• Bulletin of the Korean Chemical Society
• /
• v.2 no.1
• /
• pp.17-24
• /
• 1981

Thermodynamic properties such as sublimation pressures, enthalpies and entropies of sublimation, enthalpies and entropies of solid krypton and xenon are calculated from $0{\circ}K$ to the triple point, using the vacancies-in-solid model. The Mie-Lennard-Jones 12,6 potential in uniform potential field is used. The results are compared with the calorimetric and sublimation pressure values, and are in a good agreement with the available calorimetric and sublimation pressure values.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.17 no.8
• /
• pp.2088-2098
• /
• 1993

A mathematical model of freeze drying by sublimation was suggested and used to estimate the drying time. Under the various conditions, the drying time of pure water and carrot was numerically calculated for the suggested model. Optimal policies of freeze drying were investigated experimentally in a laboratory freeze dryer. It was found that the shortest drying times could be obtained when the chamber pressure and condenser temperature were kept at their lowest values and the best method of heat transfer for sublimation was the conduction involving radiation. The sublimation drying period was finished when the bottom temperature of material could be reached at near $0^{\circ}C$ from frozen temperature.

• Analytical Science and Technology
• /
• v.28 no.3
• /
• pp.187-195
• /
• 2015

The heat of sublimation (HOS) is an essential parameter used to resolve environmental problems in the transfer of organic contaminants to the atmosphere and to assess the risk of toxic chemicals. The experimental measurement of the heat of sublimation is time-consuming, expensive, and complicated. In this study, quantitative structural property relationships (QSPR) were used to develop a simple and predictive model for measuring the heat of sublimation of organic compounds. The population-based forward selection method was applied to select an informative subset of descriptors of learning algorithms, such as by using multiple linear regression (MLR) and the support vector machine (SVM) method. Each individual model and consensus model was evaluated by internal validation using the bootstrap method and y-randomization. The predictions of the performance of the external test set were improved by considering their applicability to the domain. Based on the results of the MLR model, we showed that the heat of sublimation was related to dispersion, H-bond, electrostatic forces, and the dipole-dipole interaction between inter-molecules.

• Journal of Biosystems Engineering
• /
• v.18 no.2
• /
• pp.122-132
• /
• 1993

Effects of physical properties of garlic paste and freeze dry control parameters on the sublimation drying time were investigated to verify optimal operating method in freeze drying. A mathematical model of freeze drying by sublimation was suggested and used to estimate the drying time of garlic paste. Under various conditions, the drying time of garlic paste was calculated using the computer program for the suggested model. Among the physical properties of garlic paste, melting temperature was evaluated the most important factor in affecting the drying time. In supplying methods of the required heat energy for sublimation, it would be the best way to control the upper plate temperature and the lower plate temperature independently.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.17 no.10
• /
• pp.2624-2633
• /
• 1993

Mass transfer experiment by naphthalene sublimation method has great advantages in measurement of local transfer coefficients in the region of a three dimensional flow or for a model of complex geometry, which is considered to be very difficult with conventional heat transfer measurements. Mass transfer data obtained by naphthalene sublimation technique are converted to the heat transfer data through heat/mass transfer analogy. This analogy is valid for a simple or laminar flow, but new insight is needed when applying to a turbulent flow or complex flow such as separation, reattachment and recirculation, The purpose of this research is to investigate how geometries and flow conditions incorporate heat/mass transfer analogy. Mass transfer experiments are performed using naphthalene sublimation technique for a flat plate, a circular cylinder, and rectangular cylinders. And mass transfer data are compared with earlier heat transfer measurements for the same geometries. Usefulness of analogy relation between heat and mass transfer is examined with these results.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.20 no.3
• /
• pp.1096-1105
• /
• 1996

A theoretical model of the frost formation has been presented to investigate the characteristics of the growth of frost layer by considering molecular diffusion of water vapor and heat generation caused by sublimation of water vapor in the frost layer. The present model was compared with existing experimental data as well as a previous model. The difference between the present model and existing experimental data was found to be about 6 percent. An analysis for the behavior of frost formation using present model shows a good agreement with the trend for a number of experimentally observed features. The present analysis can also provide the physical understanding on the phenomena of the frost formation.

• Applied Science and Convergence Technology
• /
• v.23 no.4
• /
• pp.179-186
• /
• 2014

Fluid model based numerical simulation was carried out for an inductively coupled plasma assisted sputter deposition system. Power absorption, electron temperature and density distribution was modeled with drift diffusion approximation. Effect of an electrically conducting substrate was analyzed and showed confined plasma below the substrate. Part of the plasma was leaked around the substrate edge. Comparison between the quasi-neutrality based compact model and Poisson equation resolved model showed more broadened profile in inductively coupled plasma power absorption than quasi-neutrality case, but very similar Ar ion number density profile. Electric potential was calculated to be in the range of 50 V between a Cr rod source and a conductive substrate. A new model including Cr sputtering by Ar+was developed and used in simulating Cr deposition process. Cr was modeled to be ionized by direct electron impact and showed narrower distribution than Ar ions.

• Korean Journal of Food Science and Technology
• /
• v.25 no.4
• /
• pp.313-320
• /
• 1993

A sublimation model of the freeze drying process, which accounted for the removal of free water, was presented and used to study the operation conditions of freeze driers for carrot juice. It was found that the shortest drying time was obtained when the condenser temperature and chamber pressure were kept at heir lowest values and the plate temperature was controlled independently so that the scorch and melting constraints were both held throughout the drying period. The effect of sample thickness on the drying time was significant. Optimal policies were investigated experimentally in laboratory freeze dryer.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.31 no.7 s.262
• /
• pp.628-634
• /
• 2007

The present study investigated the heat/mass transfer characteristics in an equilateral triangular channel simulating the leading edge cooling passage in gas turbine blade. Using naphthalene sublimation method and pressure measurement experiments, local mass (heat) transfer and pressure coefficients were obtained. The experiments were conducted with three rotating numbers between 0.0 and 0.1; two channel orientations of $0^{\circ}$ (model A) and $30^{\circ}$ (model B); the fixed Reynolds number of 10,000. The results showed that the channel rotation caused the heat transfer discrepancy between suction and pressure sides. Due to the secondary flow induced by Coriolis force, the high heat transfer appeared on the pressure side. When the channel orientation was $30^{\circ}$ (model B), the secondary flow caused the more uniform heat transfer distribution among leading edge and inner wall on pressure side than that of the model A.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.14 no.3
• /
• pp.685-693
• /
• 1990

The heat transfer coefficients were calculated numerically to see the effects of radiation around the porous medium put on the flat plate at a distance from the leading edge of flat plate for the two-dimensional laminar flows. To verify the analytical model developed and invoke the heat/mass transfer analogy, an experiment was carried out using naphthalene sublimation technique. From the effects of the wake, Sherwood number is maximum around the region where the porous medium is attached. The theoretical results correspond well with the experimental results at small Darcy number. Permeability of ceramic blocks used for experiment was also measured and the Forchheimer equation is applicable in our measurement range.