• Title/Summary/Keyword: sulfate resistance test

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Oxygen Index of Fire-Retardant-Treated Plywood in Burning Test (산소지수법(酸素指數法)에 의한 내화처리합판(耐火處理合板)의 연소시험(燃燒試驗))

  • Lee, Phil Woo;Eom, Young Geun;Kim, Hyun Joong
    • Journal of Korean Society of Forest Science
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    • v.78 no.4
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    • pp.419-424
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    • 1989
  • To obtain relative effectiveness in fire resistance among fire retardant chemicals, oxygen indices were determined for 3.5 mm thick, three-ply, meranti plywoods, treated with 5 commercial chemicals and water and then press-dried, through Up and Down method following oxygen index test of ASTM D 2863-77. The oxygen indices obtained were 28.4 for ammonium sulfate, 26.9 for monoammonium phosphate, 43.4 for diammonium phosphate, 30.1 for borax-boric acid, 32.4 for minalith, and 25.5 for water. Therefore, diammonium phosphate was found to rank first in fire-retardant effectiveness, followed by minalith, borax-boric acid, ammonium sulfate, and monoammonium phosphate in turn, judging from the fact that highly flammable materials are likely to have a low oxygen index.

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EFFECT OF MAGNESIUM OXIDE CONTENTS ON THE PROPERTIES OF EXPERIMENTAL ALGINATES (산화마그네슘 함량이 실험적 알지네이트 인상재의 특성에 미치는 영향)

  • Bae Ill-Hwan;Woo Yi-Hyung;Choi Dae-Gyun
    • The Journal of Korean Academy of Prosthodontics
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    • v.41 no.5
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    • pp.551-564
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    • 2003
  • Statement of problem : Magnesium oxide may increase pH of alginate, and supply magnesium ions to the polymerization reaction of alginate. Purpose : This study was designed to evaluate the influence of incorporation of magnesium oxide to alginate composition. Material and Method : Seven kinds of experimental alginates were prepared and used for the experiments. Components with unchanging concentrations were sodium alginate 15%, calcium sulfate 14%, sodium phosphate 2%, and zinc fluoride 3%. Contents of magnesium oxide were varied as 0%, 1%, 2%, 3%, 4%, 5%, 6%. Diatomaceous earth were added to each experimental groups as balance to be 100%. Control group was a MgO 0% group. Working time, setting time, elastic recovery strain in compression, compressive strength and tear resistance were measured were measured. Sample size for each groups were 10. Arithmetic means were used as each groups representative values. Regression test between MgO contents and results, Duncan's multiple range test, and One-way ANOVA test were done between groups at level of 0.05. Results : 1 Magnesium oxide made the working time and setting time as longer(p<0.0001). 2 Magnesium oxide did not alter the elastic recovery(p>0.05). 3. Magnesium oxide contents between 2% and 4% exhibited the lowest strain in compression on alginates(p<0.0001). 4. Magnesium oxide made the compressive strength and the tear resistance stronger(p<0.0001). Conclusion : These results mean that setting time of alginate maybe controlled and that mechanical properties maybe improved by the incorporation of magnesium oxide into alginate, without any reduction of elasticity.

Durability of Concrete Using Ternary Blended Cement (삼성분계 시멘트를 사용한 콘크리트의 내구성)

  • 심은철;배수호;박광수;이준구;임병탁;하재담
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.78-81
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    • 2003
  • Recently, physical properties of concrete containing ternary blended cement were actively researching to develop durability, mobility, and atc. as well as strength increase of concrete. In this study, durability of concrete such as the resistance against chloride ion penetration, rebar corrosion, freeze and thaw, and sulfate were researched for concrete containing ordinary portland cement(OPC) and ternary blended cement(TBC), respectively. For this purpose, concrete specimens containing OPC and TBC, respectively, were made for 37.5% of W/C, and then various durability experiments described above were carried out. As a result, it was observed from the test that concrete containing TBC showed excellent durability than concrete containing OPC.

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A Comparison Study on Quality Regulation of China and Korea Cement (중국과 한국 시멘트의 품질규정에 대한 비교 연구)

  • Pei, Chang-Chun;Jin, Hu-Lin;Li, Bai-Shou;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.05a
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    • pp.159-162
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    • 2006
  • This study generally compared and investigated cement type and quality of China and Korea. Cement in Korea is divided into five such as ordinary, high early strength, moderate heat, low heat and sulfate resistance portland cement. However cement in China is divided into portland cement($P{\cdot}I,\;P{\cdot}II$) and ordinary portland cement($P{\cdot}O$) with admixture displacement ratio and it is again divided into 6 level and 7 level with 28 days compressive strength. In addition China classified cement into several standards, such as Mgo, SO3,, igloss, blame, setting time, stability, strength, alkali and sampling test. Therefore it should be careful to conclude so quickly without right understanding whether quality of China cement is bad or good. The better way to evaluate China cement is synthetically understanding a value engineering and consumer awareness.

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Quality Evaluation of Basalt Aggregates from JEJU Island (제주산 현무암의 콘크리트용 골재 사용을 위한 품질 특성 평가)

  • Jang, Myung-Houn;Choi, Hee-Bok
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.5
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    • pp.449-456
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    • 2013
  • This study was carried out to assess the suitability in terms of the standards of material quality of basalt aggregates from JEJU Island as a source for concrete aggregate. Quality assessments on the basalt aggregates were performed to assess the soundness of coarse aggregates using sodium sulfate solution, aggregate crushing test, and Los Angeles abrasion test. In addition, XRD, XRF, porosity, and compressive and tensile strength tests were performed to analyze the chemical components and the mechanical properties. In general, the mechanical properties of basalt aggregates from some areas did not meet the Korea Standards (KS), but the levels of compressive and tensile strength were higher than those of granite, andesite, and sandstone of other regions.

INTERGRANULAR CORROSION-RESISTANT STAINLESS STEEL BY GRAIN BOUNDARY ENGINEERING

  • Hiroyuki Kokawa;Masayuki Shimada;Wang, Zhan-Jie;Yutaka S. Sato
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.250-254
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    • 2002
  • Intergranular corrosion of austenitic stainless steels is a conventional and momentous problem during welding and high temperature use. One of the major reasons for such intergranular corrosion is so-called sensitization, i.e., chromium depletion due to chromium carbide precipitation at grain boundaries. Conventional methods for preventing sensitization of austenitic stainless steels include reduction of carbon content in the material, stabilization of carbon atoms as non-chromium carbides by the addition of titanium, niobium or zirconium, local solution-heat-treatment by laser beam, etc. These methods, however, are not without drawbacks. Recent grain boundary structure studies have demonstrated that grain boundary phenomena strongly depend on the crystallographic nature and atomic structure of the grain boundary, and that grain boundaries with coincidence site lattices are immune to intergranular corrosion. The concept of "grain boundary design and control", which involves a desirable grain boundary character distribution, has been developed as grain boundary engineering. The feasibility of grain boundary engineering has been demonstrated mainly by thermomechanical treatments. In the present study, a thermomechanical treatment was tried to improve the resistance to the sensitization by grain boundary engineering. A type 304 austenitic stainless steel was pre-strained and heat-treated, and then sensitized, varying the parameters (pre-strain, temperature, time, etc.) during the thermomechanical treatment. The grain boundary character distribution was examined by orientation imaging microscopy. The intergranular corrosion resistance was evaluated by electrochemical potentiokinetic reactivation and ferric sulfate-sulfuric acid tests. The sensitivity to intergranular corrosion was reduced by the thermomechanical treatment and indicated a minimum at a small roll-reduction. The frequency of coincidence-site-lattice boundaries indicated a maximum at a small strain. The ferric sulfate-sulfuric acid test showed much smaller corrosion rate in the thermomechanically-treated specimen than in the base material. An excellent intergranular corrosion resistance was obtained by a small strain annealing at a relatively low temperature for long time. The optimum parameters created a uniform distribution of a high frequency of coincidence site lattice boundaries in the specimen where corrosive random boundaries were isolated. The results suggest that the thermomechanical treatment can introduce low energy segments in the grain boundary network by annealing twins and can arrest the percolation of intergranular corrosion from the surface.

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Experimental Study to Evaluate the Durability of 100 MPa Class Ultra-high Strength Centrifugal Molding Concrete (100MPa급 초고강도 원심성형 콘크리트의 내구성 평가를 위한 실험연구)

  • Jeong-Hoi Kim;Sung-Jin Kim;Doo-Sung Lee
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.28 no.1
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    • pp.12-23
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    • 2024
  • In this study, a structural concrete square beam was developed using the centrifugal molding technique. In order to secure the bending stiffness of the cross section, the hollow rate of the cross section was set to 10% or less. Instead of using the current poor mixture of concrete and a concrete mixing ratio with a high slump (150-200) and a design strength of 100 MPa or more was developed and applied. In order to investigate the durability of centrifugally formed PSC square beams to be used as the superstructure of the avalanch tunnel or ramen bridge, the durability performance of ultra-high-strength centrifugally formed concrete with a compressive strength of 100 MPa was evaluated in terms of deterioration and chemical resistance properties.Concrete durability tests, including chloride penetration resistance, accelerated carbonation, sulfate erosion resistance, freeze-thaw resistance, and scaling resistance, were performed on centrifugally formed square beam test specimens produced in 2022 and 2023. Considering the information verified in this study, the durability of centrifugally molded concrete, which has increased watertightness in the later manufacturing stage, was found to be superior to that of general concrete.

Evaluation of Durability of Cement Matrix Replaced with Limestone Powder (석회석 미분말을 혼합한 시멘트 경화체의 내구성능 평가)

  • Woo-Sik Jang;Kwang-Pil Park
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.1
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    • pp.102-109
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    • 2024
  • In order to use limestone powder as a material for concrete, the mechanical and durability characteristics of cement matrices manufactured by varying the substitution rate were evaluated. In general, limestone powder did not contribute to the cement hydration reaction, so as a result of the compressive strength test of cement mortar using it, the compressive strength decreased as the substitution rate increased. However, as a result of evaluating the durability performance of cement mortar using limestone powder, such as chloride ion penetration resistance, carbonation resistance, and chemical attack resistance, small particles of limestone powder showed superior results compared to the unsubstituted control mortar due to the micro-filler effect of filling the fine pores inside the cement matrix. Therefore, limestone powder is expected to be used as an effective method for improving the durability of concrete. In this study, the durability was evaluated by changing the mixing amount of limestone powder to 0 %, 5 %, 10 %, and 15 %, but it is judged that it is necessary to study in more detail the effect on the durability by changing the end and mixing amount of limestone powder to various levels in the future.

Electromechanical Properties of Conductive MWCNT Film Deposited on Flexible Substrate Affected by Concentration of Dispersing Agent (분산제 농도에 따른 MWCNT 전도성 유연필름의 전기-기계적 특성)

  • HwangBo, Yun;Kang, Yong-Pil;Kim, Jae-Hyun;Kim, Duck-Jong;Lee, Hak-Joo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.5
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    • pp.517-521
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    • 2012
  • Carbon nanotubes (CNTs) have been regarded as a promising material for the fabrication of flexible conductors such as transparent electrodes, flexible heaters, and transparent speakers. In this study, a multiwalled carbon nanotube (MWCNT) film was deposited on a polyethylene terephthalate (PET) substrate using a spraying technique. MWCNTs were dispersed in water using sodium dodecyl sulfate (SDS). To evaluate the effect of the weight ratio between SDS and MWCNTs on the electromechanical properties of the film, direct tensile tests and optical strain measurement were conducted. It was found that the CNT film hardly affected the mechanical behavior of CNT/PET composite films, while the electrical behavior of the CNT film was strongly affected by the SDS concentration in the CNT film. The electrical resistance of CNT/PET films gradually increased with the strain applied to the PET substrate, even up to a large strain that ruptured the substrate.

A Study on the Manganese Oxidation and Characteristics of Aeromonas sp (Aeromonas sp. MN44의 특성과 망간 산화에 관한 연구)

  • Koo Jong Seo;Park Kyeong Ryang
    • Journal of Life Science
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    • v.15 no.1 s.68
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    • pp.94-99
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    • 2005
  • Sixty four bacterial colonies which were able to oxidize the manganese were isolated from soil samples in Mokcheon and Ochang area. Among them, one bacterial strain was selected for this study based on its higher manganese oxidation, and this selected bacterial strain was identified as Aeromonas sp. MN44 through physiological-biochemical test and analysis of its 16s rRNA sequence. Aeromonas sp. MN44 was able to utilize lactose but did not utilize various carbohydrates as a sole carbon source. Aeromonas sp. MN44 showed a very sensitive to antibiotics such as kanamycin, chloramphenicol, ampicillin, tetracycline and spectinomycin, and heavy metal such as cadmium. But this strain showed a high resistance up to mg/ml unit to heavy metals such as lithium and manganese. Optimal manganese oxidation condition of Aeromonas sp. MN44 was pH 7.4 and manganese oxidation activity was inhibited by proteinase K and boiling treatment. So, we concluded that this factor was protein. The manganese oxidizing factor produced by Aeromonas sp. MN44 was partial purified by ammonium sulfate precipitation, DEAE-Toyopearl 650M ion exchange chromatography and Sephadex gel filtration chromatography. Its molecular mass was about 113 kDa.