• Title/Summary/Keyword: substitution

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Crystal Chemistry and Dielectric Properties of $Bi_4Ti_3O_{12}$ by the Substitution of Rare Earth Elements (Y, Nd, Sm, Gd) (희토류원소(Y, Nd, Sm, Gd)의 치환에 의한 $Bi_4Ti_3O_{12}$의 결정화학 및 유전물성)

  • 고태경;방규석
    • Journal of the Korean Ceramic Society
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    • v.32 no.10
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    • pp.1178-1188
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    • 1995
  • Bi4Ti3O12 (BIT) and its rare earth (Y, Nd, Sm, Gd)-substituted derivatives were synthesized using a sol-gel method to investigate their microstructures, cystal structures and electrical properties depending on the subsituted elemetns. Nd- or Sm-substitution into BIT appeared to be favorable, while Y- or Gd-substitution occurred with a pyrochlore phase. This suggests that a smaller trivalent rare earth ion may not be favorable in the structure of BIT. The rare earth derivatives showed that their particle sizes and shapes were considerably different depending on the kinds of substituted elements. Y-substitution resulted in developing a relatively even particle size and a dense microstructure. In structure, they may be similar to the pseudo-orthorhombic BIT but close to a paraelectric tetragonal phase. Their a (or b) axes were shortened, compared to the one of BIT. Such a distortion may result a decrease in the tilting of TiO6. BIT and the derivatives showed that their dielectric constants and losses were 40~120 and less than 0.03, respectively in the frequency range of 1~10 MHz. The dielectric loss of Y-substituted derivative was the lowest one and changed a little to frequency. Curie points were observed in all the derivatives like BIT to suggest that they would be ferroelectric. The temperature stability of the delectric properties of the derivatives below the Curie points were relatively better than the one of BIT.

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An Experimental Study on the Strength of Recycled Concrete with Steam Curing (증기양생 재생콘크리트의 강도특성에 관한 실험연구)

  • Lee, Myung-Kue;Kim, Kwang-Seo;Lee, Keun-Ho;Jung, Sang-Hwa
    • Journal of the Korea Institute of Building Construction
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    • v.5 no.2 s.16
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    • pp.89-95
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    • 2005
  • Various tests are performed with the recycled concrete including compressive strength, flexural strength, splitting tensile strength, bonding strength and chloride ion penetration test. The basic data obtained from the presented test could be accumulated for the purpose of utilization in concrete structure. Most of the strength tests show that strength decrease a little extent with increasing substitution ratio of recycled coarse aggregate except splitting tensile test for the concrete with $100\%$ recycled fine aggregate. But in case of the $50\%$ substitution of recycled coarse aggregate, compressive strength, flexural strength and bonding strength are almost equal to the normal concrete. Chloride ion penetration test shows that the penetration amounts of chloride ion becomes more in proportion to the substitution ratio of recycled aggregate. But most of the results show that the permeability of recycled concrete is proper to use. The results of present study nay imply that the use of recycled aggregate for steam curing concrete is possible but the substitution ratio of recycled aggregate should be determined through further studies.

A Study on the Properties of the Low Temperature Sintered Piezoelectrics for Actuator Application (압전 액츄에이터에 활용할 저온소결 압전 세라믹스에 관한 연구)

  • Ryu, Sung-Lim;Lee, Sang-Ho;Yoo, Ju-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.3
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    • pp.232-235
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    • 2008
  • In this study, in order to develop the composition ceramics for multilayer piezoelectric actuator, PMN-PNN-PZT ceramics were fabricated using $Li_2CO_3$, $Na_2CO_3$, ZnO as sintering aids and their piezoelectric and dielectric properties were investigated according to the Bi substitution, Bi substitution induced grain growth and increase of sinterablity, And also, Bi substitution suppress secondary phase due to the liquid phase sintering effect. Bi substitution enhanced electromechanical coupling factor ($k_p$) and dielectric constant ($\varepsilon_r$), However, mechanical quality factor($Q_m$) was deteriorated, At the sintering temperature of 870 $^{\circ}C$ and Bi substitution of 1 mol%, density, electromechanical coupling factor ($k_p$), mechanical quality factor ($Q_m$), Dielectric constant ($\varepsilon_r$) and piezoelectric constant ($d_{33}$) of specimen showed the optimum values of 7,878 $g/cm^3$, 0,608, 835, 1603 and 397 pC/N, respectively for multilayer piezoelectric actuator application.

Dielectric and Piezoelectric Properties of Low Temperature Sintering PSN-PZI Ceramics with BiFe3 Substitution (BiFe3첨가에 따른 저온소결 PSN-PZT세라믹스의 유전 및 압전 특성)

  • 류주현;정광현;정영호
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.5
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    • pp.492-496
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    • 2004
  • In this study, (0.96 -x)(PSN-PZT)-xBF-0.04 PNW+0.3wt%MnO$_2$+0.6wt%CuO ceramics were fabricated with the variations of the amount of BiFeO$_3$substitution and sintering temperature for the development of modified ceramics which can be sintered in the low temperature($\leq$100$0^{\circ}C$ ), and their microstructural, dielectric and piezoelectric characteristics were investigated. As the amount of BiFeO$_3$ substitution was increased, the density, mechanical quality factor(Q$_{m}$) and electromechanical coupling factor(k$_{p}$) showed the maximum value at each of sintering temperature. At sintering temperature of 98$0^{\circ}C$ and BiFeO$_3$substitution of 2 mol%, the density, dielectric constant and electromechanical coupling factor(k$_{p}$) showed the maximum value of 7.84 g/㎤, 1415 and 0.49, respectively. And at sintering temperature of 95$0^{\circ}C$ and BiFeO$_3$substitution of 3mol%, mechanical quality factor showed the maximum value of 1062. 1062.

Effects of PSN Substitution on the Microstructural and Piezoelectric Characteristics of PNN-PZT Ceramics (PSN 치환이 PNN-PZT 세라믹스의 미세구조 및 압전 특성에 미치는 영향)

  • 윤광희;민석규;류주현;박창엽;정희승
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.5
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    • pp.356-361
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    • 2001
  • The structureal, dielectric and piezoelectric properties of Pb[(Sb$\_$1/2/Nb$\_$1/2/)$\_$x/-(Ni$\_$1/3/Nb$\_$2/3/)$\_$0.15-x/-(Zr$\_$y/Ti$\_$1-y/)$\_$0.85/]O$_3$(x=0∼0.05, y=0.47∼0.52) ceramics were investigated with the substitution of Pb(Sb$\_$1/2/Nb$\_$1/2/)O$_3$(abbreviated PSN) and the Zr/Ti ratio. At Zr/Ti ratio of 50/50, tetragonality was decreased and grain size abruptly decreased with the increase of PSN substitution. Curie temperature was decreased and dielectric constant increased with the substitution of PSN. The coercive field increased and remnant polarization decreased with the substitution of PSN. Electromechanical coupling factor(k$\_$p/) showed the highest value of 0.622 at 1mol% PSN, but mechanical quality factor(Q$\_$m/) showed the minimum value at that composition. Dielectric constant and electromechanical coupling factor with the Zr/Ti ratio showed maximum values at Zr/Ti ratio of 50/50 and mechanical quality factor showed minimum values near the Zr/Ti ratio of 50/50.

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An Experimental Study on the Properties of the High Strength Crushed Sand Concrete Using Blast-Furnace Slag (고로슬래그를 사용한 고강도 부순모래 경화콘크리트의 물성에 관한 실험적 연구)

  • Choi, Young-Wha;Kim, Jong-In
    • Journal of the Korean Society of Industry Convergence
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    • v.8 no.3
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    • pp.169-176
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    • 2005
  • The purpose of this study is to develop the high strength crushed sand concrete in conditions of water binder ratios of 25, 30, 35% and blast-furnace slag substitutions of 0, 15, 30, 45%. Additionally, in case of water binder ratio of 30%, the maximum size of coarse aggregate is two kinds of 13, 19 mm. The conclusions of this study are as follows ; 1. The compressive strength appeared lower in early age as compared with that of plain concrete according to increasing of the blast-furnace slag substitution. But, the compressive strength was respectively 5, 6, 10% larger than that of plain concrete in case of 25, 30, 35% water binder ratios, 28 days, 30% blast-furnace slag substitution and 19mm coarse aggregate. 2. According to increasing of the blast-furnace slag substitution, the modulus of elasticity and the tensile strength of concrete increased. 3. The length change by the shrinkage increased when the larger coarse aggregate was used, and decreased according to higher blast-furnace slag substitution.

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Effect of Co substitution on NiSi and $NiSi_2$: ab initio calculation (NiSi와 $NiSi_2$에 대한 Co 치환의 영향: ab initio 계산)

  • Kim, Yeong-Cheol;Seo, Hwa-Il
    • Journal of the Semiconductor & Display Technology
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    • v.6 no.3
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    • pp.13-17
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    • 2007
  • Effect of Co substitution on crystal structures of two nickel silicides, NiSi and $NiSi_2$, is investigated by using an ab initio calculation. Relaxed NiSi and $NiSi_2$ structures are calculated and the calculated lattice parameters are in good agreement with experimentally determined lattice parameters within about 2%. A Co atom substitutes a Ni and Si site, respectively, to evaluate the preferable site between them. Co prefers Ni site to Si site in both NiSi and $NiSi_2$. The calculated total energy also indicates that the Co substitution to Ni site stabilizes both the NiSi and $NiSi_2$ structures. Co also prefers Ni site in $NiSi_2$ to that in NiSi, indicating that $NiSi_2$ becomes more stable than NiSi with Co substitution. As Co addition to NiSi improves its thermal stability experimentally, this indicates that the energy barrier between the two phases is high enough to prevent the phase transformation from NiSi to $NiSi_2$ up to high temperature.

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Mechanical Properties of Rice Noodles When Adding Cellulose Ethers (셀룰로오스 에테르를 첨가한 쌀면의 기계적 물성)

  • Um, In Chul;Yoo, Young Jin
    • Current Research on Agriculture and Life Sciences
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    • v.31 no.3
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    • pp.177-181
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    • 2013
  • This study examined the effect of the molecular weight, substitution degree, and substitution type of cellulose ether on the mechanical properties of dried rice noodles. When increasing the molecular weight of the hydroxypropyl methylcellulose (HPMC), the bending strength of the dried rice noodles also increased. However, the bending strength of the rice noodles with added HPMCs was still lower than that of the wheat noodles. Meanwhile, the bending elongation of the dried rice noodles was higher than that of the wheat noodles and was increased when decreasing the molecular weight of the HPMC. In conclusion, the bending strength and elongation of dried rice noodles is affected by the substitution degree and type of cellulose ether.

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Effect of Co-Substitution on the Crystallization and Magnetic Properties of a Mechanically Milled Nd15(Fe1-xCox)77B8 (x=0-0.6) Alloy

  • Kwon, H.W.;Yang, C.J.
    • Journal of Magnetics
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    • v.7 no.4
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    • pp.143-146
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    • 2002
  • Mechanical milling technique is considered to be a useful way of processing the fine Nd-Fe-B-type powder with high coercivity. In the present study, phase evolution of the $Nd_{15}(Fe_{1-x}Co_{x})_{77}B_{8}$ (x=0-0.6) alloys during the high energy mechanical milling and annealing was investigated. The effect of Co-substitution on the crystallization of the mechanically milled $Nd_{15}(Fe_{1-x}Co_{x})_{77}B_{8}$ amorphous material was examined. The Nd-Fe-B-type alloys can be amorphized completely by a high-energy mechanical milling. On annealing of the amorphous material, fine $\alpha$-Fe crystallites form first from the amorphous. These fine $\alpha$-Fe crystallites reacts with the remaining amorphous afterwards, leading to crystallization to $Nd_2Fe_{14}$B phase. The Co-substitution for Fe in $Nd_{15}(Fe_{1-x}Co_{x})_{77}B_{8}$ ($\mu$x=0∼0.6) alloys lower significantly the crystallization temperature of the amorphous phase to the $Nd_2Fe_{14}$B phase. The mechanically milled and annealed $Nd_{15}Fe_{77}B_8$ alloy without Co-substitution exhibits consistently better magnetic properties with respect to the alloys with Co-substitution.

Technological Trends in Sensory Substitution (감각치환 기술 동향)

  • Moon, K.D.;Kim, M.S.;Jeong, C.Y.;Park, Y.K.;Shin, S.Y.;Oh, C.M.;Park, J.S.;Shin, H.C.
    • Electronics and Telecommunications Trends
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    • v.34 no.4
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    • pp.65-75
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    • 2019
  • Sensory substitution involves mapping the characteristics of one sensory modality to the stimuli of another sensory modality. In general, when a person is visually impaired or deaf, they do not actually lose their ability to see or hear completely; however, they only lose their ability to transmit sensory signals from the periphery to the brain. It has been experimentally proven that a person who has lost the ability to retrieve data from the retina can still visualize subjective images by using data transferred from other sensory modalities such as tactile or auditory modalities. This is because vision processing pathways are still intact in most cases. Therefore, sensory substitution uses human perception and the plasticity of the human brain to transmit sensory signals through pathways that have not been lost. In this study, we analyze the characteristics and problems of various devices used for sensory substitution and summarize the recent technological trends in these devices.