• Title/Summary/Keyword: sulfomethylated pulping

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A New Hanji Manufacturing from Morus Resources (뽕나무자원의 새로운 한지제조 특성)

  • Yi, Il-Roh;Choi, Tae-Ho;Cho, Nam-Seok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.3 s.116
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    • pp.38-46
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    • 2006
  • This study was carried out to investigate the sheet properties of Morus Hanji, made by different pulping methods, such as alkali, alkali-peroxide and sulfomethylated pulping, and different stocks composed to bast and whole stalk fibers. Two species of Morus, M. alba and M. lhou, were used. Pulp yield of the whole stalk parts, its brightness and opacity were higher than those of bast part. In particular sulfomethylated pulp has higher brightness of $62{\sim}63%$, than other pulps(average brightness $30{\sim}40%$). In mechanical properties, paper made of bast fiber has higher strength than those of the whole stalks. Hanji made from M. lhou, whole stalk, and sulfomethylated pulp gave better sheet formation and higher strength than those of the others. Hanji from M. alba bast fiber and whole stalk pulps were not so good sheet properties.

Studies on the Manufacturing of Pollution-Free Korean Traditional Paper without Bleaching (I) (표백(漂白)이 필요없는 무공해(無公害) 전통한지(傳統韓紙)의 제조(製造)에 관한 연구(硏究) (제(第) 1 보(報)))

  • Cho, Nam-Seok
    • Journal of the Korean Wood Science and Technology
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    • v.21 no.2
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    • pp.49-56
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    • 1993
  • This study was performed to investigate the pollution-free Korean traditional papermaking characteristics from paper mulberry by sulfomethylation pulping. Bast fibers were pulped by sulfomethylated cooking liquor, and by alkali and alkali-peroxide processes for the comparison. Sulfomethylated pulping resulted in the superior pulp with high yield and better quality compared to those of alkali and alkali-peroxide pulps. Since the pulp was so bright, there was almost no need additional bleaching. Pollutant loads of sulfomethylated pulping effluent were very low in terms of pH, turbidity and color compared to those of alkali. Pollution-free effluents was accomplished by simple filtering treatment with pine bark, charred rice hull and sawdust compost. Pine bark was the most effective in reduction rate of pollutants.

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Hanji Manufacturing from Bast Fibers of Kenaf, Hibiscus cannabinus (양마의 인피섬유를 이용한 한지제조)

  • Cho, Nam-Seok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.4
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    • pp.1-9
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    • 2008
  • The utilization of non-woody fibers with the fast growing annual plants has occurred in the paper industry to replace wood and preserve environment of the earth. The non-woody fibers generally used for papermaking are paper mulberry, gampi, manila hemp, rice straw, bamboo, and coton linter etc.. Recently Kenaf has been spot-lighted for the same application. Kenaf is an annual plant of Hibiscus species of Malvaceae family. Kenaf, a rapid growing and high harvesting non-woody fiber plant, was identified as one of the promising fiber sources for the production of paper pulp. This study was carried out to investigate the pulping characteristics of Kenaf bast fiber for Hanji (traditional Korean paper) manufacturing by different pulping methods, such as alkali, alkali-peroxide and sulfomethylated pulpings. It was possible to make superior grade of Hanji. Especially sulfomethylated pulping was resulted in superior pulp in terms of higher yields and qualities in comparison to those of the other pulping methods. Hanji from sulfomethylated pulp was shown the highest brightness of over 60% and higher sheet strength. In addition, the morphological features of pulp fibers (pulp compositions) affect to the sheet properties. Therefore the effect of fiber distribution index(FDI) which was calculated from the data of Confocal laser scanning microscopy(CLSM) on the sheet properties of Kenaf Hanji was also discussed.

Characteristics of Lotus (Nelumbo nucifera G.) Leafstalk Pulp for the Development of High Performance Paper (기능성 섬유원료 개발을 위한 연잎줄기 펄프의 특성)

  • Choi, Tae-Ho;Seo, Ji-Cheol;Lee, Ji-Nyeon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.2
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    • pp.67-74
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    • 2010
  • This study was carried out to investigate the pulping and papermaking characteristics of lotus (Nelumbo nucifera G.) leafstalk for the development of high performance paper. Anatomical and chemical properties of the lotus leafstalk were analyzed. The pulping and papermaking properties of the lotus leafstalk by conventional alkali and sulfomethylated pulping processes were also evaluated. The length and width of fibers were 0.06-3.32 mm (av. 1.23 mm) and 3.47-25.6 ${\mu}m$ (av. 20.7 ${\mu}m$), respectively. The length and width of vessel elements were 0.07-0.78 mm (av. 0.20 mm) and 14.1-330.0 ${\mu}m$ (av. 54.13 ${\mu}m$), respectively. The fiber length/fiber width ratio was 60.20. The extractives (cold water, hot water, 1% NaOH and ethanol-benzene) and lignin content of lotus leafstalk were higher than those of plant bast fiber. The contents of holocellulose, lignin, and ash were 73.8%, 24.3%, and 4.3%, respectively. The pulp yields based on pulping methods were sulfomethylated pulping av. 52%, and alkaline pulping av. 42%. The conventional alkaline pulping shows better pulp and sheet properties than the sulfomethylated pulping which was modified pulping processes. But the sulfomethylated pulping shows higher brightness than alkali pulping. In the consequence of FE-SEM observation, lotus leafstalk pulp consists of various kinds of thin walled fibers which have large amount of small pits.

Manufacturing of Korean Paper(Hanji) with Indian Mallow (Abutilon avicennae Gaertner) as the Alternative Fiber Resources(II) - Manufacturing of The Hajis Made from Bast Fiber and woody core fibers - (대용섬유자원으로써 어저귀를 이용한 한지제조(제2보) -인피 및 목질부 섬유를 이용한 한지 제조-)

  • Jeong, Seong-Hwa;Cho, Nam-seak;Choi, Tae-Ho
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.1
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    • pp.1-8
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    • 2004
  • This study was carried out to investigate the sheet properties of Indian mallow Hanji, made by different pulping methods, such as alkali and sulfomethylated pulpings, and different stock compositions, various mixing ratios of bast fiber and woody core fibers. Indian mallow hanjis made from the sulfomethylated pulps had higher brightness and sheet strength than the alkali pulps. It was found that the brightness of sulfomethylated pulp was enough high without an extra-bleaching. In the mechanical properties of Indian mallow hanjis mixed with bast fiber and woody core stalk pulps, the sheet strength were decreased as wood core pulps contents were increased. The sheet formation were increased as the increase of woody core pulps contents, while the sheet strength decreased. Although the sulfomethylated pulping resulted in higher pulp yield, no morphological differences of fiber surfaces were shown as compared to the different pulping methods.

The Effects of the Cutting Length of Paper Mulberry Bast Fiber on Pulping and Hanji Properties(I) - White bast of Korea grown paper mulberry - (닥나무 인피섬유의 절단장이 펄프화 및 한지의 물성에 미치는 영향(제1보) - 국산 닥 백피의 특성 -)

  • Lim, Gang-Hyouk;Choi, Tae-Ho
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.2
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    • pp.57-64
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    • 2008
  • In general, the entire of paper mulberry bark, which is not cut into pieces with an appropriate length, have been used in the pulping. This kind of pulping method couldn't accomplish the improvement of beating and sheet forming efficiency. For this reason, we investigated the effects of the cutting length of paper mulberry bast fiber on pulping and Hanji (Korean traditional paper) properties, in order to develop high quality Hanji manufacturing process. The cutting length variation of paper mulberry white bast did not great effects on pulp yields. The pulp yields based on pulping methods were sulfomethylated pulping av. 57.4%, alkali-hydrogen peroxide pulping av. 55.4%, and alkaline pulping av. 53.5% respectively. The optical properties such as brightness, opacity, scattering coefficient, and absorption coefficient were slightly improved by the increase of paper mulberry white bast cutting length. The increase of paper mulberry white bast cutting length resulted in poor sheet formation. Physical properties such as breaking length, TEA, tear index, burst index, and folding endurance were slightly improved by the increase of cutting length. The modified pulping processes, which used sulfomethylated method and alkali-hydrogen peroxide method, showed better pulp and sheet properties than conventional alkaline pulping.

Manufacturing of Korean Paper (Hanji) with Indian Mallow (Abutilon avicennae Gaertner) as the Alternative Fiber Resources (III) - Characteristics of Chinese Ink Spreading Distance by Korean Paper with Indian Mallow - (대용섬유자원으로써 어저귀를 이용한 한지제조(제3보) - 어저귀 한지의 발묵 특성 -)

  • Jeong, Seon-Hwa;Cho, Nam-Seok;Choi, Tae-Ho
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.4 s.132
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    • pp.60-65
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    • 2005
  • This study was carried out to investigate the sheet properties of Indian mallow Hanji, made by different pulping methods, such as alkali and sulfomethylated pulpings, and different stock compositions, various mixing ratios of bast fiber and wood core fibers. Indian mallow Hanjis made with 60% of woody core pulps were shown better Chinese ink spreading distance than those of the others. The Chinese ink spreading distance of the Indian mallow Hanjis made from bast fiber pulp only were unsuitable for Hwaseonji. The Chinese ink spreading distance of Indian mallow Hanji was closely related to the mixing ratio of long fiber and short fiber. Especially sulfomethylated pulping method was superior to alkali pulping method.

Characteristics of New Hanji (Korean Paper) Produced by Modified Pulping Process (개량펄프화법으로 제조한 새로운 한지의 특성)

  • Cho, Nam Seok
    • Journal of Conservation Science
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    • v.5 no.1 s.5
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    • pp.3-10
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    • 1996
  • In this study, bast fibers, woody parts and whole woods were pulped separately by alkali, alkali-hydrogen peroxide and sulfomethylated processes and their papermaking characteristics for the special Hanji were evaluated. Also properties of new Hanji products obtained from mixed stocks of various ratios were discussed. Solfomethylated pulps were shown higher brightness and sheet strengths than those from alkali and alkali-peroxide pulps. On the mechanical properties of Hanjis mixed with bast-and woody-parts pulps, and with bast and whole stem pulps, handsheet strengths were decreased with the increasing contents of woody and whole stem pulps. Various Hanjis could make by various mixing of separated cooked Pulps. Especially an excellant Hwaseonji(calligrapy Paper) could be made by one stage cooking of whole stem of paper mulberry by sulfomethylated pulping method.

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Manufacturing of Korean Paper(Hanji) with Indian Mallow (Abutilon avicennae Gaertner) as the Alternative Fiber Resources(I) - Productivity and Pulping Characteristics of Indian Mallow - (대용섬유자원으로써 어저귀를 이용한 한지제조(제1보) - 어저귀의 건물 생산량 및 펄프화 특성 -)

  • Jeong, Seon-Hwa;Cho, Nam-Seok;Choi, Tae-Ho
    • Journal of the Korean Wood Science and Technology
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    • v.30 no.2
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    • pp.144-150
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    • 2002
  • Indian mallow is characterized by the rapid growth and high harvest of the fibrous materials. This study was carried out to investigate the sheet properties of Hanji using Indian mallow, made by different pulping methods, such as alkali and sulfomethylated pulpings and different stock compositions, various mixing ratios of bast fiber, woody core and whole stalk fibers. The results from this study were summarized as follows. The length and width of the bast fibers were 1.40-430 mm(av. 235 mm), and 9.2-26.4 ㎛(av.18.3 ㎛), respectively. The cell wall thickness was 4.0-115 ㎛(av. 7.7 ㎛). Runkel ratio, flexibility coefficient and fiber length/fiber width ratio were 1.38, 0.42 and 128 respectively. Bast fiber and whole stalk were cooked by alkali and sulfomethylated methods. Sulfomethylated pulping resulted in superior pulp in terms of yield and quality as compared with those of alkali pulping. The pulp yields of bast fiber was higher than those of whole stalk

Sheet Formation Properties of Morus Hanji (뽕나무 한지의 지합특성)

  • Yi, Il-Roh;Cho, Nam-Seok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.3 s.116
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    • pp.47-60
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    • 2006
  • This study was carried out to investigate the sheet formation properties of Morus Hanjis, made of bast and whole stalk pulps by different pulping methods, such as alkali, alkali-peroxide and sulfomethylated pulping. Two species of Morus, M. alba and M. lhou, were used. Effect of morphological properties of pulp stocks on the sheet formation and its gray levels based on optical property were evaluated using an Image analyzer. In addition, the effect of fiber distribution index(FDI) which was calculated from tile data of Confocal laser scanning microscopy(CLSM) on the sheet formation and optical properties of Morus Hanji were also discussed. On the sheet formation, Hanji from whole stalk pulp was superior than that of bast pulp. The more the sheet formation improved, the more paper opacity decreased. In the aspect of Hanji's surface characteristics analyzed by an Image analyzer, the average gray level and its standard deviation of Hanji from the whole stalk pulp were rather lower than those of bast pulp because of better sheet formation of the former. However, high brightness Hanji showed high value of gray level. The sheet formation and paper opacity were increased with the decrease of standard deviation of gray level. From these results, gray level measurement could be used to predict the paper opacity as well as sheet formation. Sheet formation of whole stalk Hanji and its FDI measured by CLSM were higher than those of bast fibers. In conclusion, the sheet formation and opacity of Hanji could be evaluated by standard deviation value of Hanji's gray level using an Image analyzer and by fiber distribution index using CLSM.