 Kp, KL 값은 증가하였다. 전하수가 1, 2인 Dye I과 Dye II는 견섬유와 피브로인 막에 대하여 stoichiometric adsorption이 잘 적용될 수 있었으나 전하수가 3인 Dye III는 잘 적용되지 않았다. sulfonic acid group이 산성염료에 도입됨에 따라 각각의 sulfonic acid group의 표준친화력은 감소하였고, 모든 엔탈피 값은 음(-)으로 나타난 반면에 엔트로피 값은 양(+)으로 나타났다. 견섬유와 피브로인 막의 흡착 constant를 비교한 결과, 견 피브로인에 대한 산성염료의 흡착거동은 견 피브로인의 구조에 영향을 받는다는 것을 알 수 있다.

• Bulletin of the Korean Chemical Society
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• v.31 no.8
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• pp.2399-2401
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• 2010

• Journal of the Korean Chemical Society
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• v.13 no.1
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• pp.5-8
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• 1969

Acid dissociation constants and chelate stability constants of 8-hydroxyquinoline-5-sulfonic acid have been determined for divalent metal ions. Co (Ⅱ), Ni (Ⅱ) and Zn (Ⅱ) by means of the Calvin-Bjerrum technique at the various temperatures. The standard free energy changes for the reactions at $20^{\circ}$, $30^{\circ}$, $40^{\circ}$and $50^{\circ}C$ were calculated, and the corresponding values of ${\Delta}H^{\circ}$ and ${\Delta}S^{\circ}$ applying over this temperature range are reported. The results are interpreted on the basis of current theories of metal chelate formation in aqueous solution.

• Journal of the Korean Chemical Society
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• v.42 no.3
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• pp.292-296
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• 1998

The elution behavior of copper(Ⅱ) and iron(Ⅱ) ions by phenol sulfonic acid(PSA) as an eluent on chelating resin, Amberlite IRC-718 have been investigated. When copper(Ⅱ) and iron(Ⅱ) solutions were adsorbed on the resin and eluted with various concentration of PSA, two peaks of each ion were appeared in the elution curve. These two peak areas were changed according to the PSA concentration. Using these phenomena, the stability constants of complex formation between the two ions and PSA were calculated. The values are 7.0 for copper(II) and $4.5{\times}10^4$ for iron(II), respectively.