• 제목/요약/키워드: sulfate resistance

검색결과 239건 처리시간 0.026초

광물질 혼화재료를 혼입한 부순모래 시멘트 모르터의 황산염 침해 저항성 (Sulfate Attack Resistance of Crushed Sand Cement Mortars Containing Mineral Admixture)

  • 김명식;장희석;백동일;김강민
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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    • pp.821-824
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    • 2006
  • As this study is to estimate long term resistance of cement mortars using crushed sand under chemical attacks. Besides tests have been carried out with cement mortars by river sand and crushed sand by fine sand, cement mortars mix various proportions of silica fume and fly ash(up to 15% and 50% by weight for cement) were prepared and immersed in pure water, sodium sulfate solution, magnesium sulfate solution, seawater for 28days, 90days, 180days, 365days. Test on the change in the weight and compressive strength of cement mortars according to the duration of immersion time and the content of silica fume and fly ash was performed.

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황산염환경에 노출된 알카리프리계 급결제 사용 시멘트경화체의 성능저하 (Deterioration of Cement Matrix with Alkali-free Accelerator Exposed to Sulfate Media)

  • 이승태;;김성수;김동규
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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    • pp.277-280
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    • 2006
  • This paper presents the findings on the sulfate resistance of mortar specimens with or without alkali-free accelerator exposed to sodium sulfate solution for 270 days. Test results confirms a negative effect of alkali-free accelerator on the sulfate deterioration. Additionally, the influences of exposure concentration and temperature of sulfate solution on expansion were investigated. Especially, at a high concentration of solution a significant expansion of mortar specimens with alkali-free accelerator was observed. Further, low temperature also promoted the deterioration of the cement system due to sulfate attack.

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황산마그네슘 침식을 받은 실리카 퓸 혼합 시멘트 경화체의 성능저하에 대한 미세구조적 관찰 (Microstructural Investigation on the Deterioration of Silica Fume Blended Cement Matrix Under Magnesium Sulfate Attack)

  • 이승태
    • 한국구조물진단유지관리공학회 논문집
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    • 제12권6호
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    • pp.55-62
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    • 2008
  • 본 연구는 실리카 퓸의 대체율을 4단계(시멘트 중량의 0, 5, 10 및 15%)로 달리하여 제조한 시멘트 모르타르의 황산마그네슘 침식 저항성을 평가하며, 침식에 의한 성능저하 원인을 조사하기 위하여 수행되었다. 실리카 퓸 혼합 모르타르를 5% 황산마그네슘 용액에 360일 동안 침지한 후, 재령별 압축강도 및 팽창을 측정하였으며, XRD, SEM 및 DSC와 같은 여러 기기분석법을 활용하여 침식에 의한 시멘트 경화체의 성능저하 원인을 고찰하였다. 실험 결과에 의하면, 실리카 퓸을 혼합한 시멘트 경화체의 황산마그네슘 침식은 주로 gypsum, thaumasite 및 brucite 등의 반응생성물과 깊은 관련이 있는 것으로 나타났다.

목재방부리(木材防腐理)에 있어서 구리화합물(化合物) 정착제(定着濟)로서 키토산 이용(利用)에 관한 연구(硏究) (Studies on Utilization of Chitosan for Fixation of Copper Compound in Wood Preservative Treatment)

  • 이종신
    • Journal of the Korean Wood Science and Technology
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    • 제25권4호
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    • pp.92-98
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    • 1997
  • To make good use of chitosan forming complex with heavy metals in wood preservative treatment, woods impregnated with chitosan and copper sulfate were prepared. Amounts of leached copper, decay resistance, anti-mold efficacy, iron corrosion rates, moisture regain rates and degradation pattern in chitosan pre-treated and untreated wood were compared. After leaching test, amounts of leached copper from chitosan pre-treated wood had a much smaller than chitosan untreated wood, and good decay resistance was retained even after leaching test. From these results, it was proved that chitosan-copper complex formed in wood played and important role for decay durability. In chitosan pre-treated wood, damage values by test molds became remarkably smaller, but the growth of test molds was not perfectly inhibited. Distinct differences in iron corrosion rates between chitosan pre-treated and untreated woods was not recognized but chitosan pre-treated wood showed the lower moisture regain rates than chitosan untreated wood because of water insoluble chitosan membrane formed in wood. After leaching test, the tracheid walls in the wood treated with 2.0% copper sulfate only were eroded by the fungal attacks, but those in the wood pre-treated with chitosan remained almost intact.

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황산염 침투를 받은 콘크리트의 염소이온 확산특성 (Diffusion Characteristics for Chloride Ion of Concrete Subjected to Sulfate Attack)

  • 박재임;배수호;유재원;이광명
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
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    • pp.213-214
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    • 2010
  • 본 연구의 목적은 황산염 침투를 받은 콘크리트의 염소이온 확산특성을 평가하는 것이다. 이를 위하여, OPC, 2성분계 및 3성분계 시멘트를 혼입한 3가지 형태의 콘크리트를 물-결합재비 32% 및 43%에 대해서 제작하였다. 제작한 콘크리트 시험체를 365일 동안 황산염 용액에 침지시킨 후 NT BUILD 492에 의해 염소이온 침투 저항성 시험을 수행하였다. 그 결과, 황산염 침투를 받은 콘크리트는 동일 재령의 표준양생 콘크리트보다 염소이온 침투 저항성이 크게 저하되는 것으로 나타났다.

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서울시내 빨간집모기(Culex pipiens) 유충의 살충제에 대한 저항성에 대하여 (Resistance of Culex pipiens Mosquito Larvae to Insecticide in Seoul city)

  • 주인호;백영한;류연희
    • 한국동물학회지
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    • 제3권1호
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    • pp.9-12
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    • 1960
  • The present status of insecticide resistance of Korean mosquitoes is still unknown. The experiment cited below is a part of our series of resistance tests on Korean mosquitoes. The test was carried out during the summer of 1959 to ascertain the degree of resistance of Culex pipiens to insecticides currently used. Culex pipiens eggs were collected from ditches in Seoul City and reared in laboratory with media consisted of the following : Distrilled water 1.0 liter, Magnesium sulfate (MgSO$_4$.7$H_2O$) 1.0gram , Calcium sulfate (CasO$_4$.2$H_2O$) 0.5gram ; Sodium cholride 0.5 gram. A Sufficient amount of beer yeast was also used as a larvar food. Late third and early fourth instar larvae were selected for testing. The results are summarized in the following. THe LC-50 of Culex pipiens to insecticides were 0.061 ppm in p, p-DDT , 0.045 ppm in ${\gamma}$-BHC and0.029 ppm in malathion. Comparing these with LC-50 doses of Orlando laboratory strain, it can be pointed out that the present resistance of Seoul strain shows about a ten-fold increase in DDt, and a fourfold increase in ${\gamma}$-BHC . The resistance development of the Seoul strain has, however, not arisen so markedly as compared with data observed in other parts of Far Eastern areas received heavy insecticidal operations.

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발전소 부산물 활용 결합재를 이용한 콘크리트의 내구성 평가 (The Durability Evaluation of Concrete using CFBC-ash Binder)

  • 임귀환;강용학
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2018년도 춘계 학술논문 발표대회
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    • pp.259-260
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    • 2018
  • This study evaluated the compressive strength, freeze-thaw and sulfate resistance characteristics of concrete using CFBC-Ash. The CFBC-Ash was adjusted to a particle size of 75 ㎛ or less and using by increasing the fineness of powder through milling. As a result, it was confirmed that the concrete using CFBC-Ash shows a high compressive strength, durability. Also, it is confirmed that CFBC-ash can be used as a concrete binder.

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유연성을 갖는 콘크리트 표면보호재의 내화학적 특성 (Chemical Resistance Characteristics of Concrete Surface Coating Agent with Flexibility)

  • 한상훈;윤주용;이병로;홍기남
    • 한국안전학회지
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    • 제27권3호
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    • pp.96-103
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    • 2012
  • The purpose of this study is evaluate the ability of coating materials developed in order to prevent the durability deterioration of the concrete structure. Neutralization test, freezing and thawing test, and sulfate resistance test were performed in this study. Test results show that the developed coating material is effective against durability deterioration.

내황산성 자기치유 콘크리트 및 단면복구재 개발에 관한 연구 (A study on the development of self-healing concrete and repair materials with the resistance to sulfuric acid attack)

  • 방신영;김정미;안태호
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2015년도 춘계 학술논문 발표대회
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    • pp.84-85
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    • 2015
  • The aim of this study is to develop crack self-healing concrete and repair materials with the sulfate resistance using geo-materials and by-products for practical industrial application. Research has been done on the healing of cracks in aged concrete, but it seems that very little is known about the actual healing mechanism and its conditions. In this research, the essential properties of geo-materials with pozzolanic reaction for self-healing were analyzed and discussed.

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알칼리 활성 슬래그 기반 무시멘트 콘크리트의 장기 내구성 평가 (Long-Term Durability Estimation of Cementless Concrete Based on Alkali Activated Slag)

  • 이현진;이석진;배수호;권순오;이광명;정상화
    • 한국건설순환자원학회논문집
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    • 제4권2호
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    • pp.149-156
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    • 2016
  • 이 연구의 목적은 알칼리 활성 슬래그 기반 무시멘트 콘크리트의 염소이온 침투 및 황산염 침투 저항성과 같은 장기 내구성을 평가하는 것이다. 이를 위하여 물-결합재비에 따라 원주형 및 각주형의 무시멘트 콘크리트를 제작한 후, 이들에 대해서 재령 28일부터 365일까지 NT BUILD 492 및 JSTM C 7401 각각에 따라 장기 염소이온 침투 및 황산염 침투 저항성을 평가하였다. 그 결과, 무시멘트 콘크리트의 장기 염소이온 침투 및 황산염 침투 저항성은 물-결합재비에 관계 없이 OPC 콘크리트보다 크게 개선되는 것으로 나타나, 무시멘트 콘크리트의 장기 내구성은 매우 우수한 것으로 입증되었다.