• Title/Summary/Keyword: sulfate ions diffusivity

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Estimation on the Sulfate Ion Diffusivity in Concrete by Accelerated Test (촉진시험에 의한 콘크리트중의 황산이온 확산계수 추정)

  • 문한영;김성수;김홍삼;이승태;최두선
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.425-428
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    • 2000
  • When concrete structures are exposed to sulfate or marin environments, sulfate ions penetrated into concrete make it deteriorate. An accelerated test under potential difference method was performed to evaluate not only the sulfate ion diffusivity in ordinary portland cement and ground granulated blast-furnace slag cement concretes but the effect of slag replacement and water-cement ratio on the sulfate ions diffusivity. As the result of this study, we assumed the sulfate ion diffusivity was significantly related with total passed charge and initial current in concrete. Moreover sulfate ions penetration resistance of ordinary portland cement concrete was superior to that of ground granulated blast-furnace slag cement concrete.

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Sulfate Resistance of Concrete using Ground Granulated Blast-furnace Slag for Recycling

  • Moon, Han-Young;Lee, Seung-Tae;Kim, Hong-Sam
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.508-513
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    • 2001
  • Recently, ground granulated blast-furnace slag (GGBFS) has been increasingly used as additive for concrete. Many researchers reported that concrete using GGBFS had a better resistance under severe environments, such as marine or sulfate-rich soils, than Portland type cement concrete. The aim, therefore, of this study is to evaluate on the effectiveness of concrete using GGBFS when the concrete exposes to sulfate-rich environment. The detailed items for experiments show 2 series consisted of sulfate immersion test with mortar and sulfate diffusion test with concrete. The sulfate immersion test was performed for 400 days and contained reduction of compressive strength, length change and XRD analysis. For sulfate diffusion test, sulfate ions diffusivity was calculated on tile consideration of electrochemical theory by the diffusion cell test. As the results of this study, it was found that the concrete using GGBFS as additive was superior to portland type cement concrete. Consequently, the use of concrete with GGBFS for recycling may expect the durable and economical benefits.

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Evaluation of Strength and Chloride Diffusion in Concrete with FA Considering Temperature Effect (FA를 혼입한 콘크리트의 온도 영향을 고려한 강도 및 염화물 확산성 평가)

  • Keun-Hyeok Yang;Seung-Jun Kwon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.62-69
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    • 2023
  • For the nuclear power concrete plant structures in the UAE, it is necessary to consider the deterioration from high sulfate ions in the atmosphere and high chloride ions from the coast. In this study, two strength grade concrete mixture (40 MPa and 27 MPa) and two curing/diffusion temperatures (20 ℃ and 50 ℃) were considered for evaluating the temperature effects on diffusion and strength due to high average temperature above 38 ℃ a year in UAE. When the initial curing temperature was high, the compressive strength increased in high-temperature curing to 7 days, but the strength slightly increased in the 20 ℃ curing condition at 28 days. Regarding diffusion test, unlike the compressive test results, reduced chloride diffusion coefficients were evaluated both in 40 MPa and 27 MPa grade at 28 days. In the case of 91 days of curing, an increase in diffusivity due to high temperature and a decrease in diffusivity due to age effect occur simultaneously. Compared to the results of the curing and diffusion tests at 20 ℃ and 28 days, when the curing and diffusion tests were conducted at 50 ℃ in 91 days, the diffusion coefficients decreased to 76.2 % in 40 MPa grade and 85.4 % in 37 MPa grade with increasing curing period, respectively.

Impact of aggressive exposure conditions on sustainable durability, strength development and chloride diffusivity of high performance concrete

  • Al-Bahar, Suad;Husain, A.
    • Structural Monitoring and Maintenance
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    • v.2 no.1
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    • pp.35-48
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    • 2015
  • The main objective of this study is to evaluate the long-term performance of various concrete composites in natural marine environment prevailing in the Gulf region. Durability assessment studies of such nature are usually carried out under aggressive environments that constitute seawater, chloride and sulfate laden soils and wind, and groundwater conditions. These studies are very vital for sustainable development of marine and off shore reinforced concrete structures of industrial design such as petroleum installations. First round of testing and evaluation, which is presented in this paper, were performed by standard tests under laboratory conditions. Laboratory results presented in this paper will be corroborated with test outcome of ongoing three years field exposure conditions. The field study will include different parameters of investigation for high performance concrete including corrosion inhibitors, type of reinforcement, natural and industrial pozzolanic additives, water to cement ratio, water type, cover thickness, curing conditions, and concrete coatings. Like the laboratory specimens, samples in the field will be monitored for corrosion induced deterioration signs and for any signs of failureover initial period ofthree years. In this paper, laboratory results pertaining to microsilica (SF), ground granulated blast furnace slag (GGBS), epoxy coated rebars and calcium nitrite corrosion inhibitor are very conclusive. Results affirmed that the supplementary cementing materials such as GGBS and SF significantly impacted and enhanced concrete resistivity to chloride ions penetration and hence decrease the corrosion activities on steel bars protected by such concretes. As for epoxy coated rebars applications under high chloride laden conditions, results showed great concern to integrity of the epoxy coating layer on the bar and its stability. On the other hand corrosion inhibiting admixtures such as calcium nitrite proved to be more effective when used in combination with the pozzolanic additives such as GGBS and microsilica.