• Title/Summary/Keyword: sulfonate

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Effect of Adsorption of Surfactant to the Particles on Dispersion Stability of Particulate Soil in Anionic-nonionic Surfactant Mixed Solution (음-비이온계 혼합계면활성제 용액에 있어 입자에의 계면활성제 흡착량이 고형오구의 분산안정성에 미치는 영향)

  • 정선영;강인숙
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.436-437
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    • 2003
  • 고형오구의 분산안정화 작용은 고체 입자의 계면에 흡착한 계면활성제에 의한 전기적 반발력과 입체적 보호작용에 영향을 받게 된다. 특히 현재 시판세제의 조성에서 비이온계 계면활성제의 혼합이 점차 중요시되는 이때 입체적 보호작용에 의한 고형오구의 분산안정성은 의류제품의 세척성 제고에 좋은 정보가 되리라 생각된다. 따라서 본 연구는 시판되고 있는 세제 대부분이 음-비이온계 계면활성제의 혼합으로 되어 있는 점을 고려하여 음이온 계면활성제로서 D5S(sodium dodecyl benzene sulfonate), 비이온계 계면활성계 NPE(nonyl phenol polyoxyethylene ether, EO$_{10}$) 혼합용액에서 음이온과 비이온계 계면활성제의 입자에의 흡착과 고형오구의 안정성을 관련시켜 고찰하였다. (중략)

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Drug-Biomacromolecule Interaction VII

  • Kim, Chong-Kook;Yang, Ji-Sum;Lim, Yun-Su
    • Archives of Pharmacal Research
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    • v.7 no.1
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    • pp.11-15
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    • 1984
  • Binding of sic cephalosporins (cefotaxime, cefuroxime, cafazoline, cephalothin, cephaloridine, cephacetrile) to human serum albumin was studied. Fluorescence probe technique and difference spectrophotometry were employed to evaluate the nature and degree of association of cephalosporin-albumin complex. 1-anilinonaphthalene-8-surfonate was used as the fluorescence probe, and 2-(4'-hydroxybenzeneazo)benzoic acid as the UV spectrophotometric probe. Competitive bindings between cephalosporins and probe were observed. For the binding of cephalosporins to human serum albumin, three binding sites were identified by fluorescence probe technique but four binding constants of cephalosporins to human serum albumin measured by fluorescence probe technique are higher than those meausred by UV spectrophotometry.

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Preparation and characterization of nanosized hollow silica in the presence of aluminum isopropoxide

  • Nguyen, Ngoc Anh Thu;Kim, Hyun-Ik;Kim, Sang Hern
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.3
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    • pp.421-427
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    • 2016
  • Nanosized hollow silica was prepared by $St{\ddot{o}}ber$ method in the presence of aluminum isopropoxide. The mixture of polyelectrolytes such as poly(sodium 4-styrene sulfonate)(PSS) and polyacrylic acid(PAA) were used as templates. Tetraethylorthosilicate(TEOS) and aluminum isopropoxide were used as precursors for silica and alumina, respectively. The function of aluminum isopropoxide is to increase the porosity of silica shell. The characterizations of hollow silica were examined by TEM(transmission electron microscopy), TGA(thermogravimetric analysis), BET(Brunauer Emmett Teller), Energy-dispersive X-ray spectroscopy(EDS), and FT-IR spectrum. It was found that the shell thickness of hollow silica was around 8 nm and the core diameter was around 20 nm by TEM.

Design of AF Lens Actuator using IPMC-EMIM (IPMC-EMIM을 이용한 AF Lens Actuator 설계)

  • Kim, Sung-Joo;Kim, Chul-Jin;Yang, Hyun-Seok;Park, Young-Pil;Park, No-Cheol;Park, Gang-Ho;Lee, Hyung-Gun;Choi, Nak-Jin
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2007.11a
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    • pp.829-833
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    • 2007
  • IPMC-EMIM (Ionic Polyer Metal Composites + 1-ethyl-3- methyl imidazolium trifluromethane sulfonate, EMIM-Tfo) is fabricated by substituting ionic liquid for water in Nafion film, which improves water sensitiveness of IPMC and guarantees uniform performance regardless of the surrounding environment. In this paper, we will introduce the design and analysis of AF Lens Actuator using IPMC-EMIM. We will briefly introduce the procedure of fabrication of IPMC-EMIM first, and proceed on to define the necessary variables, analyze performance by changing the value of the variables, make a designed AF Lens Actuator, and measure the performance of one of them.

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Isolation and characterization of glutamate dehydrogenase defective mutant of brevibacterium flavum (Brevibacterium flavum의 glutamate dehydrogenase결핍돌연변이주의 분리 및 특성)

  • 최순영;성하진;민경희
    • Korean Journal of Microbiology
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    • v.26 no.2
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    • pp.93-100
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    • 1988
  • In order to understand the regulation of glutamate dehydrogenase(GDH) synthesis in Brevibacterium flavum, we have isolated a mutant lacking NADP-linked GDH activity by ethlmethane sulfonate treatment. The $gdh^-$ mutant was grown on the minimal plate with 1mM ammonium chloride and not that with 300mM ammonium chloride. The cell-free extracts from $gdh^-$ mutant and prototroph were also examined with glutamine synthetase(GS) and glutamate synthase (GOGAT) production by niteogen sources. The growth of $gdh^-$ mutant in presence of 20mM ammonium chloride means that GOGAT synthesis is sufficient to allow growth in this condition. GS production of $gdh^-$ mutant as well as parental strain was induced by 1mM urea and ammonium tartrate, but it was repressed by higher concentration of ammonia, and also induced by 20mM to 50mM glutamate as a substrate. It was special attention that GOGAT synthesis from $gdh^-$ strain was more repressed by higher concentration of ammonia than prototroph as described in E. coli system.

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A Study on Validation of Condition Monitering Method of Accelerated Thermal Aging CSPE (가속열화 된 CSPE 상태감시법의 유효성 연구)

  • Shin, Yong-Deok;Goo, Cheol-Soo;Kim, In-Yong;Lee, Jung-Hoon
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1447-1448
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    • 2011
  • The CSPE cables are used for three years in nuclear power plant. The accelerated thermal aging of chloro sulfonate polyethylene(CSPE) jacket of test cables were carried out for the period equal to 10, 20 and 30 years in air at 90 and $100^{\circ}C$, respectively. The electrical volume resistivity, density, XPS, FE-SEM, EDS and XRF of the accelerated thermal aging of CSPE were measured. The validation of condition monitering method of accelerated thermal aging CSPE was estimated by them. The best validation of condition monitoring method of accelerated aging CSPE is electrical volume resistivity because change thermal of the specimen showed distinction.

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A Study on Adsorption of Anionic Surfactants with Nonionic Resins (비이온성 수지를 이용한 음이온 계면활성제의 흡착에 관한 연구)

  • Seo, Yang-Gon;Ahn, Jou-Hyeon;Heo, Byeong-Young
    • Journal of Environmental Science International
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    • v.5 no.3
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    • pp.369-376
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    • 1996
  • The adsorption of the anionic surfactants, sodium lauryl sulfate (SLS) and sodium dodecylbenzene sulfonate (SDBS) anion surfactants form aqueous solutions with nonionic resins, Amberlite XAD-2, XAD-4 and XAD-7 at temperatures in 15~45$^{\circ}C$ range was studied. Several adsorption isotherm models were used to fit the experimental data, The best results were obtained with the Redlich-Peterson equation and the Freundlich model provided remarkably good fits. For a particular resin at a particular temperature, SDBS was more extensively adsorbed than SLS. The highest adsorption were obtained with XAD-4 resin and the specific surface area of the resins plays a major role in adsorption of the surfactants. Estimations of the isosteric heat of adsorption were indicative of an exothermic process, and their magnitudes manifested a physisorption process.

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Cloning and Nucleotide Sequence of the recA Gene from Shigella sonnei KNIH104S Isolated in Korea

  • Park, Yong-Chjun;Shin, Hee-Jung;Kim, Young-Chang
    • BMB Reports
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    • v.32 no.5
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    • pp.436-439
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    • 1999
  • Shigella sonnei is an important cause of human enteric infections. S. sonnei KNIH104S was previously reported to be isolated from Korean shigellosis patients. We cloned a 2.8-kb KpnI fragment containing the recA gene encoding a recombinase from the chromosomal DNA of S. sonnei KNIH104S. This recombinant plasmid was named pRAK28. E. coli HB101, a recA mutant, cannot grow on Luria-Bertani medium in the presence of the alkylating agent methylmethane sulfonate, however, E. coli HB101 harboring pRAK28 was found to grow on this medium. As far as we know, we are the first to sequence the recA gene from S. sonnei. This gene is composed of 1062 base pairs with an ATG initiation codon and a TAA termination codon. Nucleotide sequence comparison of the S. sonnei recA gene exhibited 99.7% and 99.5% identity with those of S. flexneri and E. coli, respectively.

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PEDOT:PSS and Graphene Oxide Composite Hydrogen Gas Sensor (전도성 고분자 PEDOT:PSS와 산화 그래핀 복합물 수소 가스 센서)

  • Maeng, Sunglyul
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.2
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    • pp.69-73
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    • 2018
  • The power law is very important in gas sensing for the determination of gas concentration. In this study, the resistance of a gas sensor based on poly (3, 4-ethylenedioxythiophene) polystyrene sulfonate+graphene oxide composite was found to exhibit a power law dependence on hydrogen concentration at $150^{\circ}C$. Experiments were carried out in the gas concentration range of 30~180 ppm at which the sensor showed a sensitivity of 6~9% with a response and recovery time of 30s.

Preparation of blood-compatible polyurethanes by surface modification (표면개질에 의한 혈액적합성 폴리우레탄의 제조)

  • Han, Dong-Keun;Jeong, Seo-Young;Kim, Young-Ha;Min, Byoung-Goo
    • Proceedings of the KOSOMBE Conference
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    • v.1990 no.11
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    • pp.61-63
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    • 1990
  • To develop better blood compatibility of commercial polyurethane(PU), PU surface was chemically modified wi th a hydrophobic perfluorocarhon or a hydrophilic polyethylene oxide(PEO) and/or sulfonated groups, respectively. The water contact angle of modified PUs varied from $110^{\circ}$ to $0^{\circ}$. All the modified PUs were more blood compatible than untreated PU. In particular, PEO-sulfonate grafted PUs showed a very enhanced antithrombogenicity due to the synergistic effect of PEO and $SO_3$ groups. Therefore more hydrophobic and hydrophilic PU surfaces are promising for improving the blood compatibility.

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