• Title/Summary/Keyword: sulfate environment

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Characteristics of Aerobic Granular Activated Sludge According to Electron Acceptors in Sequencing Batch Reactor Process (SBR공정에서 전자수용체에 따른 호기성 입상활성슬러지의 공정별 특성)

  • Kim, I-Tae;Lee, Hee-Ja;Bae, Woo-Keun
    • Journal of Korean Society on Water Environment
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    • v.20 no.5
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    • pp.480-487
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    • 2004
  • This study was conducted to find the effect of electron acceptors on the formation of granular sludge by using four different types of electron acceptors. The phosphorous uptake, denitrification, and sulfate reduction in anoxic modes were simultaneously occured because of the presence of the polyphosphate accumultating organism(PAO) that utilize nitrate and sulfate as an electron acceptor in the anoxic zone. Denitrirying phosphorous removal bacteria(DPB) was enriched under anaerobic/anoxic/aerobic condition with a nitrate as an electron acceptor, and desulfating phosphorous removal bacteria(DSPB) was enriched under anaerobic/anoxic/aerobic condition with a sulfate as an electron acceptor. Polyphosphate accumulating organism(PAO) were enriched in the anaerobic/aerobic SBR. PAO took up acetate faster than DPB and DSPB during the aerobic phase. The sludge with nitrate and sulfate as an electron acceptors grew as a granules which possessed high activity and good settleability. In the anaerobic/aerobic modes, typical floccular growth was observed. In the result of bench-scale experiment, simultaneous reactions of phosphorus uptake, denitrification and sulfate reduction were observed under anoxic condition with nitrate and sulfate as an electron acceptors. These results demonstrated that the anaerobic/anoxic modes with nitrate and sulfate as an electron acceptors played an important role in the formation of the sludge granulation.

Numerical Studies of Cloud Acidification Processes Using a One Dimensional Cumulus Cloud Model (일차원 적운모델을 이용한 산성강우 형성에 관한 수치적 연구)

  • 곽노혁;안상욱;홍민선
    • Journal of Korean Society for Atmospheric Environment
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    • v.7 no.3
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    • pp.145-149
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    • 1991
  • A one dimensiional cumulus cloud model has been developed for the investigation of temporal and altitudinal variation of trace gases and the wet deposition rates of sulfate for different simulation conditions. The results show that the dynamic field, liquid mixing ratios and the solubility of trace gases affect the distribution of trace gases and the droplet pH. Temporal variation of the predicted surface precipitation and sulfate deposition rates agree well with the field data.

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Solubilization isotherms of MTBE in various surfactant solutions for application of micellar-enhanced ultrafiltration (MEUF)

  • 양지원;백기태
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.103-106
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    • 2002
  • Solubilization isotherms for methyl tort-butyl ether (MTBE) in sodium dodecyl sulfate(SDS), dowfax 8390, sodium dodecylbenzenesulfonate and cetylpyridinium chloride (CPC) were investigated for application to micellar enhanced remediation. Dowfax 8390 showed maximum extent of solubilization among surfactants tested in this study. It seems that sulfate group in anionic surfactants playes a important role in solublization of MTBE. Chemical shiftes in NMR of surfactant and MTBE supports this point.

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갱내 황산염환원시설(IASRS)을 이용한 산성광산배수 처리에 관한 연구

  • 지상우;이상훈;유상희;김재욱;김선준
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.184-187
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    • 2003
  • To solve the problems of operating passive mine drainage treatment systems, the In Adit Sulfate Reducing System(IASRS) was suggested. By placing the SAPS inside the adit, the condition of constant temperature of 10~15$^{\circ}C$ can be maintained. The experiments using the models made up by four sections showd good efficiencies in pH control and metal removal rate, but showed still low sulfate removal rate of about 30% with high COB in the begining of the operation.

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Major Factors Affecting PM2.5 Water Content in Seoul and Gosan (서울과 고산의 미세입자 수분함량에 영향을 미치는 주요 인자)

  • Choi E. K;Kim Y.P
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.6
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    • pp.803-810
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    • 2004
  • Water contents in fine particles at Seoul and Gosan are estimated by using a gas/particle equilibrium model, SCAPE (Simulating Composition of Atmospheric Particles at Equilibrium). Also, sensitivity of particulate inorganic ionic concentrations on the total ionic species is estimated. Water content at Gosan is more sensitive to ambient relative humidity (RH) than Seoul. At both sites water content is most sensitive to sulfate concentration among sulfate, nitrate, and ammonium. Solid salts levels and compositions are also studied.

Effect of $Cd^{2+}$ and $Cu^{2+}$ on the Growth of a Methanogen and a Sulfate-Reducing Bacterium isolated from sea-based landfill (해안폐기물매립지로부터 분리한 메탄생성균과 환산염 환원균의 $Cd^{2+}$$Cu^{2+}$에 대한 감수성 검토)

  • Chang, Young-Cheol;Jeong, Kweon;Jeon, Eun-Mi;Bae, Il-Sang;Kim, Kwang-Jin
    • Journal of Environmental Health Sciences
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    • v.26 no.4
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    • pp.65-74
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    • 2000
  • The sensitivity of a mehtanogen and sulfate-reducing bacterium isolated from a sea-based landfill site Cd$^{2+}$ and CU$^{2+}$ was studied. Methanogens and sulfate-reducing bacteria in leachates of the waste disposal site were enumerated using the MPN method. Methanobacterium thermoautotrophicum KHT, isolated from the leachate, could not grow at 0.5 mM Cd$^{2+}$ or 1.0 mM CU$^{2+}$. Desulfotomaculum sp. RHT, isolated from the same leachate, was able to insolubilization 3.0 mM Cd$^{2+}$ or 2.0 mM CU$^{2+}$ by production of hydrogen sulfide. When strains KHT and RHT were cultured together in the presence of the heavy metals, strain KHT could grow at high heavy metal concentrations after insolubilization of the metals by strain RHT. strain RHT.

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Size Distribution Characteristics of Water-soluble Ionic Components in Airborne Particulate Matter in Busan (부산 도심지역 대기중 입자상물질의 크기분포에 따른 수용성 이온성분의 특성)

  • Park, Gee-hyeong;Lee, Byeong-kyu
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.3
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    • pp.287-301
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    • 2015
  • This study was conducted to investigate size distribution characteristics of water-soluble ionic components in the airborne particulate matter (PM) collected from an urban area in Busan using a MOUDI cascade impactor from March to October 2010. The inorganic constituents in the fine particles (${\leq}1.8{\mu}m$) predominantly consisted of sulfate, nitrate, ammonium, and potassium. Sulfate and ammonium concentrations showed a high correlation and similar equivalent concentrations in the fine modes including $0.18{\sim}0.32{\mu}m$, $0.32{\sim}0.56{\mu}m$, and $0.56{\sim}1.0{\mu}m$. This indicates that the main chemical component in the fine particles would be forms of ammonium sulfate such as $(NH_4)_3H(SO_4)_2$, $(NH_4)_2SO_4$, and $(NH_4)HSO_4$. Back trajectory analysis showed that relatively higher concentrations of ammonium, nitrate, and sulfate in the fine mode, compared to the coarse mode, are caused both by domestic sources and long-range transports originated from China continent. High concentration episodes of PM both in the fine mode and the coarse mode were attributed both by anthropogenic sources, such as ship emissions and traffic emissions, and by natural sources such as seawater (sea salt), respectively.

High Time-resolution Characterization of PM2.5 Sulfate Measured in a Japanese Urban Site

  • Ma, Chang-Jin;Kang, Gong-Unn;Kim, Ki-Hyun
    • Asian Journal of Atmospheric Environment
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    • v.9 no.4
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    • pp.280-287
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    • 2015
  • The high time-resolution monitoring data are essential to estimate rapid changes in chemical compositions, concentrations, formation mechanisms, and likely sources of atmospheric particulate matter (PM). In this study, $PM_{2.5}$ sulfate, $PM_{2.5}$, $PM_{10}$, and the number concentration of size-resolved PMs were monitored in Fukuoka, Japan by good time-resolved methods during the springtime. The highest monthly average $PM_{2.5}$ sulfate was found in May ($8.85{\mu}g\;m^{-3}$), followed by April ($8.36{\mu}g\;m^{-3}$), March ($8.13{\mu}g\;m^{-3}$), and June ($7.22{\mu}g\;m^{-3}$). The cases exceed the Japanese central government's safety standard for $PM_{2.5}$ ($35{\mu}g\;m^{-3}$) reached 10.11% during four months campaign. The fraction of $PM_{2.5}$ sulfate to $PM_{2.5}$ varied from 12.05% to 68.11% with average value of 35.49% throughout the entire period of monitoring. This high proportion of sulfate in $PM_{2.5}$ is an obvious characteristic of the ambient $PM_{2.5}$ in Fukuoka during the springtime. However, the average fraction of $PM_{2.5}$ sulfate to $PM_{2.5}$ in three rain events occurred during our intensive campaign fell right down to 15.53%. Unusually high $PM_{2.5}$ sulfate (> $30{\mu}g\;m^{-3}$) marked on three days were probably affected by the air parcels coming from the Chinese continent, the natural sulfur in the remote marine atmosphere, and a large number of ships sailing on the nearby sea. The theoretical number concentration of $(NH_4)_2SO_4$ in $PM_{0.5-0.3}$ was originally calculated and then compared to $PM_{2.5}$ sulfate. A close resemblance between the diurnal variations of the theoretically calculated number concentration of $(NH_4)_2SO_4$ in $PM_{0.5-0.3}$ and $PM_{2.5}$ sulfate concentration indicates that the secondary formed $(NH_4)_2SO_4$ was the primary form of sulfate in $PM_{2.5}$ during our monitoring period.

Photodegradation of Endosulfan alpha, beta, and sulfate in Aqueous Solution by UV Irradiation Only (자외선 조사에 의한 수용액 중에 함유되어 있는 엔도설판 alpha, beta, sulfate의 광분해)

  • Ryoo, Keon-Sang;Kim, Mi-Hyang;Lee, Hwa-Sung;Hwang, Hyun-Gick
    • Journal of Environmental Science International
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    • v.15 no.11
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    • pp.1061-1067
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    • 2006
  • Photodegradation of endosulfan alpha, beta, and sulfate known as the most toxic substance among organochlorine pesticides by UV irradiation was studied at experimental conditions such as different pH aqueous solution and reaction time. The initial concentration of endosulfan alpha, beta, and sulfate in aqueous solution was 500 ppb, respectively. The experiment of photodegradation was conducted in a quartz reactor equipped with a low pressure mercury lamp (100 W, 240 nm). The samples were withdrawn from the photo reactor at intervals of 0, 10 min, 30 min, 1 hr, 2 hr, and 4 hr. Endosulfan sulfate was never hydrolyzed and photodegraded in wide range of pH. At pH 5 and reaction time (240 min), endosulfan alpha was photodegraded up to 67%. Both endosulfan alpha and beta were started to photodegrade at pH 6.5 with the lapse of time, resulting in approximately 99.9% and 87.2% of photodegradation efficiency, respectively. Furthermore, at pH 9, endosulfan alpha and beta was partially hydrolyzed and photodegraded to 99.5% at 120 min of reaction time. During the photolysis, any photo-products of endosulfan alpha, beta, and sulfate were not observed.

Reuse of Sodium Sulfate Recovered from Farm Drainage Salt as Dyeing Builder of Levelling Dyes - Analysis of Color Difference -

  • Jung, Jiyoon
    • The International Journal of Costume Culture
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    • v.6 no.1
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    • pp.11-18
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    • 2003
  • Agricultural drainage salt generated during irrigation of crops in San Joaquin Valley, California, exceeds 600,000 tons annually and cumulates in the field in a rapid rate. As a result, the waste is taking out more farmlands for salt storage and disposal, imposing serious concerns to environment and local agricultural industry. In searching for a potential solution to reduce or eliminate the waste, this research explored feasibility of producing a value-added product, sodium sulfate, from the waste and utilizing the product in textile dyeing. The results indicated that sodium sulfate could be produced from the salt and could be purified by a recrystallization method in a temperature range within the highest and lowest daily temperatures in summer in the valley. The recovered sodium sulfate samples, with purities ranging from 67% to 99.91, were compared with commercially available sodium sulfate in the dyeing of levelling dyes. In nylon fabrics, the salt samples had little color difference in the dyeing with C.I. Acid Yellow 23 and C.I. Acid Blue 158. All salt samples' gray scale was 5 grade. In wool fabrics, the salt samples had little color difference in dyeing with C.I. Acid Yellow 23 and C.I. Arid Blue 158. All salt samples' gray scale was 5 grade. Generally, the dyeing of levelling dyes using recovered salts from farm drainage had little color difference than the dyeing of levelling dyes using commercial sodium sulfate.

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