• Title/Summary/Keyword: substitution

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Research of stone pagoda weathering degree from contaminated distribution analysis of 10-storied pagoda in the temple of Kyoungchunsa (경천사십층석탑의 오염물분포별 현황조사를 통한 석탑 풍화도에 관한 연구)

  • Kim, Jin-Hyoung;Lee, Joo-Wan;Kang, Dai-Ill
    • 보존과학연구
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    • s.25
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    • pp.75-92
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    • 2004
  • The conservation treatments of 10-storied pagoda in the temple of Kyoungchunsa is progressed favorably to come to the finish since 1995. Most of all, the important conservation treatments are stone crack, exfoliation and partial form modification. This pagoda has been made up a complicated structure constructed using 142 stones. Therefore, the stone crack and exfoliation have been occurred as very varied forms. Especially, the stylobate of the pagoda has 19 substitution stones of 48 stones, which is40% of modern stone substitution. It is supposed that there is serious weathering on the stones. The other stones, which are no substitution stones, have some kinds of weathering and so we carried out inside replenishment and partial outside reconstruction of crack stones using high molecular resin and substitution stone. The stone of each storey has also partial difference, but the condition of serious weathering on the whole. We can detect general degree through treatment of high molecule resin or distribution research of contaminated material on 10-storied pagoda in the temple of Kyoungchunsa. Especially, we are able to analyze general weathering degree and know details weathering of each storey or direction for the difference of replenishment quantity and different pattern of stone crack degree. Also, the distribution research will accomplish very important parts of examining environment effects and use as research data of cultural heritage conservation field.

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Development and Characterization of Rice Cookies Containing Germinated Yakkong Powder (발아콩의 첨가가 쌀쿠키의 특성에 미치는 영향)

  • Han, Jung-Ah
    • Korean journal of food and cookery science
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    • v.27 no.6
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    • pp.681-689
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    • 2011
  • Yakkong germinated for 48 h at $23^{\circ}C$(48G), which showed the highest isoflavone content, was prepared with no heat treatment(48G-NH) or with additional heat treatment entailing 20 min boiling(48G-20B) or 15 min roasting(48G-15R). After being ground, each powder was substituted for rice flour by 10, 20, or 30% in rice cookies and compare with the control(100% rice flour cookies). The rice cookies containing 20 or 30% 48G-NH showed the highest crispness in texture and the lowest spreadability. The rice cookies containing 48G-20B and 48G-15R did not show a change in spreadibility, regardless of substitution level. For the rice cookies with 48G-15R, when the substitution level increased to 30%, the crispness decreased and hardness increased. The rice cookies with 48G-20B showed the lowest crispness regardless of substitution level. In terms of color, rice cookies substituted with Yakkong powder showed lower L and higher a* values than the control, however there were no tendencies related to b* value change. In sensory testing, rice cookies substituted with YK-48G had an improved quality, especially in flavor and texture as well as in function. The most acceptable substitution level was 20% of 48G-15R.

Effects of Bundle Type and Substitution with Spent Laying Hen Surimi on Quality Characteristics of Imitation Crabsticks

  • Jin, Sang-Keun;Choi, Jung-Seok;Kim, Gap-Don
    • Food Science of Animal Resources
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    • v.37 no.2
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    • pp.200-209
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    • 2017
  • The purpose of this study was to evaluate the effects of bundle type (BT) and substitution with spent laying hen (SH) surimi on quality characteristics of imitation crabsticks made from Alaska Pollack (AP) during 6 wk of cold storage. Diagonally bundled samples had poorer gel characteristics and more lipid oxidation when compared with straight bundled ones (p<0.05). The color of diagonally bundled imitation crabsticks deteriorated with storage time (p<0.01). However, BT did not affect sensory characteristics (p>0.05). SH substitution had an effect on most quality characteristics of imitation crabsticks; darker and poorer gel characteristics were observed and its effect on sensory evaluation was seen at the initial storage. Thus, BT and SH substitution can be considered to have a slight effect on eating quality of imitation crabsticks, despite their negative effects on color, gel characteristics, and lipid oxidation.

Piezoelectric and Dielectric Characteristics of Low Loss Low Temperature Sintering PMN-PNN-PZT Ceramics with the amount of PNN Substitution (PNN 치환량에 따른 저손실 저온소결 PMN-PNN-PZT 세라믹스의 압전 및 유전특성)

  • Yoo, Ju-Hyun;Kim, Kook-Jin;Jeong, Yeong-Ho;Lee, Su-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.9
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    • pp.766-770
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    • 2007
  • In this study, in order to develop low temperature sintering ceramics for multilayer piezoelectric actuator, $0.07Pb(Mn_{1/3}Nb_{2/3})O_3-xPb(Ni_{1/3}Nb_{2/3})O_3-(0.93-x)Pb(Zr,Ti)O_3$ ceramics system were fabricated using $Li_2CO_3-Bi_2O_3-CuO$ sintering aids and the specimens were sintered at $930^{\circ}C$. Thereafter, their piezoelectric and dielectric characteristics were investigated according to the amount of PNN substitution. At 9 mol% PNN substitution, density, electromechanical coupling factor ($k_p$), dielectric constant, mechanical quality factor ($Q_m$) and piezoelectric constant ($d_{33}$) showed the optimum value of $7.86g/cm^3$, 0.60, 1640, 1323 and 387 pC/N, respectively. It is considered that these values are suitable for piezoelectric divece application such ad multilayer piezoelectric actuator and ultrasonic vibrator with pure Ag internal electrode.

Preparation and Characterization of Alumina Thin Film by Sol-Gel Method (II); Synthesis of Alumina Sol for Coating and Preparation of Coating Films (졸겔법에 의한 알루미나 박막의 제조 및 특성(II);코팅용 알루미나 졸의 합성 및 박막 제조)

  • 이재호;최세영
    • Journal of the Korean Ceramic Society
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    • v.31 no.8
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    • pp.911-919
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    • 1994
  • As the study for preparation of single-layer anti-reflective coating on glass, the conditions of synthesis of sol for coating and of reproducible coating procedure were investigated. In case of water-based sol, coating was impossible because of poor wettability of sol. The Substitution of solvent with ethanol improved the wettability of sol on the glass surface, and optimum amount of ethanol for substitution was 70 vol%. Maximum specific surface area and total pore volume of water-based sol were 268.7$m^2$/g and 0.315 cc/g, but after substitution, those values increased to 404.1 $m^2$/g and 0.376 cc/g, respectively. The upper limit withdrawl speed of coating in order to get clean coated films without aggregations or stains was 7 cm/min. In case of addition of 0.1 mol HNO3 and substitution with 70 vol% ethanol and heat-treatment at 40$0^{\circ}C$ for 1 hour, thin film with thickness of 94 nm was obtained at withdrawl speed of 4 cm/min. The thickness of thin film was independent of drying time.

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Catalytic Combustion of Methane over Perovskite-Type Oxides

  • Hong, Seong-Soo;Sun, Chang-Bong;Lee, Gun-Dae;Ju, Chang-Sik;Lee, Min-Gyu
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.2
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    • pp.95-102
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    • 2000
  • Methane combustion over perovskite-type oxides prepared using the malic acid method was investigated. To enhance the catalytic activity, the perovskite oxides were modified by the substitution of metal into their A or B site. In addition, the reaction conditions, such as the temperature, space velocity, and partial pressure of the methane were varied to understand their effect on the catalytic performance. With the LaCoO3-type catalyst, the partial substitution of Sr or Ba into site A enhanced the catalytic activity in the methane combustion. With the LaBO3(B=Co, Fe, Mn, Cu)-type catalyst, the catalytic activities were exhibited in the order of Co>Fe Mn>Cu. Futhermore, the partial substitution of Co into site B enhanced the catalytic activity, whereas an excess amount of Co decreased the activity. The surface area and catalytic activity of the perovskite catalysts prepared using the malic acid method showed higher values than those prepared using the solid reaction method. The catalytic activity was enhanced with decreased methane concentration and with a decrease in the space velocity.

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Substitutions of coloring ions and their effects on wagnerite pigments for cetamic glazes (도자기 유약용 wagnerite의 합성 및 발색원소의 영향)

  • 정용선;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.160-168
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    • 1998
  • In order to investigate the color variation and the solubility limit in wagnerites by metal ion substitution, wagnerite ($A_2XO_4Z$) was synthesized and then, substituted by coloring metal ions, especially $CO^{2+},Ni^{2+}$ and $Cu^{2+}$ ions. When calcium was replaced with Mg, Co, Ni and Cu divalent ions, solid solutions were formed with a limited solubility. Single phase wagnerites were synthesized by the substitution of Ca with Mg and Co, and their colors were white and purple, respectively. Substitutions with $Li^+$ were succeeded in the specific composition and the substitution of vanadium for $X^{5+}$ were attempted, resulting in the wagnerites of dark purple, dark gold and light yellow colors. The substitution of chlorine was, also, attmepted for the fluorine site.

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The Analysis of Manufactured Cellulose Acetate Using Old Newsprint by Acetosolv Pulping (초산펄프화법에 의해 신문고지로부터 제조된 셀룰로오스 아세데이트의 분석)

  • 임부국;이종윤;양재경;장준복
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.1
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    • pp.41-47
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    • 2003
  • Recently, interest in utilization plan of recycling paper have been enhanced. Therefore, this research aimed to develop the manufacture process of cellulose acetate using old newsprint by acetosolv pulping process. And the manufactured cellulose acetate was also analyzed, especially based on chemical properties. The summarized results in this research were as follows; Reaction time, kind and amount of catalyst, and ratio of liquor to material were varied during acetosolv pulping process of old newsprint. Ratio of liquor to material did not give the significant difference in reaction product. Delignification rate was increased with increasing reaction time during acetosolv pulping, but yield and degree of substitution decreased with increasing reaction time. Sulfuric acid are better catalyst than hydrochloric acid in acetosolv pulping process for old newsprint, and optimal addition amount of catalyst was 1% based on reaction material. Delignification, yield, and degree of substitution were influenced by the catalyst and reaction time. Under pulping condition of $120^{\circ}C$ in 1/12 liquor to material ratio and 60min, degree of substitution was about 0.7. The acetylation reaction was not completely caused by these reaction condition. The examination of the FT-IR spectra revealed that absorption band(1200$\textrm{cm}^{-2}$, 1,750$\textrm{cm}^{-1}$) caused by carbonyl group were confirmed.

Forecasting the Demand for the Substitution of Next Generations of Digital TV Using Choice-Based Diffusion Models (선택기반확산모형을 이용한 디지털 TV 수요예측)

  • Jeong U-Su;Nam Seung-Yong;Kim Hyeong-Jun
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 2006.05a
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    • pp.1116-1123
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    • 2006
  • The methodological framework proposed in this paper addresses the strength of the applied Bass model by Mahajan and Muller(1996) that it reflects the substitution of next generations among products. Also this paper is to estimate and analyze the forecast of demand for products that do not exist in the marketplace. We forecast the sales of digital TV using estimated market share and data obtained by the face to face Interview. In this research, we use two methods to analyze the demand for Digital TV that are the forecasting the Demand for the Substitution and binary logit analysis. The logit analysis is to estimate the decisive factor of purchasing digital TV. The decisive factors are composed of purchasing plan, region, gender, TV price, contents, coverage, income, age, and TV program. We apply the model to South Korea's market for digital TV. The results show that (1) Income, region and TV price play a prominent part which is the decisive factor of purchasing digital TV. (2) We forecaste the demand of digital TV that will be demanded about 18 millions TVs in 2015

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Highly Stable Photoluminescent Qunatum Dot Multilayers by Layer-by-Layer Assembly via Nucleophilic Substitution Reaction in Organic Media

  • Yun, Mi-Seon;Kim, Yeong-Hun;Jeong, Sang-Hyeok;Baek, Hyeon-Hui;Jo, Jin-Han
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.244.2-244.2
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    • 2011
  • We introduce a novel and robust method for the preparation of nanocomposite multilayers, which allows the excellent photoluminescent (PL) properties as well as the accurate control over the composition and dimensions of multilayers. By exchanging the oleic acid stabilizers of CdSe@ZnS quantum dots (QDs) synthesized in organic solvent with 2-bromo-2-methylpropionic acid (BMPA) in the same solvent, these nanoparticles were be alternately deposited by nucleophilic substitution reaction with highly branched poly(amidoamine) dendrimer (PAMA) through layer-by-layer (LbL) assembly process. Our approach does not need to be transformed into the water-dispersible nanoparticles with electrostatic or hydrogen-bonding groups, which can deteriorate their inherent properties, for the built-up of multilayers. The nanocomposite multilayers including QDs exhibited the strong PL properties achieving densely packed surface coverage as well as long-term PL stability under atmospheric conditions in comparison with those of conventional LbL multilayers based on electrostatic interaction. Furthermore, we demonstrate that the flexible multilayer films with optical properties can be easily prepared using nucleophilic substitution reaction between bromo and amino groups in organic media. This robust and tailored method opens a new route for the design of functional film devices based on nanocomposite multilayers.

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