• Title/Summary/Keyword: sulfate resistance

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Sulfate Attack Resistance of Crushed Sand Cement Mortars Containing Mineral Admixture (광물질 혼화재료를 혼입한 부순모래 시멘트 모르터의 황산염 침해 저항성)

  • Kim, Myung-Sik;Jang, Hui-Suk;Beak, Dong-Il;Kim, Kang-Min
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.821-824
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    • 2006
  • As this study is to estimate long term resistance of cement mortars using crushed sand under chemical attacks. Besides tests have been carried out with cement mortars by river sand and crushed sand by fine sand, cement mortars mix various proportions of silica fume and fly ash(up to 15% and 50% by weight for cement) were prepared and immersed in pure water, sodium sulfate solution, magnesium sulfate solution, seawater for 28days, 90days, 180days, 365days. Test on the change in the weight and compressive strength of cement mortars according to the duration of immersion time and the content of silica fume and fly ash was performed.

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Deterioration of Cement Matrix with Alkali-free Accelerator Exposed to Sulfate Media (황산염환경에 노출된 알카리프리계 급결제 사용 시멘트경화체의 성능저하)

  • Lee, Seung-Tae;Hooton, R.D.;Kim, Seong-Soo;Kim, Dong-Gyou
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.277-280
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    • 2006
  • This paper presents the findings on the sulfate resistance of mortar specimens with or without alkali-free accelerator exposed to sodium sulfate solution for 270 days. Test results confirms a negative effect of alkali-free accelerator on the sulfate deterioration. Additionally, the influences of exposure concentration and temperature of sulfate solution on expansion were investigated. Especially, at a high concentration of solution a significant expansion of mortar specimens with alkali-free accelerator was observed. Further, low temperature also promoted the deterioration of the cement system due to sulfate attack.

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Microstructural Investigation on the Deterioration of Silica Fume Blended Cement Matrix Under Magnesium Sulfate Attack (황산마그네슘 침식을 받은 실리카 퓸 혼합 시멘트 경화체의 성능저하에 대한 미세구조적 관찰)

  • Lee, Seung-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.6
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    • pp.55-62
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    • 2008
  • This paper reports the effect of replacement levels of silica fume on the resistance to magnesium sulfate attack. Mortar specimens incorporating silica fume were exposed to 5% magnesium sulfate solution for 360 days at ambient temperature. The main variable was the replacement levels of silica fume(0, 5, 10 and 15% of cement by mass). The resistance of mortar specimens incorporating silica fume against magnesium sulfate attack was regularly monitored by measuring compressive strength and expansion. In addition, in order to investigate the reactants formed by magnesium sulfate attack, various instrumental analyses such as XRD, SEM and DSC were used. Results demonstrated that the formation of gypsum, thaumasite and brucite led to a significant deterioration due to magnesium sulfate attack in cement matrix incorporating silica fume.

Studies on Utilization of Chitosan for Fixation of Copper Compound in Wood Preservative Treatment (목재방부리(木材防腐理)에 있어서 구리화합물(化合物) 정착제(定着濟)로서 키토산 이용(利用)에 관한 연구(硏究))

  • Lee, Jong-Shin
    • Journal of the Korean Wood Science and Technology
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    • v.25 no.4
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    • pp.92-98
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    • 1997
  • To make good use of chitosan forming complex with heavy metals in wood preservative treatment, woods impregnated with chitosan and copper sulfate were prepared. Amounts of leached copper, decay resistance, anti-mold efficacy, iron corrosion rates, moisture regain rates and degradation pattern in chitosan pre-treated and untreated wood were compared. After leaching test, amounts of leached copper from chitosan pre-treated wood had a much smaller than chitosan untreated wood, and good decay resistance was retained even after leaching test. From these results, it was proved that chitosan-copper complex formed in wood played and important role for decay durability. In chitosan pre-treated wood, damage values by test molds became remarkably smaller, but the growth of test molds was not perfectly inhibited. Distinct differences in iron corrosion rates between chitosan pre-treated and untreated woods was not recognized but chitosan pre-treated wood showed the lower moisture regain rates than chitosan untreated wood because of water insoluble chitosan membrane formed in wood. After leaching test, the tracheid walls in the wood treated with 2.0% copper sulfate only were eroded by the fungal attacks, but those in the wood pre-treated with chitosan remained almost intact.

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Diffusion Characteristics for Chloride Ion of Concrete Subjected to Sulfate Attack (황산염 침투를 받은 콘크리트의 염소이온 확산특성)

  • Park, Jae-Im;Bae, Su-Ho;Yu, Jae-Won;Lee, Kwang-Myong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.213-214
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    • 2010
  • An objective of this experimental research is to investigate the diffusion characteristics for chloride ion of concrete subjected to sulfate attack. For this purpose, concretes with three types of cement such as ordinary portland cement(OPC), binary blended cement(BBC), and ternary blended cement(TBC) containing mineral admixtures were made for water-binder ratios of 32% and 43%. The concrete specimens were immersed in sulfate solution for 365 days, and then the resistance against chloride ion penetration of them were estimated by using NT BUILD 492. It was observed from the test results that the resistance to chloride ion penetration of concrete subjected to sulfate attack was greatly decreased than that of standard curing concrete under the same age.

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Resistance of Culex pipiens Mosquito Larvae to Insecticide in Seoul city (서울시내 빨간집모기(Culex pipiens) 유충의 살충제에 대한 저항성에 대하여)

  • 주인호;백영한;류연희
    • The Korean Journal of Zoology
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    • v.3 no.1
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    • pp.9-12
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    • 1960
  • The present status of insecticide resistance of Korean mosquitoes is still unknown. The experiment cited below is a part of our series of resistance tests on Korean mosquitoes. The test was carried out during the summer of 1959 to ascertain the degree of resistance of Culex pipiens to insecticides currently used. Culex pipiens eggs were collected from ditches in Seoul City and reared in laboratory with media consisted of the following : Distrilled water 1.0 liter, Magnesium sulfate (MgSO$_4$.7$H_2O$) 1.0gram , Calcium sulfate (CasO$_4$.2$H_2O$) 0.5gram ; Sodium cholride 0.5 gram. A Sufficient amount of beer yeast was also used as a larvar food. Late third and early fourth instar larvae were selected for testing. The results are summarized in the following. THe LC-50 of Culex pipiens to insecticides were 0.061 ppm in p, p-DDT , 0.045 ppm in ${\gamma}$-BHC and0.029 ppm in malathion. Comparing these with LC-50 doses of Orlando laboratory strain, it can be pointed out that the present resistance of Seoul strain shows about a ten-fold increase in DDt, and a fourfold increase in ${\gamma}$-BHC . The resistance development of the Seoul strain has, however, not arisen so markedly as compared with data observed in other parts of Far Eastern areas received heavy insecticidal operations.

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The Durability Evaluation of Concrete using CFBC-ash Binder (발전소 부산물 활용 결합재를 이용한 콘크리트의 내구성 평가)

  • Lim, Gwi-Hwan;Kang, Yong-Hak
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.259-260
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    • 2018
  • This study evaluated the compressive strength, freeze-thaw and sulfate resistance characteristics of concrete using CFBC-Ash. The CFBC-Ash was adjusted to a particle size of 75 ㎛ or less and using by increasing the fineness of powder through milling. As a result, it was confirmed that the concrete using CFBC-Ash shows a high compressive strength, durability. Also, it is confirmed that CFBC-ash can be used as a concrete binder.

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Chemical Resistance Characteristics of Concrete Surface Coating Agent with Flexibility (유연성을 갖는 콘크리트 표면보호재의 내화학적 특성)

  • Han, Sang-Hoon;Yoon, Ju-Yong;Lee, Byung-Ro;Hong, Ki-Nam
    • Journal of the Korean Society of Safety
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    • v.27 no.3
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    • pp.96-103
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    • 2012
  • The purpose of this study is evaluate the ability of coating materials developed in order to prevent the durability deterioration of the concrete structure. Neutralization test, freezing and thawing test, and sulfate resistance test were performed in this study. Test results show that the developed coating material is effective against durability deterioration.

A study on the development of self-healing concrete and repair materials with the resistance to sulfuric acid attack (내황산성 자기치유 콘크리트 및 단면복구재 개발에 관한 연구)

  • Bang, Sin-Young;Kim, Jeong-Mi;Ahn, Tae-Ho
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.84-85
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    • 2015
  • The aim of this study is to develop crack self-healing concrete and repair materials with the sulfate resistance using geo-materials and by-products for practical industrial application. Research has been done on the healing of cracks in aged concrete, but it seems that very little is known about the actual healing mechanism and its conditions. In this research, the essential properties of geo-materials with pozzolanic reaction for self-healing were analyzed and discussed.

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Long-Term Durability Estimation of Cementless Concrete Based on Alkali Activated Slag (알칼리 활성 슬래그 기반 무시멘트 콘크리트의 장기 내구성 평가)

  • Lee, Hyun-Jin;Lee, Seok-Jin;Bae, Su-Ho;Kwon, Soon-Oh;Lee, Kwang-Myong;Jung, Sang-Hwa
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.2
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    • pp.149-156
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    • 2016
  • It has been well known that concrete structures exposed to chloride and sulfate attack environments lead to significant deterioration in their durability due to chloride ion and sulfate ion attack. The purpose of this experimental research is to evaluate the long-term durability against chloride ion and sulfate attack of the alkali activated cementless concrete replacing the cement with ground granulated blast furnace slag. For this purpose, the cementless concrete specimens were made for water-binder ratios of 40%, 45%, and 50%, respectively and then this specimens were cured in the water of $20{\pm}3^{\circ}C$ and immersed in fresh water, 10% sodium sulfate solution for 28, 91, 182, and 365 days, respectively. To evaluate the long-term durability to chloride ion and sulfate attack for the cementless concrete specimens, the diffusion coefficient for chloride ion and compressive strength ratio, mass change ratio, and length change ratio were measured according to the NT BUILD 492 and JSTM C 7401, respectively. It was observed from the test results that the resistance against chloride ion and sulfate attack of the cemetntless concrete were comparatively largely increased than those of OPC concrete irrespective of water-binder ratio.